Heat Transfer Engineering
Heat Transfer Engineering
Heat Transfer Engineering
Xiaolin Wang , Kim Choon Ng , Anutosh Chakarborty & Bidyut Baran Saha
a
To cite this article: Xiaolin Wang , Kim Choon Ng , Anutosh Chakarborty & Bidyut Baran Saha (2007) How Heat and Mass
Recovery Strategies Impact the Performance of Adsorption Desalination Plant: Theory and Experiments, Heat Transfer
Engineering, 28:2, 147-153, DOI: 10.1080/01457630601023625
To link to this article: http://dx.doi.org/10.1080/01457630601023625
A prototype adsorption desalination facility is experimentally studied, and the performance tests are conducted with and
without the heat and mass recovery procedures. The experiments show that practical and yet effective methods could yield a
significant boost to the specific daily water production and performance ratio of the desalination plant by 15.7% and 42.5%,
respectively.
INTRODUCTION
Adsorption desalination (AD) is a novel method of producing potable water, despite the adsorption cycle, for cooling applications found in chemical, power and co-generation plants.
Hitherto, there are several kinds of commercial-scale desalination plants in many water scarce countries, such as the multistage flash (MSF) [1] type; the multi-effect desalination [2] type;
the membrane-based reverse osmosis (RO) [3] plants; the hybrid
plants, which combine the RO and MSF processes [4, 5]; and
electrodialysis (ED) or electrodialysis reversal (EDR) [6]. All
of the mentioned desalination methods are found to be either
highly energy-intensive to maintain the processes of desalination or prone to serious erosion and fouling problems in the evaporating units operating at elevated evaporating temperatures [7].
The AD cycle is proposed to mitigate the shortcomings of
the conventional desalination methods [811]. The advantages
of the AD cycle are that
1. it employs waste heat at low temperatures for the cycle, temperatures of 85 C or lower;
2. the vaporization of saline or brackish water in the evaporator
is kept at a low temperature, typically between 2025 C, to
mitigate problems of corrosion and fouling; and
Address correspondence to Dr. K. C. Ng, Mechanical Engineering Department, National University of Singapore, 10 Kent Ridge Crescent, Singapore
119260. E-mail: mpengkc@nus.edu.sg
3. the complete elimination of any bio-contamination by desorption at 65 C or more where any unwanted aerosolentrained microbes or cells from the evaporator would be
killed.
The reduced corrosion and fouling rates in the evaporator
imply a low maintenance cost for the AD plants as compared
with the conventional plants. Other than the evaporator, which is
usually made of stainless steel, the other components of the AD
plant use a comparatively inexpensive carbon steel. In addition,
the AD plants employ low-temperature waste heat from industries that otherwise would have been purged into the ambient,
not only saving the primary energy resource but also reducing
global warming.
Wang and Ng [11] have recently reported the performance of
a four-bed silica gel-water adsorption desalination plant, where
both the specific daily water production (SDWP) and the plant
performance ratio (PR) are yet to be optimized. The PR is defined here as the ratio of the equivalent latent heat associated with
the potable water production to the energy input to the adsorption cycle. Being a batch-operated cycle, the effects of thermal
mass from the reactor beds and the mixing of the residual heat
of the coolant remaining in the cycle during switching could be
substantial in relation to the total heat input per cycle. One of
the pioneering works in heat and mass recovery procedures that
was applied to adsorption cycle employed to provide cooling
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is the HIJC USA, Inc. [12], where both the water circulation
and mass recovery schemes were applied to the beds during the
switching interval. It reported some improvement to the chiller
cooling capacity. More recently, Wang [13] analyzed in some
detail the energy recovery principle of the adsorption cycle, and
Liu et al. [14] attempted to explain the functional aspects of
heat and mass recovery schemes for chillers by considering an
open-loop design for the adsorption cycle, as well as the use of
an external heat source and cooling tower. They concluded that
for the chiller performance to improve, an independent fluid recirculation loop is necessary to augment the heat recovery. Such
a process could be operated either in a continuous manner or
only during the switching period [15]. Such an active heat recovery scheme works best with a high-temperature heat source,
which seems incompatible with the novel aim of utilizing lowtemperature waste heat. On the other hand, Ng et al. [16, 17]
employed only passive heat and mass recovery schemes on a
four-bed adsorption plant that was operated as a water desalination plant. Although many possible heat and mass combinations
or schemes could be applied to the adsorption cycle, the authors
have demonstrated two methods that require minimal changes
to the plant hardware and yet significantly improve the system
performance of the adsorption desalination plant.
EXPERIMENTS
The schematic and prototype adsorption desalination plant is
shown in Figures 1 and 2, comprising the four beds, condenser,
and evaporator. For a two-bed mode, each pair of beds operates in
tandem, either concomitantly as the adsorber or desorber. During
the desorption process, a low-temperature heat source is supplied
to the desorber bed, where the water vapor from the silica gel
is expelled and the vapor is allowed to condense on the tubes
of the condenser. The heat rejected by the condenser is cooled
by circulating water from the cooling tower, and the condensate
produced within the condenser is collected as the potable water.
At the same time, the designated adsorber is in heat and mass
communications with the evaporator through the controlled vapor valve, thus causing boiling to occur within the evaporator.
As adsorption is an exothermic process, external cooling water
from the cooling tower is circulated to the designated adsorber,
enhancing the vapor uptake to the adsorbent. Details of the plant
switching and cycle operations have been previously described
in literature [17] and thus will not be elaborated here. It is noted
that the equipment found below the platform is the purpose-built
rating facility, which enables constant supply conditions for the
coolant or heat source temperatures, such as chilled water and
cooling and hot water temperatures, to within an accuracy of
0.3 C.
The saline or brackish water is first pre-treated (e.g., filtering
and de-aeration) and feeds to the evaporator, while purging from
the evaporator is conducted intermittently for salt concentration
control. Potable water is produced in the adsorption cycle in
two steps. First, vapor is evaporated by the thermal load from
the circulating evaporator-water loop, and the spray evaporation
is employed as compared to conventional pool boiling. Vapor uptake or adsorption is maintained by the unsaturated properties of
adsorbent in the designated water-cooled adsorber. Secondly, vapor is purged out from the designated hot-water driven desorber
and condensed in the condenser to produce the pure water. The
condensate is collected in a collection tank and intermittently
pumped out to the ambient.
X. WANG ET AL.
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X. WANG ET AL.
180720
40
85
29.4
12.2
48
38
125
46
X. WANG ET AL.
Figure 5 Temperature profile of the cooling and heat source at the system
inlet and outlet with and without heat recovery scheme. Symbols:
Hot
water inlet,
Hot water outlet with heat recovery scheme,
Hot water
outlet without heat recovery scheme,
Cooling water inlet,
Cooling
Cooling water outlet without heat
water outlet with heat recovery scheme,
recovery scheme.
Figure 6
cycle.
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X. WANG ET AL.
CONCLUSION
hADS
hfg
M
P
PR
q
Q
SDWP
t
T
Greek Symbol
Table 2 The effect of raising water temperature at inlet to the evaporator for
the basic AD cycle, as well as the comparisons with cycles with pressure
equalization (PE) and valve-closure delay (VD) of an AD plant
in
Tevap
4.32
5.09 6.30
7.60
0.315
0.599
half-cycle interval, s
Subscripts
ads
ads start
ads end
c, cond
cold
des
des end
des start
evap, e
hot
adsorption
start of the adsorption process
end of the adsorption process
condenser
cold coolant stream
desorption
end of the desorption process
start of the desorption process
evaporator
heat source stream
X. WANG ET AL.
i
in
in-sw
max
min
out-sw
PE
residual
s
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[15] Amar, N. B., Sun, L. M., and Meunier, F., Numerical Analysis of
Adsorptive Temperature Wave Regenerative Heat Pump, Applied
Thermal Engineering, vol. 16, no. 5, pp. 405418, 1996.
[16] Ng, K. C., Gordon, J. M., Chua, H. T., and Anutosh, C., ElectroAdsorption Chiller: A Miniaturized Cooling Cycle with Applications from Microelectronics to Conventional Air-Conditioning,
USPO no. 6,434,955, August 2002.
[17] Ng, K. C., Chua, H. T., Wang, X. L., Kashiwagi, T., and Saha, B. B.,
Prototype Testing of a Novel Four-Bed Regenerative Silica GelWater Adsorption Chiller, Proceedings of International Congress
on Refrigeration, Washington D.C., USA, 2003.
REFERENCES
[1] Al-Wazzan, Y., and Al-Modaf, F., Seawater Desalination
in Kuwait Using Multistage Flash Evaporation TechnologyHistorical Overview, Desalination, vol. 134, pp. 257267,
2001.
[2] Al-Shammiri, M., and Safar, M., Multi-Effect Distillation Plants:
State of the Art, Desalination, vol. 126, pp. 4559, 1999.
[3] Amjad, Z., Reverse Osmosis: Membrane Technology, Water
Chemistry, and Industrial Applications, Chapman & Hall, International Thomson Publishing, New York, 1993.
[4] Awerbuch, L., May, S., Soo-Hoo, R., and Van Dermast, V.,
Hybrid Desalting Systems, Desalination, vol. 76, pp. 189197,
1989.
[5] EI-Sayed, E., Ebrahim, S., Ai-Saffa, A., and Abdeljawad, M., Pilot Study of MSF-RO Hybrid Systems, Desalination, vol. 120,
pp. 121128, 1998.
[6] Hummel, R. L., Solar Distillation with Economies of Scale, Innovation and Optimization, Desalination, vol. 134, pp. 159171,
2001.
[7] Ehrenman, G., From Sea to Sink, Mechanical Engineering,
vol. 126, no. 10, pp. 3843, 2004.
[8] Broughton, D. B., Continuous Desalination Process, USPO
4,447,329, May 8, 1984.
[9] Zejli, D., Benchrifa, R., Bennouna, A., and Bouhelal, O. K., A
Solar Adsorption Desalination Device: First Simulation Results,
Desalination, vol. 168, pp. 127135, 2004.
[10] Al-Kharabsheh, S., and Goswami, D. Y., Theoretical Analysis of a
Water Desalination System Using Low-Grade Solar Heat, Journal
of Solar Energy Engineering, Transactions of the ASME, vol. 126,
no. 2, pp. 774780, 2004.
[11] Wang, X. L., and Ng, K. C., Experimental Investigation of an
Adsorption Desalination Plant Using Low-Temperature Waste
Heat, Applied Thermal Engineering, vol. 25, pp. 27802789,
2005.
[12] Waste Heat Adsorption ChillerFunction, HIJC USA, Inc.,
P.O. Box 820307, Houston, Texas 77282-0307, USA. Available
at:
http://www.adsorptionchiller.bigstep.com/homepage.html.
Accessed October 2004.
[13] Wang, R. Z., Performance Improvement of Adsorption Cooling
by Heat and Mass Recovery Operation, International Journal of
Refrigeration, vol. 24, no. 7, pp. 602611, 2001.
[14] Liu, Y. L., Wang, R. Z., and Xia, Z. Z., Experimental Performance
of a Silica Gel-Water Adsorption Chiller, Applied Thermal Engineering, vol. 25, pp. 359375, 2005.