Pagodane
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| Ball and stick model of pagodane | |
| Identifiers | |
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89683-62-5  |
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| ChemSpider | 128087 |
| Jmol 3D model | Interactive image |
| PubChem | 145202 |
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| Properties | |
| C20H20 | |
| Molar mass | 260.38 g·mol−1 |
| Density | 1.629 g/ml |
| Structure | |
| D2h | |
| 0 D | |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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| Infobox references | |
Pagodane is an organic compound with formula C
20H
20 whose carbon skeleton was said to resemble a pagoda, hence the name. It is a polycyclic hydrocarbon whose molecule has the D2h point symmetry group. The compound is a highly crystalline solid that melts at 243 °C, is barely soluble in most organic solvents and moderately soluble in benzene and chloroform. It sublimes at low pressure.[1]
The name pagodane is used more generally for any member of a family of compounds whose molecular skeletons have the same 16-carbon central cage as the basic compound. Each member can be seen as the result of connecting eight atoms of this cage in pairs by four alkane chains. The general member is denoted [m.n.p.q]pagodane where m, n, p and q are the number of carbons of those four chains. The general formula is then C
16+sH
12+2s where s= m+n+p+q. In particular, the basic compound C
20H
20 has those carbons connected by four methylene bridges (m=n=p=q=1), and its name within that family is therefore [1.1.1.1]pagodane.[1]
Synthesis and structure
The compound was first synthesized by H. Prinzbach et al. in 1987, by a 14-step sequence starting from isodrin.[1] In the process they also synthesized [2.2.1.1]pagodane C
22H
24 and several derivatives.
Prinzbach and co-workers remarked that "the obvious need for [the short name 'pagodane'] can be readily understood in view of the von Baeyer/IUPAC and Chemical Abstracts nomenclature", undecacyclo[9.9.0.01,5.02,12.02,18.03,7.06,10.08,12.011,15.013,17.016,20]icosane.[1]
In carbon skeleton of pagodane, there can be distinguished many propellane-type fragments.[1]
The overall synthesis can be summarized as follows: [1][2]
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File:Pagodane Synthesis en.png
Synthesis of pagodane starting from isodrin
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The scheme depicted here may be shortened to 14 one-pot operations with 24% overall yield. Yet, this variation requires the use of tetrachlorothiophenedioxide instead of tetrachloro-dimethoxycyclopentadiene in two of the early steps. While lesser steps and higher yield look attractive at first sight, this approach had to be given up due to high cost and restricted availability of the dioxide.[1]
Derivatives
Several derivatives are available, such as the diketone C
20H
16O
2 (melting point about 322 °C).[1]
Both [1.1.1.1]pagodane and [2.2.1.1]pagodane form divalent cations in SbF
5/SO
2ClF. In these cations the electron deficiency is spread over the central cyclobutane ring.[3] These dications were the first examples to show the phenomenon of σ-bishomoaromaticity which was subsequently studied by the Prizbach group to great length.[4]
Pagodane is an isomer of dodecahedrane and can be chemically converted to it.[5][6]
References
- ↑ 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 Wolf-Dieter Fessner, Gottfried Sedelmeier, Paul R. Spurr, Grety Rihs, H. Prinzbach (1987), "Pagodane": the efficient synthesis of a novel, versatile molecular framework. J. Am. Chem. Soc., volume 109 issue 15, pp. 4626–42 doi:10.1021/ja00249a029
- ↑ H. Prinzbach, F. Wahl, A. Weiler, P. Landenberger, J. Woerth, L.T. Scott, M. Gelmont, D. Olevano, F. Sommer, B. von Issendorff: C20 Carbon Clusters: Fullerene - Boat - Sheet Generation, Mass Selection, PE Characterization. Chem. Eur. J. 2006, 12, 6268-6280 | doi:10.1002/chem.200501611
- ↑ G. K. Surya Prakash (1998), Investigations on intriguing long lived carbodications. Pure & Appl. Chem., volume 70 issue 10, pp. 2001–06. Online version at iupac.org accessed on 2010-01-14. doi:10.1351/pac199870102001
- ↑ G.K.S. Prakash, V.V. Krishnamurthy, R. Herges, R. Bau, H. Yuan, G.A Olah, W.-D. Fessner, H. Prinzbach: [1.1.1.1]- and [2.2.1.1]Pagodane Dications: Frozen Two-Electron Woodward-Hoffmann Transition State Models. J. Am. Chem. Soc. 1988, 110, 7764-7772
- ↑ Wolf-Dieter Fessner, Bulusu A. R. C. Murty, Horst Prinzbach (1987), The Pagodane Route to Dodecahedranes – Thermal, Reductive, and Oxidative Transformations of Pagodanes Angewandte Chemie International Edition in English Volume 26, Issue 5, pp. 451–52 doi:10.1002/anie.198704511
- ↑ Wolf-Dieter Fessner, Bulusu A. R. C. Murty, Jürgen Wörth, Dieter Hunkler, Hans Fritz, Horst Prinzbach, Wolfgang D. Roth, Paul von Ragué Schleyer, Alan B. McEwen, Wilhelm F. Maier (1987), Dodecahedranes from [1.1.1.1]Pagodanes. Angewandte Chemie International Edition in English, Volume 26, Issue 5, pp. 452–54 doi:10.1002/anie.198704521
