Unit 040 NHDS Presentation

Confidential
Naphtha Hydro DeSulphurizer

- NHDS-
1. Position of NHDS
Confidential
PENEX
Overview
FRN from LRU

Unit 011
FRN from Intermediate

Storage, Unit 152 (NNF)
Off-Gas to LRU 011
NHDS
Net Ovhd Liquid to LRU

(C4 Spike case only)
Raffinate from Sulfolane

Unit 048
DLN to PENEX
DSO from Merox

Unit 012/024
DHN to CCR
Platforming
Makeup H2
from HCDS
(NNF)
Makeup H2
from CCR Platforming
Unit 042
2. Outline
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Licensor
: UOP
Capacity
Turn down
: 54100 BPSD
: 50% of Capacity
Feed
: Full range naphtha from LRU
Application of Product Oil

- DLN
- DHN
- Off Gas
- Unstabilized Naphtha
: to PENEX
: to CCR-PL
: to Fuel gas
: to LRU
3. Feedstock and Product Properties

Feedstock Properties
-
IBP
FBP
PONA
SG @ 60oF
Sulphur
Nitrogen
Arsenic
: 45oC
: 180oC
: 69.59/0/19.57/10.84 wt%
: 0.721
: 500 ppm wt
: 1 ppm wt
: < 1ppb wt
Product Properties
-
DLN
: C7+ < 2% wt
: Benzene < 5% wt
: C4 < 4% LV%
DHN
: Sulphur < 0.5 ppm wt

: Nitrogen < 0.5 ppm wt
: End point < 204oC
: Arsenic < 1 ppb wt
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4. Reaction Chemistry
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1. Conversion of organic sulfur compounds to hydrogen sulfide
Confidential
2. Conversion of organic nitrogen compounds to ammonia
3. Oxygen Removal
4. Halide Removal
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5. Saturation of olefins
6. Metal Removal
Removal of metals is essentially complete, at temperatures above 315C,
up to a metal loading of about 2-3 weight percent of the total catalyst.
Desulfurization (HDS)
Confidential
Denitrogenation (HDN)
Oxygen removal
Halides removal
Olefins Saturation
Aromatics Saturation
Catalyst
Catalyst shapes:
Confidential
Catalyst
Bed grading strategy:
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Catalyst
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S-120 (Co/Mo)
Catalyst
Catalyst composition:
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Catalyst
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Active
Promoter
Catalyst
Key performance criteria:
Activity (required temperature)
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Catalyst
Stability (coke make)
Selectivity (desired products)
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5. Simple PFD
H2 From
Plat
Confidential
Corrosion inhibited
Water
AC-101
AC-201
V-101
REACTOR
H-101
V-102
E-203
SWS
R-101
OFF GAS
K-101
To LRU
V-201
P-201A/B
STRIPPER
E-101
SWS
LPG
To LRU
25
C-201
AC-202
From SF
RAFFINATE
E-204
From LRU
V-202
FRN
V-001
FRN FROM TANK
Sulfide
P-001A/B
SPLITTER
23
E-202
From MEROX
P-202A/B
L.NAPHTA
TO PENEX
54
E-206
C-202
E-205
E-201
L.NAPHTA
TO TANK
P-203A/B
TO CCR
H.NAPHTA
AC-203
H.NAPHTA
TO TANK
6. Process variable
Confidential
1. Pressure:
For straight run naphtha desulfurization, 20 to 35 kg/cm2g
2. Temperature:
Minimum reactor inlet temperature is 315C
3. Feed:
If the sulfur level decreases below 0.15 wt-ppm sulfur,
then sulfur should be injected into the feed.
4. Hydrogen to Hydrocarbon ratio:
For straight run naphtha from 40-75 nm3/m3
5. Space velocity:
SRN is processed at 4-12 LHSV
6. Catalyst protection, aging and poisons:
Coke ( 5% wt is OK)
Metals ( 2-3% of the catalyst)
Accumulation of deposit on top of the catalyst bed
Process Variables
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1. Temperature
- Major control variable
- Increased throughout cycle to compensate for decreasing
catalyst activity
- Catalyst activity correlates to Average Bed Temperature
Process Variables
- Temperature set by product specifications
- Increasing reactor temperatures will
+ Lower product sulfur
+ Lower product aromatics
+ Higher temperature rise in reactor
+ Higher deactivation rate
+ Lower product Nitrogen and Oxygen
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Process Variables
2. Fresh Feed Quality
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Process Variables
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Process Variables
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Process Variables
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Process Variables
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Process Variables
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Process Variables
3. Feed rate (LHSV)
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Process Variables
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Process Variables
4. Recycle Gas Rate
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Process Variables
5. Pressure
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Catalyst Deactivation
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7. Corrosion Flow Sheet
Confidential
50oC
H2 From
Plat
52oC
Water
- Wet H2S service

- Ammonia Chloride
54oC
105oC
AC-101
V-102
AC-201
E-203
88oC
R-101
- Wet H2S service
V-101
REACTOR
H-101
Corrosion inhibited
SWS
40oC
K-101
OFF GAS
To LRU
V-201
P-201A/B
STRIPPER
E-101
126oC
SWS
LPG
To LRU
25
C-201
AC-202
From SF
RAFFINATE
E-204
164oC
From LRU
V-202
FRN
V-001
FRN FROM TANK
Sulfide
P-001A/B
90oC
SPLITTER
23
E-202
From MEROX
P-202A/B
L.NAPHTA
TO PENEX
54
E-206
C-202
E-205
E-201
L.NAPHTA
TO TANK
P-203A/B
TO CCR
H.NAPHTA
AC-203
H.NAPHTA
TO TANK
8. Corrosion Management
1. Water Injection
Purpose:
- Dilute corrosive agents
- Prevented fouling ( Ammonia Chloride)
Amount of injection:
- 3% of feed
2. Inhibited Injection
Purpose:
- Protect equipment surface
Amount of injection:
- 5.5 to 6 ppm Wt. in reflux.
Confidential
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THANK YOU FOR YOUR ATTENTION

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Confidential

Naphtha Hydro DeSulphurizer

FRN from LRU

FRN from Intermediate

Off-Gas to LRU 011

Net Ovhd Liquid to LRU

Raffinate from Sulfolane

DSO from Merox

: Full range naphtha from LRU

Application of Product Oil

3. Feedstock and Product Properties

: Sulphur < 0.5 ppm wt

1. Conversion of organic sulfur compounds to hydrogen sulfide

2. Conversion of organic nitrogen compounds to ammonia

Selectivity (desired products)

FRN FROM TANK

7. Corrosion Flow Sheet

- Wet H2S service

- Wet H2S service

FRN FROM TANK

THANK YOU FOR YOUR ATTENTION

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