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Polyphenylene Oxide (PPO) &

Polyphenylene Sulfide (PPS)


Properties and Applications
By
Mr. Sirawit Witpathomwong
Polymer Engineering Laboratory
Department of Chemical Engineering
Faculty of Engineering, Chulalongkorn University
1 Feb 2016

Structures

Structures

Polyphenylene Oxide
(PPO)

Polyphenylene Sulfide
(PPS)

Class: Polyether thermoplastics

Class: Polysulfides
3

Properties

Physical and Mechanical Properties


Properties

PPO

PPS

Density (g/cm3)
Molecular weight of
repeat unit (g/mol)
Water absorption over 24 hours ( % )
Tensile strength
(MPa)
Tensile modulus
(MPa)
Tensile elongation
(%)

1.06-1.08
92.03

1.31-1.81
109

Test
Method
ASTM D792
-

0.1-0.5

0.02-0.03

ASTM D750

54

66

ASTM D638

3,310

2,480

ASTM D638

20-30

0.6-25

ASTM D638

Ref.: Grene Joseph. Engineering Thermoplastics. [Online]. Available: http://www.csuchico.edu/~jpgreene/itec041/m41_ch07/sld001.htm [Accessed: 18 Jan
2016].

Physical and Mechanical Properties


Properties
Flexural strength
(MPa)
Flexural modulus
(MPa)
Compressive
strength (MPa)
Notched Impact
Strength(J/m)
Friction coefficient
Hardness
Optical

PPO
93

PPS
58-254

Test Method
ASTM D790

2,480

2,400

ASTM D790

110-113

110

ASTM D695

93-96

16

ASTM D256

0.2-0.25
R115
Opaque

0.09-0.40 ASTM D1894


R123
ASTM D785
Opaque
-

Ref.: Mark, James E. Polymer Data Handbook. New York: Oxford University Press 2000.
Grene Joseph. Engineering Thermoplastics. [Online]. Available: http://www.csuchico.edu/~jpgreene/itec041/m41_ch07/sld001.htm [Accessed: 18 Jan
2016].

Maximum Tensile Strength

Ref.: Grene Joseph. Engineering Thermoplastics. [Online]. Available: http://www.csuchico.edu/~jpgreene/itec041/m41_ch07/sld001.htm [Accessed: 18 Jan
2016].

Thermal Properties
Properties
Melting temperature
(tm:oC)
Glass transition
temperature (tg:oC)
Maximum operating
temperature (oC)
Heat-deflection
temperature (oC)
At 0.45 MPa
At 1.8 MPa

PPO
250

PPS
275-290

Test method
ISO 11357-3

110-140

85-90

DSC

80-120

200-230

137
125

390
212-275

ASTM D648
ASTM D648

Ref.: Mark, James E. Polymer Data Handbook. New York: Oxford University Press 2000.
Polyphenylene Oxide ( PPO ) Modified - Properties and Applications - Supplier Data by Goodfellow. [Online]. Available: http://www.azom.com/article.
aspx?ArticleID=1999 [Accessed: 18 Jan 2016].
Noryl modified PPO (Polyphenylene Oxide - Styrene) Specifications. [Online]. Available: http://www.boedeker.com/noryl_p.htm [Accessed: 18 Jan 2016].
.
Polyphenylene Sulfide (PPS) Typical Properties Generic PPS. [Online]. Available: http://plastics.ulprospector.com/generics/41/c/t/polyphenylene-sulfidepps-properties-processing [Accessed: 21 Jan 2016].

Thermal Properties
Properties

PPO

PPS

Test
method
ASTM
D696

Coefficient of
thermal expansion
(x10-6 K-1)
Thermal
conductivity
(W/m K)
Heat of fusion
(kJ/mol)
Heat capacity
(J/mol K)
Flammability rating

60

15-27

0.22

0.084

ASTM
C177

7.416-8.254

4.6-5.5

DSC

13-14

0.112

V-0

V-0

UL94

Ref.: Mark, James E. Polymer Data Handbook. New York: Oxford University Press 2000.
Noryl modified PPO (Polyphenylene Oxide - Styrene) Specifications. [Online]. Available: http://www.boedeker.com/noryl_p.htm [Accessed: 18 Jan 2016].
.
Polyphenylene Sulfide (PPS) Typical Properties Generic PPS. [Online]. Available: http://plastics.ulprospector.com/generics/41/c/t/polyphenylene-sulfidepps-properties-processing [Accessed: 21 Jan 2016].

Maximum Using Temperature


PPS
PPO

Ref.: Noryl modified PPO (Polyphenylene Oxide - Styrene) Specifications. [Online]. Available: http://www.boedeker.com/noryl_p.htm [Accessed: 18 Jan 2016].
.
Polyphenylene Sulfide (PPS) Typical Properties Generic PPS. [Online]. Available: http://plastics.ulprospector.com/generics/41/c/t/polyphenylene-sulfidepps-properties-processing [Accessed: 21 Jan 2016].
10

Chemical Properties
Properties
Oxidation resistant
UV Resistant
Chemical Resistant
Acids
Alkalines
Alcohols
Aromatic hydrocarbons
Oils
Halogens
Ketones

PPO
good
fair

PPS
good
fair

good
good
fair
poor
good
poor
fair

poor
good
good
poor
good
good
good

Ref.: Polyphenylene Oxide ( PPO ) Modified - Properties and Applications - Supplier Data by Goodfellow. [Online]. Available: http://www.azom.com/article.
aspx?ArticleID=1999 [Accessed: 18 Jan 2016].
Chemical Resistance Guide at 73F. [Online]. Available: http://www.proplasticsinc.com/chemical_resistance_guide.pdf [Accessed: 21 Jan 2016].
Ryton PPS - Chemical Resistance. [Online]. Available: http://www.solvay.com/en/markets-and-products/featured-products/Ryton-Chemical-Resistance.
html [Accessed: 18 Jan 2016].
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Electrical Properties
Properties
Dielectric strength
(V/mil)
Dielectric constant
Dissipation factor
Surface resistivity
(Ohm/sq)
Volume resistivity
(Ohm/cm)

PPO
500

PPS
400-450

Test method
ASTM D149

2.7
0.001

ASTM D150
ASTM D150

2x1016

3.00-3.05
0.00060.005
2.5x1015

1017

2.5x1016

ASTM D257

ASTM D257

Ref.: Mark, James E. Polymer Data Handbook. New York: Oxford University Press 2000.
Noryl modified PPO (Polyphenylene Oxide - Styrene) Specifications. [Online]. Available: http://www.boedeker.com/noryl_p.htm [Accessed: 18 Jan 2016].
.
Polyphenylene Sulfide (PPS) Typical Properties Generic PPS. [Online]. Available: http://plastics.ulprospector.com/generics/41/c/t/polyphenylene-sulfidepps-properties-processing [Accessed: 21 Jan 2016].
12

Applications

PPO Applications

Ink catridge

Washing & Disk washing machine part

Ref.: Dishwashers. [Online]. Available: http://www.kirbysupply.com/Equipment/Work_Area_Equipment/Cat_Listings/Dishwashers.htm) [Accessed: 23 Jan 2016]


Poly(p-phenylene oxide). [Online]. Available: https://en.wikipedia.org/wiki/Poly(p-phenylene oxide) [Accessed: 18 Jan 2016].
Washing Machines. [Online]. Available: http://cambridgeqatar.com/washing-machine/ [Accessed: 23 Jan 2016].

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PPO Applications

Fiber optic connectors

Sterilizable instruments

Seperation membrane

Ref.: Schmeling, N., Konietzny, R., Sieffert, D., Rolling, P. and Staudt, C: Functionalized copolyimide membranes for the separation of gaseous and liquid
mixtures. Beilstein Journal of Organic Chemistry, 6 (2010): 789-800.
Optical Fiber Connector. [Online]. Available: https://en.wikipedia.org/wiki/Optical_fiber_connector [Accessed: 23 Jan 2016]
Plastic Instrument Trays. [Online]. Available: https://www.surgicalinstruments.com/sterilization-trays/plastic-sterilization-trays [Accessed: 23 Jan 2016].15

PPO Applications

Pump impellors

Automotive parts

Instrument panels

Ref.: Automotive Parts Canadien Automotive. [Online]. Available: http://www.canadien.biz/snowblower-maintaining-tips-automotive-parts/automotive-partscanadien-automotive/ [Accessed: 29 Jan 2016].
Instrument Panels. [Online]. Available http://www.paravion.com/products/instrument-panels/ [Accessed: 29 Jan 2016].
Pump Impellor Casting. [Online]. Available: http://www.castingquality.com/casting-products/pump-fittings-casting-casting-products/pump-impeller.html
[Accessed: 29 Jan 2016]

16

PPS Applications

Bobbins
(coil formers)

Thermostat

Terminal blocks

Ref.: Products from Ouge Electronic. [Online]. Available: http://www.globalsources.com/si/AS/Ouge-Electronic/6008846494063/pdtl/Transformer-BobbinsCoilFormer/1061202771.htm/ [Accessed: 23 Jan 2016].
Terminal Blocks. [Online]. Available: http://elecshop.blog.com/terminal-block/ [Accessed: 23 Jan 2016].
Thermostat. [Online]. Available: https://en.wikipedia.org/wiki/Thermostat [Accessed: 23 Jan 2016]

17

PPS Applications
Hairdryers

Flow control
valves

Carburettors

Cooking
appliances

Ref.: Carburettor for a Triumph T100 Racing 1949-50. [Online]. Available: http://amalcarb.co.uk/carburettor-for-a-triumph-t100-racing-paired-with-76ah.html
[Accessed: 23 Jan 2016].
Flow Control Valve. [Online]. Available: http://www.rotexautomation.com/products/Pneumatic_Accessories/FLOW_CONTROL_VALVE.html [Accessed:
23 Jan 2016].
Salon hair equipment Double Side air outlet grill Professional turbo hair dryer, Powerful hair blow dryer with AC motor. [Online]. Available: http://www.
alibaba.com/product-detail/Salon-hair-equipment-Double-Side-air_60252873108.html [Accessed: 23 Jan 2016].
Top 10 Small Appliances. [Online]. Available: http://www.overstock.com/guides/top-10-small-appliances [Accessed: 23 Jan 2016].
18

PPS Applications

Computer components

Submersible pump enclosures

Dental equipments

Laboratory equipments

Ref.: Dental Equipment. [Online]. Available: https://www.linkedin.com/topic/dental-equipment [Accessed: 29 Jan 2016].


Five Health Destroying Frankenfoods. [Online]. Available: http://kimberlysnyder.com/blog/2012/12/16/five-health-destroying-frankenfoods-2/ [Accessed:
29 Jan 2016].
How Computers Work. [Online]. Available: http://www.carnegiecyberacademy.com/facultyPages/computer/computers.html [Accessed: 29 Jan 2016].
Submersible. [Online]. Available: http://www.arayawell.com/Default.aspx?pageid=9 [Accessed: 29 Jan 2016].
19

References
Mark, James E. Polymer Data Handbook. New York: Oxford University Press 2000.
Schweitzer, Philip A. Mechanical and Corrosion-Resistant Properties of Plastics and
Elastomers. Boca Raton, Florida: CRC Press, 2000.
Nohara, L. B., Nohara, E. L., Moura, A., Goncalves, J. M. R. P., Costa, M. L:, Rezende, M.C.
Study of Crystallization behavior of Poly(Phenylene Sulfide). Cincia e Tecnologia
2, 16 (2006): 104-110.
Grene Joseph. Engineering Thermoplastics. [Online]. Available: http://www.csuchico.edu/
~jpgreene/itec041/m41_ch07/sld001.htm [Accessed: 18 Jan 2016].
Chemical Resistance Guide at 73F. [Online]. Available: http://www.proplasticsinc.com/
chemical_resistance_guide.pdf [Accessed: 21 Jan 2016].
Noryl modified PPO (Polyphenylene Oxide - Styrene) Specifications. [Online]. Available:
http://www.boedeker.com/noryl_p.htm [Accessed: 18 Jan 2016].
Polyphenylene Oxide ( PPO ) Modified - Properties and Applications - Supplier Data by
Goodfellow. [Online]. Available: http://www.azom.com/article.aspx?ArticleID=1999
[Accessed: 18 Jan 2016].
Polyphenylene Oxide PPO. [Online]. Available: http://www.bpf.co.uk/plastipedia/polymers/
PPO.aspx [Accessed: 18 Jan 2016].
Polyphenylene Sulphide PPS. [Online]. Available: http://www.bpf.co.uk/plastipedia/polymers/
PPS.aspx [Accessed: 18 Jan 2016].
20

References
Polyphenylene Sulfide (PPS) Typical Properties Generic PPS. [Online]. Available: http://
plastics.ulprospector.com/generics/41/c/t/polyphenylene-sulfide-pps-propertiesprocessing [Accessed: 21 Jan 2016].
Poly(p-phenylene oxide). [Online]. Available: https://en.wikipedia.org/wiki/Poly(p-phenylene
oxide) [Accessed: 18 Jan 2016].
Poly(p-phenylene sulfide). [Online]. Available: https://en.wikipedia.org/wiki/Poly(p-phenylene
sulfide) [Accessed: 18 Jan 2016].
PPE processing conditions. [Online]. Available: http://www.viewmold.com/Injection%20Mold
%20Management/resin%20processing%20condition/PPE%20processing%20condition.
html [Accessed: 22 Jan 2016].
PPO. [Online]. Available: http://www.matbase.com/material-categories/natural-and-syntheticpolymers/engineering-polymers/material-properties-of-polyphenylene-oxide-ppo.html#
properties [Accessed: 29 Jan 2016].
Ryton PPS - Chemical Resistance. [Online]. Available: http://www.solvay.com/en/markets and-products/featured-products/Ryton-Chemical-Resistance.html [Accessed: 18 Jan
2016].

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Thank you for your attention

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