Min Qiu - Basics of Plasmonics-2 PDF

Basics of Plasmonics
Min Qiu
Laboratory of Photonics and Microwave Engineering
School of Information and Communication Technology
Royal Institute of Technology (KTH)
Electrum 229, 164 40 Kista, Sweden
http://www.nanophotonics.se/ or http://web.it.kth.se/~min/
What is plasmonics?
The science of plasmonics is dealing with

generation, manipulation, and detection of
surface plasmon polaritons (SPPs).
SPP: Quasi-particle due to coupling of light and
surface plasmon (SP).
SP: electron oscillation wave at metal surfaces.
Nanophotonics KTH 2
Broad picture of polaritonics
The frequency spectra of polaritonics (shown in the

diagram as magnon polariton, phonon polariton,
exciton polariton, and surface plasmon polariton) can
cover both those of conventional electronics and
photonics, as well as the frequency gap between the
two.
Nanophotonics KTH 3
Noble metals: plasmonic

materials at optical regime
Gold
Silver
Nanophotonics KTH 4
Lycurgus cup
British Museum, AD fourth century
The cup illustrates the myth of King Lycurgus. He is seen being dragged into the
underworld by the Greek nymph Ambrosia, who is disguised as a vine.
Viewed in reflected light (daylight)
when a light is shone into the cup
Gold nanoparticles in glass,~70 nm in diameter.

Color response different to that of gold in bulk
Particles resonantly reflect green light
Strong absorbance around 500nm and below
Plasmonic resonance!
Nanophotonics KTH 5
Gold nano-particle
plasmonic resonance
Surface waves give:
Stained glass window on a Gothic

church. Colors are induced by
gold particles of different sizes.
Plasmonic resonance
Nanophotonics KTH 6
Field pattern of a SPP

= p/2
kx
vacuum
metal
2D field distribution in xz plane. The colormap

denotes Hy field, while the arrows indicate the
E field (consisting both Ex and Ez).
Nanophotonics KTH 7
Waveguiding with one interface
Metal has a negative .

Nanophotonics KTH 8
Why does a surface wave exist?

By using the Drude model for metals, we can obtain the
permittivities of metals as a function of frequency in the following
form
where p is the plasmon frequency of the corresponding bulk metal,
and is the electron relaxation time in that metal. When one neglect
the collision (lossless), one has
Therefore, the permittivity is negative when the frequency is lower

than p. When such a metal meets another material with a positive
permittivity, a wave can be bounded by their interface according to
the Maxwell equations.
Nanophotonics KTH 9
Maxwell equations and

SPP solution
(1)
(2)
Maxwell equations:
TM equations:
TM wave equation:
Nanophotonics KTH 10
Maxwell equations and SPP

solution
(1)
(2)
z>0
where
z<0
where
Maxwell equations and SPP

solution
Boundary conditions:
We have
Consider the expressions for K1 and K2, we have the dispersion relation
Further consider
we then have
SPP dispersion
1/ 2
m d
k x = k 'x + ik "x =
c m + d
Comparison of SPPs
at different frequencies
Group velocity dispersion
Field enhancement at the

surface
One can obtain the ratio between E and H field as
We therefore define the field enhancement factor as

For a plane wave propagating in free space, f=1
Excitation
It is not possible to excite a SPP directly from
free space using light due to momentum
mismatch.
Excitation methods: (1) Otto setup; (2) Grating
Excitation of a SPP through the Otto setup.

SPP waveguides
Various plasmonic waveguides with lateral confinement.

(a) Strip SPP waveguide; (b) Suspended strip waveguide; (c) Slot
waveguide; (d) V-channel waveguide; (e) -wedge waveguide; (f)
metallic fiber waveguide. Line-shaded regions are metal; greyshaded regions are dielectric materials.
Plasmonic gap waveguides

=1.55m
Au=-115-11.2i
Subwavelength confinement!
Loss is a big issue!

Channel plasmon subwavelength waveguide

components
V-channel Plasmon polariton guide

Propagation length is only a few tens of micrometers
Bozhevolnyi, S.I., et.al., Nature, 440,508,2006
M. Yan and M. Qiu, J. Opt. Soc. Am. B 24, p. 2333 (2007)
Broadband high-efficiency
PlasmonicSilicon waveguide coupler
Au
Si
SiO2
Au
250nm Au
Air
Au
SiO2
J. Tian et al, Broadband high-efficiency surface-plasmon-polariton coupler with siliconmetal interface, Appl. Phys. Lett. 95, 013504 (2009)
Broadband coupler
Average coupling efficiency is about

4.5 dB (35%).
Appl. Phys. Lett. 95, 013504 (2009)
The average loss is about 2.5 dB/m

(Simulation results 1.5 dB/m)
Coupling of Plasmonic and Photonic

Nanowires for Hybrid Nanophotonic Circuits
Prof. Limin Tongs group in Zhejiang U, China
Q factor 520!
X. Guo, M. Qiu, et al, Direct Coupling of Plasmonic and Photonic Nanowires for Hybrid
Nanophotonic Components and Circuits, Nano Lett. 9 (12), pp 45154519 (2009)
Extraordinary optical transmission through

sub-wavelength hole arrays
For a hole in a metal film, it is well
known that the transmission of the
normal incidence is in the order of
(r/)4, where r is the hole radius.
Therefore, the transmission is very
weak through a subwavelength hole.
For a subwavelength hole array,

extraordinary optical transmission is
observed. This is usually attributed to the
surface plasmon resonance.

Nature, 391, 667, 1998
Thomas Ebbesen
Wavelength of the peak transmission is usually

the same as the lattice constant (distance
between holes).
Potential applications for LED, PV, Detector, etc

Colored nano-slits
(a) single slit (length 15 m, width 170 nm) surrounded by periodic grooves
(period 600 nm). Blue:constant groove depth of 100 nm; Red:from 150 nm to 5 nm;
Green:light polarized perpendicular to the slits; Black: parallel to the slits
(b) 450 nm (purple), 500 nm (green) and 580 nm (red)
Ebbesen group
Nature Photonics , March 2008
PLasmon EnhAnced PhotonicS

FP6 project
Exploratory plasmon research aimed at concepts and

phenomena that can be exploited in the targeted
applications.
Investigation of specific plasmon enhancing
structures for emitters and detectors, along with an
investigation of the technologies to implement them.
Achieve a proof of concept of plasmon enhanced
photonics devices in 2 applications:
(a) Inorganic LEDs: enhancing electrical to
optical energy conversion.
(b) Silicon photodetectors: Improving signal-tonoise ratio and increasing speed.
Light focusing
(a)19 200-nm holes
arranged on a
quarter circle with
a 5-m radius.
(c) horizontal
polarization.
75% Intensity
(e) Vertical
polarization.
Yin et al, Nano Lett., Vol. 5, No. 7, 2005
Plasmonic Nearfield Scanning Probe

with High Transmission
plasmonic lens
single aperture
Al layer thickness 100nm

aperture diameter 100nm
ring periodicity 300nm
ring width
50nm
Cone angle
75
wavelength is 365 nm.

NANO LETTERS 2008 Vol. 8, No. 9 3041-3045
Plasmonics-based high
nonlinear effect
High-harmonic generation by focusing a

femtosecond laser onto a gas, assisted by
plasmonic modes.
Seungchul Kim et al., Nature 453 p.757
Hybrid plasmonic waveguides

c = 12.25(GaAs )
d = 2.25( SiO2 )
m = 129 + 3.3i( Ag )
(c)[d,h ] = [400, 100] nm (d)[d,h ] = [200, 100] nm

(e) [d,h ] = [200, 2] nm (f) [d,h ] = [400, 2] nm
Oulton, R. F. et al, Nature Photon. 2008, 2, 495-500.
30
Coupling from silica nano-fiber to

hybrid plasmonic waveguide
d=190 nm
15 m long
1.9 m
Diameter of silicon nanowire 130-230 nm

Thickness of the silica layer h=13 nm
d=180 nm
14 m long
Thickness of silver: >70 nm
Propagation length ~30 m

To be submitted
31
Plasmon lasers
Rupert F. Oulton et al, Plasmon lasers at deep subwavelength scale, Nature 461, p 629 (2009).
Spaser-based laser
Noginov, M. A. et al. Nature 460, 11101112 (2009).
Small-divergence semiconductor
lasers by plasmonic collimation
wavelength is 9.9 m with 15 grooves

s =2 m, =8.9 m, w =0.8 m,
h =1.5 m, d1 =7.3 m , d2 =3.5 m.
Federico Capasso group
nature photonics | VOL 2 | SEPTEMBER 2008
34
Plasmonic metamaterial absorber
Au- Dielectric -Au
Polarization indepedent
Angle indepedent
Submitted for publication
35
Highly efficient absorber!

Before test
After test
36
Applications of
plasmonic devices

SERS
Bio-imaging
Near-field optical microscope
Lithography
Nano antenna
Surface-enhanced Raman spectroscopy
Nanolaser (field enhancement)
Plasmon Enhanced Fluorescence
Solar cells!
Waveguiding using plasmonics (for high

density integration) has no clear future unless
the loss problem is solved
Field enhancement with pasmonics (PV, LED,
SERS, detector, small laser, etc ) has a better
future

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Basics of Plasmonics

The science of plasmonics is dealing with

Broad picture of polaritonics

The frequency spectra of polaritonics (shown in the

Noble metals: plasmonic

Viewed in reflected light (daylight)

when a light is shone into the cup

Gold nanoparticles in glass,~70 nm in diameter.

Surface waves give:

Stained glass window on a Gothic

Field pattern of a SPP

2D field distribution in xz plane. The colormap

Waveguiding with one interface

Metal has a negative .

Why does a surface wave exist?

Therefore, the permittivity is negative when the frequency is lower

Maxwell equations and

Maxwell equations and SPP

Maxwell equations and SPP

Group velocity dispersion

Field enhancement at the

We therefore define the field enhancement factor as

Excitation of a SPP through the Otto setup.

Various plasmonic waveguides with lateral confinement.

Plasmonic gap waveguides

Loss is a big issue!

Channel plasmon subwavelength waveguide

V-channel Plasmon polariton guide

Average coupling efficiency is about

Appl. Phys. Lett. 95, 013504 (2009)

The average loss is about 2.5 dB/m

Coupling of Plasmonic and Photonic

Extraordinary optical transmission through

For a subwavelength hole array,

surface plasmon resonance.

Wavelength of the peak transmission is usually

Potential applications for LED, PV, Detector, etc

Nature Photonics , March 2008

PLasmon EnhAnced PhotonicS

Exploratory plasmon research aimed at concepts and

Yin et al, Nano Lett., Vol. 5, No. 7, 2005

Plasmonic Nearfield Scanning Probe

Al layer thickness 100nm

wavelength is 365 nm.

High-harmonic generation by focusing a

Hybrid plasmonic waveguides

(c)[d,h ] = [400, 100] nm (d)[d,h ] = [200, 100] nm

Oulton, R. F. et al, Nature Photon. 2008, 2, 495-500.

Coupling from silica nano-fiber to

Diameter of silicon nanowire 130-230 nm

Thickness of silver: >70 nm

Propagation length ~30 m

Noginov, M. A. et al. Nature 460, 11101112 (2009).

wavelength is 9.9 m with 15 grooves

nature photonics | VOL 2 | SEPTEMBER 2008

Plasmonic metamaterial absorber

Au- Dielectric -Au

Highly efficient absorber!

Waveguiding using plasmonics (for high