Ppo PPS
Ppo PPS
Ppo PPS
Structures
Structures
Polyphenylene Oxide
(PPO)
Polyphenylene Sulfide
(PPS)
Class: Polysulfides
3
Properties
PPO
PPS
Density (g/cm3)
Molecular weight of
repeat unit (g/mol)
Water absorption over 24 hours ( % )
Tensile strength
(MPa)
Tensile modulus
(MPa)
Tensile elongation
(%)
1.06-1.08
92.03
1.31-1.81
109
Test
Method
ASTM D792
-
0.1-0.5
0.02-0.03
ASTM D750
54
66
ASTM D638
3,310
2,480
ASTM D638
20-30
0.6-25
ASTM D638
Ref.: Grene Joseph. Engineering Thermoplastics. [Online]. Available: http://www.csuchico.edu/~jpgreene/itec041/m41_ch07/sld001.htm [Accessed: 18 Jan
2016].
PPO
93
PPS
58-254
Test Method
ASTM D790
2,480
2,400
ASTM D790
110-113
110
ASTM D695
93-96
16
ASTM D256
0.2-0.25
R115
Opaque
Ref.: Mark, James E. Polymer Data Handbook. New York: Oxford University Press 2000.
Grene Joseph. Engineering Thermoplastics. [Online]. Available: http://www.csuchico.edu/~jpgreene/itec041/m41_ch07/sld001.htm [Accessed: 18 Jan
2016].
Ref.: Grene Joseph. Engineering Thermoplastics. [Online]. Available: http://www.csuchico.edu/~jpgreene/itec041/m41_ch07/sld001.htm [Accessed: 18 Jan
2016].
Thermal Properties
Properties
Melting temperature
(tm:oC)
Glass transition
temperature (tg:oC)
Maximum operating
temperature (oC)
Heat-deflection
temperature (oC)
At 0.45 MPa
At 1.8 MPa
PPO
250
PPS
275-290
Test method
ISO 11357-3
110-140
85-90
DSC
80-120
200-230
137
125
390
212-275
ASTM D648
ASTM D648
Ref.: Mark, James E. Polymer Data Handbook. New York: Oxford University Press 2000.
Polyphenylene Oxide ( PPO ) Modified - Properties and Applications - Supplier Data by Goodfellow. [Online]. Available: http://www.azom.com/article.
aspx?ArticleID=1999 [Accessed: 18 Jan 2016].
Noryl modified PPO (Polyphenylene Oxide - Styrene) Specifications. [Online]. Available: http://www.boedeker.com/noryl_p.htm [Accessed: 18 Jan 2016].
.
Polyphenylene Sulfide (PPS) Typical Properties Generic PPS. [Online]. Available: http://plastics.ulprospector.com/generics/41/c/t/polyphenylene-sulfidepps-properties-processing [Accessed: 21 Jan 2016].
Thermal Properties
Properties
PPO
PPS
Test
method
ASTM
D696
Coefficient of
thermal expansion
(x10-6 K-1)
Thermal
conductivity
(W/m K)
Heat of fusion
(kJ/mol)
Heat capacity
(J/mol K)
Flammability rating
60
15-27
0.22
0.084
ASTM
C177
7.416-8.254
4.6-5.5
DSC
13-14
0.112
V-0
V-0
UL94
Ref.: Mark, James E. Polymer Data Handbook. New York: Oxford University Press 2000.
Noryl modified PPO (Polyphenylene Oxide - Styrene) Specifications. [Online]. Available: http://www.boedeker.com/noryl_p.htm [Accessed: 18 Jan 2016].
.
Polyphenylene Sulfide (PPS) Typical Properties Generic PPS. [Online]. Available: http://plastics.ulprospector.com/generics/41/c/t/polyphenylene-sulfidepps-properties-processing [Accessed: 21 Jan 2016].
Ref.: Noryl modified PPO (Polyphenylene Oxide - Styrene) Specifications. [Online]. Available: http://www.boedeker.com/noryl_p.htm [Accessed: 18 Jan 2016].
.
Polyphenylene Sulfide (PPS) Typical Properties Generic PPS. [Online]. Available: http://plastics.ulprospector.com/generics/41/c/t/polyphenylene-sulfidepps-properties-processing [Accessed: 21 Jan 2016].
10
Chemical Properties
Properties
Oxidation resistant
UV Resistant
Chemical Resistant
Acids
Alkalines
Alcohols
Aromatic hydrocarbons
Oils
Halogens
Ketones
PPO
good
fair
PPS
good
fair
good
good
fair
poor
good
poor
fair
poor
good
good
poor
good
good
good
Ref.: Polyphenylene Oxide ( PPO ) Modified - Properties and Applications - Supplier Data by Goodfellow. [Online]. Available: http://www.azom.com/article.
aspx?ArticleID=1999 [Accessed: 18 Jan 2016].
Chemical Resistance Guide at 73F. [Online]. Available: http://www.proplasticsinc.com/chemical_resistance_guide.pdf [Accessed: 21 Jan 2016].
Ryton PPS - Chemical Resistance. [Online]. Available: http://www.solvay.com/en/markets-and-products/featured-products/Ryton-Chemical-Resistance.
html [Accessed: 18 Jan 2016].
11
Electrical Properties
Properties
Dielectric strength
(V/mil)
Dielectric constant
Dissipation factor
Surface resistivity
(Ohm/sq)
Volume resistivity
(Ohm/cm)
PPO
500
PPS
400-450
Test method
ASTM D149
2.7
0.001
ASTM D150
ASTM D150
2x1016
3.00-3.05
0.00060.005
2.5x1015
1017
2.5x1016
ASTM D257
ASTM D257
Ref.: Mark, James E. Polymer Data Handbook. New York: Oxford University Press 2000.
Noryl modified PPO (Polyphenylene Oxide - Styrene) Specifications. [Online]. Available: http://www.boedeker.com/noryl_p.htm [Accessed: 18 Jan 2016].
.
Polyphenylene Sulfide (PPS) Typical Properties Generic PPS. [Online]. Available: http://plastics.ulprospector.com/generics/41/c/t/polyphenylene-sulfidepps-properties-processing [Accessed: 21 Jan 2016].
12
Applications
PPO Applications
Ink catridge
14
PPO Applications
Sterilizable instruments
Seperation membrane
Ref.: Schmeling, N., Konietzny, R., Sieffert, D., Rolling, P. and Staudt, C: Functionalized copolyimide membranes for the separation of gaseous and liquid
mixtures. Beilstein Journal of Organic Chemistry, 6 (2010): 789-800.
Optical Fiber Connector. [Online]. Available: https://en.wikipedia.org/wiki/Optical_fiber_connector [Accessed: 23 Jan 2016]
Plastic Instrument Trays. [Online]. Available: https://www.surgicalinstruments.com/sterilization-trays/plastic-sterilization-trays [Accessed: 23 Jan 2016].15
PPO Applications
Pump impellors
Automotive parts
Instrument panels
Ref.: Automotive Parts Canadien Automotive. [Online]. Available: http://www.canadien.biz/snowblower-maintaining-tips-automotive-parts/automotive-partscanadien-automotive/ [Accessed: 29 Jan 2016].
Instrument Panels. [Online]. Available http://www.paravion.com/products/instrument-panels/ [Accessed: 29 Jan 2016].
Pump Impellor Casting. [Online]. Available: http://www.castingquality.com/casting-products/pump-fittings-casting-casting-products/pump-impeller.html
[Accessed: 29 Jan 2016]
16
PPS Applications
Bobbins
(coil formers)
Thermostat
Terminal blocks
Ref.: Products from Ouge Electronic. [Online]. Available: http://www.globalsources.com/si/AS/Ouge-Electronic/6008846494063/pdtl/Transformer-BobbinsCoilFormer/1061202771.htm/ [Accessed: 23 Jan 2016].
Terminal Blocks. [Online]. Available: http://elecshop.blog.com/terminal-block/ [Accessed: 23 Jan 2016].
Thermostat. [Online]. Available: https://en.wikipedia.org/wiki/Thermostat [Accessed: 23 Jan 2016]
17
PPS Applications
Hairdryers
Flow control
valves
Carburettors
Cooking
appliances
Ref.: Carburettor for a Triumph T100 Racing 1949-50. [Online]. Available: http://amalcarb.co.uk/carburettor-for-a-triumph-t100-racing-paired-with-76ah.html
[Accessed: 23 Jan 2016].
Flow Control Valve. [Online]. Available: http://www.rotexautomation.com/products/Pneumatic_Accessories/FLOW_CONTROL_VALVE.html [Accessed:
23 Jan 2016].
Salon hair equipment Double Side air outlet grill Professional turbo hair dryer, Powerful hair blow dryer with AC motor. [Online]. Available: http://www.
alibaba.com/product-detail/Salon-hair-equipment-Double-Side-air_60252873108.html [Accessed: 23 Jan 2016].
Top 10 Small Appliances. [Online]. Available: http://www.overstock.com/guides/top-10-small-appliances [Accessed: 23 Jan 2016].
18
PPS Applications
Computer components
Dental equipments
Laboratory equipments
References
Mark, James E. Polymer Data Handbook. New York: Oxford University Press 2000.
Schweitzer, Philip A. Mechanical and Corrosion-Resistant Properties of Plastics and
Elastomers. Boca Raton, Florida: CRC Press, 2000.
Nohara, L. B., Nohara, E. L., Moura, A., Goncalves, J. M. R. P., Costa, M. L:, Rezende, M.C.
Study of Crystallization behavior of Poly(Phenylene Sulfide). Cincia e Tecnologia
2, 16 (2006): 104-110.
Grene Joseph. Engineering Thermoplastics. [Online]. Available: http://www.csuchico.edu/
~jpgreene/itec041/m41_ch07/sld001.htm [Accessed: 18 Jan 2016].
Chemical Resistance Guide at 73F. [Online]. Available: http://www.proplasticsinc.com/
chemical_resistance_guide.pdf [Accessed: 21 Jan 2016].
Noryl modified PPO (Polyphenylene Oxide - Styrene) Specifications. [Online]. Available:
http://www.boedeker.com/noryl_p.htm [Accessed: 18 Jan 2016].
Polyphenylene Oxide ( PPO ) Modified - Properties and Applications - Supplier Data by
Goodfellow. [Online]. Available: http://www.azom.com/article.aspx?ArticleID=1999
[Accessed: 18 Jan 2016].
Polyphenylene Oxide PPO. [Online]. Available: http://www.bpf.co.uk/plastipedia/polymers/
PPO.aspx [Accessed: 18 Jan 2016].
Polyphenylene Sulphide PPS. [Online]. Available: http://www.bpf.co.uk/plastipedia/polymers/
PPS.aspx [Accessed: 18 Jan 2016].
20
References
Polyphenylene Sulfide (PPS) Typical Properties Generic PPS. [Online]. Available: http://
plastics.ulprospector.com/generics/41/c/t/polyphenylene-sulfide-pps-propertiesprocessing [Accessed: 21 Jan 2016].
Poly(p-phenylene oxide). [Online]. Available: https://en.wikipedia.org/wiki/Poly(p-phenylene
oxide) [Accessed: 18 Jan 2016].
Poly(p-phenylene sulfide). [Online]. Available: https://en.wikipedia.org/wiki/Poly(p-phenylene
sulfide) [Accessed: 18 Jan 2016].
PPE processing conditions. [Online]. Available: http://www.viewmold.com/Injection%20Mold
%20Management/resin%20processing%20condition/PPE%20processing%20condition.
html [Accessed: 22 Jan 2016].
PPO. [Online]. Available: http://www.matbase.com/material-categories/natural-and-syntheticpolymers/engineering-polymers/material-properties-of-polyphenylene-oxide-ppo.html#
properties [Accessed: 29 Jan 2016].
Ryton PPS - Chemical Resistance. [Online]. Available: http://www.solvay.com/en/markets and-products/featured-products/Ryton-Chemical-Resistance.html [Accessed: 18 Jan
2016].
21