Lab 2 - Stoichiometry

NAME: Kat Pierce
STUDENT ID:
QUIZ SECTION:
LAB PARTNER:
1461881
BX
John Redfield
Chem 142 Experiment #2: Stoichiometry I

I. Reaction of Hydrogen Peroxide and Bleach
II. Reaction of Fe2+ with 1,10-Phenanthroline
Grading: 55 pts total (45 pts for this template, 10 pts for notebook pages)
Notebook pages: Purpose/Method section complete? Are they organized and legible? Have you plotted your data as instructed?
Note:
ALL sections of this report MUST be typed. With this and all future Excel-based reports, make sure that
the report prints correctly (graphs, tables, and text boxes are not split across page breaks) before you
turn it in. If you print it and it doesn't look okay, use the tools in Excel to adjust the page breaks and
then re-print the report before submitting it.
By signing below, you certify that you have not falsified data, that you have not plagiarized any part of this lab report, and
that all calculations and responses other than the reporting of raw data are your own independent work. Failure to sign
this declaration will result in 5 points being deducted from your report score.
Signature: Kate Z. Pierce
DATA, CALCULATIONS AND GRAPHS

Part I: Reaction of hydrogen peroxide and bleach
Concentration of stock solutions
Measurement
1
2
3
4
2 pts
Bleach, NaOCl(aq)
6.00
%m/m NaOCl
Hydrogen Peroxide, H2O2(aq)
3.00
% m/m H2O2
Mass of 0.500 mL Bleach, g

0.545
0.544
0.543
0.542
Average Density, g/mL
Density of Bleach, g/ml

1.09
1.09
1.09
1.08
1.09
Type your calculation of the density of bleach using the mass data from measurement #1.
2 pts
0.545 g of bleach/0.500 mL of bleach = 1.09 g/mL
Type your calculation of the average density of bleach using the mass data from all four measurements.
(0.545 g) + (0.544 g) + (0.543 g) + (0.542 g) = 2.17 g

2.17 g / 0.500 mL x 1/4 = 1.09 g/mL
1 pt
Run Number
Run 1
Run 2
Run 3
Run 4
Run 5
Run 6
Run 7
Run 8
Run 9
Run 10
Run 11
mL of Bleach
Grams of Hydrogen Peroxide
mL of Oxygen
Generated
4
4
4
4
4
4
4
4
4
4
4
1.026
1.528
2.033
2.567
3.025
3.502
4.088
4.612
2.53
4.58
5.11
23.4
31.1
44.1
55.6
69.2
72.8
79.2
81.1
58.10
79.10
78.90
Put your Plot of Volume (mL) of O2 vs Mass (g) of H2O2 here. Make your graph big enough to cover this
instruction box so that it is an appropriate size for someone else to read it.
Use the online resources if you need help figuring out how to plot a graph in Excel. (See the
links on the postlab page for this report.)
Title the graph and label the X and Y axis, including the correct units. Be sure to double check
your units and formatting once you print the report.
Using the line tool on the drawing toolbar, draw the three straight lines: 1) best fit for the data
where H2O2 is limiting, 2) best fit for the data where H2O2 is in excess, and 3) a vertical line from
the intersection of lines 1 and 2 down to the x-axis in order to clearly identify the
equivalence/stoichometric point.
4 pts
Indicate on your graph where the H2O2 is the limiting reagent and where it is in excess.
Grams of H2O2 solution at the Eqv Point
3.73
Moles H2O2 at the Eqv Point
3.29E-03
moles
Moles NaOCl at the Eqv Point
3.52E-03
moles
Stoichiometry: moles H2O2/moles NaOCl
1 pt
0.935
1 pts
Type your calculation for the moles of H 2O2 at the equivalence point.
3.73 g of H2O2 solution x 3% concentration of H 2O2 = 0.112 g of H2O2
(1.008 g x 2 mol) + (16.0 g x 2 mol) =34.016 g/mol H 2O2
0.112 g of H2O2 x (1 mol H2O2/34.016 g) = 0.00329 mol of H 2O2
3 pts
Type your calculation for the moles NaOCl at the equivalence point.
1.09 g/mL NaOCl x 4mL of bleach solution = 4.36 g of NaOCl
4.36 g of NaOCl x 6% concentration of NaOCl = 0.262 g of NaOCl
4 pt
0.262 g of NaOCl x (1 mol of NaOCl/74.44 g) = 0.00352
Part II: Iron(II) -Phenanthroline Reaction

Concentration of stock 1,10 phenanthroline solution
Concentration of stock Fe2+ solution
Volume of stock 1,10 phenanthroline solution you obtained
3.60E-03
2.50E-03
M
M
1.00
mL
1 pt
1 pt
Total Volume of Fe2+ added, mL

0
100
200
300
400
500
600
700
800
Absorbance
0
0.044
0.077
0.126
0.18
0.21
0.242
0.245
0.236
Put your Absorbance vs mL Fe2+ here. Make your graph big enough to cover this instruction box so that it is
an appropriate size for someone else to read it.
Use the online resources if you need help figuring out how to plot a graph in Excel. (See the links
on the postlab page for this report.)
Title the graph and label the X and Y axis, including the correct units (Absorbance data is unitless).
Be sure to double check your units and formatting once you print the report.
Using the line tool on the drawing toolbar, draw the three straight lines: 1) best fit for the data
where Fe 2+ is limiting, 2) best fit for the data where Fe 2+ is in excess, and 3) a vertical line from the
intersection of lines 1 and 2 down to the x-axis in order to clearly identify the
equivalence/stoichometric point.
5 pts
Indicate on your graph where the iron is the limiting reagent and where it is in excess.
mL of Fe(II) at the Equivalence Point
550
Moles phen at the Eqv Point

Moles Fe2+ at the Eqv Point
Stoichiometry: moles phen/moles Fe
mL
3.60E-06
moles
1.38E-06
moles
2+
2.60
1 pt
1 pt
Type your calculation of the moles of 1,10 phenanthroline that you transferred to the 50 mL volumetric flask.
3 pts
1mL phen x 3.6 x 10^-3 M of phen = 3.6 x 10^-3 mL

3.6 x 10^-3 mL x 10^-3 L/mL = 3.6 x 10^-9 moles
Type your calculation for the moles Fe2+ at the equivalence point.
3 pts
550 L x 10^-6 L/L = 5.50 x 10^-4 L

5.50 x 10^-4 L x 2.50 x 10^-3 M (concentration of stock Fe2+ solution) = 1.38 x 10^-6
Type your calculation for the ratio of moles of phen to moles of Fe2+.
3.6 x 10^-6 moles of phen / 1.38 x 10^-6 moles of
Fe2+ =
2.61
1 pt
Results and Discussion

Part I
1. The expected stoichiometry is 1:1. How does your result compare (calculate the % error between your mole ratio and the expected value)? Are you
within 5% of this value? (2 pts)
% error = 0.935 - 1 / 1 x 100 = -6.5.
We were 6.5% within the expected stoichiometry.
2. What is your biggest source of error in this part of the experiment? (2 pts)
The biggest source of error may have been measuring out the hydrogen peroxide. We did have a range of grams we could measure for each run, but
the error could have come from hydrogen peroxide dripping on the side of the vial and onto the balance but it wasn't included inside the vial's mass.
.
3. On the basis of the stoichiometry above, predict the other two products (O2 was one of the products) and write a balanced equation for the reaction
between H2O2 and NaOCl. (2 pts)
H2O2 + NaOCl ----> O2 + NaCl + H2O
Part II
1. The expected stoichiometry is 3 phen:1 Fe2+. How does your result compare (calculate the % error between your mole ratio and the expected)?
Are you within 5% of this value? (2 pts)
% error = 2.61 - 3 / 3 x 100 = -13
We were 13% within the expected stoichiometry.
2. What is your biggest source of error in this part of the experiment? (2 pts)
Measurements of Fe2+ solutions may not have been precise enough. Or maybe we swirled the solution too roughly when mixing it before waiting 5
minutes.
Laboratory Waste Evaluation (1 pt)

Laboratory waste is considered anything generated during an experiment that is disposed of down the sewer drain, thrown in the garbage, collected in a
container for disposal by the UW Environmental Health & Safety department, or released into the environment. Based on the written lab procedure and your
actions during the lab, list the identity and approximate amount (mass or volume) of waste that you generated while performing this experiment.
Part 1
4.0 mL x 1.09 g/mL = 4.36 g bleach
4.36 g x 11 runs = 48 g bleach
34.60 g of H2O2 used + 48 g bleach used = 82.6 g waste
Part 2
49 mL deionized water + 1 mL Fe solution = 50. mL
total volume of Fe added: 0.1 mL + 0.2 mL + 0.3 mL + 0.4 mL + 0.5 mL + 0.6 mL + 0.7 mL + 0.8 mL
50. mL + 3.6 mL = 53.6 mL waste
Other
11 kimtech wipes = 6.7 g

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NAME: Kat Pierce

Chem 142 Experiment #2: Stoichiometry I

DATA, CALCULATIONS AND GRAPHS

Hydrogen Peroxide, H2O2(aq)

Mass of 0.500 mL Bleach, g

Density of Bleach, g/ml

0.545 g of bleach/0.500 mL of bleach = 1.09 g/mL

(0.545 g) + (0.544 g) + (0.543 g) + (0.542 g) = 2.17 g

Grams of Hydrogen Peroxide

Grams of H2O2 solution at the Eqv Point

Moles H2O2 at the Eqv Point

Moles NaOCl at the Eqv Point

Stoichiometry: moles H2O2/moles NaOCl

0.262 g of NaOCl x (1 mol of NaOCl/74.44 g) = 0.00352

Part II: Iron(II) -Phenanthroline Reaction

Total Volume of Fe2+ added, mL

mL of Fe(II) at the Equivalence Point

Moles phen at the Eqv Point

1mL phen x 3.6 x 10^-3 M of phen = 3.6 x 10^-3 mL

550 L x 10^-6 L/L = 5.50 x 10^-4 L

Results and Discussion

Laboratory Waste Evaluation (1 pt)

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