Upgrading Sharky Baghdad Heavy Crude Oil: Hussain K. Hussain Salah M. Ali Yazan M. Ali

Al-Khwarizmi Engineering Journal, Vol. 7, No.
3, PP 19 - 29 (2011)
Al-Khwarizmi
Engineering
Journal
Upgrading Sharky Baghdad Heavy Crude Oil

Hussain K. Hussain*
Salah M. Ali **
Yazan M. Ali **
* Department of Chemical Engineering/ College of Engineering/ University of Baghdad

** Petroleum Research and Development Center/ Ministry of Oil
(Received 28 February 2011; accepted 19 Jun 2011)
Abstract
Shaky Baghdad heavy crude oil 22 API is processed by distillation and solvent extraction. The purpose of
distillation is to separate the light distillates (light fractions) which represent 35% of heavy crude oil, and to obtain the
reduced crude oil. The heavy residue (9 API) is extracted with Iraqi light naphtha to get the deasphaltened oil (DAO),
the extraction carried out with temperature range of 20-75 oC, solvent to oil ratio 5-15:1(ml:g) and a mixing time of 15
minutes. In general, results show that API of DAO increased twice the API of reduced crude oil while sulfur and metals
content decreased 20% and 50% respectively. Deasphaltened oil produced from various operating conditions blended
with the light distillates obtained from distillation in a constant blending percentage of 35% light for all mixtures. These
blends produced synthetic crude oil with API up to 30 suitable for using in the subsequent hydrocarbon processes.
Keyword: synthetic crude oil, deasphaltening, distillation, extraction.
1. Introduction
Asphaltenes are high molecular weight
polycyclic compounds containing nitrogen, sulfur,
oxygen, and metals. The relative concentrations of
these compounds vary in terms of the crude oil,
and make up a unity which makes it a useful
parameter for general comparisons of oils. All of
these compounds are present in different oils
which vary from light to heavy crudes with a
broad spectrum of varying densities in which the
conventional unit of gravity API gravity decreases
or the oil becomes heavier, making this unit an
important correlational factor. Additional general
correlational factors describing different types of
oils are the H/C ratios, which also decrease as the
oil becomes heavier. Further, the polar N, S, O
compounds become concentrated in the heavy
ends of crudes. The heteroatom contents of these
oils are measurable quantities and are also useful
for correlational purposes. Thus, as the sulfur and
nitrogen concentrations increase, the API value
decreases, consistent with an increase in the
concentrations
of
compounds
containing
heteroatoms and increasing molecular weights.
The high molecular weight fractions also

concentrate organometallic compounds [1].
Reduction of asphaltenes and metal content
can be achieved by disturbing the solvation
equilibrium via addition of suitable solvents, e.g.,
propane, pentane, heptane or carbon dioxide,
resulting in the flocculation of asphaltenes [2].The
solvent deasphaltation treats the residue through a
pressurized liquid-liquid extraction, using specific
properties of the solvent. The deasphaltation
produces the deasphalted oil and the asphalted
residue [3].The Residuum Oil Supercritical
Extraction process is the premier deasphalting
technology available in industry today. This stateof-art process extracts high-quality deasphalted oil
(DAO) from atmospheric or vacuum residues and
other feedstocks. The asphaltene products from
the ROSE process are often blended to fuel oil,
but can also be used in the production of asphaltic
blending components, solid fuels, or fuel
emulsions. The development of the deasphaltation
technology using supercritical fluid appears as a
solution to improve the separation of the
deasphalted oil (ODES) from the asphaltenes. The
use of supercritical fluid has some advantages
like: the difference of the densities between the
Hussain K. Hussain
Al-Khwarizmi Engineering Journal, Vol. 7, No. 3, PP 19 - 29 (2011)
extraction phase and the refining phase is greater

than that obtained by the conventional liquid
extraction, becoming the separation between the
phases easier; the mass transport is faster using
the supercritical fluid; the quantity and the quality
of the ODES can be easily controlled adjusting
the temperature and the pressure of the extraction
system and the efficiency to recover the oil is a
function of the density of the supercritical fluid
[3].
The solvent deasphalting process (SDA) which
is based on liquidliquid extraction by using
paraffinic solvents (C4C7) is one of the most
efficient approaches to reduce metal and
asphaltene contents of heavy oil cuts before
sending them to hydro-desulphurization and
Hydrocracking units.
A number of deasphalting process parameters
are to be considered, amongst which the DAO
process yield and the levels of demetalization and
deasphalting could be noted. The important
factors influencing the mentioned parameters are
solvent composition and ratio of the solvent to the
feed, temperature, pressure and the type of
extractor equipment.
The precipitation increases substantially as the
solvent/feed ratio increases up to 10 folds.
Beyond this value, precipitation increases by very
small amounts [4].
Extraction temperature must be maintained
below the critical temperature of the solvent,
however, because at higher temperatures no
portion of the residue is soluble in the solvent and
no separation occurs[5].
In industrial plants, increasing the solvent to
feed ratio compensates for the DAO yield
reduction with temperature rise. In consequence,
the extraction process selectivity for paraffinic

oils escalates and eventually the extracted oil will
have an improved quality due to the reduction of
undesirable components [6].
Direct hydro-desulphurization followed by
Hydrocracking of crude oil heavy cuts and
vacuum residues is one of the best methods of
heavy residue upgrading in refining industry. But,
problem emerges when metal and asphaltene
contents of residue are high. In fact, the presence
of these compounds adversely influences the
activities of the hydro-desulphurization and
Hydrocracking catalysts.
The aim of this work is to separate the light
distillates from Sharky Baghdad heavy crude oil
and to obtain deasphaltened oil by solvent
extraction with light naphtha. The light and the
blended DAO distillate to produce high API
synthetic crude oil with low sulfur and metals
content.
2. Experimental Work
2.1. Distillation Process
The distillation process for separation of light
distillates (light fractions) from sharky Baghdad
heavy crude oil was achieved by a computerized
laboratory distillation apparatus (according
ASTM 5236) (PIGNAT COMPANY, FRANCE)
that consists of distillation flask, heating mantle,
distillation column, condenser, thermometers,
fraction collector. The physical properties of
Sharky Baghdad heavy crude oil and distillation
results are shown in Table (1). Figure (1) shows
the schematic diagram of the laboratory
distillation apparatus.
Table 1,
Physical Properties of Sharky Baghdad Crude Oil.
Property
Value
Preliminary distillation (IP 24/55)

Temperature, C
Vol. %
Specific gravity 15.6/15.6 C

API gravity
Viscosity at 37.5 C, Cs
Sulfur content, wt. %
Vanadium, ppm
Iron, ppm
Nickel, ppm
Saturate compounds, wt. %
Naphthene compounds, wt. %
Polar aromatic compounds,wt.%
0.922
22
47
5.044
88
25
38
42.66
23.87
17.8
IBP(85 C)
100
125
150
175
200
225
250
275
3.5
5
8.6
11.6
15.1
18.4
23
27.5
Asphultene content,wt. %
15.67
300
33.7
20
Hussain K. Hussain
Fig.1. Schematic Diagram of the Laboratory Distillation Unit.
of light naphtha and the physical properties of

atmospheric residue are given in Tables 2 and 3,
respectively.
The extraction process consists of three stages
mixing, filtration and solvent recovery.
2.2. Extraction Process

Asphaltenes are separated from atmospheric
residue (350+oC) obtained from distillation stage
by extraction with light naphtha. The composition
Table 2,
Composition of Iraqi Light Naphtha.
n-Paraffins
wt %
i-Paraffins
C3
n-C4
n-C5
n-C6
n-C7
0.067
0.329
7.006
14.809
10.192
i-C4
i-C5
2MC5
3MC5
2MC6
3MC6
wt %
Naphthenes
wt %
Aromatics
wt %
0.045
3.956
10.787
7.421
6.976
6.106
CC5
NC6
CC6
NC7
NC8
0.302
4.37
2.844
4.11
7.091
Benzene
Toluene
0.683
1.904
Table 3,
Physical Properties of Atmospheric Residue.
Property
Value
Specific gravity 15.6/15.6 C
1.002
API gravity
9.66
Asphaltenes ,wt %
Mixing was carried out with 1-liter 2-neck

glass flask, magnetic stirrer, heating mantle, high
efficiency condenser and thermometers. 50 g of
atmospheric residue was mixed with light naphtha
at temperatures of 20, 50, 75oC, Solvent to oil
ratio 5, 10, 15:1 (ml:g) and mixing time of 15
minutes with 200 rpm. A high efficient vertical
condenser operating at total reflux was mounted
on mixing flask in order to decrease the solvent
losses to the minimum. Figure (2) shows a scheme
of mixing process. When the mixing step was
complete, the flask left for 1 hour at ambient
temperature to let asphaltenes settle to the bottom
of the flask.
23
Asphaltenes ,g
11.5
Sulfur ,wt %
5.7
Sulfur ,g
2.85
Vanadium ,ppm
A- Mixing Stage
90
Nickle ,ppm
35.2
Chrome ,ppm
2.35
21
Hussain K. Hussain
3. Results and Discussions

The tests results of DAO produced from
various operating conditions are shown in Table
(4). The effective parameters of process included
in these tables are specific gravity, API,
asphaltene content, sulfur and metals content.
Table 4,
Tests results of Deasphaltened Oil.
Temperature
Oil:Solvent
01:05
Specific gravity
15.6/15.6 C
API
Fig.2. Scheme of the Mixing Unit.
Asphaltenes removed,g
8.32
10.5
11
Sulfur content, wt%
4.4
4.3
4.4
Vanadium,ppm
35
24.6
24
Nickle,ppm
16
15.2
14.9
Chrome,ppm
0.1
0.1
0.1
29.2065
30.5
30.8055
01:10
01:15
0.946488
0.937086
0.93461
18
19.5
19.9
7.81
8.2
8.4
Sulfur content, wt%
4.5
4.6
4.6
Vanadium,ppm
41.4
31
24.3
Nickle,ppm
18
17.5
17.1
Chrome,ppm
0.6
0.3
0.2
After blending
API of synthesis crude
oil
29.2
30.175
30.435
DAO produced from various operating

conditions blended with the light distillates is
produced from distillation stage which formed
35% from these mixtures to produce synthetic
crude oil.
01:10
01:15
0.95634
0.955436
0.9555
16.46
16.6
16.59
5.1
7.3
7.1
Sulfur content, wt%
4.8
4.7
4.6
Vanadium,ppm
58.4
57
50.9
Nickle,ppm
18.2
18
17.5
Chrome,ppm
0.64
0.56
0.3
28.199
28.29
28.2835
After blending
oil
22
75 oC
01:05
Specific gravity
15.6/15.6 C
API
2.3. Blending
50 oC
01:05
Temperature
Oil:Solvent
Solvent and deasphaltened oil is introduced to

distillation unite in order to separate the solvent
from DAO.
0.933993 0.931105
20.47
Specific gravity
15.6/15.6 C
API
C- Evaporation
01:15
20
Temperature
Oil:Solvent
In order to filter the solvent-oil mixture in a

reasonable time, a vacuum filtration unit was
assembled, which consisted of a filtration flask,
Buchner funnel, vacuum pump and trap for
condensing the high volatility solvent in order to
avoid vacuum pump damage. The filter paper
(Whatman no. 1) was wetted with solvent before
the filtration step. At the end of the filtration, the
filter paper was put in a hot electrical furnace to
evaporate the solvent associated with the
precipitated asphaltenes. The dried filter paper
was then weighed to estimate the percentage of
asphaltenes yield.
01:10
18.01
After blending
oil
B- Filtration
0.946425
20 oC
Hussain K. Hussain

temperature respectively due to decreasing of
asphaltenes removal with increasing temperature.
Figure (6) shows that sulfur content of DAO
increased with increasing temperature due to the
decreasing removal of asphaltenes. A figure 7, 8
and 9 shows that metals impurity reduction of
vanadium, nickel and chrome respectively
decreased with increasing temperature. These
behaviors due to increasing asphaltenes content
with increasing temperature.
3.1. Effect of Temperature

Figure (3) shows that asphaltenes yield
decreased with increasing temperature. This
behavior is due to increasing the solubility of oil
with increasing temperature which permits
asphaltenes and resinous materials to escape to the
oil phase.
Figures 4 and 5 show that API of DAO and
synthetic crude oil decreased with increasing
R em o ved A sp h .
Asphaltenes Removed (g)
Fig.(1) Effect of temp on rem oved Asph o f RCR

15
01:05
10
01:10
5
01:15
0
20
50
75
Tem p.(C)
Temperature
(oC)
Fig.3. Effect of Temperature on Asphaltenes Removal from RCR at Various Oil to Solvent Ratio.
25
20
15
API
01:05
10
01:10
01:15
0
20
50
75
Temperature(C)
Fig.4. Effect of Temperature on API of Deasphaltened Oil at various Oil to Solvent Ratio.
23
API
Hussain K. Hussain
31.5
31
30.5
30
29.5
29
28.5
28
27.5
27
26.5
01:05
01:10
01:15
20
50
75
Temperature(C)
Fig.5. Effect of Temperature on API of Synthesis Crude Oil at various Oil to Solvent Ratio
4.9
4.8
Sulfur Content (wt%)
4.7
4.6
4.5
01:05
4.4
01:10
4.3
01:15
4.2
4.1
4
20
50
75
Temperature(C)
Fig.6. Effect of Temperature on Sulfur Content of Deasphaltened Oil at various Oil to Solvent Ratio.
80
70
Vanadium Reduction (wt%)
60
50
40
01:05
30
01:10
20
01:15
10
0
20
50
75
Temperature (C)
Fig.7. Effect of Temperature on Vanadium Reduction of Deasphaltened Oil at various Oil to Solvent Ratio.
24
Hussain K. Hussain
60
58
56
Nickle Reduction (wt%)
54
52
01:05
50
01:10
48
01:15
46
44
42
20
50
75
Temperature(C)
Fig.8. Effect of Temperature on Nickel Reduction of Deasphaltened Oil at various Oil to Solvent Ratio.
120
Chrome Reduction (wt%)
100
80
60
01:05
01:10
40
01:15
20
0
20
50
75
o
Temperature ( C)
Fig.9. Effect of Temperature on Chrome Reduction of Deasphaltened Oil at various Oil to Solvent Ratio.
of API due to increasing solvent power and

selectivity for the removing of asphaltenes and
then to steady state.
Figure (13) shows approximately steady state
effect of increasing the solvent to oil ratio on
sulfur content. Figures 14, 15 and 16 show the
effect of increasing solvent to oil ratio on
Vanadium, Nickel and Chrome impurity
reduction, respectively. In this case, increasing
solvent to oil ratio led to the increasing of metals
impurity reduction due to increasing the removing
of asphaltenes.
3.2. Effect of Solvent to Oil Ratio

Figure (10) shows the effect of increasing
solvent to oil ratio on the removing of asphaltene.
In this case, increasing solvent to oil ratio led to
increasing asphaltenes removal and then to steady
state at 10:1. This behavior is due to increasing
solvent power and selectivity toward asphaltenes
removal.
Figures 11 and 12 shows the effect of
increasing the solvent to oil ratio on API of DAO
and synthetic crude oil respectively. In this case,
the increasing of solvent to oil ratio led to increase
25
Hussain K. Hussain
12
10
8
Asphaltenes
Removed (g)
20
6
50
4
75
2
0
1:05
1:10
1:15
Oil:Solvent Ratio (g:ml)

Fig.10. Effect of Oil to Solvent Ratio on Asphaltenes Removal from RCR at Different Temperatures.
25
20
API
15
20
50
10
75
0
1:05
1:10
1:15

Fig.11. Effect of Oil to Solvent Ratio on API of Deasphaltened Oil at Different Temperatures.
31.5
31
30.5
30
API
29.5
20
29
50
28.5
75
28
27.5
27
26.5
1:05
1:10
1:15

Fig.12. Effect of Oil to Solvent Ratio on API of Synthesis Crude Oil at Different Temperatures.
26
Hussain K. Hussain
4.9
4.8
4.7
Sulfur Content
4.6
20C
4.5
4.4
50C
4.3
75C
4.2
4.1
4
1:05
1:10
1:15

Fig.13. Effect of Oil to Solvent Ratio on Sulfur Content of Deasphaltened Oil at Different Temperatures.
80
70
Vanadium Reduction
(wt%)
60
50
20C
40
50C
30
75C
20
10
0
1:05
1:10
1:15

Fig.14. Effect of Oil to Solvent Ratio on Vanadium Reduction of Deasphaltened Oil at Different Temperatures.
60
58
Nickel Reduction (wt%)
56
54
52
20C
50
48
50C
46
75C
44
42
1:05
1:10
1:15
Fig.15. Effect of Oil to Solvent Ratio on Nickel Reduction of Deasphaltened Oil at Different Temperatures.
27
Hussain K. Hussain
120
Chrome Reduction (wt%)
100
80
60
20C
40
50C
75C
20
0
1:05
1:10
1:15
Fig.16. Effect of Oil to Solvent Ratio on Chrome Reduction of Deasphaltened Oil at Different Temperatures.
4. Conclusions
[2]
1- Removing asphaltenes from the reduced crude

oil produces DAO with 19 API with low sulfur
and metals content.
2- Increasing extraction temperature led to
decreasing API of DAO and other properties.
3- Increasing solvent to oil ratio led to increasing
API of DAO and other properties with no
significant changes beyond solvent to oil ratio
10:1 (ml:g).
4- Optimum extraction process is carried out at
temperature 20oC and 10:1 solvent to oil ratio.
5- Blending of light distillates in a percentage
35% with DAO led to producing synthetic
crude oil with 30 API and low sulfur and
metals content.
[3]
[4]
[5]
5. References
[6]
[1] E. T. Premuzic and M. S. Lin, 212TH

National Acs Meeting Induced Biochemical
28
Interactions In Crude Oils, August 18-22,

1996, Orlando, FL.
Eckermann B. and Vogelpohl A.,
Deasphaltization and Demetalling of Heavy
Crude Olis and Distillation Residues with
CO2,
Chemical
Engineerring
and
Technology. V13,P.258-264, 1990.
Mendes M. F., Ferreira C. Z. and Pessoa F.
L. P., Deasphaltion of Petroleum Using
Supercritical Propane. 2nd Mercosur
Congress on Chemical Engineering, 4 nd
Mercosur Congress on Process Systems
Engineering, Enpromer, Costa Verde
Brasil, 2005.
Gonzalez, E. B., C. L. Galeana, A. G.
Villegas, J. Wu, AICHE Journal, Vol. 50,
No. 10 Oct. 2004, p. 2552
Meyers, R. A., Handbook of petroleum
Refining processes, 10th ed., McGraw-Hill,
2003.
Ditman, J. G., van Hook, J. P. :ACS Meeting
Atlanta, April 1981.
7 3 (2011) 29 - 19
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Al-Khwarizmi Engineering Journal, Vol. 7, No.

Upgrading Sharky Baghdad Heavy Crude Oil

* Department of Chemical Engineering/ College of Engineering/ University of Baghdad

The high molecular weight fractions also

Al-Khwarizmi Engineering Journal, Vol. 7, No. 3, PP 19 - 29 (2011)

extraction phase and the refining phase is greater

the extraction process selectivity for paraffinic

Preliminary distillation (IP 24/55)

Specific gravity 15.6/15.6 C

Al-Khwarizmi Engineering Journal, Vol. 7, No. 3, PP 19 - 29 (2011)

Fig.1. Schematic Diagram of the Laboratory Distillation Unit.

of light naphtha and the physical properties of

2.2. Extraction Process

Mixing was carried out with 1-liter 2-neck

Al-Khwarizmi Engineering Journal, Vol. 7, No. 3, PP 19 - 29 (2011)

3. Results and Discussions

Fig.2. Scheme of the Mixing Unit.

Sulfur content, wt%

Sulfur content, wt%

DAO produced from various operating

Sulfur content, wt%

Solvent and deasphaltened oil is introduced to

In order to filter the solvent-oil mixture in a

Al-Khwarizmi Engineering Journal, Vol. 7, No. 3, PP 19 - 29 (2011)

3.1. Effect of Temperature

Asphaltenes Removed (g)

Fig.(1) Effect of temp on rem oved Asph o f RCR

Al-Khwarizmi Engineering Journal, Vol. 7, No. 3, PP 19 - 29 (2011)

Sulfur Content (wt%)

Vanadium Reduction (wt%)

Al-Khwarizmi Engineering Journal, Vol. 7, No. 3, PP 19 - 29 (2011)

Nickle Reduction (wt%)

Chrome Reduction (wt%)

of API due to increasing solvent power and

3.2. Effect of Solvent to Oil Ratio

Al-Khwarizmi Engineering Journal, Vol. 7, No. 3, PP 19 - 29 (2011)

Oil:Solvent Ratio (g:ml)

Oil:Solvent Ratio (g:ml)

Oil:Solvent Ratio (g:ml)

Al-Khwarizmi Engineering Journal, Vol. 7, No. 3, PP 19 - 29 (2011)

Oil:Solvent Ratio (g:ml)

Oil:Solvent Ratio (g:ml)

Nickel Reduction (wt%)

Oil:Solvent Ratio (g:ml)

Al-Khwarizmi Engineering Journal, Vol. 7, No. 3, PP 19 - 29 (2011)

Chrome Reduction (wt%)

Oil:Solvent Ratio (g:ml)

1- Removing asphaltenes from the reduced crude

[1] E. T. Premuzic and M. S. Lin, 212TH

Interactions In Crude Oils, August 18-22,

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