Coatings Formulation Guide
Coatings Formulation Guide
Coatings Formulation Guide
Formulation
Guide
Formulating High-Quality
Coatings with Celatom
Functional Additives
Case
Studies:
Mica
Talc
Unlike these typical minerals, DE is of biogenic origin, made by microscopic unicellular aquatic plants, called
diatoms. The individual diatom structures are made of nearly pure silica, with a complex, highly porous threedimensional structure.
Comment
Excellent
Function
Comment
Effect on brightness
Good
Good
Good
Good
Touch-up improvement
Good
Suspendability
Good
Good
Ease of wetting
Excellent
Sanding improvement
Good
Scrub resistance
Good
Mar resistance
Good
Chip resistance
Good
Good
Stain removal
Good
Viscosity stability
Good
Excellent
In general, the larger the particle size, the more flat the finish. For a semi-gloss finish, choose Celabrite or MW25. For a matte finish, LCS-3, MW-27, and MW-31 are the best choices. For a textured or non-slip finish, we
offer particle size ranges up to 100 microns.
In addition, our consistent high-quality and uniform particle sizes assure perfect batch-to-batch matching of
color and sheen, as well as clog-free performance in professional spray equipment.
Because of the low density and high matting efficiency of Celatom DE, a high degree of matting can be
achieved with lower mineral content. The resulting lower pigment volume concentration (PVC) means a
stronger and more durable, higher quality coating, at an equivalent or reduced cost. In addition, Celatom DE
will provide all of the other benefits described above.
Celabrite
MW-25
MW-27
MW-31
LCS-3
Sieve Analysis1
%+150 Mesh
%+325 Mesh
0.0
0.0
0.1
1.0
5.0
0.7
Median Particle
Diameter (microns)
9.0
11.0
13.0
16.0
11.0
Hegman
4.0
3.5
1.0
2.0
Density (lbs/ft3)
Wet Bulk
Dry Bulk
31
10
30
10
27
12
25
13
22
9.5
Density (g/l)
Wet Bulk
Dry Bulk
500
160
480
160
430
190
400
210
350
152
pH (10%) Slurry)
9.5
10.0
10.0
10.0
7.5
Color
White
White
White
White
Off-White
GE Brightness
91
90
90
90
83
Oil Absorption2
Water Absorption2
120
-
120
-
135
-
145
-
170
-
Refractive Index
1.46
1.46
1.46
1.46
1.46
CaCO3
Talc
Flux-Calcined
DE
Natural
DE
0
100
200
300
400
500
600
700
100 parts of talc can be replaced with only 30 parts of Celatom MW-25
Alternatively, to maintain the equal solids, 25 parts of Celatom MW-25 and 75 parts of calcium
carbonate may be used in combination
Talc only
MW-25 only
MW-25 + CaCO3
(Equal solids)
225
100
225
-
225
-
30
25
75
45
47.6
35.1
1.258
95.9
2.014
5
40
42.9
32.5
1.234
98.6
2.225
4.5
45
47.6
35.1
1.222
99.7
2.117
3.8
1.3
5
10
0.96
95.89
-0.89
2.84
973
1.3
4.6
4.7
0.971
96.29
-0.77
3
1476
1.2
3.3
1.8
0.948
95.85
-0.69
3.04
1283
15.0
17.3
15.3
7.6
8.8
15.8
3.6
4.3
19.4
Paint Properties
% PVC
% Solids by weight
% Solids by volume
Density (kg per liter)
Stormer, KU
ICI, poise
Grind
Film Properties
Gloss, 20
Gloss, 60
Sheen, 85
Contrast Ratio, 3-mil film
L*
a*
b*
Scrub resistance, cycles
Burnish resistance
Initial 85
85 after burnish
% Increase in gloss after burnish
Interior Acrylic
Talc Replacement
Sample Formulations
Talc Only
MW-25 Only
MW25 + CaCO3
(Equal Parts)
Ingredients
Water
Natrosol Plus
Grams
150.0
0.5
Grams
150.0
0.5
Grams
150.0
0.5
Nopocide N96
2.0
2.0
2.0
Drewplus Y-381
Tamol 731
Triton X-100
PK-80
1.2
5.4
2.8
2.4
1.2
5.4
2.8
2.4
1.2
5.4
2.8
2.4
Tiona 595
Talc
Celatom MW-25
225.0
100.0
225.0
-
225.0
-
30.0
25.0
12.9
100.0
12.9
100.0
75.0
12.9
100.0
290.0
2.0
290.0
2.0
290.0
2.0
Water
Natrosol Plus
150.0
1.6
150.0
1.6
150.0
1.6
Ammonium Hydroxide
Drewplus Y-381
Aquaflow 300
Aquaflow 220
1.6
3.6
15.0
20.0
1.6
3.6
8.5
15.0
1.6
3.6
15.0
20.0
Total
1086
1004
1086
Paint ID
Premix
Texanol
Water
Premix
Replace 25 parts of CaCO3 carbonate and 25 parts of calcined clay with 25 parts of Celatom MW-25
(by weight)
Paint Properties
Paint ID
Without MW-25
With MW-25
1.400
1.361
107
110
2.056
2.135
3.5
Gloss, 20
1.2
1.2
Gloss, 60
1.9
1.7
Sheen, 85
1.2
0.9
0.978
0.964
L*
95.94
96.7
a*
-0.77
-0.74
b*
3.03
3.24
350
396
Burnish resistance
Initial 85
85 after burnish
1.9
4.4
1.4
2.9
131.6
111.3
Film Properties
Interior Acrylic
Partial Replacement of Clay and Ground CaCO3
Sample Formulations
Paint ID
Without MW-25
With MW-25
Grams
172.0
0.5
Grams
172.0
0.5
Diwcil 75
2.0
2.0
Drewplus Y-381
Tamol 731
Trycol 7000
PK-80
1.2
5.4
2.8
2.4
1.2
5.4
2.8
2.4
175.0
175.0
175.0
125.0
150.0
100.0
5.0
12.9
100.0
25.0
5.0
12.9
100.0
175.0
2.0
175.0
2.0
Water
Natrosol Plus
110.0
1.6
110.0
1.6
Ammonium Hydroxide
Drewplus Y-381
Aquaflow 300
Aquaflow 220
Water
1.6
3.6
8.0
15.0
45.0
1.6
3.6
8.0
15.0
45.0
1141
1116
Ingredients
Water
Natrosol Plus
Premix
Attegal 50
Texanol
Water
Premix
10
20% to 30% of Microcrystalline Silica (MS) in semi-gloss paint can be replaced with Celatom MW-25
Reduced cost
Equivalent Performance
Formulation
Microcrystalline
Silica
Replace 20% of MS
with MW-25
Replace 30% of
MS with MW-25
25
20
17.5
7.5
% PVC
21.3
21.3
21.3
% Solids by volume
37.6
37.6
37.6
1.271
1.266
1.268
95
98
99
1.400
1.408
1.420
Gloss, 20
5.7
5.8
6.6
Gloss, 60
38.1
33.6
31.9
Sheen, 85
64.2
54.3
49.8
0.969
0.946
0.958
L*
96.01
96.83
96.43
a*
-0.22
-0.27
-0.23
b*
1.44
1.20
1.20
2581
2635
2705
Burnish resistance
Initial 60
60 after burnish
49.5
50.2
38.2
40.1
37.9
38.8
1.4
4.5
Paint ID
Imsil A 15
Celatom MW-25
Paint Properties
Stormer, KU
ICI, poise
Film Properties
11
Interior Semi-Gloss
Partial Replacement of Microcrystalline
Sample Formulations
Microcrystalline
Silica
Replace 20% of MS
with MW-25
Replace 30% of MS
with MW-25
Ingredients
Grams
Grams
Grams
Water
110.5
110.5
110.5
1.8
1.8
1.8
Dowicil
3.0
3.0
3.0
Propylene Glycol
32.0
32.0
32.0
AMP 95
1.5
1.5
1.5
Strodex PK 05G
3.5
3.5
3.5
Drew L-495
1.9
1.9
1.9
Tamol 731A
7.4
7.4
7.4
5.0
7.5
25.0
20.0
17.5
Paint ID
Premix
Celatom MW-25
Imsil A 15
300.0
300.0
300.0
Drew L-495
2.5
2.5
2.5
Rhoplex
530.0
530.0
530.0
Texanol
19.0
19.0
19.0
Aquaflow 220
15.0
15.0
15.0
5.7
5.7
5.7
1059
1059
Water
1059
12
Replace a portion of the TiO2 with Celatom LCS-3, MW-27, and CelaBrite
PVC = 29%
Conclusion: 5% to 10% replacement is reasonable and effective, with minimal negative effects on
coating color, opacity, and performance.
Formulation
Paint ID
10
15
20
25
30
35
10
Water
20.0
20.0
20.0
20.0
21.0
22.0
23.0
24.0
20.0
20.0
20.0
20.0
20.0
20.0
Tamol 731A
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.3
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
Dowicil 75
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Tiona 595
17.0
16.15
Celatom LCS-3
TiO0.1
0.1
0.1
0.1 by0.1LCS-3
0.1
2 Replacement
15.3 14.45
13.6 12.75
11.9 11.05 17.0
Sample
Formulations
0.2
10.0
10.85
11.7
12.55
13.4
14.25
15.1
15.95
Celatom MW-27
or CelaBrite
10.0
TiO2 Replacement
by LCS-3 (%)
TiO2 Replacement
by MW-27 or
CelaBrite (%)
Potassium
Hydroxide
Drew Plus 381
0.1
16.66
-
10.34 10.68
15.3
11.02
11.36
11.7
4.0
4.0
4.0
4.0
3.0
2.0
2.0
2.0
4.0
4.0
4.0
4.0
4.0
4.0
Ucar 367
40.0
40.0
40.0
40.0
40.0
40.0
40.0
40.0
40.0
40.0
40.0
40.0
40.0
40.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
3.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0
13
2.5
1.5
0.5
0
0
10
15
20
25
30
35
40
% TiO2 reduction
Sheen 85 degrees
b*
10
15
20
25
30
35
83
82
84
84
86
83
85
85
1.961
1.10
1.192
1.183
1.125
1.158
1.567
1.575
Gloss, 20
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
Gloss, 60
3.5
3.4
3.0
2.6
2.4
2.3
2.3
2.3
Sheen, 85
3.1
2.6
2.2
2.1
2.1
1.9
1.8
1.7
0.980
0.969
0.976
0.965
0.968
0.965
0.969
0.983
L*
94.9
94.9
94.6
94.7
94.5
94.5
94.6
94.4
a*
-1.6
-1.8
-1.7
-1.7
-1.7
-1.6
-1.6
-1.6
b*
1.3
1.4
1.4
1.4
1.8
2.0
2.3
2.4
Paint Properties
Stormer, KU
ICI, poise
Film Properties
14
0.8
0.6
0.4
0.2
0
0
10
11
% TiO2 reduction
Sheen 85 degrees
b*
10
89
86
87
86
88
89
0.856
0.75
0.965
0.958
1.022
0.866
Gloss, 20
1.1
1.1
1.1
1.1
1.2
1.2
Gloss, 60
2.1
2.1
2.0
2.0
2.1
2.1
Sheen, 85
0.6
0.6
0.6
0.6
0.6
0.6
0.973
0.971
0.946
0.949
0.937
0.945
L*
96.39
96.44
96.49
96.69
96.20
96.21
a*
-0.35
-0.28
-0.28
-0.27
-0.40
-0.39
b*
1.12
0.69
0.81
0.69
0.69
0.70
Paint Properties
Stormer, KU
ICI, poise
Film Properties
15
10
% TiO2 reduction
Sheen 85 degrees
b*
10
86
85
86
84
85
85
0.869
0.890
0.965
0856
0.902
0.952
Gloss, 20
1.1
1.1
1.1
1.1
1.1
1.1
Gloss, 60
2.3
2.3
2.1
2.1
2.1
1.9
Sheen, 85
1.2
1.2
1.2
1.1
0.6
0.5
0.972
0.952
0.942
0.969
0.950
0.948
L*
96.16
95.80
95.46
96.10
95.65
95.20
a*
-0.28
-0.28
-0.25
-0.13
-0.29
-0.28
b*
0.86
1.15
0.87
1.19
0.82
0.98
Paint Properties
Stormer, KU
ICI, poise
Film Properties
16
Formulation
Ground
Silica
Celatom
LCS-3
74
84.3
Gloss, 20
Gloss, 60
Sheen, 85
Contrast Ratio, 3-mil film (76 m)
L*
86.9
98.6
119.8
0.790
94.86
61.1
91.4
114.4
0.804
94.78
a*
b*
ASTM D 4145 Flexibility
ASTM D2794 - Impact
(1.8 kg weight, 1.27 cm diameter)
-0.61
-0.87
90
-0.72
-0.45
90
10 cm
10 cm
Paint ID
Paint Properties
Stormer, KU
Film Properties
Sample Formulations
Paint ID
Ingredients
Polymac 220-1001
Cymel 303FL
Tiona 595
Dowanol PMA
Aromatic 150 fluid
Total
Ground Silica
Celatom LCS-3
Grams
455.0
75.0
287.0
Grams
455.0
75.0
287.0
4.0
33.5
20.0
4.0
21.0
4.0
33.5
20.0
4.0
-
33.5
67.0
1000
21.0
33.5
67.0
1000
17
Purpose
Supplier
AMP 95
Dispersant
Dow Chemical
Aquaflow 220
Rheology Modifier
Aqualon
Aquaflow 300
Rheology Modifier
Aqualon
Retarder Solvent
Exxon Mobil
Thickener
BASF
Cymel 303FL
Extender
World Minerals
Dowanol PMA
Dibasic Ester
Dow Chemical
Drew L-495
Defoamer
Drewplus Y-381
Defoamer
Cellulose Ester
Extender
Imerys
Pigment
Unimin
Minusil 30 (Silica)
Extender
US Silica
Nacure 1051
King Industries
Thickener
Aqualon
Nopocide N96
Fungicide
Cognis
Filler
Omya
Retarder Solvent
PM Acetate
Solvent
Polymac 220-1001
Propylene Glycol
Solvent
Dow Chemical
Rhoplex ML 200
Sericron 3M (Talc)
Extender
SMI
Strodex PK-80
Hercules
Strodex PL 95G
Hercules
Tamol 731
Dispersant
Texanol
Coalescent
Eastman Chemical Co
Pigment
Dupont
Triton X-100
Non-ionic Surfactant
Trycol 7000
Surfactant
Cognis
Polyvinyl Resin
Dow Chemical
18