Guía Práctica de Laboratorio Calidad Del Agua PDF
Guía Práctica de Laboratorio Calidad Del Agua PDF
Guía Práctica de Laboratorio Calidad Del Agua PDF
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𝐴−𝐵
𝑆𝑇 = × 1000
𝑉
𝑆𝐷𝑇 = 𝑆𝑇 − 𝑆𝑆𝑇
𝐻2 𝑂 ↔ 𝐻 + + 𝑂𝐻 −
[𝐻 + ][𝑂𝐻 − ]
=𝐾
[𝐻2 𝑂]
[𝐻 + ][𝑂𝐻 − ] = 𝐾𝑤
𝑃𝐻+
1
𝑝𝐻 = − log[𝐻 + ] 𝑜 𝑝𝐻 = log
[𝐻 + ]
° °
+
𝐻2 𝐶𝑂3 ↔ 𝐻(𝑎𝑐) + 𝐻𝐶𝑂3− (𝑎𝑐)
+
𝐻𝐶𝑂3− (𝑎𝑐) ↔ 𝐻(𝑎𝑐) + 𝐶𝑂3−2 (𝑎𝑐)
𝑂𝐻 −
𝐶𝑂3= 𝐻𝐶𝑂3−
>
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(𝐴 × 𝐵) × 50 × 1000
𝐴𝑐𝑇 = ×𝐷
𝑉
𝑚𝑔 𝐶𝑎𝐶𝑂3
𝐴𝑐𝑇 : 𝐴𝑐𝑖𝑑𝑒𝑧 𝑡𝑜𝑡𝑎𝑙 [ ].
𝐿
𝐴: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒 𝑁𝑎𝑂𝐻 𝑐𝑜𝑛𝑠𝑢𝑚𝑖𝑑𝑜 ℎ𝑎𝑠𝑡𝑎 𝑝𝐻 8.3 [𝑚𝐿].
𝐵: 𝑁𝑜𝑟𝑚𝑎𝑙𝑖𝑑𝑎𝑑 𝑑𝑒 𝑙𝑎 𝑠𝑜𝑙𝑢𝑐𝑖ó𝑛 𝑑𝑒 𝑁𝑎𝑂𝐻 [𝑁].
𝑉: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒 𝑚𝑢𝑒𝑠𝑡𝑟𝑎 𝑢𝑠𝑎𝑑𝑜 [𝑚𝐿].
𝐷: 𝐹𝑎𝑐𝑡𝑜𝑟 𝑑𝑒 𝑑𝑖𝑙𝑢𝑐𝑖ó𝑛.
(𝐸 × 𝐵) × 50 × 1000
𝐴𝑐𝑀 = ×𝐷
𝑉
𝑚𝑔 𝐶𝑎𝐶𝑂3
𝐴𝑐𝑀 : 𝐴𝑐𝑖𝑑𝑒𝑧 𝑚𝑖𝑛𝑒𝑟𝑎𝑙 [ ].
𝐿
𝐸: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒 𝑁𝑎𝑂𝐻 𝑐𝑜𝑛𝑠𝑢𝑚𝑖𝑑𝑜 ℎ𝑎𝑠𝑡𝑎 𝑝𝐻 4.5 [𝑚𝐿].
𝐵: 𝑁𝑜𝑟𝑚𝑎𝑙𝑖𝑑𝑎𝑑 𝑑𝑒 𝑙𝑎 𝑠𝑜𝑙𝑢𝑐𝑖ó𝑛 𝑑𝑒 𝑁𝑎𝑂𝐻 [𝑁].
𝑉: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒 𝑚𝑢𝑒𝑠𝑡𝑟𝑎 𝑢𝑠𝑎𝑑𝑜 [𝑚𝐿].
𝐷: 𝐹𝑎𝑐𝑡𝑜𝑟 𝑑𝑒 𝑑𝑖𝑙𝑢𝑐𝑖ó𝑛.
𝑚𝑔 𝐶𝑎𝐶𝑂3
𝐴𝑐𝐶 : 𝐴𝑐𝑖𝑑𝑒𝑧 𝑐𝑎𝑟𝑏𝑜𝑛á𝑐𝑒𝑎 [ ].
𝐿
𝑚𝑔 𝐶𝑎𝐶𝑂3
𝐴𝑐𝑇 : 𝐴𝑐𝑖𝑑𝑒𝑧 𝑡𝑜𝑡𝑎𝑙 [ ].
𝐿
(𝐴 × 𝐵) × 50 × 1000
𝑀= ×𝐷
𝑉
𝑚𝑔 𝐶𝑎𝐶𝑂3
𝑀: 𝐴𝑙𝑐𝑎𝑙𝑖𝑛𝑖𝑑𝑎𝑑 𝑡𝑜𝑡𝑎𝑙 [ ].
𝐿
𝐴: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒 á𝑐𝑖𝑑𝑜 𝑐𝑜𝑛𝑠𝑢𝑚𝑖𝑑𝑜 ℎ𝑎𝑠𝑡𝑎 𝑝𝐻 4.5 [𝑚𝐿].
𝐵: 𝑁𝑜𝑟𝑚𝑎𝑙𝑖𝑑𝑎𝑑 𝑑𝑒 𝑙𝑎 𝑠𝑜𝑙𝑢𝑐𝑖ó𝑛 𝑑𝑒 á𝑐𝑖𝑑𝑜 [𝑁].
𝑉: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒 𝑚𝑢𝑒𝑠𝑡𝑟𝑎 𝑢𝑠𝑎𝑑𝑜 [𝑚𝐿].
𝐷: 𝐹𝑎𝑐𝑡𝑜𝑟 𝑑𝑒 𝑑𝑖𝑙𝑢𝑐𝑖ó𝑛.
(𝐶 × 𝐵) × 50 × 1000
𝐹= ×𝐷
𝑉
𝑚𝑔 𝐶𝑎𝐶𝑂3
𝐹: 𝐴𝑙𝑐𝑎𝑙𝑖𝑛𝑖𝑑𝑎𝑑 𝑝𝑜𝑟 ℎ𝑖𝑑𝑟ó𝑥𝑖𝑑𝑜𝑠 𝑦 𝑐𝑎𝑟𝑏𝑜𝑛𝑎𝑡𝑜𝑠 [ ].
𝐿
𝐶: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒 á𝑐𝑖𝑑𝑜 𝑐𝑜𝑛𝑠𝑢𝑚𝑖𝑑𝑜 ℎ𝑎𝑠𝑡𝑎 𝑝𝐻 8.3 [𝑚𝐿].
𝑉: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒 𝑚𝑢𝑒𝑠𝑡𝑟𝑎 𝑢𝑠𝑎𝑑𝑜 [𝑚𝐿].
𝐷: 𝐹𝑎𝑐𝑡𝑜𝑟 𝑑𝑒 𝑑𝑖𝑙𝑢𝑐𝑖ó𝑛.
𝑚𝑔 𝐶𝑎𝐶𝑂3
𝑀: 𝐴𝑙𝑐𝑎𝑙𝑖𝑛𝑖𝑑𝑎𝑑 𝑡𝑜𝑡𝑎𝑙 [ ].
𝐿
𝑚𝑔 𝐶𝑎𝐶𝑂3
𝐹: 𝐴𝑙𝑐𝑎𝑙𝑖𝑛𝑖𝑑𝑎𝑑 𝑝𝑜𝑟 ℎ𝑖𝑑𝑟ó𝑥𝑖𝑑𝑜𝑠 𝑦 𝑐𝑎𝑟𝑏𝑜𝑛𝑎𝑡𝑜𝑠 [ 𝐿
].
>
𝐶𝑎+2 𝐻𝐶𝑂3−
𝑀𝑔+2 𝑆𝑂4=
𝑆𝑟 +2 𝐶𝑙 −
𝐹𝑒 +2 𝑁𝑂3−
𝑀𝑛+2 𝑆𝑖𝑂3=
• <
• >
(𝐶8 𝐻4 𝑂6 𝑁5 )−
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𝐴 × 1000
𝐶=
𝑉
𝐴 × 𝐵 × 1000
𝐷𝑇 =
𝑉
𝑚𝑔 𝐶𝑎𝐶𝑂3
𝐷𝑇 : 𝐷𝑢𝑟𝑒𝑧𝑎 𝑡𝑜𝑡𝑎𝑙 [ ].
𝐿
𝐴: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒 𝐸𝐷𝑇𝐴 𝑐𝑜𝑛𝑠𝑢𝑚𝑖𝑑𝑜 𝑒𝑛 𝑙𝑎 𝑚𝑢𝑒𝑠𝑡𝑟𝑎 (𝑚𝐿).
𝐵: 𝐶𝑎𝑛𝑡𝑖𝑑𝑎𝑑 𝑑𝑒 𝐶𝑎𝐶𝑂3 𝑒𝑞𝑢𝑖𝑣𝑎𝑙𝑒𝑛𝑡𝑒 𝑎 1 𝑚𝐿 𝑑𝑒 𝐸𝐷𝑇𝐴 𝑐𝑜𝑛 𝑛𝑒𝑔𝑟𝑜 𝑑𝑒 𝑒𝑟𝑖𝑜𝑐𝑟𝑜𝑚𝑜 − 𝑇 (𝑚𝑔).
𝑉: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑢𝑠𝑎𝑑𝑜 𝑑𝑒 𝑙𝑎 𝑚𝑢𝑒𝑠𝑡𝑟𝑎 (𝑚𝐿
𝐴 × 𝐶 × 1000
𝐷𝐶 =
𝑉
𝑚𝑔 𝐶𝑎𝐶𝑂3
𝐷𝐶 : 𝐷𝑢𝑟𝑒𝑧𝑎 𝑐á𝑙𝑐𝑖𝑐𝑎 [ ]
𝐿
𝐴: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒 𝐸𝐷𝑇𝐴 𝑐𝑜𝑛𝑠𝑢𝑚𝑖𝑑𝑜 (𝑚𝐿).
𝐶: 𝐶𝑎𝑛𝑡𝑖𝑑𝑎𝑑 𝑑𝑒 𝐶𝑎𝐶𝑂3 𝑒𝑞𝑢𝑖𝑣𝑎𝑙𝑒𝑛𝑡𝑒 𝑎 1 𝑚𝐿 𝑑𝑒 𝐸𝐷𝑇𝐴 𝑐𝑜𝑛 𝑚𝑢𝑟𝑒𝑥𝑖𝑑𝑒 (𝑚𝑔).
𝑉: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑢𝑠𝑎𝑑𝑜 𝑑𝑒 𝑙𝑎 𝑚𝑢𝑒𝑠𝑡𝑟𝑎 (𝑚𝐿).
𝐷𝑁𝐶 = 𝐷𝑇 − 𝐷𝐶
𝑚𝑔 𝐶𝑎𝐶𝑂3
𝐷𝑁𝐶 : 𝐷𝑢𝑟𝑒𝑧𝑎 𝑛𝑜 𝑐á𝑙𝑐𝑖𝑐𝑎 ( ).
𝐿
𝑚𝑔 𝐶𝑎𝐶𝑂3
𝐷𝑇 : 𝐷𝑢𝑟𝑒𝑧𝑎 𝑡𝑜𝑡𝑎𝑙 ( ).
𝐿
𝑚𝑔 𝐶𝑎𝐶𝑂3
𝐷𝐶 : 𝐷𝑢𝑟𝑒𝑧𝑎 𝑐á𝑙𝑐𝑖𝑐𝑎 ( ).
𝐿
𝑭−
𝐶𝑙 −
𝑵𝑶−
𝟐
𝑩𝒓−
𝑵𝑶−
𝟑
𝑷𝑶−𝟑
𝟒
𝑃𝑂4−3
-
- µ
-
-
- 𝑁𝑎2 𝐶𝑂3
- 𝑁𝑎𝐻𝐶𝑂3
- 𝑁𝑎2 𝐶𝑂3 𝑁𝑎𝐻𝐶𝑂3
- 𝐻2 𝑆𝑂4
-
𝑏𝑎𝑐𝑡𝑒𝑟𝑖𝑎𝑠
𝑛𝑖𝑡𝑟𝑜𝑠𝑜𝑚𝑜𝑛𝑎𝑠
2𝑁𝐻3 + 3𝑂2 → 2𝑁𝑂2− + 2𝐻 + + 2𝐻2 𝑂
•
𝑏𝑎𝑐𝑡𝑒𝑟𝑖𝑎𝑠
𝑛𝑖𝑡𝑟𝑜𝑏𝑎𝑐𝑡𝑒𝑟𝑖𝑎𝑠
2𝑁𝑂2− + 𝑂2 → 2𝑁𝑂3−
-
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(𝐴 − 𝐵) × 280
𝑁𝐴 =
𝑉
𝑂2(𝑔) ↔ 𝑂2(𝑎𝑐)
[𝑂2(𝑎𝑐) ]
𝐾𝐻 =
𝑃𝑂2
−∆𝐻°
log 𝐾𝐻 = + 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡𝑒
2,3 𝑅𝑇
Δ °
°
°
α β
α α β
1
𝑀𝑛+2 + 2𝑂𝐻 − + 𝑂2 → 𝑀𝑛𝑂2 ↓ +𝐻2 𝑂 (𝑝𝑟𝑒𝑐𝑖𝑝𝑖𝑡𝑎𝑑𝑜 𝑚𝑎𝑟𝑟ó𝑛)
2
-
-
𝑑𝐿
= −𝐾𝐿𝑡
𝑑𝑡
𝑚𝑔
𝐿𝑡 : 𝐷𝐵𝑂 𝑟𝑒𝑚𝑎𝑛𝑒𝑛𝑡𝑒 𝑒𝑛 𝑒𝑙 𝑎𝑔𝑢𝑎 𝑝𝑎𝑟𝑎 𝑒𝑙 𝑡𝑖𝑒𝑚𝑝𝑜 𝑡 ( ).
𝐿
𝐿𝑡
= 𝑒 −𝐾𝑡 = 10−𝑘𝑡
𝐿
𝐿𝑡 = 𝐿𝑒 −𝐾𝑡 = 𝐿 × 10−𝑘𝑡
𝑦 = 𝐿 − 𝐿𝑡 = 𝐿 − 𝐿𝑒 −𝐾𝑡 = 𝐿 − 𝐿 × 10−𝑘𝑡
𝑦 = 𝐿(1 − 𝑒 −𝐾𝑡 ) = 𝐿(1 − 10−𝑘𝑡 )
𝐿 = 𝑦 + 𝐿𝑡
𝐿𝑡 𝐿𝑡
𝐿
1− 𝐿
𝐾𝑇 = 𝐾20 𝜃 𝑇−20
-
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- °
•
•
•
•
-
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-
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-
- °
- ~
- ~
(𝐷 − 𝐸) × 𝑀 × 8000
𝐷𝑄𝑂 =
𝑉
𝑚𝑔 − 𝑂2
𝐷𝑄𝑂: 𝐷𝑒𝑚𝑎𝑛𝑑𝑎 𝑞𝑢í𝑚𝑖𝑐𝑎 𝑑𝑒 𝑜𝑥í𝑔𝑒𝑛𝑜 ( ).
𝐿
𝐷: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒 𝐹𝐴𝑆 𝑐𝑜𝑛𝑠𝑢𝑚𝑖𝑑𝑜 𝑒𝑛 𝑒𝑙 𝑏𝑙𝑎𝑛𝑐𝑜 (𝑚𝐿).
𝐸: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒 𝐹𝐴𝑆 𝑐𝑜𝑛𝑠𝑢𝑚𝑖𝑑𝑜 𝑒𝑛 𝑙𝑎 𝑚𝑢𝑒𝑠𝑡𝑟𝑎 (𝑚𝐿).
𝑀: 𝐶𝑜𝑛𝑐𝑒𝑛𝑡𝑟𝑎𝑐𝑖ó𝑛 𝑑𝑒 𝐹𝐴𝑆 (𝑀).
𝑉: 𝑉𝑜𝑙𝑢𝑚𝑒𝑛 𝑑𝑒 𝑚𝑢𝑒𝑠𝑡𝑟𝑎 𝑢𝑠𝑎𝑑𝑜 (𝑚𝐿).
± ±
46
44
42
[ ], mg/Kg
40
38
36
34
32
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
N° de medición
A−B
(A + B ) 2
12
Diferencia entre duplicados, DRP, %
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
N° de medición
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