Perfluorobutanesulfonic acid

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Perfluorobutanesulfonic acid
Perfluorobutanesulfonic acid.svg
Names
Preferred IUPAC name
Perfluorobutanesulfonic acid
Systematic IUPAC name
1,1,2,2,3,3,4,4,4-Nonafluorobutane-1-sulfonic acid
Other names
FC-98

Nonaflate
Nonafluorobutanesulphonic acid
Perfluorobutane sulfonate

PFBS
Identifiers
375-73-5 N
59933-66-3 N
ChemSpider 61132 YesY
EC Number 206-793-1
Jmol 3D model Interactive image
PubChem 67815
RTECS number EK5930000
UN number 3094, 3265
  • InChI=1S/C4HF9O3S/c5-1(6,3(9,10)11)2(7,8)4(12,13)17(14,15)16/h(H,14,15,16) YesY
    Key: JGTNAGYHADQMCM-UHFFFAOYSA-N YesY
  • InChI=1S/C4HF9O3S/c5-1(6,3(9,10)11)2(7,8)4(12,13)17(14,15)16/h(H,14,15,16)
    Key: JGTNAGYHADQMCM-UHFFFAOYSA-N
  • OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
Properties
C4HF9O3S
Molar mass 300.10 g/mol
Melting point 76 to 84 °C (169 to 183 °F; 349 to 357 K) [1]
Boiling point 211 °C (412 °F; 484 K)[2]
Vapor pressure {{{value}}}
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references

Perfluorobutanesulfonic acid (PFBS) is a chemical compound with a four carbon fluorocarbon chain and a sulfonic acid functional group. As an anion it functions as a stable fluorosurfactant because of the strength of carbon–fluorine bonds.

PFBS has served as a replacement for the persistent, toxic, and bioaccumulative perfluorooctanesulfonic acid (PFOS) in 3M's Scotchgard stain repellents since June 2003.[3][4] PFBS has a much shorter half-life in people than PFOS (a little over one month vs. 5.4 years).[5] While PFBS is expected to be persistent in the environment, multiple studies indicate that PFBS is neither toxic nor bioaccumulative.[4]

3M markets surfactant with PFBS in two fluorosurfactants.[4]

See also

References

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  2. Perfluorobutanesulfonic acid in the ChemIDplus database
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