Review of Lecture 5 The Quantum Harmonic Oscillator

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Review of Lecture 5 The Quantum Harmonic Oscillator:

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Potential:

1 V (x) = m 2 x2 2

The ladder operators: Raising operator: 1 a+ = (ip + m x) 2m h Lowering operator: 1 a = (ip + m x) 2m h Denition of commutator: [A, B] = AB BA Canonical commutation relation: [x, p] = ih The ground (lowest) solution of the time-independent Schrdinger equation for the harmonic oscillator is: 0 (x) = m 1/4 m x2 h e 2 h 1 E0 = h 2

To nd all other functions we can use n (x) = An (a+ )n 0 (x). The possible energies are: En = n +
&

1 h 2

Exercise 5
Find the rst excited state of the harmonic oscillator. Useful integrals:
0

x2n ex
0

2 /a2

dx =

(2n)! a n! 2 dx =

2n+1

x2n+1 ex

2 /a2

n! 2n+2 a 2

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You can also get the normalization algebraically using

Then,

Therefore, the normalization constant An is

Other useful formulas:

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The Harmonic Oscillator: The Analytic Method


We now solve the Schrdinger equation for the harmonic oscillator directly:

Change variables for convenience:

Therefore, we look for solutions in the form

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We look for solutions in the form of a power series

The coefcient of each power of must vanish:

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Problem: not all solutions are normalizable

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We have recovered our previous result that was obtained using the algebraic method! Note: the condition above will terminate either odd or even power series; the other must be zero from the start. How do we generate the wave functions?

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Apart from the overall factor (a0 or a1 ) the polynomials hn ( ) are the so-called Hermite polynomials Hn ( ). By tradition, the arbitrary multiplicative factor is chosen so that the coefcient of the highest power of is 2n . With this convention, the normalized stationary states for the harmonic oscillator are

Summary The Quantum Harmonic Oscillator: The Analytic Method


Our mission: Solve
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h 2 d2 1 + m 2 x2 = E 2m dx2 2

(1)
$

Step 1: Change variables m x h 2E K h (2)


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Resulting equation: d2 = ( 2 K ) d 2
&

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Step 2: Determine the solution for and separate out the resulting 2 function e /2 . 2 ( ) = h( )e /2 Resulting equation: dh d2h 2 + (K 1)h = 0 2 d d
& '

(3)
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Step 3: Look for solutions of this equation (Equation 3) in the form of a power series: h( ) = a0 + a1 + a2 2 + . . . = Resulting equation: Recursion formula a j+2 =
& '
j=0

a j j

(2 j + 1 K ) aj ( j + 1)( j + 2)

(4)
% $

Step 4: Need to truncate

j=0

a j j somewhere to ensure that all solutions are


an+2 = 0

normalizable. Thus the power series must terminate, i.e.

for some n = jmax . Resulting equation: K = 2n + 1 1 h En = n + , n = 0, 1, 2, . . . 2


& ' % $

Step 5: Put it all together and generate the wave functions n (x) =
&

m h

1/4

2 1 Hn ( )e /2 2n n!

where Hn are Hermite polynomials.

As expected, we get the same result as before using a operators.

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Note that the probability of nding the particle outside of the classically allowed regions is not zero. The potential energy curve represents the classically-allowed maximum displacement of the oscillator. All the wave functions extend beyond the curve.
1 2 2 2 Classically, the energy of the oscillator is E = 1 2 Ka = 2 m a , where a is the amplitude.

Only for large n do we see some resemblance to the classical case:

Computer simulation: http://www.falstad.com/mathphysics.html, 1D Quantum mechanics applet, Harmonic oscillator

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