JEE Main 2014 Answer Key Online 11-04-2014
JEE Main 2014 Answer Key Online 11-04-2014
JEE Main 2014 Answer Key Online 11-04-2014
1. A radioactive nuclei with 0.5/s is being produced at a 100 nuclei/s. If at t=0 there the time when there are 50 decay constant constant rate of were no nuclei, nuclei is : is inside the capacitor up to distance x (See figure). If the charge on the capacitor is Q then the force on the dielectric when it is near the edge is
Q 2d K (1) 2wl2 e0
Ans. (3) 2. Match the List - I (Phenomenon associated with electromagnetic radiation) with List - II (Part of electromagnetic spectrum) and select the correct code from the choices given below the lists :
List-I I Double of sodium Wavelength corresponding to temperature associated with the isotropic radiation filling all space A List-II
(2)
Q 2w (K - 1) 2dl2 e0
l
Q 2d (K - 1) (3) 2wl2 e0
(4)
EN
Visible radiation Microwave
Q 2w K 2dl2 e0
Ans. (3) 4. A cone of base radius R and height h is located r in a uniform electric field E parallel to its base. The electric flux entering the cone is :(1) 4EhR (2)
II
1 EhR 2
III
A
IV
LL
C Short radiowave X-rays
(3) EhR (4) 2EhR Ans. (3) 5. Three identical bars A, B and C are made of different magnetic materials. When kept in a uniform magnetic field, the field lines around them look as follows :
(1) (I)-(A), (II)-(B), (III)-(B), (IV)-(C) (2) (I)-(D), (II)-(C), (III)-(A), (IV)-(B) (3) (I)-(A), (II)-(B), (III)-(C), (IV)-(C) (4) (l)-(B), (II)-(A), (III)-(D), (IV)-(A) Ans. (4) 3. A parallel plate capacitor is made of two plates of length l , width w and separated by distance d. A dielectric slab (dielectric constant K) that fits exactly between the plates is held near the edge of the plates. It is pulled into the capacitor by a force F = -
Make the correspondence of these bars with their material being diamagnetic (D) ferromagnetic (F) and paramagnetic (P) (1) AP, BF, CD (2) AF, BP, CD (3) AD, BP, CF (4) AF, BD, CP Ans. (4)
1
EN
(2) Zero
3 cm
5 cm
I = 10 A
LL
(2) 300 K (4) 1000 K
A
(1) 500 K
(4) 3 104 toward right Ans. (4) 11. A body of mass 5 kg under the action of r constant force F = Fx i + Fy j has velocity at
r - 2 j m/s and at t = 10 s as t = 0 s as n = 6i
:-
3 4 (1) i - j N 5 5
( ) - 4 j) N (3) ( 3i
+ 4 j N (2) -3i
(A)
K1 K2 R G S
(B)
K1 K2 S
LL
G R K1
A tank with a small hole at the bottom has been filled with water and kerosene (specific gravity 0.8). The height of water is 3 m and that of kerosene 2 m. When the hole is opened the velocity of fluid coming out from it is nearly : (take g = 10 ms -2 and density of water = 103 kg m3) (1) 7.6 ms-l (2) 9.6 ms1 (3) 10.7 ms 1 (4) 8.5 ms1 Ans. (2) 14. A photon of wavelength l is scattered from an electron, which was at rest. The wavelength shift Dl is three times of l and the angle of scattering q is 60. The angle at which the electron recoiled is f. The value of tan f is : (electron speed is much smaller than the speed of light) (1) 0.28 (2) 0.22 (3) 0.25 (4) 0.16 Ans. (3) 15. The Bulk moduli of Ethanol, Mercury and Water are given as 0.9, 25 and 2.2 respectively in units of 10 9 Nm 2 . For a given value of pressure, the fractional compression in volume 13. is
(C)
A
R S G
K2
(D)
K1
(1) Circuit C with G = S (2) Circuit B with G = S (3) Circuit A with G = (4) Circuit D with G = Ans. (4)
RS (R - S)
RS R -S
EN
about
(1) Water > Ethanol > Mercury (2) Ethanol > Mercury > Water (3) Ethanol > Water > Mercury (4) Mercury > Ethanol > Water Ans. (3) 16. A hot body, obeying Newton's law of cooling is cooling down drom its peak value 80C to an ambient temperature of 30C. It takes 5 minutes in cooling down from 80C to 40C. How much time will it take to cool down from 62C to 32C? (Given ln 2 = 0.693, ln5 = 1.609) (1) 9.6 minutes (2) 6.5 minutes (3) 8.6 minutes (4) 3.75 minutes Ans. (2)
3
21.
A small ball of mass m starts at a point A with speed v0 and moves along a frictionless track AB as shown. The track BC has coefficient of friction m. The ball comes to stop at C after travelling a distance L which is : A
I 60 V
h
(1) 12.5 mA, 5 mA, 7.5 mA (2) 15 mA, 7.5 mA, 7.5 mA (3) 12.5 mA, 7.5 mA, 5 mA (4) 15 mA, 5 mA, 10 mA Ans. (3) 18. An air bubble of radius 0.1 cm is in a liquid having surface tension 0.06 N/m and density 103 kg/m 3. The pressure inside the bubble is 1100 Nm 2 (1) h v2 + 0 2m 2mg
L
(2)
C
2h v2 + 0 m 2mg
pressure. At what depth is the bubble below the surface of the liquid? (g = 9.8 ms2) :(1) 0.1 m (3) 0.15 m Ans. (1) 19. (2) 0.20 m (4) 0.25 m
LL
5W 20 W 10 W 5W 30 V
EN
22. Ans. (2) 23. (1)
2L l 0 L2 3 6M L l 0 L2 2 4M L l 0 L2 + 3 4M L l 0 L2 + 3 8M
h v2 + 0 (4) 2m mg
In a compound microscope the focal length of objective lens is 1.2 cm and focal length of eye piece is 3.0 cm. When object is kept at 1.25 cm in front of objective, final image is formed at infinity. Magnifying power of the compound microscope should be : (1) 400 (2) 200 (3) 100 (4) 150
In the circuit shown, current (in A) through the 50 V and 30 V batteries are, respectively :-
A thin bar of length L has a mass per unit length l, that increases linearly with distance from one end. If its total mass is M and its mass per unit length at the lighter end is l0, then the distance of the centre of mass from the lighter end is :
A
50 V
During an adiabatic compression, 830 J of work is done on 2 moles of a diatomic ideal gas to reduce its volume by 50%. The change in its temperature is nearly : (R = 8.3 JK1mol1) (1) 40 K (3) 33 K (2) 20 K (4) 14 K Ans. (1) (4) (3)
Ans. (2)
4
28.
that the cavity made in the original sphere is between its centre and the periphery. (See figure). For the configuration in the figure where the distance between the centre of the original sphere and the removed sphere is 3R, the gravitational force between the two spheres is :
EN
(1)
59 GM 2 450 R 2 41GM 2 450 R 2
the rifle must be aimed in order to hit the target (1) 4.2 m (3) 1.0 m Ans. (2) 26. (2) 6.1 m (4) 9.8 m
(2)
An object is located in a fixed position in front of a screen. Sharp image is obtained on the screen for two positions of a thin lens separated by 10 cm. The size of the images in two situations are in the ratio 3 : 2. What is the distance between the screen and the object ? (1) 99.0 cm (2) 124.5 cm (3) 144.5 cm (4) 65.0 cm
(3)
(4)
LL
(2)
An electromagnetic wave of frequency 1 1014 hertz is propagating along z-axis. The amplitude of electric field is 4 V/m. If e0 = 8.8 1012 C2/N-m2, then average energy density of electric field will be : (1) 35.2 1012 J/m3
A
resultant pattern is : (1)
(2) 35.2 1013 J/m3 (3) 35.2 1011 J/m3 (4) 35.2 1010 J/m3 Ans. (1) 30. Two factories are sounding their sirens at 800 Hz. A man goes from one factory to other at a speed of 2 m/s. The velocity of sound is 320 m/s. Ihe number of beats heard by the person in one second will be : (1) 8 (2) 4 (4) 2
Two monochromatic light beams of intensity 16 and 9 units are interfering. The ratio of intensities of bright and dark parts of the
4 3
49 1
16 (3) 9
Ans. (2)
7 (4) 1
7.
Given :Fe3+(aq) + e Fe2+ (aq); E = + 0.77 V Al3+(aq) + 3e Al (s); E = 1.66 V Br2(aq) + 2e 2Br ; E = + 1.09 V Considering the electrode potentials, which of the following represents the correct order of reducing power? (1) Al < Fe2+ < Br (2) Al < Br < Fe2+ (4)Br < Fe2+ < Al
Ans. 2.
Ans. 3.
EN
(1) NH3 Ans. (2) 9. as 10. (1) P(CH3)3 (3) (CH3)3N Ans. (2) 11.
OH
White precipitate of AgCl appears on adding which of the following? (2) Aqueous NaCl (4) Aqueous HNO3
Ans. 4.
Tischenko reaction is a modification of (1) Cannizzaro reaction (2) Claisen condensation (3) Pinacol-pinacolon reaction
Ans. 5.
rate
of
LL
reaction was measured
(4) Aldol condensation Ans. (1) Which one of the following does not have a pyramidal shape ? (2) (SiH3)3N (4) P(SiH3)3
d[O 2 ] = -2.5 10-4 mol L 1 s 1 . The rate of dt reaction in terms of [SO2] in mol L1s1 will be (1) 2.50 104 (2) 5.00 104 (3) 1.25 104 (4) 3.75 104 Ans. (2) 6. Based on the equation 1 1 DE = -2.0 10-18 J 2 - 2 n 2 n1 the wavelength of the light that must be absorbed to excite hydrogen electron from level n = 1 to level n = 2 will be (h = 6.625 1034 Js, C = 3 108 ms1) (1) 2.650 107 m (2) 1.325 107 m (3) 1.325 1010 m (4) 5.300 1010 m Ans. (2)
CHO
is known as (1) Perkin reaction (2) Kolbe's reaction (3) Gattermann reaction (4) Gattermann-Koch Formylation Ans. (4)
+ HCCCl3
Cl
(3) Cl
C CH2Cl
Cl
(4) Cl
CH CCl3
Cl
Ans. (4) 13. Shapes of certain interhalogen compounds are stated below. Which one of them is not correctly stated? (1) IF 7 : Pentagonal bipyramid (2) BrF5 : Trigonal bipyramid (3) ICl3 : Planar dimeric (4) BrF 3 : Planar T-shaped Ans. (2) 14. Which one of the following statements is not correct? (1) Alcohols are weaker acids than water
O C H
in methanol is
108.9 (3) Acid strength of alcohols decreases in the following order RCH2OH > R2CHOH > R3COH (4) Carbon-oxygen bond length in methanol, CH3OH is shorter than that of CO bond length in phenol Ans. (4)
Which of the following series correctly represents relations between the elements from X to Y? XY (1) 18Ar 54Xe Noble character increases (2) 3Li 19K Ionization enthalpy increases (3) 6C 32Ge Atomic radii increases (4) 9F 35Br Electron gain enthalpy with negative sign increases Ans. (3) 16. Which of the following statements about the depletion of ozone layer is correct? (1) The problem of ozone depletion is more serious at poles because ice crystals in the clouds over poles act as catalyst for photochemical reactions involving the decomposition of ozone by Cl and ClO radicals (2) The problem of ozone depletion is less serious at poles because NO2 solidifies and is not available for consuming ClO radicals (3) Oxides of nitrogen also do not react with ozone in stratosphere (4) Freons, chlorofluorocarbons, are inert chemically, they do not react with ozone in stratosphere Ans. (1) 17. The initial volume of a gas cylinder is 750.0 mL. If the pressure of gas inside the cylinder changes from 840.0 mm Hg to 360.0 mm Hg, the final volume the gas will be (1) 1.750 L (2) 7.50 L (3) 3.60 L (4) 4.032 L Ans. (1) 18. If l 0 and l be the threshold wavelength and wavelength of incident light, the velocity of photoelectron ejected from the metal surface is 15. (1)
2hc l 0 - l m ll 0
LL
EN
(3) Ans. (1)
(2)
2h 1 1 - m l0 l
2h ( l0 - l ) m
(4)
2hc ( l0 - l ) m
Ans. 20.
Ans. 21.
d[N 2O5 ] d[NO 2 ] = k[N 2O5 ] and + = k[N 2O5 ] dt dt k and k are related as (1) k = k (2) k = 4k (3) 2k = k (4) k = 2k Ans. (3) 24. An organic compound A, C5H8O; reacts with H2O, NH3 and CH3COOH as described below: O H2O CHCOH O NH3 A CHCNH2 O O CH3COOH CHCOCCH3 A is 8
Ans. 23.
LL
EN
Ans. 22.
CH3 Ans. (1) 25. A gaseous compound of nitrogen and hydrogen contains 12.5%(by mass) of hydrogen. The density of the compound relative to hydrogen is 16. The molecular formula of the compound is : (1) NH2 (2) NH3 (3) N3H (4) N2H4 Ans. (4) 26. Assuming that the degree of hydrolysis is small, the pH of 0.1 M solution of sodium acetate (Ka = 1.0 105) will be (1) 5.0 (2) 8.0 (3) 6.0 (4) 9.0 Ans. (4) 27. The reagent needed for converting Ph H PhC CPh C=C Ph H is (1) H2/Lindlar Cat. (2) Cat. Hydrogenation (3) LiAlH4 (4) Li/NH3 Ans. (4) 28. Consider the coordination compound, [Co(NH 3 ) 6 ]Cl 3 . In the formation of this complex, the species which acts as the Lewis acid is : (1) [Co(NH3)6]3+ (2) NH3 (3) Co3+ (4) CI Ans. (3) 29. The correct order of bond dissociation energy among N2, O2, O 2is shown in which of the following arrangements? (1) N2 > O2 > O2 (2) O2> O>N2 2 (3) N2 > O> O2 (4) O> O2 > N2 2 2 Ans. (1) 30. In some solutions, the concentration of H3O+ remains constant even when small amounts of strong acid or strong base are added to them. These solutions are known as :(1) Colloidal solutions (2) True solutions (3) Ideal solutions (4) Buffer solutions Ans. (4)
(2)
p 3
The proposition ~(pv~q)v~(pq) is logically equivalent to (1) ~p (2) ~q (3) p (4) q Ans. (1) 7. If the general solution of the differential 6. equation y =
x y + F , for some function F, x y
p 2
(4) 2 p
2.
is given by y ln |cx| = x, where c is an arbitrary constant, then F (2) is equal to (1) 4 (2) 4 (3)
1 4
(4) -
1 4
EN
(1) (3)
Ans. (4) 8. For the curve y = 3 sin q cos q , x = e qsin q , 0 q p, the tangent is parallel to x-axis when q is
p 2
(2) (4)
3p 4 p 6
11p is equal to 6
p 4
Ans. (3) 9.
LL
3 (2) - - 2 3 2 3 +2 3 2
(4) containing the line (2)
3 -2 3 2
If for n 1, Pn =
(log x)
1
dx , then P 90P 10 8
x y z = = passes through the point 1 1 4 (1) (1, 0, 5) (2) (0, 3, 5) (3) (1, 3, 0) (4) (1, 2, 5) Ans. (1) 5. The volume of the largest possible right circular cylinder that can be inscribed in a sphere of
radius = 3 is (1) 4 p Ans. (1)
is equal to (1) 10e (2) 10 (3) 9 (4) 9e Ans. (4) 10. Let f(x) = x|x|, g(x) = sinx and h(x) = (gof)(x). Then (1) h (x) is differentiable at x = 0 (2) h (x) is continuous at x = 0 but is not differentiable at x = 0 (3) h(x) is differentiable at x = 0 but h(x) is not continuous at x = 0 (4) h(x) is not differentiable at x = 0 Ans. (2) 11. A set S contains 7 elements. A non-empty subset A of S and an element x of S are chosen at random. Then the probability that xA is (1) Ans. (1)
9
4 8 3p (3) 3p (4) 2p 3 3
64 127
(2)
63 128
(3)
1 2
(4)
31 128
If lim
18.
1 2
(2)
46 5
(3) 2
(4)
11 2
q + f = hyperbola
(1) (3)
-11 3 13 2
(2) (4)
-13 2 11 3
Ans. (2) 14. In a geometric progression, if the ratio of the sume of first 5 terms to the sum of their reciprocals is 49, and the sum of the first and the third term is 35. Then the first term of this geometric progression is (1) 42 (2) 28 (3) 21 (4) 7 Ans. (2) 15. Let A {2, 3, 5}, B ( 1, 3, 2) and C(l, 5, m) be the vertices of a DABC. If the median through A is equally inclined to the coordinate axes, then (1) 8l 5m = 0 (2) 10l 7m = 0 (3) 5l 8m = 0 (4) 7l 10m = 0 Ans. (2) 16. The set of all real values of l for which exactly two common tangents can be drawn to the circles x2 + y2 4x 4y + 6 = 0 and x2 + y2 10x 10y + l = 0 is the interval (1) (18, 48) (2) (12, 24) (3) (18, 42) (4) (12, 32) Ans. (3) 17. If z 1 , z 2 and z 3, z 4 are 2 pairs of complex conjugate numbers, then
EN
(1)
(1000)! (50)!(950)! (1000)! (49)!(951)!
Ans. (2) 19. An eight digit number divisible by 9 is to be formed using digits from 0 to 9 without repeating the digits. The number of ways in which this can be done is : (1) 18 (7!) (2) 40 (7!) (3) 36 (7!) (4) 72 (7!) Ans. (3) 20. The coefficient of x50 in the binomial expansion of (1 + x)1000 + x(1 + x)999 + x2(1 + x)998 + ......... + x1000 is (2) (4)
(1001)! (50)!(951)! (1001)! (51)!(950)!
(3)
LL
(2)
Ans. (2) 21. Let L1 be the length of the common chord of the curves x2 + y2 = 9 and y2 = 8x, and L2 be the length of the latus rectum of y2 = 8x then (1) L1 < L2 (2) L1 > L2
L1 (3) L = 2 2
(4) L1 = L2
Ans. (1) 22. The angle of elevation of the top of a vertical tower from a point P on the horizontal ground was observed to be a. After moving a distance 2 metres from P towards the foot of the tower, the angle of elevation changes to b. Then the height (in metres) of the tower is
A
(1) 0
p 2
(3)
3p 2
(4) p
Ans. (1)
10
(1) 4 2 (2) 24 (3) 12 2 (4) 12 Ans. (3) 28. Let A be a 3 3 matrix such that
1 2 3 0 0 1 A 0 2 3 = 1 0 0 0 1 1 0 1 0
260 37
80 37
(2)
80 37
260 37
(3)
(4)
Then A1 is
3 2 1 3 2 0 (1) 1 1 0 0 1 3 0 2 3 (3) 1 1 1 3 1 2 3 0 2 (2) 1 0 1 1 2 3 0 1 1 (4) 0 2 3
p1 (x) p1 (x) p1(x) Let, A(x) = p 2 (x) p 2 (x) p 2 (x) p3 (x) p3 (x) p3 (x)
LL
(4) -280 2 Ans. (2) 25. Let for i = 1, 2, 3 p i(x) be a polynomial of degree 2 in x, pi(x) and pi(x) be the first and second order derivatives of pi(x) respectively.
EN
(1) Ans. (1)
4 3 15
Ans. (2) 29. A stair-case of length l rests against a vertical wall and a floor of a room,. Let P be a point on the stair-case, nearer to its end on the wall, that divides its length in the ratio 1 : 2. If the stair-case begins to slide on the floor, then the locus of P is : (1) An ellipse of eccentricity (2) A circle of radius
3 2
and B(x) = [A(x)]TA(x). Then determinant of B(x) (1) Does not depend on x (2) Is a polynomial of degree 6 in x (3) Is a polynomial of degree 3 in x (4) Is a polynomial of degree 2 in x Ans. (1) 26. The sum of the first 20 terms common between the series 3 + 7 +11 +15 +.....and 1 + 6 + 11 +16 +....., is : (1) 4220 (2) 4020 (3) 4000 (4) 4200 Ans. (2)
l 2 1 2
Ans. (1) 30. Ihe base of an equilateral triangle is along the line given by 3x + 4y = 9. If a vertex of the triangle is (1, 2), then the length of a side of the triangle is : (2)
4 3 5
(3)
2 3 15
(4)
2 3 5
11