Engen Dynamic 95 Unleaded Petrol (Ulp)
Engen Dynamic 95 Unleaded Petrol (Ulp)
Engen Dynamic 95 Unleaded Petrol (Ulp)
Revision Date
: 27.05.2008
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2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical name
CAS-No.
Weight%
Symbol
Codes
F+
64741-46-4
> 55.00
Toluene
108-88-3
< 20.00
F, Xn
R11, R20
Xylene
1330-20-7
< 20.00
F, Xn
Benzene
71-43-2
<= 5.00
Ethyl Benzene
100-41-4
< 2.00
Naphthalene
91-20-3
< 1.00
Xn
R-Phrase Numbers
R12
R20, R45
R45
3. HAZARDS IDENTIFICATION
Emergency response data
Inhalation
Long-term exposure to petrol vapour has caused kidney and liver cancer
in laboratory animals. Case reports of chronic petrol abuse (such as
sniffing) and chronic misuse as a solvent or as a cleaning agent have
shown a range of nervous system effects, sudden deaths from heart
attacks, blood effects and leukemia. These effects are not expected to
occur at exposure levels encountered in the distribution and use of petrol
as a motor fuel.
Skin
Irritant.
Eye
Irritant.
Ingestion
Low viscosity material if swallowed may enter the lungs and cause lung
damage.
Potential environmental
effects
Skin contact
Remove contaminated clothing. Dry wipe exposed skin and cleanse with
hand cleaner, soap and water. Launder contaminated clothing before
reuse. (See Section 16 - Injection Injury)
Eye contact
Ingestion
Note to doctors
5. FIRE-FIGHTING MEASURES
Extinguishing media
Evacuate area. For large spills, fire fighting foam in sufficient quantities
should be applied to blanket the flammable product surface.
Special protective
equipment for firefighters
Products of decomposition
Flash Point
Upper Explosion Limit (UEL)
Lower Explosion Limit (LEL)
NFPA Hazard Id
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Personal precautions
See Section 8.
Environmental precautions
Prevent spill from entering municipal sewers, water sources or low lying
areas. Advise the relevant authorities if contaminations have occurred.
Electrical equipment and fittings must comply with local fire prevention
regulations for this class of product. Refer to national or local regulations
covering safety at petroleum handling and storage areas for this product.
CAS-No.
64741-46-4
Source
ACGIH
OSHA
Toluene
108-88-3
ACGIH TLV
OSHA PEL
SA OEL
Xylene
1330-20-7
ACGIH TLV
OSHA PEL
Benzene
71-43-2
ACGIH TLV
OSHA PEL
Ethyl Benzene
100-41-4
ACGIH TLV
OSHA PEL
Naphthalene
91-20-3
ACGIH TLV
OSHA PEL
TWA
Value
Notations
LTEL
STEL
LTEL
STEL
900 mg/m3
1,500 mg/m3
890 mg/m3
1,480 mg/m3
300
500
300
500
LTEL
STEL
LTEL
STEL
LTEL
STEL
188
560
375
560
188
560
mg/m3
mg/m3
mg/m3
mg/m3
mg/m3
mg/m3
50 ppm
150 ppm
100 ppm
150 ppm
50 ppm
150 ppm
LTEL
STEL
LTEL
STEL
434
651
435
655
mg/m3
mg/m3
mg/m3
mg/m3
100
150
100
150
A4; BEI
LTEL
STEL
LTEL
STEL
1.6 mg/m3
8 mg/m3
2 mg/m3
16 mg/m3
0.5 ppm
2.5 ppm
1 ppm
5 ppm
LTEL
STEL
LTEL
STEL
434
543
435
545
100
125
100
125
A3; BEI
LTEL
STEL
LTEL
STEL
52
79
50
75
mg/m3
mg/m3
mg/m3
mg/m3
mg/m3
mg/m3
mg/m3
mg/m3
10
15
10
15
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Skin
Recommende
d Limit
Skin; A4
LTEL: Long Term Exposure Limits - Time Weight Average (TWA) over 8 hours.
STEL: Short Term Exposure Limits - Time Weight Average (TWA) over 15 Minutes
Note: Limits Shown for guidance only. Follow applicable regulations.
Personal Protection Equipment (PPE)
Engineering controls
Eye protection
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Liquid.
Green
Hydrocarbon
> 30 C
< -40 C (ASTM D-56)
NA
7.6 %(V)
1.4 %(V)
200 hPa
3
0.783 g/cm3 @ 20 C (ASTM D-4052)
>1
< 1 mm2/s @ 40 C (ASTM D-445)
< 0.1 mm2/s @ 100 C
Stable.
Conditions to avoid
Materials to avoid
Hazardous decomposition
products
Skin irritation
Eye irritation
Sensitization
This product was not a skin sensitizer when tested in a Modified Buehler
Guinea Pig Sensitization Assay.
Neurological effects
Carcinogenicity
Other toxicological
information
Physico-chemical
removability
Bioaccumulation
Not established.
Toxicity to fish
This substance has also been shown to be toxic to specific fish species
(LL50 = 1-10 mg/l for rainbow trout, Atlantic silverside).
Toxicity to aquatic
organisms
Based on test results for similar products, this substance may to toxic to
aquatic organisms such as algae and daphnia (EL50/IrL50 = 1-10 mg/l).
Ecotoxicity effects
Product is suitable for burning for fuel value in compliance with applicable
laws and regulations, and consideration of product characteristics at time
of disposal.
Contaminated packaging
Other regulations
Flash Point
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GASOLINE
1203
128
3
F
II
3
Flammable
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GASOLINE
1203
128
3
F
II
3
Flammable
CFR
Proper shipping name
UN number
DOT ERG number
Class
Letter
Packing group
Labelling number
Placard
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GASOLINE
1203
128
3
F
II
3
Flammable
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GASOLINE
1203
128
3
F
II
3
Flammable
Marine pollutant
311
3-07
3141
IMDG
Proper shipping name
UN number
DOT ERG number
Class
Letter
Packing group
Labelling number
Placard
Marine pollutant
Medical First Aid Guide
(MFAG) table
Emergency Schedule (EmS)
number
IMDG code page number
Governmental Inventory
Status
EU Labelling
Symbols
F+, T, N
Extremely flammable, Toxic, Dangerous for the environment
R-Phrase(s)
S-phrase(s)
Note
U.S. Superfund
Amendments and
Reauthorization Act SARA
Title III
SARA
CAS-No.
64741-46-4
Concentration [%]
> 55.00
Toluene
108-88-3
< 20.00
Xylene
1330-20-7
< 20.00
Benzene
71-43-2
<= 5.00
Ethyl Benzene
100-41-4
< 2.00
Naphthalene
91-20-3
< 1.00
List Citations
1, 19, 20, 21,
23, 25
1, 10, 17, 18,
19, 20, 21, 22,
23, 24, 25, 26
1, 10, 18, 19,
20, 21, 22, 23,
24, 25, 26
1, 2, 4, 6, 9,
10, 16, 17, 18,
19, 20, 21, 22,
23, 24, 25, 26
1, 8, 10, 18, 19,
20, 21, 23, 24,
25, 26
16, 22
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=
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ACGIH ALL
ACGIH A1
ACGIH A2
NTP CARC
NTP SUS
6 = IARC 1
7 = IARC 2A
8 = IARC 2B
9 = OSHA CARC
10 = OSHA Z
Code Key:
11
12
13
14
15
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=
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TSCA
TSCA
TSCA
TSCA
TSCA
4
5a2
5e
6
12b
17
18
19
20
21
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=
=
=
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CA P65
CA RTK
FL RTK
IL RTK
LA RTK
22
23
24
25
26
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MI 293
MN RTK
NJ RTK
PA RTK
RI RTK
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