Cetane number

Cetane number or CN is an indicator of the combustion speed of diesel fuel. It is an inverse of the similar octane rating for gasoline (petrol). The CN is an important factor in determining the quality of diesel fuel, but not the only one; other measurements of diesel's quality include (but are not limited to) energy content, density, lubricity, cold-flow properties and sulphur content.

Definition

Cetane number or CN is an inverse function of a fuel's ignition delay, and the time period between the start of injection and the first identifiable pressure increase during combustion of the fuel. In a particular diesel engine, higher cetane fuels will have shorter ignition delay periods than lower Cetane fuels. Cetane numbers are only used for the relatively light distillate diesel oils. For heavy (residual) fuel oil two other scales are used CCAI and CII.

In short, the higher the Cetane number the more easily the fuel will combust in a compression setting (such as a diesel engine). The characteristic diesel "knock" occurs when fuel that has been injected into the cylinder ignites after a delay causing a late shock wave. Minimizing this delay results in less unburned fuel in the cylinder and less intense knock. Therefore higher-cetane fuel usually causes an engine to run more smoothly and quietly. This does not necessarily translate into greater efficiency, although it may in certain engines.

Typical values

Generally, diesel engines operate well with a CN from 40 to 55. Fuels with higher cetane number have shorter ignition delays, providing more time for the fuel combustion process to be completed. Hence, higher speed diesel engines operate more effectively with higher cetane number fuels.

In Europe, diesel cetane numbers were set at a minimum of 38 in 1994 and 40 in 2000. The current standard for diesel sold in European Union, Iceland, Norway and Switzerland is set in EN 590, with a minimum cetane index of 46 and a minimum cetane number of 51. Premium diesel fuel can have a cetane number as high as 60.

In North America, most states adopt ASTM D975 as their diesel fuel standard and the minimum cetane number is set at 40, with typical values in the 42-45 range. Premium diesels may or may not have higher cetane, depending on the supplier. Premium diesel often use additives to improve CN and lubricity, detergents to clean the fuel injectors and minimize carbon deposits, water dispersants, and other additives depending on geographical and seasonal needs.. California diesel fuel has a minimum cetane of 53. Under the Texas Low Emission Diesel (TxLED) program there are 110 counties where diesel fuel must have a cetane number of 48 or greater, or else must use an approved alternative formulation or comply with the designated alternative limits.

Additives

Alkyl nitrates (principally 2-ethylhexyl nitrate) and di-tert-butyl peroxide are used as additives to raise the cetane number.

Alternative fuels

Biodiesel from vegetable oil sources have been recorded as having a cetane number range of 46 to 52, and animal-fat based biodiesels cetane numbers range from 56 to 60. Dimethyl ether is a potential diesel fuel as it has a high cetane rating (55-60) and can be produced as a biofuel.

Chemical relevance

Cetane is the chemical compound with chemical formula n-C₁₆H₃₄, today named hexadecane according to IUPAC rules. It is an unbranched alkane, a saturated hydrocarbon chain with no cycles. Cetane ignites very easily under compression, so it was assigned a cetane number of 100, while alpha-methyl naphthalene was assigned a cetane number of 0. All other hydrocarbons in diesel fuel are indexed to cetane as to how well they ignite under compression. The cetane number therefore measures how quickly the fuel starts to burn (auto-ignites) under diesel engine conditions. Since there are hundreds of components in diesel fuel, with each having a different cetane quality, the overall cetane number of the diesel is the average cetane quality of all the components (strictly speaking high-cetane components will have disproportionate influence, hence the use of high-cetane additives).

Measuring cetane number

Accurate measurements of the cetane number are rather difficult, as it requires burning the fuel in a rare diesel engine called a Cooperative Fuel Research (CFR) engine, under standard test conditions. The operator of the CFR engine uses a hand-wheel to increase the compression ratio (and therefore the peak pressure within the cylinder) of the engine until the time between fuel injection and ignition is 2.407ms. The resulting cetane number is then calculated by determining which mixture of cetane (hexadecane) and isocetane (2,2,4,4,6,8,8-heptamethylnonane) will result in the same ignition delay.

Ignition Quality Tester (IQT)

Another reliable method of measuring the derived cetane number (DCN) of diesel fuel is the Ignition Quality Tester (IQT). This instrument applies a simpler, more robust approach to CN measurement than the CFR. Fuel is injected into a constant volume combustion chamber at approximately 575 °C and 310 psi. The time between the start of injection and the recovery of the combustion chamber pressure to 310 psi is defined as the ignition delay. This measured ignition delay is then used to calculate the DCN of the fuel. The fuel's DCN is then calculated using an empirical inverse relationship to ignition delay. Because of the reproducibility, material cost, and speed of the IQT, this has been the definitive source for DCN measurements of fuels since the late 2000s.

Fuel ignition tester

Another reliable method of measuring the derived cetane number of diesel fuel is the Fuel Ignition Tester (FIT). This instrument applies a simpler, more robust approach to CN measurement than the CFR. Fuel is injected into a constant volume combustion chamber in which the ambient temperature is approximately 575 °C. The fuel combusts, and the high rate of pressure change within the chamber defines the start of combustion. The ignition delay of the fuel can then be calculated as the time difference between the start of fuel injection and the start of combustion. The fuel's derived cetane number can then be calculated using an empirical inverse relationship to ignition delay.

Cetane index

Another method that fuel-users control quality is by using the cetane index (CI), which is a calculated number based on the density and distillation range of the fuel. There are various versions of this, depending on whether metric or Imperial units are used, and how many distillation points are used. These days most oil companies use the '4-point method', ASTM D4737, based on density, 10% 50% and 90% recovery temperatures. The '2-point method' is defined in ASTM D976, and uses just density and the 50% recovery temperature. This 2-point method tends to overestimate cetane index and is not recommended. Cetane index calculations can not account for cetane improver additives and therefore do not measure total cetane number for additized diesel fuels. Diesel engine operation is primarily related to the actual cetane number and the cetane index is simply an estimation of the base (unadditized) cetane number.

Industry standards

The industry standards for measuring cetane number are ASTM D-613 (ISO 5165) for the CFR engine, D-6890 for the IQT, and D-7170 for the FIT.

See also

• NExBTL
• Octane rating

External links

• Article by Bruce Hamilton
• Explanation of Cetane from BP