Material Safety Data Sheet

Version: 1.8
03/28/2008

SS4004P 01P-Bottle (0.900 LBS-0.409 KG)

Silicone primer solution
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufactured By:

Revised:
Preparer:
CHEMTREC

Waterford Plant
260 Hudson River Rd
Waterford NY 12188
03/28/2008
PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
1-800-424-9300

Chemical Family/Use:
Formula:

Silicone Primer
Silicone resin in solvent(s)

HMIS
Flammability:

Reactivity:

Health:

NFPA
Flammability:

Reactivity:

Health:

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING! Flammable liquid and vapor. Irritating to eyes, respiratory system and skin. Harmful by
inhalation, in contact with skin and if swallowed. May cause adverse liver, kidney, and CNS effects.
Form: Liquid
Color: pink
Odor: Pungent/Solvent
POTENTIAL HEALTH EFFECTS
INGESTION
Harmful if swallowed. Irritation of the mouth, throat, and stomach. Liver and kidney injuries may
occur. Aspiration hazard if swallowed - can enter lungs and cause damage. Causes vomiting,
nausea, and diarrhea. May cause central nervous system effects.
SKIN
Harmful if absorbed through the skin. Causes drying of the skin. May be absorbed through the skin
and contribute to the symptoms listed under "Ingestion". May cause moderate skin irritation.
INHALATION
Harmful if inhaled. Causes irritation of the mouth, nose, and throat. Symptoms of overexposure may
be headache, dizziness, tiredness, nausea and vomiting. Can cause unconsciousness if inhaled.
Coughing, chest pains, and breathing difficulty may occur. Massive inhalation immediately dangerous
to life and health.
EYES
Blurred vision May cause severe eye irritation. Causes redness and tearing. May cause corneal
injury.
MEDICAL CONDITIONS AGGRAVATED
Respiratory disorder Central nervous system disorders. Gastrointestinal disorders. Eye disorders.

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Material Safety Data Sheet

Version: 1.8
03/28/2008

SS4004P 01P-Bottle (0.900 LBS-0.409 KG)

Silicone primer solution

Pre-existing liver or kidney disorders. Skin disorders.

SUBCHRONIC (TARGET ORGAN )
Respiratory disorder; Dermatitis; Central nervous system damage.; Liver and kidney damage.;
Eye damage.; Anemia; Effect on adrenal glands; Effect on the heart.; Over exposure may result
in cardiac abnormality.; This product contains a component that is tumorigenic.; Laboratory rats
exposed to prolonged high xylene concentrations suffered hearing loss. Rats exposed to xylene
vapor during pregnancy have shown embryo/fetotoxic effects. Mice exposed orally to doses of
xylene which produced maternal toxicity have also shown embryo/fetotoxic effects.; This product
contains a component which is considered a teratogen or embryotoxin under the Canadian
WHMIS act.
CHRONIC EFFECTS / CARCINOGENICITY
This product or one of its ingredients present at 0.1% or more is listed as a carcinogen or
potential carcinogen by NTP, IARC or OSHA X Yes ___ No In a National Toxicology Program
(NTP) 2-year study of Ethylbenzene in rats and mice, there was clear evidence of carcinogenic
activity in male rats, based on increased incidence of renal tubule neoplasms and testicular
adenoma. There was some evidence of carcinogenic activity in female rats, based on increases
of renal tubule adenoma. In mice, there was also some evidence of carcinogenic activity based
on increased incidence of alveolar/bronchiolar neoplasms and hepatocellular neoplasms for
males and females, respectively.
ROUTES OF EXPOSURE
Inhalation; Dermal; Eyes; Oral.

3. COMPOSITION / INFORMATION ON INGREDIENTS

PRODUCT COMPOSITION

CAS REG NO.

WGT. %

acetone
n-BUTANOL
Xylene Isomers Mixture
Ethylbenzene
2-Propanol
Tetraethyl Silicate

67-64-1
71-36-3
1330-20-7
100-41-4
67-63-0
78-10-4

10 - 30 %
1-5%
10 - 30 %
5 - 10 %
10 - 30 %
1-5%

B. NON-HAZARDOUS
Polyalkylsiloxane

68037-74-1

10 - 30 %

A. HAZARDOUS

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Material Safety Data Sheet

Version: 1.8
03/28/2008

SS4004P 01P-Bottle (0.900 LBS-0.409 KG)

Silicone primer solution
4. FIRST AID MEASURES
INGESTION
Call a physician or Poison Control Centre immediately. Do NOT induce vomiting. Never give
anything by mouth to an unconscious person. If victim is conscious, give 2-4 glasses of water.
Never induce vomiting unless specifically directed by qualified medical personnel.
SKIN
Wash with soap and water. Get medical attention if irritation or symptoms from Section 3
develop.
INHALATION
If inhaled, remove to fresh air. If not breathing give artificial respiration using a barrier device. If
breathing is difficult give oxygen. Get medical attention.
EYES
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention if irritation persists.
NOTE TO PHYSICIAN
Treatment is symptomatic and supportive.

5. FIRE-FIGHTING MEASURES
FLASH POINT:
METHOD:
IGNITION TEMPERATURE:
FLAMMABLE LIMITS IN AIR - LOWER (%):
FLAMMABLE LIMITS IN AIR - UPPER (%):

-12.00 C; 10 F
closed cup
> 538 C; 1000 F
2.10 %(V).
12.00 %(V).

SENSITIVITY TO MECHANICAL IMPACT:

No

SENSITIVITY TO STATIC DISCHARGE

Sensitivity to static discharge is expected; material has a flash point below 200 F.
EXTINGUISHING MEDIA
Carbon dioxide (CO2), Dry chemical, Alcohol foam, Use water to dilute spills and flush away from
sources of ignition.
SPECIAL FIRE FIGHTING PROCEDURES
Extremely flammable., Pressure inside container is increased when heated, and may cause
explosion., Vapors may form explosive mixture with air., Evacuate area and fight fire from a safe
distance., Firefighters must wear NIOSH/MSHA approved positive pressure self-contained
breathing apparatus with full face mask and full protective clothing., Fire may produce poisonous
or irritating gas, fumes, or vapor., Dangerous when exposed to heat or flame., Vapors may
concentrate in confined areas.

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Material Safety Data Sheet

Version: 1.8
03/28/2008

SS4004P 01P-Bottle (0.900 LBS-0.409 KG)

Silicone primer solution

6. ACCIDENTAL RELEASE MEASURES

ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Wear proper protective equipment as specified in the protective
equipment section. Warn other workers of spill. Increase area ventilation. Person not trained should
evacuate area. Wipe, scrape, or soak up in an inert material and put in a container intended for
flammable materials for disposal.

7. HANDLING AND STORAGE

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Use only in well-ventilated areas. Use ground strap and appropriate precautions for dispensing
flammable liquids. Use only spark-proof and explosion-proof tools and equipment. Avoid contact with
skin and eyes. Avoid inhalation of vapour or mist.
STORAGE
Store away from heat, sources of ignition, and incompatibles. Keep container tightly closed. Keep out
of the reach of children.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

ENGINEERING CONTROLS
Eyewash stations; Showers; Exhaust ventilation
RESPIRATORY PROTECTION
If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Supplied air respirators may be required for non-routine or
emergency situations. Respiratory protection must be provided in accordance with OSHA regulations
(see 29CFR 1910.134).
PROTECTIVE GLOVES
Impermeable or chemical resistant gloves.
EYE AND FACE PROTECTION
Monogoggles.; Face-shield
OTHER PROTECTIVE EQUIPMENT
Wear suitable protective clothing and eye/face protection.

Exposure Guidelines

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Material Safety Data Sheet

Version: 1.8
03/28/2008

SS4004P 01P-Bottle (0.900 LBS-0.409 KG)

Silicone primer solution
Component
acetone
acetone
acetone
acetone
acetone
acetone
n-BUTANOL
n-BUTANOL
n-BUTANOL
n-BUTANOL
Ethylbenzene
Ethylbenzene
Ethylbenzene
2-Propanol
2-Propanol
2-Propanol
2-Propanol
2-Propanol
Xylene Isomers
Mixture
Xylene Isomers
Mixture
Xylene Isomers
Mixture
Xylene Isomers
Mixture
Xylene Isomers
Mixture
Tetraethyl Silicate
Tetraethyl Silicate

CAS RN
67-64-1
67-64-1
67-64-1
67-64-1
67-64-1
67-64-1
71-36-3
71-36-3
71-36-3
71-36-3
100-41-4
100-41-4
100-41-4
67-63-0
67-63-0
67-63-0
67-63-0
67-63-0
1330-20-7

Source
ACGIH, TWA
ACGIH, STEL
OSHA Z1, PEL
ACGIH,
ACGIH,
OSHA Z1,
ACGIH, Ceiling
ACGIH, SKIN_DES
OSHA Z1, PEL
ACGIH, TWA
ACGIH, TWA
ACGIH, STEL
OSHA Z1, PEL
OSHA Z1, PEL
ACGIH, TWA
ACGIH, STEL
ACGIH,
OSHA Z1,
ACGIH, TWA

Value
500 ppm
750 ppm
1,000 ppm; 2,400 mg/m3
500 ppm
Listed.
Listed.
50 ppm; 152 mg/m3
Can be absorbed through the skin.
100 ppm; 300 mg/m3
20 ppm
100 ppm
125 ppm
100 ppm; 435 mg/m3
400 ppm; 980 mg/m3
200 ppm
400 ppm
Listed.
Listed.
100 ppm; 434 mg/m3

1330-20-7

ACGIH, STEL

150 ppm; 651 mg/m3

1330-20-7

OSHA Z1, PEL

100 ppm; 435 mg/m3

1330-20-7

ACGIH, TWA

100 ppm

1330-20-7

ACGIH, STEL

150 ppm

78-10-4
78-10-4

ACGIH, TWA
OSHA Z1, PEL

10 ppm
100 ppm; 850 mg/m3

Absence of values indicates none found

PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average
OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA)
effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).

9. PHYSICAL AND CHEMICAL PROPERTIES

BOILING POINT - C & F:
VAPOR PRESSURE (20 C) (MM HG):

Not applicable
Not applicable

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Material Safety Data Sheet

Version: 1.8
03/28/2008

SS4004P 01P-Bottle (0.900 LBS-0.409 KG)

Silicone primer solution
VAPOR DENSITY (AIR=1):
FREEZING POINT:
MELTING POINT:
PHYSICAL STATE:
ODOR:
COLOR:
EVAPORATION RATE (BUTYL ACETATE=1):
SPECIFIC GRAVITY (WATER=1):
DENSITY:
ACID / ALKALINITY (MEQ/G):
pH:
VOLATILE ORGANIC CONTENT (VOL):
SOLUBILITY IN WATER (20 C):
SOLUBILITY IN ORGANIC SOLVENT (STATE
SOLVENT):
VOC EXCL. H2O & EXEMPTS (G/L):

No data available
< -34 C; -29 F
< -34 C; -29 F
Liquid
Pungent/Solvent
pink
>1
ca. 0.80
ca. 0.855 g/cm3
~7
Not applicable
56.0 %(m)
Slowly Hydrolyzes
Soluble, Aromatic Solvent
636

10. STABILITY AND REACTIVITY

STABILITY
Stable
HAZARDOUS POLYMERIZATION
Will not occur
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS
Carbon dioxide (CO2); Carbon monoxide; Silicon dioxide.; Oxides of nitrogen.
INCOMPATIBILITY (MATERIALS TO AVOID)
Contact with oxidizing agents.
CONDITIONS TO AVOID
Keep away from heat and sources of ignition. Avoid any source of ignition due to flammability.

11. TOXICOLOGICAL INFORMATION

ACUTE ORAL
Remarks: Unknown
ACUTE DERMAL
Remarks: Unknown
ACUTE INHALATION
Remarks: Unknown

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Material Safety Data Sheet

Version: 1.8
03/28/2008

SS4004P 01P-Bottle (0.900 LBS-0.409 KG)

Silicone primer solution
OTHER
Xylene has been shown to cause embryofetal toxicity and birth defects in laboratory animals, but only
at doses which also cause maternal toxicity, In higher concentrations, xylene is irritating to eyes and
the respiratory tract, causes drowsiness and may cause central-nervous effects (headache etc.).,
Animals exposed repeatedly to high vapor concentrations (800 ppm or greater) of mixed xylenes
suffered hearing loss., Long-term exposure to xylene can cause chronic headache, chest pain,
nausea, mental confusion, breathing difficulties, heartbeat abnormalities, numbness in limbs, fever,
malaise, and fatigue. Skin irritation can occur. Repeated exposures at high concentrations may cause
injury to the liver and kidneys., Isopropyl alcohol has produced fetotoxic effects and developmental
effects in animals following oral administration., Isopropyl alcohol has produced developmental effects
and reduced fetal weight in animals following inhalation exposure., Development of cataracts has
been reported in laboratory animals after prolonged repeated skin exposure to acetone., Ethylbenzene
has been shown to cause cancer in laboratory animals. The relevance of this finding to human is
uncertain. IARC (International Agency for Research on Cancer) has classified ethylbenzene as a
possible human carcinogen., Laboratory studies show that tetraethyl orthosilicate may be a possible
weak mutagen.
SENSITIZATION
No data available
SKIN IRRITATION
No data available
EYE IRRITATION
No data available
MUTAGENICITY
Unknown
OTHER EFFECTS OF OVEREXPOSURE
More severe effects if alcohol is consumed., Stimulants such as epinephrine may induce ventricular
fibrillation., Interactions with drugs may occur. May impair performance and alertness., This product
contains a component that showed unexpected acute toxicity to pregnant rabbits in a gavage study
conducted by the Chemical Manufacturers Association. There were no unexpected toxic effects in
pregnant rats exposed in the same study. No developmental effects were noted in either study. Effect
levels in rabbits were several times the maximum exposure which would occur at the TLV for this
component.

12. ECOLOGICAL INFORMATION

ECOTOXICITY
No data available
DISTRIBUTION
No data available
CHEMICAL FATE
No data available

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Material Safety Data Sheet

Version: 1.8
03/28/2008

SS4004P 01P-Bottle (0.900 LBS-0.409 KG)

Silicone primer solution

13. DISPOSAL CONSIDERATIONS

DISPOSAL METHOD
Disposal should be made in accordance with federal, state and local regulations.

14. TRANSPORT INFORMATION

DOT SHIPPING NAME:
DOT HAZARD CLASS:
DOT LABEL (S):
UN/NA NUMBER:
PACKING GROUP:

FLAMMABLE LIQUID, N.O.S.(ACETONE, ISOPROPANOL)

3
3
UN1993
II

IMDG SHIPPING NAME:

CLASS:
IMDG-LABELS:
UN NUMBER:
PACKING GROUP:
EMS No:

FLAMMABLE LIQUID, N.O.S.(ACETONE, ISOPROPANOL)

3
3
UN1993
II
F-E; S-E

IATA:
CLASS:
ICAO-LABELS:
UN NUMBER:
PACKING GROUP:

FLAMMABLE LIQUID, N.O.S. (ACETONE, ISOPROPANOL)

3
3
UN1993
II

15. REGULATORY INFORMATION

Inventories
Canada DSL Inventory
Japan Inventory of Existing &
New Chemical Substances
(ENCS)
Korea Existing Chemicals
Inventory (KECI)
China Inventory of Existing
Chemical Substances
Australia Inventory of Chemical
Substances (AICS)
Philippines Inventory of

y (Positive listing)
y (Positive listing)

y (Positive listing)
y (Positive listing)
y (Positive listing)
y (Positive listing)

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Material Safety Data Sheet

Version: 1.8
03/28/2008

SS4004P 01P-Bottle (0.900 LBS-0.409 KG)

Silicone primer solution
Chemicals and Chemical
Substances (PICCS)
TSCA list
EU list of existing chemical
substances
Canada NDSL Inventory

y (Positive listing)
y (Positive listing)

On TSCA Inventory

n (Negative listing)

For inventories that are marked as quantity restricted or special cases, please contact Momentive.

US Regulatory Information
CERCLA
Reportable quantity: 395 lbs
PRODUCT COMPOSITION

Chemical

CERCLA Reportable Quantity

Isopropyl Alcohol

67-63-0

Reportable quantity: 100 LBS

SARA (311,312) HAZARD CLASS

Acute Health Hazard; Chronic Health Hazard; Fire HazardAcute Health Hazard; Chronic Health
Hazard; Fire Hazard
SARA (313) CHEMICALS
71-36-3, n-Butanol100-41-4, Ethylbenzene67-63-0, Isopropyl Alcohol1330-20-7, Xylenes

CALIFORNIA PROPOSITION 65
WARNING! This product contains a chemical known in the State of California to cause cancer.
100-41-4, Ethylbenzene. 71-43-2, Benzene. 108-88-3, Toluene.

Canadian Regulatory Information

WHMIS HAZARD CLASS
Flammable Liquid, D2A VERY TOXIC MATERIALS, D2B TOXIC MATERIALS

Other
SCHDLE B/HTSUS:

3208.90.0000 Paints & varnishes, other

ECCN:

EAR99

16. OTHER INFORMATION

OTHER
C = ceiling limit
NEGL = negligible EST = estimated
NF = none found NA = not
applicable
UNKN = unknown NE = none established
REC = recommended ND = none
determined
V = recommended by vendor SKN = skin
TS = trade secret R =
recommended
MST = mist NT = not tested
STEL = short term exposure limit ppm =
parts per million
ppb = parts per billion By-product= reaction by-product, TSCA inventory status

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Material Safety Data Sheet

Version: 1.8
03/28/2008

SS4004P 01P-Bottle (0.900 LBS-0.409 KG)

Silicone primer solution
not required under 40 CFR part 720.30(h-2)., These data are offered in good faith as typical values
and not as product specifications. No warranty, either expressed or implied, is made. The
recommended industrial hygiene and safe handling procedures are believed to be generally
applicable. However, each user should review these recommendations in the specific context of the
intended use and determine whether they are appropriate.

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