Carbon dioxide

"CO2" redirects here. For other uses, see CO2 (disambiguation).

Carbon dioxide

Names
Other names Carbonic acid gas Carbonic anhydride Carbonic oxide Carbon oxide Carbon(IV) oxide Dry ice (solid phase)
Identifiers
CAS Number	124-38-9 Y
3DMet	B01131
Beilstein Reference	1900390
ChEBI	CHEBI:16526 Y
ChEMBL	ChEMBL1231871 N
ChemSpider	274 Y
EC Number	204-696-9
Gmelin Reference	989
Jmol 3D model	Interactive image Interactive image
KEGG	D00004 Y
MeSH	Carbon+dioxide
RTECS number	FF6400000
UNII	142M471B3J Y
UN number	1013 (gas), 1845 (solid)
InChI InChI=1S/CO2/c2-1-3 Y Key: CURLTUGMZLYLDI-UHFFFAOYSA-N Y InChI=1/CO2/c2-1-3 Key: CURLTUGMZLYLDI-UHFFFAOYAO
SMILES O=C=O C(=O)=O
Properties
Chemical formula	CO2
Molar mass	44.01 g·mol−1
Appearance	Colorless gas
Odor	Odorless
Density	1562 kg/m3 (solid at 1 atm and −78.5 °C) 1101 kg/m3 (liquid at saturation −37°C) 1.977 kg/m3 (gas at 1 atm and 0 °C)
Melting point	−56.6 °C; −69.8 °F; 216.6 K (Triple point at 5.1 atm)
Sublimation conditions	−78.5 °C; −109.2 °F; 194.7 K (1 atm)
Solubility in water	1.45 g/L at 25oC, 100 kPa
Vapor pressure	5.73 MPa (20 °C)
Acidity (pKa)	6.35, 10.33
Refractive index (nD)	1.1120
Viscosity	0.07 cP at −78.5 °C
Dipole moment	0 D
Structure
Crystal structure	trigonal
Molecular shape	linear
Thermochemistry
Specific heat capacity (C)	37.135 J/K mol
Std molar entropy (So298)	214 J•mol−1•K−1
Std enthalpy of formation (ΔfHo298)	−393.5 kJ•mol−1
Pharmacology
ATC code	V03AN02
Vapor pressure	{{{value}}}
Related compounds
Other anions	Carbon disulfide Carbon diselenide Carbon ditelluride
Other cations	Silicon dioxide Germanium dioxide Tin dioxide Lead dioxide
Related carbon oxides	Carbon monoxide Carbon suboxide Dicarbon monoxide Carbon trioxide
Related compounds	Carbonic acid Carbonyl sulfide
Supplementary data page
Structure and properties	Refractive index (n), Dielectric constant (εr), etc.
Thermodynamic data	Phase behaviour solid–liquid–gas
Spectral data	UV, IR, NMR, MS
N verify (what is YN ?)
Infobox references

Carbon dioxide, chemical formula CO₂, is a colorless and odorless gas vital to life on Earth. This naturally occurring chemical compound is composed of a carbon atom covalently double bonded to two oxygen atoms. Carbon dioxide exists in Earth's atmosphere as a trace gas at a concentration of about 0.04 percent (400 ppm) by volume. Natural sources include volcanoes, hot springs and geysers and it is freed from carbonate rocks by dissolution in water and acids. Because carbon dioxide is soluble in water, it occurs naturally in groundwater, rivers and lakes, in ice caps and glaciers and in seawater. It is present in deposits of petroleum and natural gas.

Atmospheric carbon dioxide is the primary source of carbon in life on Earth and its concentration in Earth's pre-industrial atmosphere since late in the Precambrian was regulated by photosynthetic organisms and geological phenomena. As part of the carbon cycle, plants, algae, and cyanobacteria use light energy to photosynthesize carbohydrate from carbon dioxide and water, with oxygen produced as a waste product. Carbon dioxide is produced by plants during respiration.

Carbon dioxide (CO₂) is a product of respiration of all aerobic organisms. It is returned to water via the gills of fish and to the air via the lungs of air-breathing land animals, including humans. Carbon dioxide is produced during the processes of decay of organic materials and the fermentation of sugars in bread, beer and winemaking. It is produced by combustion of wood, carbohydrates and fossil fuels such as coal, peat, petroleum and natural gas.

It is a versatile industrial material, used, for example, as an inert gas in welding and fire extinguishers, as a pressurizing gas in air guns and oil recovery, as a chemical feedstock and in liquid form as a solvent in decaffeination of coffee and supercritical drying. It is added to drinking water and carbonated beverages including beer and champagne to add sparkle. The frozen solid form of CO₂, known as "dry ice" is used as a refrigerant and as an abrasive in dry-ice blasting.

Carbon dioxide is claimed to be an important greenhouse gas. Burning of carbon-based fuels since the industrial revolution has rapidly increased its concentration in the atmosphere. In one theory this causes global warming. It is also proposed to cause a tiny reduction in the alkalinity of the surface waters of the ocean because after it dissolves in water, a small fraction of the dissolved CO₂ reacts to form carbonic acid.

Background

Crystal structure of dry ice

Carbon dioxide was the first gas to be described as a discrete substance. In about 1640, the Flemish chemist Jan Baptist van Helmont observed that when he burned charcoal in a closed vessel, the mass of the resulting ash was much less than that of the original charcoal. His interpretation was that the rest of the charcoal had been transmuted into an invisible substance he termed a "gas" or "wild spirit" (spiritus sylvestre).

The properties of carbon dioxide were studied more thoroughly in the 1750s by the Scottish physician Joseph Black. He found that limestone (calcium carbonate) could be heated or treated with acids to yield a gas he called "fixed air." He observed that the fixed air was denser than air and supported neither flame nor animal life. Black also found that when bubbled through limewater (a saturated aqueous solution of calcium hydroxide), it would precipitate calcium carbonate. He used this phenomenon to illustrate that carbon dioxide is produced by animal respiration and microbial fermentation. In 1772, English chemist Joseph Priestley published a paper entitled Impregnating Water with Fixed Air in which he described a process of dripping sulfuric acid (or oil of vitriol as Priestley knew it) on chalk in order to produce carbon dioxide, and forcing the gas to dissolve by agitating a bowl of water in contact with the gas.

Carbon dioxide was first liquefied (at elevated pressures) in 1823 by Humphry Davy and Michael Faraday. The earliest description of solid carbon dioxide was given by Adrien-Jean-Pierre Thilorier, who in 1835 opened a pressurized container of liquid carbon dioxide, only to find that the cooling produced by the rapid evaporation of the liquid yielded a "snow" of solid CO₂.

Chemical and physical properties

Structure and bonding

See also: Molecular orbital diagram § Carbon Dioxide MO Diagram

The carbon dioxide molecule is linear and centrosymmetric. The two C=O bonds are equivalent and are short (116.3 pm), consistent with double bonding. Since it is centrosymmetric, the molecule has no electrical dipole. Consequently, only two vibrational bands are observed in the IR spectrum – an antisymmetric stretching mode at 2349 cm⁻¹ and a degenerate pair of bending modes at 667 cm⁻¹. There is also a symmetric stretching mode at 1388 cm⁻¹ which is only observed in the Raman spectrum.

In aqueous solution

See also: Carbonic acid

Carbon dioxide is soluble in water, in which some fraction of it reversibly forms H₂CO₃ (carbonic acid), a weak acid since its ionization in water is incomplete.

CO₂ + H₂O ⇌ H₂CO₃

The hydration equilibrium constant of carbonic acid is $K_{\mathrm h}=\frac{\rm{[H_2CO_3]}}{\rm{[CO_2(aq)]}}=1.70\times 10^{-3}$ (at 25 °C). Hence, the majority of the carbon dioxide is not converted into carbonic acid, but remains as CO₂ molecules, not affecting the pH.

The relative concentrations of H₂CO₃, and the deprotonated forms HCO₃^- (bicarbonate) and CO₃^2-(carbonate) depend on the pH. As shown in a Bjerrum plot, in neutral or slightly alkaline water (pH > 6.5), the bicarbonate form predominates (>50%) becoming the most prevalent (>95%) at the pH of seawater. In very alkaline water (pH > 10.4), the predominant (>50%) form is carbonate. The oceans, being mildly alkaline with typical pH = 8.2–8.5, contain about 120 mg of bicarbonate per liter.

Being diprotic, carbonic acid has two acid dissociation constants, the first one for the dissociation into the bicarbonate (also called hydrogen carbonate) ion (HCO₃⁻):

H₂CO₃ ⇌ HCO₃⁻ + H⁺

K_a1 = 2.5 × 10⁻⁴ mol/L; pK_a1 = 3.6 at 25 °C.

This is the true first acid dissociation constant, defined as $K_{a1}=\frac{\rm{[HCO_3^-] [H^+]}}{\rm{[H_2CO_3]}}$, where the denominator includes only covalently bound H₂CO₃ and does not include hydrated CO₂(aq). The much smaller and often-quoted value near 4.16 × 10⁻⁷ is an apparent value calculated on the (incorrect) assumption that all dissolved CO₂ is present as carbonic acid, so that $K_{\mathrm{a1}}{\rm{(apparent)}}=\frac{\rm{[HCO_3^-] [H^+]}}{\rm{[H_2CO_3] + [CO_2(aq)]}}$. Since most of the dissolved CO₂ remains as CO₂ molecules, K_a1(apparent) has a much larger denominator and a much smaller value than the true K_a1.

The bicarbonate ion is an amphoteric species that can act as an acid or as a base, depending on pH of the solution. At high pH, it dissociates significantly into the carbonate ion (CO₃²⁻):

HCO₃⁻ ⇌ CO₃²⁻ + H⁺

K_a2 = 4.69 × 10⁻¹¹ mol/L; pK_a2 = 10.329

In organisms carbonic acid production is catalysed by the enzyme, carbonic anhydrase.

Chemical reactions of CO₂

CO₂ is a weak electrophile. Its reaction with basic water illustrates this property, in which case hydroxide is the nucleophile. Other nucleophiles react as well. For example, carbanions as provided by Grignard reagents and organolithium compounds react with CO₂ to give carboxylates:

MR + CO₂ → RCO₂M

where M = Li or MgBr and R = alkyl or aryl.

In metal carbon dioxide complexes, CO₂ serves as a ligand, which can facilitate the conversion of CO₂ to other chemicals.

The reduction of CO₂ to CO is ordinarily a difficult and slow reaction:

CO₂ + 2 e⁻ + 2H⁺ → CO + H₂O

The redox potential for this reaction near pH 7 is about −0.53 V versus the standard hydrogen electrode. The nickel-containing enzyme carbon monoxide dehydrogenase catalyses this process.

Physical properties

For more details on this topic, see Carbon dioxide data

Carbon dioxide pressure-temperature phase diagram showing the triple point and critical point of carbon dioxide

Sample of solid carbon dioxide or "dry ice" pellets

Carbon dioxide is colorless. At low concentrations, the gas is odorless. At higher concentrations it has a sharp, acidic odor. At standard temperature and pressure, the density of carbon dioxide is around 1.98 kg/m³, about 1.67 times that of air.

Carbon dioxide has no liquid state at pressures below 5.1 standard atmospheres (520 kPa). At 1 atmosphere (near mean sea level pressure), the gas deposits directly to a solid at temperatures below −78.5 °C (−109.3 °F; 194.7 °K) and the solid sublimes directly to a gas above −78.5 °C. In its solid state, carbon dioxide is commonly called dry ice.

Liquid carbon dioxide forms only at pressures above 5.1 atm; the triple point of carbon dioxide is about 518 kPa at −56.6 °C (see phase diagram, above). The critical point is 7.38 MPa at 31.1 °C. Another form of solid carbon dioxide observed at high pressure is an amorphous glass-like solid. This form of glass, called carbonia, is produced by supercooling heated CO₂ at extreme pressure (40–48 GPa or about 400,000 atmospheres) in a diamond anvil. This discovery confirmed the theory that carbon dioxide could exist in a glass state similar to other members of its elemental family, like silicon (silica glass) and germanium dioxide. Unlike silica and germania glasses, however, carbonia glass is not stable at normal pressures and reverts to gas when pressure is released.

At temperatures and pressures above the critical point, carbon dioxide behaves as a supercritical fluid known as supercritical carbon dioxide.

Infrared spectral properties

The absorbance of CO₂ at infrared wavelengths.

The transmittance of CO₂ at infrared wavelengths.

The infrared band is the most interesting part of the CO₂ spectra. The absorbance and transmittance, particularly around 15 micrometers, is used as an input to construct the climate models for global warming based on the greenhouse effect theory.

The absorbance and transmittance charts are from NIST, based on data from 1964. The spectrum is obtained from a laboratory setup. Light of a specific frequency and intensity passes through a 10 cm long cylinder with a light detector at the end. The cylinder is filled with gaseous CO₂ at a specific pressure. The resulting absorbance and transmittance spectra are found by sweeping the frequency. "Absorbance" should not be confused with "absorption". These terms are given different meanings by different authors.

Transmittance is the ratio of transmitted to incident light, which cannot exceed one. More of something can't leave than came in. The NIST graph may be a little bit misaligned vertically. In order to show the features of this spectrum, the experimenter kept the concentration of CO₂ just below the saturation point for his setup. The peak (trough) near 4 micrometers means almost no light is being transmitted.

Isolation and production

Carbon dioxide can be obtained by distillation from air, but the method is inefficient. Industrially, carbon dioxide is predominantly an unrecovered waste product, produced by several methods which may be practiced at various scales.

The combustion of all carbon-based fuels, such as methane (natural gas), petroleum distillates (gasoline, diesel, kerosene, propane), coal, wood and generic organic matter produces carbon dioxide and, except in the case of pure carbon, water. As an example, the chemical reaction between methane and oxygen is given below.

CH₄ + 2O₂ → CO₂ + 2 H₂O

It is produced by thermal decomposition of limestone, CaCO₃, by heating (calcining) at about 850 °C, in the manufacture of quicklime (calcium oxide, CaO), a compound that has many industrial uses:

CaCO₃ → CaO + CO₂

Iron is reduced from its oxides with coke in a blast furnace, producing pig iron and carbon dioxide:

Carbon dioxide is a byproduct of the industrial production of hydrogen by steam reforming and ammonia synthesis. These processes begin with the reaction of water and natural gas (mainly methane).

Acids liberate CO₂ from most metal carbonates. Consequently, it may be obtained directly from natural carbon dioxide springs, where it is produced by the action of acidified water on limestone or dolomite. The reaction between hydrochloric acid and calcium carbonate (limestone or chalk) is shown below: CaCO₃ + 2 HCl → CaCl₂ + H₂CO₃ The carbonic acid (H₂CO₃ ) then decomposes to water and CO₂ :

H₂CO₃ → CO₂ + H₂O

Such reactions are accompanied by foaming or bubbling, or both, as the gas is released. They have widespread uses in industry because they can be used to neutralize waste acid streams. Carbon dioxide is a by-product of the fermentation of sugar in the brewing of beer, whisky and other alcoholic beverages and in the production of bioethanol. Yeast metabolizes sugar to produce CO₂ and ethanol, also known as alcohol, as follows:

C₆ H₁₂ O₆ → 2CO₂ + 2C₂H₅OH

All aerobic organisms produce CO₂ when they oxidize carbohydrates, fatty acids, and proteins. The large number of reactions involved are exceedingly complex and not described easily. Refer to (cellular respiration, anaerobic respiration and photosynthesis). The equation for the respiration of glucose and other monosaccharides is:

C₆ H₁₂ O₆ + 6O₂→ 6CO₂ + 6H₂O

Photoautotrophs (i.e. plants and cyanobacteria) use the energy contained in sunlight to photosynthesize simple sugars from CO2 absorbed from the air and water:

n CO₂ + n H₂O → (CH₂O)_n + n O₂

Carbon dioxide comprises about 40-45% of the gas that emanates from decomposition in landfills (termed "landfill gas"). Most of the remaining 50-55% is methane.

Uses

Carbon dioxide bubbles in a soft drink.

Carbon dioxide is used by the food industry, the oil industry, and the chemical industry. The compound has varied commercial uses but one of its greatest use as a chemical is in the production of carbonated beverages; it provides the sparkle in carbonated beverages such as soda water.

Precursor to chemicals

In the chemical industry, carbon dioxide is mainly consumed as an ingredient in the production of urea, with a smaller fraction being used to produce methanol and a range of other products. Metal carbonates and bicarbonates, as well as some carboxylic acids derivatives (e.g., sodium salicylate) are prepared using CO₂.

In addition to conventional processes using CO₂ for chemical production electrochemical methods are also being explored at a research level. In particular, the use of renewable energy for production of fuels from CO₂ (such as methanol) is attractive as this could result in fuels that could be easily transported and used within conventional combustion technologies but have no net CO₂ emissions.

Foods

Carbon dioxide is a food additive used as a propellant and acidity regulator in the food industry. It is approved for usage in the EU (listed as E number E290), USA and Australia and New Zealand (listed by its INS number 290).

A candy called Pop Rocks is pressurized with carbon dioxide gas at about 4 x 10⁶ Pa (40 bar, 580 psi). When placed in the mouth, it dissolves (just like other hard candy) and releases the gas bubbles with an audible pop.

Leavening agents cause dough to rise by producing carbon dioxide. Baker's yeast produces carbon dioxide by fermentation of sugars within the dough, while chemical leaveners such as baking powder and baking soda release carbon dioxide when heated or if exposed to acids.

Beverages

Carbon dioxide is used to produce carbonated soft drinks and soda water. Traditionally, the carbonation of beer and sparkling wine came about through natural fermentation, but many manufacturers carbonate these drinks with carbon dioxide recovered from the fermentation process. In the case of bottled and kegged beer, the most common method used is carbonation with recycled carbon dioxide. With the exception of British Real Ale, draught beer is usually transferred from kegs in a cold room or cellar to dispensing taps on the bar using pressurized carbon dioxide, sometimes mixed with nitrogen.

Wine making

Carbon dioxide in the form of dry ice is often used in the wine making process to cool down bunches of grapes quickly after picking to help prevent spontaneous fermentation by wild yeast. The main advantage of using dry ice over regular water ice is that it cools the grapes without adding any additional water that may decrease the sugar concentration in the grape must, and therefore also decrease the alcohol concentration in the finished wine.

Dry ice is also used during the cold soak phase of the wine making process to keep grapes cool. The carbon dioxide gas that results from the sublimation of the dry ice tends to settle to the bottom of tanks because it is denser than air. The settled carbon dioxide gas creates a hypoxic environment which helps to prevent bacteria from growing on the grapes until it is time to start the fermentation with the desired strain of yeast.

Carbon dioxide is also used to create a hypoxic environment for carbonic maceration, the process used to produce Beaujolais wine.

Carbon dioxide is sometimes used to top up wine bottles or other storage vessels such as barrels to prevent oxidation, though it has the problem that it can dissolve into the wine, making a previously still wine slightly fizzy. For this reason, other gases such as nitrogen or argon are preferred for this process by professional wine makers.

Inert gas

It is one of the most commonly used compressed gases for pneumatic (pressurized gas) systems in portable pressure tools. Carbon dioxide is also used as an atmosphere for welding, although in the welding arc, it reacts to oxidize most metals. Use in the automotive industry is common despite significant evidence that welds made in carbon dioxide are more brittle than those made in more inert atmospheres, and that such weld joints deteriorate over time because of the formation of carbonic acid. It is used as a welding gas primarily because it is much less expensive than more inert gases such as argon or helium. When used for MIG welding, CO₂ use is sometimes referred to as MAG welding, for Metal Active Gas, as CO₂ can react at these high temperatures. It tends to produce a hotter puddle than truly inert atmospheres, improving the flow characteristics. Although, this may be due to atmospheric reactions occurring at the puddle site. This is usually the opposite of the desired effect when welding, as it tends to embrittle the site, but may not be a problem for general mild steel welding, where ultimate ductility is not a major concern.

It is used in many consumer products that require pressurized gas because it is inexpensive and nonflammable, and because it undergoes a phase transition from gas to liquid at room temperature at an attainable pressure of approximately 60 bar (870 psi, 59 atm), allowing far more carbon dioxide to fit in a given container than otherwise would. Life jackets often contain canisters of pressured carbon dioxide for quick inflation. Aluminium capsules of CO₂ are also sold as supplies of compressed gas for airguns, paintball markers, inflating bicycle tires, and for making carbonated water. Rapid vaporization of liquid carbon dioxide is used for blasting in coal mines. High concentrations of carbon dioxide can also be used to kill pests. Liquid carbon dioxide is used in supercritical drying of some food products and technological materials, in the preparation of specimens for scanning electron microscopy and in the decaffeination of coffee beans.

Fire extinguisher

Carbon dioxide extinguishes flames, and some fire extinguishers, especially those designed for electrical fires, contain liquid carbon dioxide under pressure. Carbon dioxide extinguishers work well on small flammable liquid and electrical fires, but not on ordinary combustible fires, because although it excludes oxygen, it does not cool the burning substances significantly and when the carbon dioxide disperses they are free to catch fire upon exposure to atmospheric oxygen. Carbon dioxide has also been widely used as an extinguishing agent in fixed fire protection systems for local application of specific hazards and total flooding of a protected space. International Maritime Organization standards also recognize carbon dioxide systems for fire protection of ship holds and engine rooms. Carbon dioxide based fire protection systems have been linked to several deaths, because it can cause suffocation in sufficiently high concentrations. A review of CO₂ systems identified 51 incidents between 1975 and the date of the report, causing 72 deaths and 145 injuries.

Supercritical CO₂ as solvent

See also: Supercritical carbon dioxide

Liquid carbon dioxide is a good solvent for many lipophilic organic compounds and is used to remove caffeine from coffee. Carbon dioxide has attracted attention in the pharmaceutical and other chemical processing industries as a less toxic alternative to more traditional solvents such as organochlorides. It is used by some dry cleaners for this reason (see green chemistry). It is used in the preparation of some aerogels because of the properties of supercritical carbon dioxide.

Agricultural and biological applications

Plants require carbon dioxide to conduct photosynthesis. The atmospheres of greenhouses may (if of large size, must) be enriched with additional CO₂ to sustain and increase the rate of plant growth. At very high concentrations (100 times atmospheric concentration, or greater), carbon dioxide can be toxic to animal life, so raising the concentration to 10,000 ppm (1%) or higher for several hours will eliminate pests such as whiteflies and spider mites in a greenhouse.

In medicine, up to 5% carbon dioxide (130 times atmospheric concentration) is added to oxygen for stimulation of breathing after apnea and to stabilize the O₂ CO₂ balance in blood.

It has been proposed that carbon dioxide from power generation be bubbled into ponds to stimulate growth of algae that could then be converted into biodiesel fuel.

Oil recovery

Carbon dioxide is used in enhanced oil recovery where it is injected into or adjacent to producing oil wells, usually under supercritical conditions, when it becomes miscible with the oil. This approach can increase original oil recovery by reducing residual oil saturation by between 7 per cent to 23 per cent additional to primary extraction. It acts as both a pressurizing agent and, when dissolved into the underground crude oil, significantly reduces its viscosity, and changing surface chemistry enabling the oil to flow more rapidly through the reservoir to the removal well. In mature oil fields, extensive pipe networks are used to carry the carbon dioxide to the injection points.

Bio transformation into fuel

Researchers have genetically modified a strain of the cyanobacterium Synechococcus elongatus to produce the fuels isobutyraldehyde and isobutanol from CO₂ using photosynthesis.

Refrigerant

Comparison of phase diagrams of carbon dioxide (red) and water (blue) as a log-lin chart with phase transitions points at 1 atmosphere

Liquid and solid carbon dioxide are important refrigerants, especially in the food industry, where they are employed during the transportation and storage of ice cream and other frozen foods. Solid carbon dioxide is called "dry ice" and is used for small shipments where refrigeration equipment is not practical. Solid carbon dioxide is always below −78.5 °C at regular atmospheric pressure, regardless of the air temperature.

Liquid carbon dioxide (industry nomenclature R744 or R-744) was used as a refrigerant prior to the discovery of R-12 and may enjoy a renaissance due to the fact that R134a contributes to climate change. Its physical properties are highly favorable for cooling, refrigeration, and heating purposes, having a high volumetric cooling capacity. Due to the need to operate at pressures of up to 130 bar (1880 psi), CO₂ systems require highly resistant components that have already been developed for mass production in many sectors. In automobile air conditioning, in more than 90% of all driving conditions for latitudes higher than 50°, R744 operates more efficiently than systems using R134a. Its environmental advantages (GWP of 1, non-ozone depleting, non-toxic, non-flammable) could make it the future working fluid to replace current HFCs in cars, supermarkets, and heat pump water heaters, among others. Coca-Cola has fielded CO₂-based beverage coolers and the U.S. Army is interested in CO₂ refrigeration and heating technology.

The global automobile industry is expected to decide on the next-generation refrigerant in car air conditioning. CO₂ is one discussed option.(see Sustainable automotive air conditioning)

Coal bed methane recovery

In enhanced coal bed methane recovery, carbon dioxide would be pumped into the coal seam to displace methane, as opposed to current methods which primarily rely on the removal of water (to reduce pressure) to make the coal seam release its trapped methane.

Niche uses

A carbon dioxide laser.

Carbon dioxide is the lasing medium in a carbon dioxide laser, which is one of the earliest type of lasers.

Carbon dioxide can be used as a means of controlling the pH of swimming pools, by continuously adding gas to the water, thus keeping the pH from rising. Among the advantages of this is the avoidance of handling (more hazardous) acids. Similarly, it is also used in the maintaining reef aquaria, where it is commonly used in calcium reactors to temporarily lower the pH of water being passed over calcium carbonate in order to allow the calcium carbonate to dissolve into the water more freely where it is used by some corals to build their skeleton.

Used as the primary coolant in the British advanced gas-cooled reactor for nuclear power generation.

Carbon dioxide induction is commonly used for the euthanasia of laboratory research animals. Methods to administer CO₂ include placing animals directly into a closed, prefilled chamber containing CO₂, or exposure to a gradually increasing concentration of CO₂. In 2013, the American Veterinary Medical Association issued new guidelines for carbon dioxide induction, stating that a displacement rate of 10% to 30% of the gas chamber volume per minute is optimal for the humane euthanization of small rodents.

Carbon dioxide is also used in several related cleaning and surface preparation techniques.

In Earth's atmosphere

Main Carbon cycle

The Keeling Curve of atmospheric CO₂ concentrations measured at Mauna Loa Observatory

Carbon dioxide in Earth's atmosphere is a trace gas, currently (early 2016) having an average concentration of 402 parts per million by volume (or 611 parts per million by mass). Atmospheric concentrations of carbon dioxide fluctuate slightly with the change of the seasons. Concentrations fall during the Northern Hemisphere spring and summer as plants consume the gas, and rise during the northern autumn and winter as plants go dormant or die and decay. Concentrations also vary on a regional basis, most strongly near the ground with much smaller variations aloft. In urban areas concentrations are generally higher and indoors they can reach 10 times background levels.

Yearly increase of atmospheric CO₂: In the 1960s, the average annual increase was 37% of the 2000–2007 average.

Combustion of fossil fuels and deforestation have enriched the atmospheric concentration of carbon dioxide, perhaps even as much as by 43% since the beginning of the age of industrialization. Most carbon dioxide from human activities is released from burning coal and other fossil fuels. Other human activities, including deforestation, biomass burning, and cement production also emit carbon dioxide. Volcanoes are estimated to emit an average of between 0.2 and 0.3 billion tons of carbon dioxide per year, compared to an estimated 29 billion tons of carbon dioxide per year emitted by human activities. Up to 40% of the gas emitted by some volcanoes during subaerial eruptions is carbon dioxide.

Carbon dioxide is said to be a greenhouse gas, absorbing and emitting infrared radiation at its two infrared-active vibrational frequencies (see Structure and bonding above). This process is said to warm the surface and lower atmosphere, while cooling the upper atmosphere. A large number of taxpayer-funded climate scientists agree that the enrichment of atmospheric CO₂, through the proposed CO₂-induced greenhouse effect, is the main reason for the claimed rise in average global temperature since the mid-20th century. Other scientists doubt that the global temperature has risen during that period, or that the greenhouse effect is a viable theory. Although carbon dioxide is said to be the atmospheric gas primarily responsible for the rise, methane, nitrous oxide, ozone, and various other long-lived atmospheric gases are also said to contribute. In the global warming theory, carbon dioxide is of greatest concern because it exerts a larger overall warming influence than all of those other gases combined, and because it has a long atmospheric lifetime. Both carbon dioxide enrichment and global warming increase the rate of growth of plant life.

CO₂ in Earth's atmosphere if half of global-warming emissions are not absorbed.
(NASA computer simulation).

Five hundred million years ago the carbon dioxide concentration was, by some estimates, 20 times greater than today, decreasing to 4–5 times during the Jurassic period and then slowly declining with a particularly swift reduction occurring 49 million years ago.

Local concentrations of carbon dioxide can reach high values near strong sources, especially those that are isolated by surrounding terrain. At the Bossoleto hot spring near Rapolano Terme in Tuscany, Italy, situated in a bowl-shaped depression about 100 m (330 ft) in diameter, concentrations of CO₂ rise to above 75% overnight, sufficient to kill insects and small animals. After sunrise the gas is dispersed by convection during the day. High concentrations of CO₂ produced by disturbance of deep lake water saturated with CO₂ are thought to have caused 37 fatalities at Lake Monoun, Cameroon in 1984 and 1700 casualties at Lake Nyos, Cameroon in 1986.

On November 12, 2015, taxpayer-funded NASA scientists reported that human-made carbon dioxide (CO₂) continues to increase above levels not seen in hundreds of thousands of years. It is estimated that currently about half of the carbon dioxide released from the burning of fossil fuels remains in the atmosphere and is not absorbed by vegetation and the oceans.

In the oceans

Carbon cycle Carbon dioxide dissolves in the ocean to form carbonic acid (H₂CO₃), bicarbonate (HCO₃⁻) and carbonate (CO₃²⁻). There is about fifty times as much carbon dissolved in the oceans as exists in the atmosphere. The oceans act as an enormous carbon sink, and have taken up about a third of CO₂ emitted by human activity.

As the concentration of carbon dioxide increases in the atmosphere, the increased uptake of carbon dioxide into the oceans is causing a measurable decrease in the pH of the oceans, which is referred to as ocean acidification. This reduction in pH affects biological systems in the oceans, primarily oceanic calcifying organisms. These effects span the food chain from autotrophs to heterotrophs and include organisms such as coccolithophores, corals, foraminifera, echinoderms, crustaceans and mollusks. Under normal conditions, calcium carbonate is stable in surface waters since the carbonate ion is at supersaturating concentrations. However, as ocean pH falls, so does the concentration of this ion, and when carbonate becomes undersaturated, structures made of calcium carbonate are vulnerable to dissolution. Corals, coccolithophore algae, coralline algae, foraminifera, shellfish and pteropods experience reduced calcification or enhanced dissolution when exposed to elevated CO₂ .

Gas solubility decreases as the temperature of water increases (except when both pressure exceeds 300 bar and temperature exceeds 393 K, only found near deep geothermal vents) and therefore the rate of uptake from the atmosphere decreases as ocean temperatures rise.

Most of the CO₂ taken up by the ocean, which is about 30% of the total released into the atmosphere, forms carbonic acid in equilibrium with bicarbonate. Some of these chemical species are consumed by photosynthetic organisms that remove carbon from the cycle. Increased CO₂ in the atmosphere has led to decreasing alkalinity of seawater, and there is concern that this may adversely affect organisms living in the water. In particular, with decreasing alkalinity, the availability of carbonates for forming shells decreases, although there's evidence of increased shell production by certain species under increased CO₂ content.

NOAA states in their May 2008 "State of the science fact sheet for ocean acidification" that:
"The oceans have absorbed about 50% of the carbon dioxide (CO₂) released from the burning of fossil fuels, resulting in chemical reactions that lower ocean pH. This has caused an increase in hydrogen ion (acidity) of about 30% since the start of the industrial age through a process known as "ocean acidification." A growing number of studies have demonstrated adverse impacts on marine organisms, including:

• The rate at which reef-building corals produce their skeletons decreases, while production of numerous varieties of jellyfish increases.
• The ability of marine algae and free-swimming zooplankton to maintain protective shells is reduced.
• The survival of larval marine species, including commercial fish and shellfish, is reduced."

Also, the Intergovernmental Panel on Climate Change (IPCC) writes in their Climate Change 2007: Synthesis Report:
"The uptake of anthropogenic carbon since 1750 has led to the ocean becoming more acidic with an average decrease in pH of 0.1 units. Increasing atmospheric CO₂ concentrations lead to further acidification ... While the effects of observed ocean acidification on the marine biosphere are as yet undocumented, the progressive acidification of oceans is expected to have negative impacts on marine shell-forming organisms (e.g. corals) and their dependent species."

Some marine calcifying organisms (including coral reefs) have been singled out by major research agencies, including NOAA, OSPAR commission, NANOOS and the IPCC, because their most current research shows that ocean acidification should be expected to impact them negatively.

Carbon dioxide is also introduced into the oceans through hydrothermal vents. The Champagne hydrothermal vent, found at the Northwest Eifuku volcano at Marianas Trench Marine National Monument, produces almost pure liquid carbon dioxide, one of only two known sites in the world.

Biological role

Carbon dioxide is an end product of cellular respiration in organisms that obtain energy by breaking down sugars, fats and amino acids with oxygen as part of their metabolism. This includes all plants, algae and animals and aerobic fungi and bacteria. In vertebrates, the carbon dioxide travels in the blood from the body's tissues to the skin (e.g., amphibians) or the gills (e.g., fish), from where it dissolves in the water, or to the lungs from where it is exhaled. During active photosynthesis, plants can absorb more carbon dioxide from the atmosphere than they release in respiration.

Photosynthesis and carbon fixation

Overview of photosynthesis and respiration. Carbon dioxide (at right), together with water, form oxygen and organic compounds (at left) by photosynthesis, which can be respired to water and (CO₂).

Figure 2. Overview of the Calvin cycle and carbon fixation

Carbon fixation is a biochemical process by which atmospheric carbon dioxide is incorporated by plants, algae and (cyanobacteria) into energy-rich organic molecules such as glucose, thus creating their own food by photosynthesis. Photosynthesis uses carbon dioxide and water to produce sugars from which other organic compounds can be constructed, and oxygen is produced as a by-product.

Ribulose-1,5-bisphosphate carboxylase oxygenase, commonly abbreviated to RuBisCO, is the enzyme involved in the first major step of carbon fixation, the production of two molecules of 3-phosphoglycerate from CO₂ and ribulose bisphosphate, as shown in the diagram at left.

RuBisCO is thought to be the single most abundant protein on Earth.

Phototrophs use the products of their photosynthesis as internal food sources and as raw material for the biosynthesis of more complex organic molecules, such as polysaccharides, nucleic acids and proteins. These are used for their own growth, and also as the basis of the food chains and webs that feed other organisms, including animals such as ourselves. Some important phototrophs, the coccolithophores synthesise hard calcium carbonate scales. A globally significant species of coccolithophore is Emiliania huxleyi whose calcite scales have formed the basis of many sedimentary rocks such as limestone, where what was previously atmospheric carbon can remain fixed for geological timescales.

Plants can grow as much as 50 percent faster in concentrations of 1,000 ppm CO₂ when compared with ambient conditions, though this assumes no change in climate and no limitation on other nutrients. Elevated CO₂ levels cause increased growth reflected in the harvestable yield of crops, with wheat, rice and soybean all showing increases in yield of 12–14% under elevated CO₂ in FACE experiments.

Increased atmospheric CO₂ concentrations result in fewer stomata developing on plants which leads to reduced water usage and increased water-use efficiency. Studies using FACE have shown that CO₂ enrichment leads to decreased concentrations of micronutrients in crop plants. This may have knock-on effects on other parts of ecosystems as herbivores will need to eat more food to gain the same amount of protein.

The concentration of secondary metabolites such as phenylpropanoids and flavonoids can also be altered in plants exposed to high concentrations of CO₂.

Plants also emit CO₂ during respiration, and so the majority of plants and algae, which use C3 photosynthesis, are only net absorbers during the day. Though a growing forest will absorb many tons of CO₂ each year, a mature forest will produce as much CO₂ from respiration and decomposition of dead specimens (e.g., fallen branches) as is used in photosynthesis in growing plants. Contrary to the long-standing view that they are carbon neutral, mature forests can continue to accumulate carbon and remain valuable carbon sinks, helping to maintain the carbon balance of Earth's atmosphere. Additionally, and crucially to life on earth, photosynthesis by phytoplankton consumes dissolved CO₂ in the upper ocean and thereby promotes the absorption of CO₂ from the atmosphere.

Toxicity

See also Carbon dioxide poisoning

Main symptoms of carbon dioxide toxicity, by increasing volume percent in air.

Carbon dioxide content in fresh air (averaged between sea-level and 10 kPa level, i.e., about 30 km (19 mi) altitude) varies between 0.036% (360 ppm) and 0.041% (410 ppm), depending on the location. -clarify reason=what date/year are these figures for?

CO₂ is an asphyxiant gas and not classified as toxic or harmful in accordance with Globally Harmonized System of Classification and Labelling of Chemicals standards of United Nations Economic Commission for Europe by using the OECD Guidelines for the Testing of Chemicals. In concentrations up to 1% (10,000 ppm), it will make some people feel drowsy and give the lungs a stuffy feeling. Concentrations of 7% to 10% (70,000 to 100,000 ppm) may cause suffocation, even in the presence of sufficient oxygen, manifesting as dizziness, headache, visual and hearing dysfunction, and unconsciousness within a few minutes to an hour. The physiological effects of acute carbon dioxide exposure are grouped together under the term hypercapnia, a subset of asphyxiation.

Because it is heavier than air, in locations where the gas seeps from the ground (due to sub-surface volcanic or geothermal activity) in relatively high concentrations, without the dispersing effects of wind, it can collect in sheltered/pocketed locations below average ground level, causing animals located therein to be suffocated. Carrion feeders attracted to the carcasses are then also killed. Children have been killed in the same way near the city of Goma by CO₂ emissions from the nearby volcano Mt. Nyiragongo. The Swahili term for this phenomenon is 'mazuku'.

Adaptation to increased concentrations of CO₂ occurs in humans, including modified breathing and kidney bicarbonate production, in order to balance the effects of blood acidification (acidosis). It was suggested that 2.0 percent inspired concentrations could be used for closed air spaces (e.g. a submarine) since the adaptation is physiological and reversible. Decrement in performance or in normal physical activity does not happen at this level of exposure for 5 days. However, with ongoing respiratory acidosis, adaptation or compensatory mechanisms will be unable to reverse this condition. There are very few studies of the health effects of long-term continuous CO₂ exposure on humans and animals at levels below 1% and there is potentially a significant risk to humans in the near future with rising atmospheric CO₂ levels associated with climate change. Occupational CO₂ exposure limits have been set in the United States at 0.5% (5000 ppm) for an 8-hour period. At this level of CO₂, International Space Station crew experienced headaches, lethargy, mental slowness, emotional irritation, and sleep disruption. Studies in animals at 0.5% CO₂ have demonstrated kidney calcification and bone loss after 8 weeks of exposure. Another study of humans exposed in 2.5 hour sessions demonstrated significant effects on cognitive abilities at concentrations as low as 0.1% (1000ppm) CO₂ likely due to CO₂ induced increases in cerebral blood flow.

Miners, who are particularly vulnerable to gas exposure, referred to mixtures of carbon dioxide and nitrogen as "blackdamp," "choke damp" or "stythe." Before more effective technologies were developed, miners would frequently monitor for dangerous levels of blackdamp and other gases in mine shafts by bringing a caged canary with them as they worked. The canary is more sensitive to asphyxiant gases than humans, and as it became unconscious would stop singing and fall off its perch. The Davy lamp could also detect high levels of blackdamp (which sinks, and collects near the floor) by burning less brightly, while methane, another suffocating gas and explosion risk, would make the lamp burn more brightly.

Carbon dioxide differential above outdoor concentrations at steady state conditions (when the occupancy and ventilation system operation are sufficiently long that CO₂ concentration has stabilized) are sometimes used to estimate ventilation rates per person. (citation needed) CO₂ is considered (by whom?) to be a surrogate for human bio-effluents (clarify) and may correlate with other indoor pollutants. Higher CO₂ concentrations are associated with occupant health, comfort and performance degradation. ASHRAE Standard 62.1–2007 ventilation rates may result in indoor levels up to 2,100 ppm above ambient outdoor conditions. Thus if the outdoor ambient is 400 ppm, indoor concentrations may reach 2,500 ppm with ventilation rates that meet this industry consensus standard. Concentrations in poorly ventilated spaces can be found even higher than this (range of 3,000 or 4,000).

Human physiology

Content

The body produces approximately 1.0 kg (2.3lb) of carbon dioxide per day per person, containing 290 g (0.63 lb) of carbon.

In humans, this carbon dioxide is carried through the venous system and is breathed out through the lungs. Therefore, the carbon dioxide content in the body is high in the venous system, and decreases in the respiratory system, resulting in lower concentrations along any arterial system. Carbon dioxide content of the blood is often given as the partial pressure, which is the pressure which carbon dioxide would have had if it alone occupied the volume.

In humans, the carbon dioxide contents are as follows:

Reference ranges or averages for partial pressures of carbon dioxide (abbreviated PCO₂)

Unit	Venous blood gas	Alveolar pulmonary gas pressures	Arterial blood carbon dioxide
kPa	5.5-6.8	4.8	4.7-6.0
mmHg	41–51	36	35-45

Transport in the blood

CO₂ is carried in blood in three different ways. (The exact percentages vary depending whether it is arterial or venous blood).

• Most of it (about 70% to 80%) is converted to bicarbonate ions HCO₃^- by the enzyme carbonic anhydrase in the red blood cells, by the reaction CO₂ + H₂O → H₂CO₃ → H⁺ + HCO₃^-.
• 5% – 10% is dissolved in the plasma
• 5% – 10% is bound to hemoglobin as carbamino compounds

Hemoglobin, the main oxygen-carrying molecule in red blood cells, carries both oxygen and carbon dioxide. However, the CO₂ bound to hemoglobin does not bind to the same site as oxygen. Instead, it combines with the N-terminal groups on the four globin chains. However, because of allosteric effects on the hemoglobin molecule, the binding of CO₂ decreases the amount of oxygen that is bound for a given partial pressure of oxygen. The decreased binding to carbon dioxide in the blood due to increased oxygen levels is known as the Haldane Effect, and is important in the transport of carbon dioxide from the tissues to the lungs. Conversely, a rise in the partial pressure of CO₂ or a lower pH will cause offloading of oxygen from hemoglobin, which is known as the Bohr Effect.

Regulation of respiration

Carbon dioxide is one of the mediators of local autoregulation of blood supply. If its levels are high, the capillaries expand to allow a greater blood flow to that tissue.

Bicarbonate ions are crucial for regulating blood pH. A person's breathing rate influences the level of CO₂ in their blood. Breathing that is too slow or shallow causes respiratory acidosis, while breathing that is too rapid leads to hyperventilation, which can cause respiratory alkalosis.

Although the body requires oxygen for metabolism, low oxygen levels normally do not stimulate breathing. Rather, breathing is stimulated by higher carbon dioxide levels. As a result, breathing low-pressure air or a gas mixture with no oxygen at all (such as pure nitrogen) can lead to loss of consciousness without ever experiencing air hunger. This is especially perilous for high-altitude fighter pilots. It is also why flight attendants instruct passengers, in case of loss of cabin pressure, to apply the oxygen mask to themselves first before helping others; otherwise, one risks losing consciousness.

The respiratory centers try to maintain an arterial CO₂ pressure of 40 mm Hg. With intentional hyperventilation, the CO₂ content of arterial blood may be lowered to 10–20 mm Hg (the oxygen content of the blood is little affected), and the respiratory drive is diminished. This is why one can hold one's breath longer after hyperventilating than without hyperventilating. This carries the risk that unconsciousness may result before the need to breathe becomes overwhelming, which is why hyperventilation is particularly dangerous before free diving.

See also

• Acidosis
• Alkalosis
• Arterial blood gas
• Bosch reaction
• Bottled gas
• Carbogen
• Carbon dioxide sensor
• Carbon sequestration
• Chemical equilibrium
• EcoCute – As refrigerants
• Emission standards
• Kaya identity
• Lake Kivu
• List of least carbon efficient power stations
• List of countries by carbon dioxide emissions
• Meromictic lake
• pCO2
• pH
• pKa
• Sabatier reaction
• Gilbert Plass (early work on CO₂ and climate change)

Further reading

• Seppanen, Fisk and Mendell, Association of Ventilation Rates and CO₂ Concentrations with Health and Other Responses in Commercial and Institutional Buildings, Indoor Air 1999.
• Shendell, Prill, Fisk, Apte1, Blake & Faulkner, Associations between classroom CO₂ concentrations and student attendance in Washington and Idaho, Indoor Air 2004.
• Soentgen, Jens, Hot air: The science and politics of CO2. In: Global Environment, Vol 7, March 2014, pp. 134–171.

External links

• International Chemical Safety Card 0021
• CID 280 from PubChem
• Carbon dioxide MSDS by Amerigas in the SDSdata.org database.
• CDC – NIOSH Pocket Guide to Chemical Hazards – Carbon Dioxide
• CO₂ Carbon Dioxide Properties, Uses, Applications
• Dry Ice information
• Trends in Atmospheric Carbon Dioxide (NOAA)
• "A War Gas That Saves Lives." Popular Science, June 1942, pp. 53–57.
• NASA's Orbiting Carbon Observatory
• The on-line catalogue of CO₂ natural emissions in Italy
• Reactions, Thermochemistry, Uses, and Function of Carbon Dioxide
• Carbon Dioxide – Part One and Carbon Dioxide – Part Two at The Periodic Table of Videos (University of Nottingham)
• CO₂ emissions from fuel combustion