Introduction To Chrome Plating
Introduction To Chrome Plating
Introduction To Chrome Plating
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Home/Sitemap Search the Site you are here: FAQs => Intro to Chrome Plating
Hard Chrome Plating? Show Chrome? Triple Chrome? Nickel Chrome? Black Chrome? Color chrome? Hex Chrome / Tri Chrome?
What is 'Chrome'
Chrome is slang for Chromium, one of the 91 naturally occurring chemical elements. Chrome is a metal, but it is not useful as a solid, pure substance. Things are never made of solid chrome. Rather, when you hear that something is chrome, what is really meant is that there is a thin layer of chrome, a plating of chrome, on the object (the bulk of the object usually being steel, but occasionally aluminum, brass, copper, plastic, or stainless steel).
A cause of occasional confusion is the fact that people may tend to describe any shiny finish as "chrome" even when it really has nothing to do with chromium. For example, brightly polished aluminum motorcycle parts, electropolished stainless steel boat rigging, vacuum metallized balloons and helmets, shiny painted wheels, and nickel plated oven racks are sometimes called 'chrome' by the lay person. Indeed it's not always easy to tell chrome plating from other finishes if the parts are not side by side. When a decorative chrome electroplated finish sits right next to another bright finish, however, the other finish usually won't compare very favorably :-) Chrome plating is more reflective (brighter), bluer (less pale, grayish, or yellowish), and more specular (the reflection is deeper, less distorted, more like a mirror) than other finishes. Put one end of a yardstick against a bright finish, and see how many inches of numbers you can clearly read in the reflection -- you can clearly see the clouds in the sky reflected in chrome plating. And there's a hard to define "glint" to top quality chrome plating that nothing else has.
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What's the difference between "Chrome Plating", "Chrome Electroplating", "Chrome Dipping", "Chroming", etc.?
Nothing. Chrome is always applied by electroplating, it is never melted onto parts in the fashion of chocolate on strawberries, or applied in any other way than by electroplating. Note the previous paragraph, though, that everything that is somewhat bright is not necessarily chrome.
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The chrome plating is exceptionally thin, measured in millionths of an inch om w. A B B Y Y . c rather than in thousandths.
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When you look at a decorative chrome plated surface, such as a chrome plated wheel or truck bumper, most of what you are seeing is actually the effects of the nickel plating. The chrome adds a bluish cast (compared to the somewhat yellowish cast of nickel), protects the nickel against tarnish, minimizes scratching, and symbiotically contributes to corrosion resistance. But the point is, without the brilliant leveled nickel undercoating, you would not have a reflective, decorative surface. By the way, there is no such thing as "decrotif chrome plating". That is just a misspelling of 'decorative'.
To do chrome plating you must first do nickel plating, and this book has a great chapter on nickel . . .
The Canning Handbook: Surface Finishing Technology Almost impossible to find, but it's the real deal for plating on plastic . . .
Standards and Guidelines for Electroplated Plastics, ASEP More for the researcher than for the amateur plater . . .
Electrodeposition, the Materials Science of Coatings and Substrates, Jack W. Dini Practical treatment
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Experts argue whether copper plating provides any additional corrosion resistance at all, but with or without copper plating, chrome on top of a single thin layer of nickel will not hold up to the severe exposure of a vehicle! Industry professionals call the two layers of nickel "duplex nickel plating", and that would be a much better term to use than "triple chrome" and such.
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Color Chrome
With the exception of Black Chrome plating, there is no such thing as colored chrome. Rather, those colored coatings are translucent paints applied over a layer of tiny aluminum flakes, and should be called "chrome-look paint"; more on this later. Some "black chrome" is probably "chrome-look paint", but real black chrome plating is achieved with a contaminant that turns the metal smoky grey or fully black. Black chrome can be a decorative finish for automobile parts, or a matte finish for non reflective coatings on microscopes and optical equipment, or a great coating for solar collectors. We have an excellent podcast interview about black chrome.
Restoration Work
Chrome plating is hardly a matter of dipping an article into a tank, it is a long involved process that often starts with tedious polishing and buffing, then cleaning and acid dipping, zincating (if the part is aluminum), and copper plating. For top reflectivity "Show Chrome", this will be followed by buffing of the copper for perfect smoothness, cleaning and acid dipping again, and plating more copper, then two or three different types of nickel plating, all before the chrome plating is done. Rinsing is required between every step. When an item needs "rechroming", understand what is really involved: stripping the chrome, stripping the nickel (and the copper if applicable), then polishing out all of the scratches and blemishes (they can't be plated over and any scratches will show after plating), then plating with copper and "mush buffing" to squash copper into any tiny pits, then starting the whole process described above. Unfortunately, simply replating an old piece may cost several times what a replacement would cost. It's the old story of labor cost. The new item requires far less prep work, and an operator or machine can handle dozens of identical parts at the same time whereas a mix of old parts cannot be processed simultaneously, but must be processed one item at a time. If a plater has to spend a whole day on your parts, don't expect it to cost less than what a plumber or mechanic would charge you for a day of their time. Follow the link if you're looking for a list of some chrome plating shops serving the public.
Peeling chrome?
If your chrome plating is peeling, this is virtually always a manufacturing defect due to insufficient
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adhesion of the plating to the substrate. Although exposure conditions can certainly harm chrome, and w om w. discolor it or make it pit, they won't make it peel! It can be very difficult for a plating shop to get good A B B Y Y.c adhesion on some things (most commonly on alloy wheels because they are not pure aluminum), but if they can't do it they shouldn't sell it. If your parts have peeling chrome, you should complain and not be deterred by nonsense about chemicals in your garage, how frequently you wash the wheels, etc. We'll say it again, we're that sure: peeling chrome is virtually always a manufacturing defect.
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Do it yourself?
The best way to chrome plate something might be to take it to a chrome plating shop. The industry is very 'job shop' oriented, with experienced people ready to handle your parts. Before thinking seriously about doing it yourself, here's some food for thought--
Regulations
Electroplating was our nation's very first categorically regulated industry. So, what does "categorically regulated" mean? It means that all of the waste products from this industry -- even very dilute rinse water -- are, as a matter of law, regulated, even if the particular substance is so dilute that it is actually harmless. Mix the waste in with other waste, and the whole mass is by law hazardous waste (see EPA 'mixture rule'). Make another product from it and (with some exception) the product is hazardous waste (see EPA 'derived from' rule).
Water and Waste Control for the Plating Shop, Kushner & Kushner
In turn this means you can't discharge a drop of hose water without pretreatment and permits; it means you can't take your bad solution anywhere without hazardous waste manifesting; it means you can't accumulate it without permits either. Finally, it means you are legally responsible for it forever regardless of how much you spend to get rid of it. But are you subject to these regulations? If you are selling plated parts or plating services, absolutely! See EPA CFR431 and try to find an exception -- you won't. If you are doing it solely as a hobby, maybe you can get away with it if you stay lucky. But if the sewer authority wants to impose an assessment for upgrading the piping, and your neighbors know that you are plating, they will probably turn you in in a heartbeat. Read the fine print on your sewer agreement: you're forbidden from putting these wastes down the drain and both your neighbors and the sewer authority would dearly love for you to have to bear the cost of repairs or upgrades. Is it likely to happen? Probably not. Can it happen? Yes.
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Chromic Acid
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Chrome plating is done in very highly concentrated (about 32 oz./gal) chromic acid, H2CrO4 -- "hexavalent chromium" -- the stuff that made Erin Brockovich a household word. If a neighborhood child develops cancer from any cause whatsoever and his/her parents find out that you were chrome plating, God help you. Factories that use this stuff require exhaust scrubbing, they require fume suppressants that are monitored every day. The workers require medical surveillance (frequent blood tests for absorbed chromium). If you do illegally dispose of chromic acid you will probably be caught because it leaches through the ground very readily and turns up in the aquifer, and it is not only easily detectable but it's visible at 1 part in a million, and all wells and water supplies are monitored for chrome. Dropped a beaker on the garage floor? That could be enough to poison all of the wells for a few city blocks in every direction, and you do not have "pollution insurance" in your homeowner's policy. On top of all this, many city councils have a written or de facto ban on chrome plating. Finally, chrome plating is notorious for hydrogen embrittlement. If you don't know how to immediately and properly bake the parts to relieve the embrittlement, you can turn hardened steel parts like springs, steering linkage, and fasteners into brittle glass.
Alternatives
There are things that are easier and safer than chrome plating. If your parts are aluminum, you could learn to polish; polished aluminum can look very good indeed! If you want an easier route to brightness than chrome plating, the new generation of "chrome-look paint" is much better than what was available even a few years ago. And you can put translucent layers on top of the shiny metallic layer to give a red chrome or blue chrome look. Want to know more about new-generation Chrome-look paint? . . .
If you insist on real electroplating, there are newer proprietary plating processes based on other metals and alloys like tin-cobalt that are still electroplating, and can still get you in trouble, but at least they don't carry the baggage of carcinogenic hexavalent chrome. Another possibility is trivalent chrome plating (this is a somewhat safer and more environmentally friendly approach to electroplating chromium than the traditional hex chrome, but the color is a bit darker and less blue). Most OEMs have not adopted trivalent chrome yet, and parts cannot be mixed because the color is a bit off.
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Think about this: suppose you wanted to open a restaurant without ever having worked in one. Although it might be a risky business, at least you've spent countless hours in hundreds of restaurants in your life. So you know what a menu is and what appetizers and soups and salads and entrees and desserts are. And coffee and tea and soft drinks. You know what a hostess is and what she does. You know what a waiter or waitress is, what the cook does, what the busboys do, what the dishwasher does. You know about tables and chairs and tablecloths and silverware and glassware and dishes, pots and pans, stoves and ovens. You know about flowers and candles and romantic music and soft lighting. And vending machines, restroom requirements, no-smoking areas. You know about insects and vermin, and that you need to cook pork and eggs thoroughly. You'd recognize food poisoning or a customer choking. You know all these things from a lifetime of experience and and take them for granted. Now, what equivalent knowledge do you have about chrome plating shops? If you've haven't spent significant time in a plating shop, you may be unprepared to even imagine what the issues are. So if you are interested in the chrome plating business, you need to read a couple of books from our "must have" book list, subscribe to a couple of journals to begin acquiring a feel for the industry, start attending monthly meetings of the AESF and a few conferences and exhibitions, take a plating course through AESF (www.nasf.org) or Kushner Electroplating School. and visit a few chrome plating shops.
Eastwood Electroplating System - Tin Zin ... $59.99 12h 50m View all disclaimer
But the best way to learn chrome plating is to work in a chrome plating shop for a little while. Think of it this way: if you aren't qualified to land a job as a journeyman in a plating shop due to lack of experience, are you really ready to compete in that business against the shop's supervisors and boss and their lifetime of experience? Why not get some hands-on training while someone else pays for your mistakes? We're NOT saying you should not take the dare and grab for a piece of the American dream -- PLEASE DO! This industry needs new blood! But educate yourself as well as possible first to give yourself a fighting chance at a successful business. Good luck! Please feel free to ask specific questions on our Hotline-Letters page! In your inquiry please tell us that you've already read this page, as that will save time and lost motion. Good luck! Back to finishing.com Home Page --> Save This Page del.icio.us
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