Examen Termo Sustancias Puras
Examen Termo Sustancias Puras
Examen Termo Sustancias Puras
1IV28
Celular: 5581994150
Correo: ohernandezr1304@gmail.com
Examen Tipo A
𝑽 = 𝟎. 𝟗𝟏𝟑𝟐 𝒎𝟑
𝑅𝑇 𝑅𝑇 𝑎 𝑎𝑏
b) 𝑉̅ 3− 𝑃 𝑉̅ 2− (𝑏 2 + 𝑃 𝑏 − 𝑃𝑇 0.5 ) 𝑉̅ − 𝑃𝑇 0.5 = 0
3
𝑅𝑇 (0.08314 𝑏𝑎𝑟 𝑚 ⁄𝑚𝑜𝑙 𝐾 )(380𝐾)
= = 𝟎. 𝟕𝟔𝟖𝟕
𝑃 41.1 𝑏𝑎𝑟
𝑅𝑇 𝑎 161.8492
(𝑏 2 + 𝑏− 0.5
) = (0.05642 + 0.7687(0.0564) − ) = −𝟎. 𝟏𝟓𝟓𝟓
𝑃 𝑃𝑇 41.1(380)0.5
𝑎𝑏 161.8492(0.0564)
0.5
= = 𝟎. 𝟎𝟏𝟏𝟑𝟗
𝑃𝑇 41.1(380)0.5
𝑉̅ 3−0.7687𝑉̅ 2−(−0.1555)𝑉̅ − 0.01139 = 0
Haciendo la ecuación cuadrática en la calculadora y tomando el resultado
con mayor valor, nos da un resultado de:
𝑚3 ̅
𝑚𝑉 50(0.50578)
𝑉̅ = 0.50578 𝑚𝑜𝑙 Convirtiendo 𝑉 = =
𝑀 42.081
𝟑
𝑽 = 𝟎. 𝟔𝟎𝟏𝟎 𝒎
𝑎
̅−𝑏 )
(𝑃+ ̅ 2 )(𝑉
𝑅𝑇 𝑎 𝑉
c) 𝑃 = − ̅2 Despejando: 𝑇 =
̅
𝑉 −𝑏 𝑉 𝑅
𝑉𝑀 0.8757 𝒎𝟑 (42.081𝐾𝑔/𝑚𝑜𝑙) 𝟑
Convirtiendo V en 𝑉̅ 𝑉̅ = = 𝒎
=0.7370𝑲𝒎𝒐𝒍
𝑚 50𝐾𝑔
6
𝑏𝑎𝑟 𝑚
8.3540 3 3
(41.1𝑏𝑎𝑟 + 𝑘𝑚𝑜𝑙 2 ) (0.7370 𝑚 − 0.0814 𝑏𝑎𝑟 𝑚 )
2 𝐾𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
𝑚3
0.7370
𝑇= 𝐾𝑚𝑜𝑙
3
0.08314 𝑏𝑎𝑟 𝑚 ⁄𝑚𝑜𝑙 𝐾
𝑻 = 𝟒𝟒𝟓. 𝟑𝟕𝟔 𝑲
𝑃 41.1𝑏𝑎𝑟 𝑇 445.376𝐾
d) 𝑃𝑟 = = = 0.8810 𝑇𝑟 = = = 1.2183
𝑃𝑐 46.65𝑏𝑎𝑟 𝑇𝑐 365.57𝐾
𝑻 = 𝟒𝟒𝟏. 𝟔 𝑲
Problema 2
Datos: P1=27.6 bar, T1=194.38 K, P2=9.2 bar, T2=162 K
𝑅𝑇
a) 𝑉̅ 𝑅 = (𝑍 − 1) Para sacar Z, tendremos que sacar Pr y Tr
𝑃
𝑃 27.6𝑏𝑎𝑟 𝑇 194.38𝐾
𝑃𝑟 = = = 0.6001 𝑇𝑟 = = = 1.0200
𝑃𝑐 45.99𝑏𝑎𝑟 𝑇𝑐 190.56𝐾
3
0.08314𝑏𝑎𝑟 𝑚 ⁄𝑚𝑜𝑙 𝐾 (194.38𝐾)
𝑍 = 0.74 Sustituyendo 𝑉̅ 𝑅 = (0.74 − 1)
27.6 𝑏𝑎𝑟
𝒎𝟑
̅ 𝑹 = −𝟎. 𝟏𝟓𝟐𝟐
𝑽
𝒎𝒐𝒍
(𝐻 𝑅 )° (𝐻 𝑅 )′
𝐻 𝑅 = 𝑅𝑇𝑐 [ +𝜔 ] Usamos las tablas para encontrar los
𝑅𝑡𝑐 𝑅𝑡𝑐
valores correspondientes.
(𝐻 𝑅 )° (𝐻 𝑅 )′
= −0.74 = −0.68 sustituyendo los valores:
𝑅𝑡𝑐 𝑅𝑡𝑐
𝐻𝑅 = 8.314 𝐾𝐽 ⁄𝐾𝑚𝑜𝑙 𝐾 (190.56𝐾)[−0.74 + 0.012(−0.68)]
𝑅 ° 𝑑𝐵 ° ′ 𝑑𝐵 ′
b) 𝐻 = 𝑅𝑇𝑐𝑃𝑟 [(𝐵 − 𝑇𝑟 ) + 𝜔 (𝐵 − 𝑇𝑟 )]
𝑑𝑇𝑟 𝑑𝑇𝑟
𝑃 9.2𝑏𝑎𝑟 𝑇 162𝐾
𝑃𝑟 = = = 0.2000 𝑇𝑟 = = = 0.8501
𝑃𝑐 45.99𝑏𝑎𝑟 𝑇𝑐 190.56𝐾
𝑑𝐵° 0.6752 0.6752
= = = 1.030
𝑑𝑇𝑟 𝑇𝑟 2.6 0.85012.6
𝑑𝐵′ 0.7224 0.7224
= = = 1.681
𝑑𝑇𝑟 𝑇𝑟 5.2 0.85015.2
0.422 0.422
𝐵° = 0.083 − = 0.083 − = −0.4642
𝑇𝑟1.6 0.85011.6
0.4172 0.4172
𝐵′ = 0.139 − = 0.139 − = −0.2012
𝑇𝑟 2.6 0.85012.6
Sustituyendo los valores en la fórmula:
𝐻 𝑅 = 𝑅𝑇𝑐𝑃𝑟[(−0.4642 − 0.8501(1.030)) + 0.012(−0.2012 − 0.8501(1.681))]
𝐾𝐽
𝐻 𝑅 = 8.314 ⁄𝐾𝑚𝑜𝑙 𝐾 (190.56𝐾)(0.2000)[−1.3593]
𝑲𝑱 ⁄
𝑯𝑹 = −𝟒𝟑𝟎. 𝟕𝟑𝟐 𝑲𝒎𝒐𝒍
c) 𝑊̇ = 𝑚̇∆ℎ