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    MSDS Vanadium Pentoxide

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    Rezer Axel
    Vanadium(V) oxide is a yellow to brown solid powder that is harmful if inhaled or swallowed and irritating to the respiratory system. Prolonged exposure can cause serious health damage and it is toxic to aquatic organisms. It requires the use of personal protective equipment like gloves, goggles and respirators during handling to prevent skin or eye contact or inhalation. It is stable under normal temperatures and pressures but generates irritating and toxic fumes if heated to high temperatures.

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    MSDS Vanadium Pentoxide

    Uploaded by

    Rezer Axel
    265 views5 pages
    Vanadium(V) oxide is a yellow to brown solid powder that is harmful if inhaled or swallowed and irritating to the respiratory system. Prolonged exposure can cause serious health damage and it is toxic to aquatic organisms. It requires the use of personal protective equipment like gloves, goggles and respirators during handling to prevent skin or eye contact or inhalation. It is stable under normal temperatures and pressures but generates irritating and toxic fumes if heated to high temperatures.

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    Vanadium(V) oxide is a yellow to brown solid powder that is harmful if inhaled or swallowed and irritating to the respiratory system. Prolonged exposure can cause serious health damage and it is toxic to aquatic organisms. It requires the use of personal protective equipment like gloves, goggles and respirators during handling to prevent skin or eye contact or inhalation. It is stable under normal temperatures and pressures but generates irritating and toxic fumes if heated to high temperatures.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    265 views5 pages

    MSDS Vanadium Pentoxide

    Uploaded by

    Rezer Axel
    Vanadium(V) oxide is a yellow to brown solid powder that is harmful if inhaled or swallowed and irritating to the respiratory system. Prolonged exposure can cause serious health damage and it is toxic to aquatic organisms. It requires the use of personal protective equipment like gloves, goggles and respirators during handling to prevent skin or eye contact or inhalation. It is stable under normal temperatures and pressures but generates irritating and toxic fumes if heated to high temperatures.

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    Material Safety Data Sheet

    Vanadium(V) oxide
    MSDS# 45278
    Section 1 - Chemical Product and Company Identification
    MSDS Name:
    Vanadium(V) oxide
    Catalog Numbers:
    20642-0000, 20642-0050, 20642-2500, 20799-0000, 20799-0050, 20799-5000,
    V/0100/48, V/0100/53, V/0100/70
    Synonyms:
    Vanadium pentoxide; Divanadium pentoxide; Vanadic anhydride; Vanadic
    acid anhydride.
    Company Identification: Fisher Scientific UK
    Bishop Meadow Road, Loughborough
    Leics. LE11 5RG
    For information in Europe, call:(01509) 231166
    Emergency Number, Europe:01509 231166
    Section 2 - Composition, Information on Ingredients
    ---------------------------------------CAS#:
    1314-62-1
    Chemical Name: Vanadium pentoxide
    %:
    >98
    EINECS#:
    215-239-8
    ---------------------------------------Hazard Symbols:
    T N
    Risk Phrases:
    20/22 37 48/23 51/53 63 68
    Section 3 - Hazards Identification
    EMERGENCY OVERVIEW
    Harmful by inhalation and if swallowed. Irritating to respiratory
    system. Toxic : danger of serious damage to health by prolonged
    exposure through inhalation. Possible risk of harm to the unborn
    child. Toxic to aquatic organisms, may cause long-term adverse
    effects in the aquatic environment.Possible risk of irreversible
    effects.
    Potential Health Effects
    Eye:
    Causes eye irritation. Causes redness and pain.
    Skin:
    May cause skin irritation. May cause skin sensitization, an
    allergic
    reaction, which becomes evident upon re-exposure to this material.
    Ingestion:
    May be fatal if swallowed. May cause central nervous system
    effects.
    Inhalation:
    Causes respiratory tract irritation. May cause effects similar to
    those described for ingestion. May cause lung damage. May cause
    asthma and shortness of breath.
    Chronic:
    Chronic inhalation and ingestion may cause effects similar to those
    of acute inhalation and ingestion.
    Section 4 - First Aid Measures
    Eyes:
    Flush eyes with plenty of water for at least 15 minutes,
    occasionally lifting the upper and lower eyelids. Get medical aid.

    Skin:
    Get medical aid. Flush skin with plenty of water for at least 15
    minutes while removing contaminated clothing and shoes.
    Ingestion:
    If victim is conscious and alert, give 2-4 cupfuls of milk or
    water.
    Never give anything by mouth to an unconscious person. Get medical
    aid immediately. Wash mouth out with water.
    Inhalation:
    Remove from exposure and move to fresh air immediately. If not
    breathing, give artificial respiration. If breathing is difficult,
    give oxygen. Get medical aid.
    Notes to Physician:
    Section 5 - Fire Fighting Measures
    General Information:
    As in any fire, wear a self-contained breathing apparatus in
    pressure-demand, MSHA/NIOSH (approved or equivalent), and full
    protective gear. Substance is noncombustible. Decomposes at high
    temperatures releasing oxygen which may cause an existing fire to
    burn more vigorously.
    Extinguishing Media:
    Use extinguishing media most appropriate for the surrounding fire.
    Section 6 - Accidental Release Measures
    General Information:
    Use proper personal protective equipment as indicated in Section 8.
    Spills/Leaks:
    Vacuum or sweep up material and place into a suitable disposal
    container. Avoid generating dusty conditions. Provide ventilation.
    Section 7 - Handling and Storage
    Handling:
    Wash thoroughly after handling. Wash thoroughly after handling.
    Remove contaminated clothing and wash before reuse. Do not get in
    eyes, on skin, or on clothing. Do not ingest or inhale. Do not
    breathe dust or fumes. Use only with adequate ventilation.
    Storage:
    Store in a tightly closed container. Store in a cool, dry,
    well-ventilated area away from incompatible substances.
    Section 8 - Exposure Controls, Personal Protection
    Engineering Controls:
    Facilities storing or utilizing this material should be equipped
    with an eyewash facility and a safety shower. Use adequate general
    or
    local exhaust ventilation to keep airborne concentrations below the
    permissible exposure limits.
    Exposure Limits
    CAS# 1314-62-1:
    United Kingdom, WEL - TWA: 0.05 mg/m3 TWA
    United Kingdom, WEL - STEL: 0.15 mg/m3 STEL
    Belgium - TWA: 0.05 mg/m3 VLE (fume, respirable fraction, as V2O5)
    France - VME: 0.05 mg/m3 VME (dust and fume, as V2O5)
    Germany: 0.05 mg/m3 TWA (respirable fraction, exposure factor 1)
    Japan: 0.05 mg/m3 OEL
    Malaysia: 0.05 mg/m3 TWA (respirable dust or fume)
    Spain: 0.05 mg/m3 VLA-ED (respirable dust or fume, as V2O5)
    Personal Protective Equipment
    Eyes:
    Wear appropriate protective eyeglasses or chemical

    safety goggles as described by OSHA's eye and face


    protection regulations in 29 CFR 1910.133 or European
    Standard EN166.
    Skin:
    Wear appropriate protective gloves to prevent skin
    exposure.
    Clothing:
    Wear appropriate protective clothing to prevent skin
    exposure.
    Respirators:
    Follow the OSHA respirator regulations found in 29
    CFR 1910.134 or European Standard EN 149. Use a
    NIOSH/MSHA or European Standard EN 149 approved
    respirator if exposure limits are exceeded or if
    irritation or other symptoms are experienced.
    Section 9 - Physical and Chemical Properties
    Physical State:
    Solid
    Color:
    yellow to brown
    Odor:
    None reported.
    pH:
    4 (50g/l slurry)
    Vapor Pressure:
    0.0443 hPa @ 700 deg C
    Viscosity:
    Not available
    Boiling Point:
    1750 deg C ( 3,182.00 F)
    Freezing/Melting Point:
    690 deg C ( 1,274.00 F)
    Autoignition Temperature:
    Not applicable
    Flash Point:
    Not applicable.
    Explosion Limits: Lower:Not available
    Explosion Limits: Upper:Not available
    Decomposition Temperature:
    Solubility in water:
    1g/125ml
    Specific Gravity/Density:
    3.35 g/cm3
    Molecular Formula:
    O5V2
    Molecular Weight:
    181.88
    Section 10 - Stability and Reactivity
    Chemical Stability:
    Stable under normal temperatures and pressures.
    Conditions to Avoid:
    Dust generation.
    Incompatibilities with Other Materials
    Alkali metals, hydrochloric acid.
    Hazardous Decomposition Products
    Irritating and toxic fumes and gases, vanadium oxide (VOx) gases.
    Hazardous Polymerization
    Has not been reported.
    Section 11 - Toxicological Information
    RTECS#:
    CAS# 1314-62-1: YW2125000 YW2450000 YW2460000
    LD50/LC50:
    RTECS: CAS# 1314-62-1: Draize test, rabbit, eye: 20 mg/24H
    Moderate; Inhalation, rat: LC50 = 126 mg/m3/6H; Oral, mouse:
    LD50 = 23.4 mg/kg; Oral, mouse: LD50 = 5 mg/kg; Oral, rat:
    LD50 = 10 mg/kg; Skin, rabbit: LD50 = 50 mg/kg;.
    Carcinogenicity:
    Vanadium pentoxide California: carcinogen, initial date 2/11/05
    IARC: Group 2B carcinogen
    Other:

    See actual entry in RTECS for complete information.


    Section 12 - Ecological Information
    Not available
    Section 13 - Disposal Considerations
    Dispose of in a manner consistent with federal, state, and local regulations.
    Section 14 - Transport Information
    IATA
    Shipping Name:
    VANADIUM PENTOXIDE
    Hazard Class:
    6.1
    UN Number:
    2862
    Packing Group:
    III
    IMO
    Shipping Name:
    VANADIUM PENTOXIDE
    Hazard Class:
    6.1
    UN Number:
    2862
    Packing Group:
    III
    RID/ADR
    Shipping Name:
    VANADIUM PENTOXIDE
    Hazard Class:
    6.1
    UN Number:
    2862
    Packing Group:
    II
    USA RQ: CAS# 1314-62-1: 1000 lb final RQ; 454 kg final RQ
    Section 15 - Regulatory Information
    European/International Regulations
    European Labeling in Accordance with EC Directives
    Hazard Symbols: T N
    Risk Phrases:
    R 20/22 Harmful by inhalation and if swallowed.
    R 37 Irritating to respiratory system.
    R 48/23 Toxic : danger of serious damage to health
    by prolonged exposure through inhalation.
    R 51/53 Toxic to aquatic organisms, may cause
    long-term adverse effects in the aquatic environment.
    R 63 Possible risk of harm to the unborn child.
    R 68 Possible risk of irreversible effects.
    Safety Phrases:
    S 36/37 Wear suitable protective clothing and
    gloves.
    S 38 In case of insufficient ventilation, wear
    suitable respiratory equipment.
    S 45 In case of accident or if you feel unwell, seek
    medical advice immediately (show the label where
    possible).
    S 61 Avoid release to the environment. Refer to
    special instructions/safety data sheets.
    WGK (Water Danger/Protection)
    CAS# 1314-62-1: 2
    Canada
    CAS# 1314-62-1 is listed on Canada's DSL List
    US Federal
    TSCA
    CAS# 1314-62-1 is listed on the TSCA Inventory.
    Section 16 - Other Information
    MSDS Creation Date:
    8/24/1997
    Revision #6 Date
    6/22/2006

    Revisions were made in Sections:


    9
    The information above is believed to be accurate and represents the
    best information currently available to us. However, we make no
    warranty of merchantibility or any other warranty, express or
    implied, with respect to such information, and we assume no liability
    resulting from its use. Users should make their own investigations to
    determine the suitability of the information for their particular
    purposes. In no event shall the company be liable for any claims,
    losses, or damages of any third party or for lost profits or any
    special, indirect, incidental, consequential, or exemplary damages
    howsoever arising, even if the company has been advised of the
    possibility of such damages.
    -------------------------------------------------------------------------------

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