Cargo Ops
Cargo Ops
Cargo Ops
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CARGO OPERATIONS
MANUAL
Tankers
Revision n. 0
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Port of Registry
International Call Sign
Flag
IMO Number
Record of Revisions
Revision / Date
Rev.0-01/01/05
Rev.1-15/05/05
Rev.2-08/08/06
Rev.2-08/08/06
Rev.3-13/09/07
Rev.4-30/10/08
Rev.5-09/03/09
Rev.6-01/04/09
Rev.7-21/04/10
Rev.8-28/10/11
Rev.9-19/04/12
Rev.10-11/07/12
Rev.11- 18/09/12
Rev.12- 15/02/13
Rev.13-31/01/14
Revision n. 13
Part
Required Action
All
Nil
3
Corrections
10
Addition
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Addition
19
Revisions
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Addition
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Corrections
10.2
Corrections
1;2;3;4;5;6 Revisions
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Revisions
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Addition/revisions
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Addition/revisions
12
Revision
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Revision
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Addition
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CONTENTS
SECTION
PAGE
Table of contents
Loaded Passage
12
13
19
Tank Cleaning
20
22
10
24
10A
31A
11
18A
32
34
12
Ballasting Operations
34
13
34
14
35
15
36
16
37
17
37
18
39
19
41
20
45
21
47
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1.
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This procedure requires Chief Officers to produce Standing Orders for the general
guidance of junior officers on port/cargo watch, supplemented by Night Orders as
necessary.
The Chief Officer is responsible for the issue and content of Standing and Night orders.
Subordinates are accountable for the implementation of these instructions.
The Chief Officer prepares Standing Orders which provide guidance for deck officers
keeping a watch in port, at offshore tanker terminals and during lightering operations.
These Standing Orders incorporate key operating procedures unique to the particular
vessel and include, instructions covering the following:
Emergency shutdown procedures
The circumstances under which the Chief Officer / Master must be called
Response to emergencies
Dealing with verbal and written enquiries from Terminal and Port Authorities
Routine and hourly checks
Checks on the pump room, including the bilges
Mandatory entries in the port (cargo) logbook
Instructions on the completion of company and Charterer's cargo records and returns
Regular inspection of the tank deck and over the ship's side
Moorings.
The Chief Officer's standing orders shall not conflict with this manual and must be
available for reference in the cargo control room. Junior Officers are required to read
these orders and then sign them to indicate acknowledgement and understanding.
Supplementary night orders are required to provide instructions specific to the particular
port and circumstances, and must also be signed by the duty deck officer to register
understanding and compliance. A Night Order book shall be used for this with a copy of
the Standing Orders affixed as a preface.
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This section prescribes general practices and precautions which shall be observed during
all cargo handling operations.
Checklists
Before starting cargo operations the Chief Officer completes Company form as detailed in
section 22 and any Terminal equivalent. Company Form contains the details included in
ISGOTT checklist.
The Ship/Shore checklist shall be completed by the vessel and the terminal. Thereafter at
intervals not exceeding four hours, the required sections shall be checked and verified by
signature.
Gangway Fire and Spill Response Equipment
The cargo manifold shall be guarded by both fixed foam monitors and fire hoses with
portable foam applicators. Dry powder fire extinguishers and foam compound shall also be
located at the manifold. Oil spill response equipment and materials shall be deployed at
the after end of the manifolds on each side of the vessel ready to be used.
Scuppers
Before starting cargo operations all deck scuppers must be plugged to contain on board
any oil spilled as a consequence of accident or equipment failure. Accumulations of
water shall be drained periodically as authorised by the Duty Officer (DO), and scupper
plugs replaced immediately afterwards. Cargo manifold and fuel tank air pipe save-all
plugs must also be in place including plugs around winch containment.
Deck Scuppers are to be effectively plugged at all times whilst alongside a berth and
during any cargo/bunker operations whilst at sea, at anchor or during ship to ship transfer
operations. Opened scuppers must not be left unattended at any time during this
operation.
Fire Wires
One forward and one after fire wire is to be rigged in accordance with terminal
requirements, or with the outboard eye at the water's edge. The inboard end of the fire
wires shall be turned up on bitts and lashed as per ISGOTT recommendation. The fire
wires must be tended regularly by the deck watchmen as the draft changes, to keep the
outboard eye at the water's edge.
Arm/Hose Manifold Connections/Disconnections
Connections and disconnections to the vessel's manifolds are normally carried out by
Terminal personnel, but the ship's crew have to attend to remove and fit the blank flanges
and provide any assistance requested.
Hose connection and disconnection at buoy moorings is normally made by the ship's crew,
using equipment supplied by the terminal.
The connections and disconnections shall be always supervised by the responsible deck
Officer who shall check that the whole operation is done in compliance with the best
marine practice and Company procedures, paying a particular attention to, but not limited
to:
required and appropriate gaskets, as well as reducers, are used;
selected and fair screwing bolts and nuts are used;
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This section prescribes the preparation of a written plan for the cargo loading operation,
and the procedures to be followed in its implementation.
The Chief Officer is responsible for producing the loading plan. The Master is accountable
for ensuring that the plan is written and implemented to the prescribed standard, corrected
and acknowledged by other officers.
The loading process begins on receipt of the Charterer's voyage orders, on which basis
the Chief Officer shall develop the loading plan using the vessel's computer and
hydrostatic data.
The plan must be as flexible as the orders permit, to allow for possible changes in the
cargo nomination and/or ports of discharge. It shall take account of the following:
The plan must be sufficiently detailed to enable officers and crew members to both
understand and implement it. It shall identify the valves and the sequence of their
operation at each stage of the loading operation;
The API or density and the loading temperature of the cargo;
Bunker quantities and disposition;
Cargo characteristics. Handling instructions for specialized crudes such as static
accumulator oils, or those with high levels of hydrogen sulphide;
Calculation of the total quantity to load in long tons, tonnes (Metric Tons), and US
barrels at 60 deg F or cubic metres at 15 deg C;
A stowage plan;
Optimum load and discharge times;
Segregation requirements and line up of tanks and groups;
Draft and trim, air draft, Under Keel Clearance (Company established that UCK during
loading operations should be never less than 2 feet ), stresses (Shear forces and
Bending moments) with estimated hogging or sagging and stability at intervals not
greater than one hour, and in addition at any critical stage of cargo/ballast operations;
Contingency plans for emergency situations;
Finishing the loading operation on a slack tank;
COW requirements at the discharge port;
Load line zones enroute, and changes in sea/harbour water densities;
Finishing loading on an even keel , if circumstances permit, and sailing with a small
stern trim;
Avoiding/minimising dead freight when loading more than one grade at more than one
port;
Handling of ballast and use of ballast pumps.
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The Cargo Officer shall as soon as possible survey and record the level in every cargo,
ballast and bunker tank, including any tank or void space which may have influence on
stability if they should have been accidentally filled or discharged.
The result of the tank survey shall be compared with the Cargo Plan, at the actual step
(or believed) step of operation. If there is any sever discrepancy, and/or there is
evidence that the filling level in any tank does not correspond with the Cargo Plan,
immediate actions shall be taken to Restore Stability.
Actions to Restore Stability may include, but not be limited to the following
considerations:
1. No action to Restore Stability shall be initiated unless the cargo connections have
been disconnected.
2. Mooring stations shall be manned during the operation to Restore Stability.
3. It shall be noted that if the vessel is listing away from the berth, and hanging in the
moorings, the moorings shall be secured and not slacked out. If the vessel is listing
towards the berth, the moorings should be tended just to pick up the slack, and
maintained slack during restoring operation.
4. When it has been verified what is the reason for the Unstable Condition, the Load
indicator shall be used to verify intended corrective actions, and these shall be
documented.
5. If the Unstable Condition is due to excessive free surface in cargo and/or ballast
tanks, extreme caution must be observed when filling liquid in tanks in order to upright
the vessel. If the free surface effect is not reduced, the vessel is likely to tilt to the
opposite side, with even more list than before. Therefore, the free surface effect should
be reduced before trying to upright the vessel.
6. If the Unstable Condition is due to a severe difference in tank levels on opposite
sides of the vessels, this uneven distribution may be corrected by filling or reducing the
levels of the uneven tanks. The reason for the uneven distribution must be ascertained,
and it must be ensured that this will not recur during continued operation.
PRODUCT CARRIERS REQUIRED TO BE FITTED WITH AN INERT GAS
SYSTEM
The basic principles of inerting are exactly the same on product carriers as on crude
carriers.
There are, however, some differences in operational detail, as outlined in the following
paragraphs.
Carriage of Products Having a Flashpoint Exceeding 60C
The 1974 SOLAS Convention, as amended, implies that tankers may carry petroleum
products
having a flashpoint exceeding 60C (i.e. bitumens, lubricating oils, heavy fuel oils, high
flashpoint, jet fuels and some diesel fuels, gas oils and special boiling point liquids)
without inert gas systems having to be fitted or, if fitted, without tanks containing such
cargoes having to be kept in the inert condition.
However, when cargoes with a flashpoint exceeding 60C are carried at a cargo
temperature higher than their flashpoint less 5C, the tanks should be maintained in an
inert condition because of the danger that a flammable condition may occur.
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It is recommended that, if inert gas systems are fitted, cargo tanks are maintained in an
inert condition whenever there is a possibility that the ullage space atmosphere could be
within the flammable range.
When a non-volatile cargo is carried in a tank that has not been previously gas freed,
the tank should be maintained in an inert condition.
The hazards associated with the handling, storage and carriage of residual fuel
oils
Although residual fuel oil normally has a Flashpoint above 60C, it is often stored and
managed at temperatures close to, or even above, its Flashpoint. High Flashpoint fuels
sometimes contain residual quantities of light components that slowly migrate into
vapour spaces after loading, so raising the flammability. It must therefore never be
assumed that the vapour spaces in, and emissions from, bunker tanks will always be
safe simply on account of a high specified Flashpoint.
The first part of this section deals with the flammability hazards associated with residual
fuel oils and provides information on Flashpoint and vapour composition measurement,
together with recommended precautionary procedures to be adopted when handling,
storing or carrying residual fuel oils.
It should be noted that this guidance refers only to residual fuel oils and not distillate
fuels.
Nature of hazard
Residual fuel oils are capable of producing light hydrocarbons in the tank headspace
such that the vapour composition may be near to or within the flammable range. This
can occur even when the storage temperature is well below the measured Flashpoint.
This is not normally a function of the origin or manufacturing process of the fuel,
although fuels containing cracked residues may show a greater tendency to generate
light hydrocarbons.
Although light hydrocarbons may be present in the headspaces of residual fuel oil tanks,
the risk associated with them is small unless the atmosphere is within the flammable
range and an ignition source is present. In such a case an incident could result. It is
therefore recommended that residual fuel oil headspaces are regarded as being
potentially flammable.
Flashpoint
Fuel oils are classified for their safety in storage, handling and transportation by
reference to their closed cup Flashpoint. However, information on the relationship
between the calculated flammability of a headspace atmosphere and the measured
Flashpoint of the residual fuel oil has shown that there is no fixed correlation. A
flammable atmosphere can therefore be produced in a tank headspace even when a
residual fuel oil is stored at a temperature below its Flashpoint
Headspace Flammability
Traditionally, gas detectors such as explosimeters have been used to check that
enclosed spaces are gas free and they are entirely suited to this purpose. They have
also been used to measure the flammability of headspaces in terms of percentage of
the lower flammability limit (LFL).
Such detectors rely on a calibration carried out normally on a single hydrocarbon, such
as methane, which may have LFL characteristics that are far removed from the
hydrocarbons actually present in the headspace. When using an explosimeter to assess
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Advice to Charterer
After approval of the completed loading plan the Master should notify the Charterer of the
details specifically requested in the loading orders, always including the following
information:
1. Confirmation or otherwise that the nominated cargo quantity can be loaded, with the
total quantity in Metric tons/long tons, US barrels/m3. The amount of any dead freight;
2. The cargo API or Density and temperature used;
3. The estimated arrival and departure drafts at the load and discharge ports.
If the voyage or loading orders fail to provide any basic data needed for the cargo uplift
calculation, any assumptions must be stated clearly in the acknowledgement to the
Charterer with a request for confirmation or correction of them.
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Loading Preparations
Preparations for loading the cargo must be largely finished before the vessel's arrival at
the loading terminal. Loading preparations should include:
Check the cargo system pipeline and valve line up. The line up shall be checked by
the Chief Officer and independently by another officer. All cargo and ballast tanks
must be sounded/ullaged prior to starting cargo operations, and the results logged;
The IG deck main non-return valve, block valve, and the engine room master valves
confirmed shut; correct water level in the pressure/vacuum breaker and the deck seal;
Cargo tank high velocity vent-valves (auto mode);
All cargo tank openings must be confirmed closed and properly secured;
Cargo control equipment such as hydraulics, pneumatics and instrumentation
checked before arrival on the berth;
Hydraulics must be test-operated to check for leaks. The hydraulic fluid service tank
topped up to its working level, and a spare drum of oil kept nearby ready for use.
Test communication systems and ensure that all radio batteries have been charged;
Check of 02 content in all Cargo/Slop tanks below 8%.
Tank Survey Before Loading
Shore staff must be accompanied by the Chief Officer when the arrival condition survey is
conducted. All tanks must be checked and a record made of dips and ullages and
corresponding quantities of any oil, water or sediment found. An OBQ certificate is then
drawn up by the Chief Officer for signature by all parties. The Chief Officer has a particular
responsibility to protect the interests of the Company and the Charterer during tank
surveys.
Pre-Transfer Conference (PTC)
The Chief Officer holds a meeting with Terminal authorities to discuss the cargo loading
plan, ship/shore communications, safety regulations, pollution prevention and response
measures, and emergency procedures. Before loading there must be agreement on the
cargo quantity, loading API or Density and temperature, and whether a ship or shore stop
applies; and also on starting, bulk loading and topping off rates, emergency shutdown
procedures, etc.
Starting to Load
When the Terminal gives notice of readiness to start loading the Chief Officer shall make a
final check of the line up, and then open the cargo manifold valve and the first tank valve.
Deck Officer and Deck watch must be equipped with walkie-talkies, with the DO at the
manifold, the pumpman to pumproom, a rating standing by on deck around the cargo
lines, and the Chief Officer in the cargo control room (CCR).
Radar-gauging beams tend to reflect off internal tank structures and may give false
readings during the early stages of loading a tank. In every case the manufacturer's
specific operating and maintenance instructions must always be observed.
After confirming that cargo is entering the opened tank, and only that tank, the main
deck and the manifold connection(s) must be checked for any signs of leakage. The
pump room must be similarly checked. With all checks satisfactory the Chief Officer can
proceed with the loading plan by opening the first-stage tanks and asking the Terminal
slowly to increase to the requested bulk loading rate. The loading rate must not exceed the
limits specified by the shipbuilder, which are based on the vessel's tank-venting capacity.
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Once the requested loading rate has been made checks must again be made of all cargo
tanks, deck and pump room. These areas must be kept under regular and frequent
observation until the loading operation is completed and the cargo system is shut down as
per company check list. The pump room must be inspected and the event recorded at
intervals not exceeding one hour. No changes may be made to the written loading plan
without the Chief Officer's knowledge and authority.
When the cargo flow into more than one cargo tank, levels must be monitored and
controlled to prevent uneven loading and consequent listing or trimming. Only hydraulic
valves should be adjusted to effect the required control, not manual valves. At an
appropriate stage the loading rate of the working tanks should be controlled to stagger
completion of each tank at safe intervals and in a convenient sequence. All completed or
empty tanks shall be checked at each stage of the loading plan, and at regular intervals
not exceeding one hour, to confirm that the tank valves are fully shut and tight. Prints of
on-line cargo computer to be collected hourly.
Care must be taken to ensure that the required minimum number of hydraulic valves is
fully open to accommodate the agreed loading rate. Hydraulic butterfly valves can creep
when the valve controller is left in the neutral position, and may close under the pressure
of oil flowing through the line. Valve controllers must therefore be left only in the open or
shut positions.
The loading plan incorporates a plan for deballasting concurrent with loading cargo. It
must be scheduled for completion well before starting to top off cargo tanks, and aim to
strip dry all ballast tanks by means of the eductors while the vessel is trimmed well by the
stern. The surface of the ballast in the tanks must be sighted and checked free of oil prior
to commencing discharge, and overside checks made when deballasting begins. The
Terminal must be notified before starting.
Topping - Off
This operation must be carefully organised and controlled throughout by the Chief Officer.
It is essential that there are sufficient personnel to maintain continuous monitoring of all
working tanks, and to maintain checks on any tanks, which have been shut down either
temporarily or on completion. The Chief Officer shall ensure that the following steps are
taken in good time before topping-off operations begin:
1. Inform the Terminal and confirm the loading rate;
2. Check the level of the hydraulic service tank;
3. Test the hydraulic valve emergency hand-pump, and station it in the vicinity of the
valve box(es) for the working tanks;
4. Carefully test and confirm the full function of the working tank-valves, and those next
in the loading sequence;
5. Cross check the remote ullaging equipment readings of these tanks against manual
ullages;
Ensure that the maximum flow rate for tank valves is not exceeded.
Use should be made of the remote ullaging equipment display to maintain an overall view
of the loading operation: but for final topping off the U.T.I./M.M.C. manual tape must be
used.
Final ullage should be communicated to Chief Officer by radio to confirm radar reading in
CCR.
The Chief Officer must liaise with the Terminal to agree on notice requirements for
reducing the loading rate, and for stopping; and he must allow for the time needed by the
Terminal to effect such requests.
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Letters of Protests
Whether EDP applies or not protests must always be registered in the specific
circumstances of the following list, which is not exhaustive:
1. There is any difference between ship and shore final cargo figures, however small,
except on specific instructions to the contrary from the Charterer. For example, the
Charterer may stipulate that protest shall not be made unless the ship/shore
discrepancy exceeds defined limits;
2. The vessel is delayed waiting for a berth;
3. The vessel is delayed in the berth for Terminal requirements;
4. The loading rate is less than that requested by the vessel;
5. There is a significant difference between the API or temperature shown on the Cargo
documents, and those quoted in the loading orders and used to calculate the vessel's
cargo requirements and final figures;
6. The agreed cargo nomination was not supplied in full, or was significantly exceeded
on a shore stop;
7. When the vessel's departure is delayed for Terminal requirements after leaving the
berth (usually to await the delivery of cargo documents).
If there is an abnormal difference between ship and shore final figures the Master shall ask
the Terminal to check and confirm their calculations, and instruct the Chief Officer similarly
to check the ship's figures. If these checks confirm the ship/shore difference the Master
shall first contact the Charterer and/or Company for guidance. If the shore figure is greater
than the ship's by more than one percent the Owners must be notified and the Bills of
Lading may be signed only after obtaining a letter of indemnity from the Charterers, in
addition to registering the required routine letter of protest.
Securing the Vessels for Sea
On departure from the loadport the following routine procedure must be effected and
confirmation reported positively to Chief Officer when complete:
1. Check the complete shutdown of the cargo system including all valves whether or not
used during the loading operation;
2. Ensure that all tank and system pressure/vacuum valves are set in the service
position;
3. Operate the IG system to generate a positive system pressure as appropriate in the
prevailing circumstances.
4. Restow and secure all fire fighting and lifesaving equipment placed ready for use in
the berth;
5. Remove and stow main deck scupper plugs;
6. Check the water level in the IG pressure /vacuum breaker and the deck seal;
7. Secure anchors, moorings and fire wires; accommodation ladders and all other loose
deck equipment and fittings.
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LOADED PASSAGE
This section specifies routine procedures to be followed during the passage to the
discharge port.
The Chief Officer is responsible for ensuring compliance with this instruction.
During the loaded passage the following procedures shall be implemented.
Pressurising Cargo Tanks
A positive pressure of inert gas must be maintained in the ullage space at all times in order
to prevent the ingress of air. Loss of pressure is usually associated with leakages from the
system, or falling air and sea temperatures. Every effort must be made to eliminate leaks
at tank hatches, ullage caps, tank cleaning machine openings, PV valves etc. If the
pressure falls below the low pressure alarm level the inert gas plant must be started to repressurise the system.
IG high pressure should be regulated in a controlled manner by opening PV valve
according to Vocon operational procedure before the tank safety devices lift. These are
normally set at 1400mm wg, therefore IG pressure should be released in good time to
prevent this pressure being reached.
Pre-Arrival Checks and Tests
Operational tests of critical equipment and systems must be conducted and routine
inspections made before the vessel's arrival at the discharge port. In order to allow
sufficient time to rectify any defects found these checks shall be made two to three days
before arrival, given a sufficiently long sea passage. Tests and inspections shall include
but not be limited to the following:
Inert Gas System (IGS)
Checks to be performed as per company checklist related to IGS.
A Check Sheet from the IGS Log must be completed on every occasion that an inert gas
operation is carried out.
Cargo Hydraulics System
The hydraulic power unit must be run to pressurise the system to check for leaks and
correct valve operation, and to confirm that both sets are operational. Control system
alarms shall be tested, namely high and low pressure, low oil level, and also the automatic
stop/start function. The portable emergency hand pumps must also be proved to be in
good operational order.
Crude Oil Washing System (COW)
To check for leaks the COW system must be pressure tested to the maximum working
pressure specified in the vessel's COW Operations and Equipment Manual. Any leaking
flanges must be tightened up, or flange gaskets replaced as necessary and the tankcleaning heater must be blanked to isolate it from the COW system. All portable tankwashing machine connections must also be blanked inboard of the branch valve. This is in
order to avoid the possibility an oil leak should the valve fail. This has occurred in the past
due to undrained water being trapped in valve body and expanding in freezing conditions.
Any COW machine-drive units found defective when last used must be checked and
overhauled as necessary. The gearing casings and turbines shall be topped up with oil
and all moving parts such as speed controllers must be checked free and greased. A
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weekly routine shall be established requiring the pumpman to move each machine and its
delivery valve manually over the full operational range to verify and maintain their free
movement.
The checklist pre-arrival at discharge port in vessels approved COW manual should be
copied and completed satisfactorily.
Portable Instruments
The multipurpose U.T.I./M.M.C portable gauging tapes shall be carefully checked for
correct operation and for any signs of developing wear and tear. All portable oxygen
analysers, tankscopes, multi-gas detection units etc. shall be checked and calibrated as
necessary and the findings recorded in the dedicated file.
Note that this pre-arrival check does not supersede or cancel the requirement to complete
the portable analyser Instrument as scheduled. All UHF portable radios and torches must
be tested satisfactorily.
Oil Spill Contingency Drill
An oil spill drill shall be held on every loaded passage to ensure a practised and efficient
response in the event of an accidental spill. Such exercises shall be preceded by a briefing
session to ensure a clear understanding of the plan and its priorities, followed by a
debriefing to discuss and eliminate any identified failings, and to consider possible
improvements.
A record of the drill shall be entered in the deck logbook.
Water Dips
Water dips shall be taken of all cargo tanks the day before arrival at the discharge port,
and the findings recorded in the cargo logbook and reported to the Company.
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This section lays down the process of preparing a cargo discharge plan and prescribes the
cargo operations and procedures associated with putting it into effect.
The Chief Officer is responsible for the plan and its practical implementation, and the
Master for approving and monitoring it.
The Discharge Plan
The Chief Officer shall prepare a detailed cargo discharge plan not less that 48 hours
prior to arrival at the port of discharge, circumstances permitting.
The plan must be presented to the Master and on approval circulated to the deck
officers.
It is essential that the Chief Officer liaise closely with the First and Chief Engineers over
his requirements for services and machinery, such as cargo and ballast pumps, inert
gas, crude oil washing etc; and also regarding other port operations such as taking
stores and arranging repairs.
The plan must provide the following:
1. An overview of the main objectives of the plan, including arrival and departure
conditions and the estimated overall discharge time;
2. The discharge sequence of grades and tanks, with pump and valve lineup;
3. The ballasting operation sequence and lineup must be similarly detailed;
4. The condition of the vessel at least every six hours comprising draft and trim, airdraft,
UKC, stresses with estimated hog or sag and stability, and estimates of quantities
discharged and remaining-on-board;
5. A crude oil washing (COW) plan specifying washing cycles with an overall time
estimate;
6. A narrative section summarising the sequence of discharge operations together with
line up, pump and valve operations at each successive stage. It must be in sufficient
detail to enable duty officers and ratings to follow the plan and verify all lining-up and
changeover operations;
7. It should include which checklists to be completed and when.
Terminal Notification
If voyage sub-Charterers or cargo receivers do not request or accept COW beyond the
mandatory Marpol requirements, the time-Charterer may be held liable for any delays
resulting from additional COW operations. Protest must be noted holding the receivers
liable for any consequent shortage in the out turn if they restrict COW.
The Master shall consult the time Charterer to agree the proposed COW programme in
good time before arrival at the discharge port.
He should then request permission from the terminal authorities to COW, and provide
them with the following information:
1. The discharge and COW plan;
2. The cargo stowage plan and percentage of tanks to be washed;
3. The estimated increase in discharge time resulting from COW operations, if any;
4. Details of personnel in charge of COW operations;
5. Confirmation of satisfactory COW line pressure tests, and operation of IGS.
Reports of various kinds may be required by different port authorities, for example the
EEC tanker check list and USCG requirements.
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Discharge Preparations
Preparations for loading operations, apply in the most part to discharge operations
withparticular attention being paid to line up. If more than one grade of oil is to be
discharged, pumps and pipelines shall be segregated as far as circumstances permit.
Contamination shall otherwise be minimised by draining pumps and pipelines before
changing to a different grade. Particular attention should be paid to heated cargoes and
the order in which they are discharged. Before arrival at the discharge port the Chief
Officer shall conduct a meeting to explain and discuss the discharge and COW plan to all
officers and ratings involved in these operations.
Pre-Transfer Conference
On arrival in the berth the discharge/COW plan must be discussed and agreed with the
Terminalauthorities before starting to discharge.
Shore restrictions or limitations may require changes to the plan, and subsequent
revisions shall be circulated to all concerned without delay.
In addition the PTC must cover the following:
1. Completion of the ISGOTT and Terminal safety checklists, signed by the Chief
Officer and Terminal representative;
2. Ship and Terminal safety regulations and emergency procedures;
3. Ship/shore communications and notification requirements;
4. Pollution prevention and response measures;
5. Slop discharge (if any) and tank stripping procedures;
6. Procedures for draining shore hoses or hardarms on completion of discharge.
Tank Survey Before Discharge
The Chief Officer shall provide the attending cargo surveyor(s) with details of the
discharge plan and the loadport cargo figures, and shall accompany him on the tank
inspection to ensure its correct procedure and accuracy in the interests of the vessel and
owners.
The arrival cargo figures shall be calculated by the Chief Officer independently of the
surveyor(s) and then compared with their results. Any significant difference must be
investigated and reconciled, and a final official figure agreed. The surveyor will usually
take cargo samples on arrival at the berth.
Starting the Discharge
The Chief Officer shall notify the Terminal when he is ready to start the discharge, and
then await confirmation of their readiness to receive cargo.
He shall make a final check of the starting lineup and confirm that:
1. All overboard discharges are blanked;
2. The cargo tank ullaging system are satisfactory working;
3. All IGS operational checks have been completed satisfactorily and that the system is
functioning correctly;
4. Cargo pumps have been primed by means of the purge cocks on the pump casing.
When the Terminal confirms readiness to receive cargo the Chief Officer shall
observer the following procedure:
Position of Duty Officer (DO) at the cargo manifold, the Pumpman in the
pumproom, and one duty rating close to cargo lines, each equipped with a portable
radio;
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Notify the Terminal that the discharge of cargo is about to begin. When pump
control has been transferred to the cargo control room (CCR) the emergency trip
shall be operated to stop the pump. This trip test procedure must be observed on
every occasion that a cargo pump is first started during cargo operations;
After confirming satisfactory operation of the emergency trips the cargo pump(s)
can be restarted and the discharge proper begun;
Adjust IG pressure in the cargo system and switch to automatic. Always make an
additional independent check that the IG delivery valve is open to each individual
tank before starting to discharge from it
Open the cargo manifold valve(s) fully and the pump discharge valve about10-15%.
Obtain confirmation from the Terminal that they are receiving cargo and from the
deck watch that cargo is passing in the manifold; then slowly increase pump speed
in stages while monitoring the back pressure;
Check the manifold hose/arm connections, the tank deck, and the pump room for
any sign of leakage, and also overboard right round the vessel;
Continue to increase pump revolutions while opening the pump discharge valve,
and watch the back pressure and suction readings. Maintain close liaison with the
engine room to keep them informed of the increasing demand on plant and
machinery. If there is any sign of anything other than the normal and satisfactory
operation of all systems, stop the discharge and investigate;
Once the first pump has been run up to the appropriate full speed and the
discharge from the starting tank has settled down, the other first stage tanks can be
opened and additional pumps started.
Care must be exercised when operating two pumps on a common discharge line.
Discharge pressures of both pumps must be equalised to avoid uneven loading and
consequent overheating of one or other pump. Pump revolutions must not differ
significantly.
Keep an adequate back pressure on the pumps by throttling in the pump discharge
valve as necessary: do not use the cargo manifold valves or deck line valves to control
discharge pressures or rates.
Bulk Discharge
The contents of any tank to be used as a source of COW medium must first be discharged
by at least one metre before being used, to ensure the removal of any water in the tank
bottom. If slops are carried the slop tank(s) shall be discharged first and thoroughly crude
oil washed, and then refilled with dry crude oil if they are to be used as the source of the
washing medium.
During bulk discharge the following practices shall be maintained:
1. An hourly record of the manifold back pressure, pump control gauge readings, tank
ullages and average discharge rate. The on line cargo computer shall print data every
hour;
2. An hourly check of the pumproom with a record;
3. Careful monitoring of the operating condition of the cargo pumps for overheating,
excessive vibration, cavitation or hammering;
4. Continuous checks by the deck watchkeepers of the deck, manifold and cargo lines,
and overboard.
5. Periodical inspections of the tank deck by the DO, subject to the proviso that the CCR
shall never be left unattended.
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This section summarises the objectives and prescribes the procedure for the crude oil
washing (COW) of cargo tanks.
The Chief Officer is responsible for preparing the COW plan as an integral part of the
overall cargo discharge plan, and for ensuring its correct and safe implementation.
The main objectives of COW are as follows:
1. A reduction in the potential for polluting the marine environment by oil;
2. The removal of oil fractions and sediment from cargo tanks, minimising or eliminating
the need to water wash them;
3. An improved cargo discharge outturn;
4. A reduction in the extent and duration of tank de-sludging operations in preparation for
drydock/repair periods;
5. Reduced corrosion of tank internals by minimising saltwater washing;
6. More efficient draining and stripping of tanks resulting from the removal of
accumulating sediment and sludge;
7. A reduction in the wear and tear on cargo pumps caused by sediment and solids in
the system;
The Chief Officer must prepare an integrated COW and discharge plan which as far as
possible does not extend the overall discharge time, and which meets the Charterer's
requirements. Approval of the vessel's COW intentions shall be obtained from the
competent authority and the terminal at least 24 hours in advance of arrival. The plan must
comply with the procedures laid down in the ship's Class-approved COW manual.
The checklists in the vessels approved COW manual must be completed satisfactorily
and recorded.
COW operations must be stopped in the following situations:
1. When the oxygen content in the tank cannot be maintained at 8% or less;
2. When instructed to do so by the Terminal;
3. When the IGS fails or is unreliable;
4. When the safety of the operation cannot be maintained.
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This instruction prescribes operational procedures for the inert gas system (IGS). Master is
responsible for any decision relative to the use of IGS while Chief Engineer responsibility
is the availability of a functional and efficient IGS Plant. The Chief Officer and the First
Engineer are jointly responsible for the IGS management according with this instruction.
According with SOLAS, product tankers may carry petroleum products having a flashpoint
exceeding 60C (i.e. bitumens, heavy fuel oils, high jet point fuels, gas oils, etc.) without
inert gas system having to be fitted, or, if fitted , without tanks containing such cargoes
having to be kept in the inert condition. However, when cargoes with a flash point
exceeding 60C are carried at a cargo temperature higher than their flash point less 5C,
the tanks should be maintained in an inert condition because of the danger that a
flammable condition may occur. Company recommend that, cargo tanks are to be
maintained in an inert condition, whenever its possible.
Reference must be made to the ship's IGS instruction book.
Loading Operations
The IGS deck isolating valves shall be shut during loading operations, and safety barriers
such as the deck seal and non-return flap valves confirmed operational.
Individual tank HY JET in auto, I.G. branch line valves and the mast riser (or VECS
manifold valve to shore reception facility) must be open to vent the cargo tanks during
loading. All high velocity vent valves on each tank, must be in the service condition to
provide a backup venting system.
Loaded Passage
On passage the IGS is to be used to maintain a safe positive atmosphere inside the cargo
tanks. VOC MANAGEMENT PLAN is to be applied.
Discharging Operations
A positive IG pressure must be maintained in the cargo system throughout all cargo
discharge operations. Pressurization of the cargo tanks improves cargo pump
performance and reduces stripping time. During tank stripping, when the discharge rate is
low, operation of the IGS shall be closely monitored and controlled to prevent prolonged
periods of re-circulation.
The I.G. system must be capable of (1) delivering inert gas with an oxygen content of not
more than 5% by volume in the inert gas supply main to the cargo tanks, at any required
rate of flow; and (2) maintaining the atmosphere of any cargo tank with an oxygen content
not exceeding 8% by volume, and a positive pressure at all times. Should the oxygen
content of any tank rise above 8% all cargo operations must cease until satisfactory
conditions are re-established.
The IGS oxygen and pressure dual recorder must be used whenever the plant is operated,
and endorsed with the date, time and type of operation. These records are to be retained
and filed for routine inspection and IGS survey.
A Check Sheet from the IGS Log must be completed on every occasion that an inert gas
operation is carried out.
In the event of an inert gas plant failure, when its use was agreed with terminal (other
vessel/barge for STS operation), prior to or during cargo discharge or de- ballasting
operations (from cargo tanks), discharge should not commence or continue until the inert
gas plan operation is restored.
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TANK CLEANING
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This section describes tank purging and gas freeing methods, and prescribes the
procedures to be followed in their application.
The Chief Officer is responsible for the accomplishment of this procedure.
Instructions
1. Prior to a tank being gas freed it must be purged with inert gas to reduce the
hydrocarbon content to 2% or less by volume, so that during the subsequent gas
freeing no part of the tank atmosphere is brought within the flammable range;
2. Depending upon the design of the vessel, the replacement of a tank atmosphere with
inert gas may be accomplished by one of two methods, dilution or displacement;
3. Dilution takes place when the incoming inert gas mixes with the original tank
atmosphere to form a homogeneous mixture throughout the tank. This process
requires maximum turbulence in the tank and the incoming gas must have sufficient
entry velocity to penetrate to the tank bottom. Simultaneous inerting of more than one
tank must therefore be limited to ensure this condition;
4. The displacement method uses the fact that inert gas is slightly lighter than
hydrocarbon gas, so that by introducing it at the top of the tank the heavier
hydrocarbon gas is pushed out via the bottom piping. This method requires a very low
entry velocity to produce a stable horizontal interface between the incoming and
escaping gas, and allows several tanks to be inerted or purged simultaneously;
5. After purging, the tank must be gas freed until gas concentration is not more than 1%
of the LFL;
6. Gas freeing methods- By means of portable fans, hydraulically, pneumatically driven,
delivering air to the tank through the tank cleaning openings. The IGS fans can be
used, but have less effect and penetration than the portable units. The combined use
of portable fans and the IG fans is usually the quickest and most efficient way to reach
the required gas free condition;
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7. The displaced gas/air mixture can be vented to the via the Hy-jet vent, bottom cargo
lines, or purge pipes if fitted. The degree of ventilation and number of openings shall
be controlled to produce an exit velocity sufficient to carry the gas clear of the deck.
Venting must be maintained until the required gas free condition is attained. If a tank
has been crude oil washed and is to be entered for inspection only, it may be possible
to purge and gas free to the prescribed level of safety without water washing;
8. The gas freeing operation must follow a comprehensive written plan, and observe the
following precautions:
Keep all tank cleaning openings closed until ventilation is about to begin.
Portable blowers must be of approved design and construction. They shall be
placed in such positions that all parts of the tank are equally and effectively gas
freed. Ventilation outlets shall be as remote as possible from the fans.
Each tank shall be isolated to prevent the transfer of gas to or from other tanks.
Internal corrosion can cause IG valves to so the line in question must be blanked.
All tank IG valves/lines must be clearly marked to indicate whether they are open
or shut. Check that there are no sources of ignition in the vicinity of tank exhaust
outlets.
9. A log must be kept of the entire gas freeing operation, including periodic atmospheric
test results.
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HEATED CARGOES
Charterers normally specify the temperature at which the cargo must be maintained
during the voyage, and at which it is to be discharged. Voyage orders often require the
application of heating at the start of a lengthy voyage, even though there is ample time
to reach the required discharge temperature by starting to heat much later in the loaded
passage.
While it is clearly desirable to avoid unnecessary fuel consumption the Master should
bear in mind that if specific written heating instructions from the Charterer are
disregarded, he will be held responsible if the vessel arrives with the cargo below the
specified discharge temperature. It may be prudent to heat early as instructed, rather
than later in the voyage with the attendant risk of failing to reach the required
temperature before arrival.
The Master must not expose the vessel and Owners to the risk of breaching charter
party requirements as a result of delaying heating to economise on fuel consumption. In
the event of any uncertainty the Master must seek clarification from the Charterers and
keep the Company fully informed.
Preparation of the loading plan shall take account of the heating coil capacity of each tank.
High viscosity or high pour point crudes should as far as possible be loaded into centre
tanks to reduce heat loss to the sea, and via the shortest route to reduce the heat lost in
pipelines during transfer. Due allowance must be made for cargo expansion as a
consequence of heating during the passage to the discharge port.
Given the opportunity and sufficient notice, any waxy sludge should be removed or
reduced by thorough crude oil washing at the preceding discharge port.
Heating coil pressure tests and any essential maintenance must be completed prior to
arrival at the load port. All coils must be drained and checked for any sign of oil
contamination.
When opening the steam supply to the coils, liaise closely with the engine room to avoid
abrupt steam surges and the possibility of water hammer in the coils.
Raise the oil temperature slowly to avoid overheating and having to shut down for a time,
as this will prolong the settling down period.
When loading is finished, or the operation is suspended for long periods, the lines used for
loading are stripped before their contents solidify. Stripping pump strainers must be
opened up and cleaned out following line stripping operations. The rate of temperature
change in any tank depends on the volume of oil in it, how much heating is applied, tank
location and local conditions. During loaded passage tank temperatures are taken twice
daily at upper, middle and lower levels, and recorded with the sea temperature and
weather. The indicated temperature trend and rate of change in known conditions can be
used to decide if heating adjustments are necessary. There are two ways of controlling the
temperature of the cargo during the loaded passage:
A specific temperature is maintained will be the pour point of the crude plus an allowance
to prevent it from solidifying. This method requires heating sufficient only to reach the
specified carriage/discharge throughout. In the case of HPPC the required temperature,
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with minimum fuel consumption. Excessive heating will waste fuel and may cause
vaporisation of cargo light ends.
The cargo is left unheated at the start of the voyage. Heating is started in sufficient time to
reach the discharge port with the cargo at the temperature stipulated in the charter party
and/or voyage instructions. This method can save fuel as a result of a shorter heating
period. But there are risks associated with the timing of the start of heating, which must
take into account the characteristics of the crude, the expected weather and sea
temperature throughout the passage, and the vessel's heating capacity.
Suspension of heating could cause layering and solidification at the tank bottom, and
impede or prevent further cargo discharge. The cargo temperature must be taken and
recorded daily on departure from the loading port, and twice daily after heating is started.
Thermometers used for this purpose shall be checked for accuracy.
Cargo must be heated to the temperature specified by the Charterer or consignee. The
pour point plus 20o to 25o C is considered a suitable discharge temperature range. If more
than one grade of oil is to be discharged, pumps and pipelines shall be segregated as far
as circumstances permit. Contamination shall otherwise be minimised by draining pumps
and pipelines before changing to a different grade. Any HPPC or HVC parcel should be
discharged last if possible, to avoid the risk of blocking lines with solidified cargo.
As the cargo level falls in a tank, adjust the supply of steam to the heating coils as
appropriate. Once the tank level falls below the heating coils the cargo will begin to cool,
particularly in winter conditions with low sea temperatures. To minimise the risks of
solidification ensure that the cargo is appropriately heated before stripping begins, and that
the stripping operation is done quickly. Bear in mind that excessive heating may cause
light ends to vaporise inside a MCP casing and cause the pump to lose suction. The
objective must be to discharge as much cargo as possible with the MCPs to minimise
stripping time. Should any cargo solidify between the heating coils and the tank bottom,
the transfer of heated crude from another tank combined with increased coil heating may
succeed in reliquifying it.
If any solidification of line contents occurs, try to reliquify it by recirculating part of the
cargo discharge back into a suitable tank via the drop lines. Use only one tank for this
purpose and keep a close check on the tank ullage. Alternatively, connect a steam hose
from the tank-cleaning heater to the manifold drain line to apply heat directly to the
solidified oil.
Crude oil washing. Some crude oils with high pour point temperatures or high viscosity
must not be used for this purpose. The list of such crudes shown the Crude Oil Washing
Operations and Equipment Manual should be regarded as a guide only: it is not
exhaustive. In general only crudes with a low viscosity or pour point should be used.
When COW is effected with a heated crude cargo great care must be taken to avoid
solidification of oil in pipelines and tank cleaning machines. Crude oil washing with high
pour point crudes must be avoided altogether in very cold climatic conditions. The
Charterer's approval must be obtained before crude oil washing a tank with a grade more
suitable for this purpose, but different from that carried in the tank.
On completion of discharge any oil left lying in cargo lines and pumps must be stripped
back to the shore terminal or back to a suitable reception tank on board. If a parcel of
low pour point crude is to be discharged in addition to the heated cargo, permission shall
be sought from the terminal/Charterer to retain some on board for use as a final flush of all
cargo lines ashore.
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Hydrogen sulfide is heavier than air having a vapor density of 1.19 with respect to air.
Therefore, higher concentrations will be found at ground or lower levels.
H2S is highly corrosive to certain metals and can cause a buildup of iron sulfide scale
inside the pipe. When the moisture is removed from this compound, it can
spontaneously combust and burn on its own. Prolonged contact with H2S may corrode
and weaken metal pipes resulting in a major H2S leak and/or exposure incidents.
There are many different hazards associated with this poisonous gas. The main hazard
is inhalation. Absorption of the material through the skin is not considered a significant
hazard. Low levels of exposure may cause the following symptoms individually or in
combinations, increasing with longer exposure:
Fatigue;
Eye Irritation;
Headache;
Dizziness;
Excitement;
Coughing;
Drowsiness;
Nausea;
Pain in the nose, throat and chest;
Higher levels of exposure can intensify symptoms and if the concentration is high
enough, death can result.
The way H2S affects you depends on the following factors:
Duration or the length of time the individual is exposed;
Frequency- how often the person is exposed?;
Intensity- How high a concentration the individual was exposed to? And Individual
Susceptibility or the persons physiological makeup;
At .13 parts per million there is a minimal perceptible odor.
At 4.60 parts per million there is an easily detectable moderate odor
At 10 parts per million, eye irritation begins
At 27 parts per million there is a strong, unpleasant odor.
At 100 parts per million there is coughing, eye irritation and a loss of smell after 2 to 15
minutes.
At 200 to 300 parts per million there is marked eye inflammation and respiratory tract
irritation after 1 hour of exposure.
At 500 to 700 parts per million there will be rapid unconsciousness, cessation of
breathing and death.
At 1000 parts per million and above, the victim falls unconscious immediately and dies
within a few minutes.
The Threshold Limit Value or TLV of H2S is 10 parts per million.
The Short-term Exposure Limit or STEL is 15 parts per million.
The IDLH or Immediate Danger to Life and Health of H2S is 100 parts per million.
The PEL or Permissible Exposure Limit is 10 parts per million as established by OSHA.
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Respiratory Protection
Anyone assigned to a work area that has a concentration of more than 10 parts per
million of H2S must wear protective breathing equipment. If worn properly will protect
the wearer from the potential dangers of H2S. If not worn properly, it does nothing at all!
That is why you must be trained in proper respiratory protection procedures and know
how to fit test your equipment properly.
Monitors and Detectors
There are different types of devices used to monitor a work-site for H2S gas.
Mechanical detectors incorporate a pump, detector tube and a scale to give readings of
H2S. The pump draws air to be tested through the detector tube to react with acetatesilica gel granules. Presence of H2S is shown by the development of a dark brown stain
in the granules. Anytime a situation requires you to use a hand held detector, you are
required to wear or to have ready for use the proper respiratory protective equipment.
Where there is a continuous possibility of encountering H2S (i.e. in pump room),
electronic monitors are installed to give an additional measure of protection to
personnel. These electronic units continuously monitor the area for H2S. When the level
of H2S reaches an established point, an alarm is triggered. There are usually two alarm
points. The first is, at 10 parts per million and the second is at 20 parts per million. The
first alarm is usually a visual alarm and the second alarm is usually audible. Its
important to know what is the setting of the alarms.
H2S Exposure and Concentration Limits
When the concentration of H2S is 10 ppm by volume or above all precautions must be
taken to avoid any danger to the health of personnel on board.
The working place must be all time at lowest possible gas concentration and the
maximum exposure limit is 5 ppm over a period of eight hours .
Precautions when Handling Sour Cargoes
Prior to arrive at load port vessel has to require and to obtain the MSDS of each crude
oil or product before loading in order to take all the preventive actions aimed to avoid
unsafe working practices in cargo handling and to protect the health of the personnel
and visitors. In case of impossibility to obtain the MSDS, checks must be carried out in
order to be aware about the possible H2S content in the cargo.
If the SMDS for the cargo to be loaded show presence of H2S followings precautions to
be followed:
To assure, through continuosly checks and maintenance plan, the gas-tightness
of the cargo tank/holds hatch covers, P/V valves, Vapour Lock System, I.G.S.
and all others possible sources of gas leaks;
To assure gas-tightness to all openings (doors, windows/portholes, air intake
covers etc.) in communication with the accomodation spaces, engine room and
pumproom, furthermore during the operations in port the external air intake
covers must be closed and the air conditioning internal recirculation system in
operation;
All the operations to be performed according the Company Safety Procedures;
To assure the good working condition of the H2S portable, personal and fixed
analyzer/s
;
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pairs and carry personal H2S monitors and emergency escape BA. Closed
loading devices must be used. They must be kept under observation from a safe
location so that the alarm can be raised if they appear to get into difficulties.
When through accident, leakage, or necessary opening of a closed system, H2S
becomes present in the atmosphere, employees shall wear prescribed
respiratory protection;
Any tank, or work area where H2S may be in the atmosphere, should be
approached from upwind if possible. Respiratory equipment shall be worn if H2S
is likely to exceed safe working limits;
Wind socks or equivalent means should be placed at every work location where
the concentration of H2S may be expected to reach or exceed 600 ppm.
During the navigation: If tank venting is necessary, course should be altered to put the
wind on the beam to ensure that the vented gas is blown clear of the tank deck.
Discharging sour Cargoes:prior to arrive at disport vessel has to inform the receiver
about the concentration of H2S in the cargo vapor space and to reduce the cargo tank
pressure to the minimum safety level keeping this level if possible during all the
discharging. This procedures are in addition to the other established for the loading.
After completion of discharge the cargo tanks will contain a high concentration of
hydrogen sulphide gas. To avoid contamination and emission to the atmosphere in port
all cargo tanks must be purged by displacement when in high sea taking all precautions
as above described. It may be also necessary to wash cargo tanks to remove all traces
of H2S gas prior to loading at some terminals. Masters shall establish in advance if this
degree of preparation is required for the next loading.
Entering CargoSpace that Contained High Concentrations of H2S
In areas where H2S is prevalent, an automatic resuscitator, or its equivalent, with extra
oxygen supply shall be kept available at all times. Oxygen must be Grade D breathing
air or medical oxygen.
Respirator face pieces should be cleaned after each days use by washing in warm
water with mild soap or a cleaner-disinfectant solution made for this purpose. They shall
be rinsed and thoroughly dried before being returned to the case. It is important to
remove skin oil from the mask parts to prevent damage to the rubber. Use of chemicals
or other cleaning or sterilization methods, unless recommended by the mask
manufacturer, may damage the mask or cause skin irritation.
Entering Void Space or Ballast Tanks
When carrying, loading or discharging Sour Cargoes before entering any void spaces
or ballast tank adjacent to the cargo tanks the dedicated company procedures to be
followed including the risk assessment with particular attention to the possibility of H2S
presence.
General Nuisances
Mostly of the ports limit or ban the release of H2S to the atmosphere and this is also the
company policy therefore is necessary to maintain cargo tank pressure within
acceptably low limits when discharging and/or cowing keeping in mind that tank vapour
pressure will rapidly increase if cargo is heated or agitated or tanks cowed.
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First Aid
Since the result of exposure to H2S is paralysis of the nerves controlling respiration,
persons stop breathing and lose consciousness quickly. If the victim is promptly
removed to a safe area and artificial respiration is started immediately, the chances of
complete recovery are good.
Any delay in the start of artificial respiration appreciably reduces chances of recovery.
Even though chances of recovery may seem slim, artificial respiration should be
continued until normal breathing is resumed, or until a physician assumes full
responsibility for the patient, or the rescuer is physically unable to continue.
Any person overcome by hydrogen sulfide should be treated for shock, that is, kept
warm while artificial respiration is being applied and kept quiet until he can be checked
and released by a physician.
Note: If your eyes become irritated or you notice a halo around an electric light while
working in a place or area which has been determinated to be safe from H2S, take the
following precautions:
Leave the area at once and move upwind
Flush eyes thoroughly with water.
Wear respiratory equipment with full face protection if necessary to return to safe
location.
10.3
Enormous amounts of bunker fuel are consumed each year by the world fleet of cargo
and commercial vessels as well as the military ones. Recent estimates give figures
around 290 million tons where about 80% is heavy fuel oil. Totally there are about
90.000 merchant vessels over 100 gross tons as well as almost 20.000 military vessels
in the world (1).
The heavy fuel oil (HFO) mainly consists of residual refinery streams from the distillation
or cracking units in the refineries. The crude quality as well as the refinery process
governs, to a large extent, what type of HFO youll end up with. For example a high
sulphur crude will result in a high sulphur HFO and catalytically cracked residual oil will
contain more carcinogenic polycyclic aromatics (PCA*) than a straight run residual oil
from atmospheric distillation (2).
Typical values for a European catalytically cracked HFO of the viscosity 380 cst, are
around 2.6% sulphur and 13-18% polycyclic aromatics. Low sulphur fuel ( 0.5% S) may
have lower values of polycyclic aromatics. Other components from the crude like
organo-metallic or metallic substances can also be found in the HFO as well as
additives like pour point depressants, combustion improvers etc.(5)(6)(2).
All HFOs on the market are classified as carcinogenic (cat. 2), harmful and dangerous
for the environment according to the EU Dangerous Substances Directive (3).
Additionally there are reports about hazardous waste and other chemical waste streams
finding the way into heavy fuel oils today (4).
Other bunker fuels than the HFO are the marine diesel oil (MDO) and the marine gas oil
(MGO). These are distillates from the refinery process with much lower viscosity, lower
sulphur content (MDO usually < 1%S, MGO<0.2%S) and usually lower PCA than the
HFO (6)(7).
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Bunker fuel and especially the heavy fuel oil may constitute a risk for man and
environment on a number of occasions during its handling and use on board a ship:
1. Bunker operations This is when the fuel is transferred from small bunker boats to the
receiving ship. It can be done at berth but also out at sea, day or night all the year
round. Large amounts are usually handled under sometimes bad conditions. Things
can and have gone wrong and a large spill may have a crucial effect on the marine
life.
2. Bunker handling on board Inevitably there will a direct contact between the fuel
and personnel in the engine room personnel in the engine room. HFO is classified
as carcinogenic and there is also shown a higher frequency of certain cancer types
among engine room personnel (lung, urinary bladder). Additionally it is shown that
certain PCA components from the HFO are found in the urine of persons who have
been exposed to HFO on the skin. It is also shown that a damage of the genetic
material actually occurs (8)(9).
3. Emissions from fuel burning Emissions mainly depending on fuel quality are those
of sulphur and polycyclic aromatics. The larger the amount in the fuel the large the
emission. Sulphur emissions from shipping are a major and increasing contributory
cause of acid downfall which puts a heavy burden on forests, soil and lakes in for
example Scandinavia. Sulphate particles may also create health problems in
densely populated areas (10)(11)(12).
Emission of polycyclic aromatics are also shown to be proportional to their content
in the fuel. An estimate made for Goteborg reveals that one big ship entering the
harbour and using catalytically cracked HFO, emits the same amount of PCA as
1200 heavy trucks (13)(6).
4. Sludge handling and tank cleaning Spills of fuel oil on board should end up in the
sludge tank but todays mixtures of fuel oils, lubricants, detergents, solvents and
water often create stable emulsions in the bilge water tank.
Without modern bilge water cleaning equipment this may lead to either discharge of
bilge water containing hazardous components at sea or leaving all waste water
ashore. Harbours in their turn are usually not equipped with cleaning facilities for
large amounts of these complex mixtures.
Despite over 20 years of international conventions and bans, cleaning of sludge
tanks and product tanks is still going on at sea. This leads to an everlasting
presence of thich oil-slicks all along the Swedish coast. Every year about 100.000
long-tailed duck die at Hoburgs bank in the South Baltic Sea due to oil spills
(14)(15).
SOLUTION
The best option is as usual to tackle the problem at its source. If, for example, sulphur
and PCA were removed from the residuals or cleaner distillates were more used as
bunker fuels, many of the risks would radically decrease.
The cost of desulphurized residual oil is calculated to be around 50-90 Euros extra per
ton (2002). Todays price of standard 380cST HFO is around 140 Euros/ton (5)(16).
Almost no refineries in the world desulphurize or dearmatize the residual refinery
streams yet.
There s a number of measures that can be taken at once though:
Safety bunkering. The Port of Goteborg has carried through a successful project called
Green Bunkering after having had a serious spill incident at a bunker operation. It was
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a project in cooperation with the bunker companies, environmental authorities and the
Coast Guard. A lot of safety measures were taken as better communication,
information, equipment etc. An authorization scheme for bunker boats in the harbour
was developed the Green Bunker Card.
Safer handling of bunker fuel on board. Everyone on board should be fully aware of
the fact that heavy fuel oils is carcinogenic and every contact with skin should be
avoided. Oil resistant clothing and gloves should always be used in contact with the
fuel. Better gloves should be developed for fine mechanical work.
Cleaner fuels especially in densely populated harbours. Low sulphur and low
PCA fuels should primarily be chosen to decrease the burden of acid downfall and the
emission of carcinogenic compounds in the environment. The health aspects are
especially important in harbours. There distillate fuels should be used as far as possible.
Another option is to fit cleaning equipment on board such as scrubbers and particle
filters.
Fuel quality directive. Today there is insufficient standardization and control of bunker
fuel to ships. Ship-owners do not really know what they get until it can be too late. A fuel
quality directive like the one for fuels ashore, should be developed. Primarily within the
EU but in the long run globally. To prevent that waste is blended in the fuel parameters
like polycyclic aromatics, calcium, zinc, phosphorous and organic halogens should be
controlled before the fuel is delivered.
Tanks assigned for the carriage of fuel oil following a previous cargo of crude oil must
be cleaned in strict accordance with the Charterer's instructions. If no clear instructions
on tank preparation are issued with the voyage orders they must be obtained from the
Charterer.
Protest shall be noted if the vessel is instructed to load a cargo comprising both fuel and
crude oil parcels. The heavy fuel and crude oil consignments shall be loaded and
discharged in strict segregation. If the vessel is directed to use one or more lines or pumps
for both parcels advance agreement to such a proposal must be obtained from the
Charterer and/or the receivers, and protest noted. The lines and pumps concerned must
be drained between grades to minimise the risk of contamination of the fuel oil parcel.
Fuel Oil Containing H2S
H2S as a substance can be found in bunkers in either a dissolved state (that is in the
liquid phase) or as an evolved gas originating from the bunker fuel. The example
supplied within the ISGOTT Publication suggests a correlation between the dissolved
state and the equivalent quantity of evolved gas is a factor of 100, e.g. 1 ppm dissolved
in the liquid phase will potentially create 100 ppm concentration of gas in the vapour or
head space.
Due to the relatively low concentrations of this substance in the liquid phase, there will be
negligible impact upon the total Sulphur content of the fuel oil as delivered. Thus
vessels personnel will not necessarily be aware of the presence of this type of
substance in a bunker fuel on or prior to delivery to a vessel but, subject to its
concentration, may detect it by smell (it smells like that of rotten eggs).
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Given the TLV (Threshold Limit Value) of H2S gas at 10 ppm it can be readily seen that
the extent of H2S in the dissolved state needs only to be at levels in excess of 0.1 ppm
before health/safety problems can occur. The ISGOTT Publication supplies a series of
expected symptoms for those suspected of inhaling this gas, which are as follows:
50 100 ppm
Eye and respiratory tract irritation after exposure of one hour.
200 300 ppm
Marked eye and respiratory tract irritation after exposure of 1 hour
500700 ppm
Dizziness, headache, nausea, etc. within 15 minutes, loss of
consciousness and possible death after 30-60 minutes exposure.
700 900 ppm
Rapid unconsciousness, death occurring a few minutes later
1000-2000 ppm Instantaneous collapse and cessation of breathing
Given the refining and production process involved to generate the oils used for
blending to create an acceptable quality bunker fuel, it is not to be expected that
substances such as H2S would be present. Given that H2S has a boiling point of
roughly 60 degrees Centigrade, this substance would have been removed during the
primary distillation of the crude oil, if present in the original crude oil feed stock. Thus in
order to find a possible alternative source for this substance in a fuel oil it is perhaps
necessary to look to sulphur degradation caused by micro-organisms typically
Sulphate Reducing Bacteria (SRBs). If this is the source of the production of H2S in the
bunker fuel, which is a possibility, then fuel tanks onboard the vessel will become
infested creating potential longer term problems for the vessel particularly with regard to
efficient purification of the fuel and the potential for blockage of filter systems within the
fuel supply system to the main engine. These later problems are caused by the
generation of sludges and emulsions created by these organisms.
Hydrogen Sulphide (H2S) is a flammable gas having explosive limits created by a
mixture of between 4.3% to 46% with air. Further H2S is soluble in water creating a very
acidic (sour) water or water droplet. This sour water droplet will be a very good
electrolyte promoting corrosion activity in the head space or vapour phase of the
storage tank. Some crude oil tankers have already experienced the intensive pitting
created by the by products of SRBs in their cargo tanks.
Thus, in conclusion, it is recommended that great care be exercised on board when it is
suspected (by smell) that a bunker fuel contains H2S particularly if the evolution of this
substance is due to the infestation of the bunker fuel by SRBs.
10.4
This type of crude has a pour point higher than normal ambient temperatures and it will
therefore solidify without heating. Moreover wax separation and sedimentation will begin
when the temperature falls through the cloud point, usually some 15 degrees centigrade
above the pour point temperature.
In some cases the wax cannot be reliquified by subsequent heating, leading to a high
unpumpable sediment remaining on board at discharge, and the possibility of a
consequent cargo damage claim.
HPPC is loaded in a heated condition and usually the Charterer's voyage orders will
specify heating requirements. If heating instructions are not received or are unclear,
heating must begin on loading and the Company must be notified immediately. In this
situation and until explicit instructions are received from the Charterers or the Company,
carriage temperature shall be the published pour point for the particular crude plus 15
degrees centigrade.
Heating must be controlled and continuous. Suspension for any appreciable period might
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halt thermal circulation and could result in convective layering, with wax sedimentation
occurring in the cooler layers.
This condition is not readily corrected by a resumption of heating, which can sometimes
augment layering. Cargo temperatures must be taken daily during carriage and recorded
at a range of depths down to and including the bottom plating.
Precautions when handling
The pour point and the cloud point are 2 parameters that must be known when handling
any petroleum cargoes because are very useful during the loading, carriage and
discharging in order to safely handle the cargoes with no loss of cargo at discharging port.
The pour point of petroleum product is the minimum temperature at which the fluid will
pour or flow under test conditions. This is an indicator of the ability of a fluid crude or
distillate fuel to flow at cold operating temperatures.
The cloud point is the temperature at which a wax cloud first appears on cooling crude or
product under specific conditions. At cloud point , the wax crystals tend to clog filter
preventing proper equipment operation.
Both, or at least the pour point, of above parameters are found in the cargo quality
certificate and SMDS. Once again the SMDS must be received prior the loading in order to
know also the cargo characteristics , if not received, during the pre-loading operation
Ch.Officer must require at least the Pour Point of the cargo to be loaded.
A HPPC(high pour point crude) is a crude that has a pour point higher than normal
ambient temperatures and it will therefore solidify without heating, usually occurs in crude
oils that have significant paraffin content. Moreover wax separation and sedimentation will
begin when the temperature falls through the cloud point, usually some 15 degrees
centigrade above the pour point temperature.
In some cases the wax cannot be reliquified by subsequent heating, leading to a high
unpumpable sediment remaining on board at discharge, and the possibility of a
consequent cargo damage claim.
HPPC is loaded in a heated condition and usually the Charterer's voyage orders will
specify heating requirements (see heated cargoes section instructions).
When a HPPC is to load or discharge the cargo loading/discharging plan must be
prepared taking on account the pour point of the cargo to load , the ambient and the on
board ballast water temperatures with the aim to avoid cargo cooling due to its contact
with the bulkhead between cargo and ballast tanks. For this reason when
loading/discharging the HPPC all around the tank to be loaded no ballast water must be in
contact with the bulkhead of related cargo tank unless for safety or stability or stress
reasons ,unless the ballast water has at least the same temperature of cargo to be loaded
or discharged.
Same precautions to be used during the carriage of HPPC.
During the discharge or loading, in case of stoppages, the lines must be drained if external
temperature is not at least the same of cargo loaded or discharged.
During the discharging all precautions taken as detailed in the heated cargo sections must
be also followed.
10.5
In general HVC does not solidify at ambient temperature, but is difficult to discharge
because of its high viscosity.
The viscosity of an oil increases with a decrease in temperature, and vice versa. A
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centrifugal cargo pump should be capable of discharging cargo at up to 1000 cSt but, to
reduce the likelihood of damage to the pump mechanical seal and ensure smooth
operation, viscosity should be lowered to less than 500 cSt.
Reference should be made to the viscosity/temperature conversion table on the following
page to estimate the viscosity corresponding to the temperature of a particular crude oil.
This will indicate whether heating is advisable to lower its viscosity before discharge.
10.6
Crude oils of this category are defined as having a true vapour pressure (TVP) of 1.0 bar
or higher, and a resultant tendency to vapour loss during carriage.
During loading the following precautions shall be observed:
Avoid loading when the wind velocity is less than five knots;
Ensure a very low initial flow rate into tanks;
Ensure very low topping off rates;
Avoid creating a partial vacuum in the loading line;
Maintain closed loading as far as possible;
Monitor gas dispersion and ensure compliance with all safety requirement.
During discharge the following precautions shall be observed:
Reduce the speed of the MCPs in sufficient time to prevent cavitation and loss of
pump suction at low tank levels;
Bleed off gas from MCP casings as necessary;
Pressurise the cargo tanks with inert gas to raise the suction head of the cargo
pump(s).
Completion of tanks should be staggered because stripping is more critical with crudes of
this kind, often requiring pump priming from tanks with a greater head of cargo.
If a parcel of heavier crude or one with a low vapour pressure is also carried, permission
should be requested from the Charterer or consignee to draw from this parcel when
pumping HVPC at low tank levels and when stripping. The resultant blend should pump
better, prolong the use of the MCPs, and minimize any unpumpable HVPC remaining on
board.
As far as possible HVPC should be loaded in tanks chosen to maintain the carriage
temperature, assist cooling, and facilitate efficient pumping, according to circumstances.
For example, centre tanks for a summer zone discharge port, wing tanks for a winter zone
discharge port, and after tanks for proximity to the pumps.
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Bilge water cleaning and stopped dumping. The tradition gravimetric bilge water
separation is not sufficient for the complex mixtures of oils, surfactants, solvents and
water going down to the keelson in modern ships. Active cleaning equipment breaking
the stable emulsions should be installed if the bilge water is to be discharged in the sea.
The no-special fee system in combination with active surveillance and powerful
enforcement of environmental laws should be able to decrease the dumping of oil at
sea.
* PCA or polycyclic aromatics is a parameter including polyaromatic hydrocarbons
(PAH) but is also covering substituted PAHs with for example sulphur, nitrogen or
oxygen.
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11.
Premuda
This procedure prescribes the preparation of the vessel's cargo tanks for drydocking and
major repairs.
The Chief Officer is responsible for the implementation of this instruction.
In the months preceding a scheduled drydocking or major repair undertaking, all cargo
tanks shall be inspected to determine the extent and location of sludge accumulations.
Every opportunity should be taken to progress crude oil washing of the tanks, in particular
bottom washing at slow speed to remove sludge. During the final cargo discharge before
drydocking a very thorough COW of all tanks must be carried out.
Planning Considerations
A tank cleaning plan shall be prepared by the Chief Officer and submitted in good time to
the Master and Chief Engineer for discussion and confirmation. The plan shall then be
passed to the Company for final approval. It must comprise a daily itinerary and timetable,
and encompass washing, purging, gas-freeing, inspection, hotwashing and de-sludging of
tanks; also associated operations such as cleaning pumps and main/stripping-lines and
vent systems, and work schedules for mucking gangs or riding squads as appropriate. The
following factors shall be considered:
1. The length of the ballast voyage and manpower available to accomplish the plan;
2. Weather conditions expected en route to the repair port, which might adversely affect
tank cleaning operations, such as cold air and sea temperatures, and bad weather;
3. The number and capacity of fixed and portable tank cleaning machines and gas
freeing fans;
4. The capacity of the tank cleaning heater;
5. Ballast requirements for the repair berth or dry dock;
6. Contingency arrangements for equipment failure, operational difficulties, and delays;
7. Assessment of equipment, consumables and fuel needed for the proposed cleaning
operation. Additional equipment and stores might include the following:
Portable washing machines, hoses and couplings
Portable gas-freeing fans, ventilation tubing and air ducts
Portable gas detection instrument
Air driven turbo-lamps
Air hoists and spare wires
Spare parts for all tank cleaning equipment
Shovels, brushes, mops, tools, buckets, ladders, stages, rope
Cleaning rags, sawdust, chemicals, oil and grease remover
Sludge sacks, plywood, Personal protective equipment
The Tank Cleaning Plan
The precise details of the plan will be ship-specific, but shall conform with the following
outline:
1. Wash top and bottom cargo lines, manifold and pumps, flushing back to the slop
tanks.
2. Commission the tank cleaning heater and slop tank heating coils. Hot wash all cargo
tanks with the fixed machines on a full washing programme.
3. Purge and gas free the tanks, and check that the atmosphere is safe. Inspect all tanks
and start de-sludging operations.
4. Inspect each tank on completion of desludging, and decide if any further cleaning is
necessary. Use portable washing machines to hot spotwash any areas where sludge
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The Chief Officer will remain in charge of operations and will maintain close liaison with the
foreman throughout. Riding squads are prohibited from entering any tank without the
authority of the Chief Officer who will observe the enclosed space entry procedure on
every occasion, and regularly monitor conditions inside any tank in which men are
working.
11A. CLEANING PROCEDURE FOR CHANGE OF PRODUCTS
In case the vessel has to change product it is normally requested one tank cleaning of
those tanks dedicated to load the new product. The Tank Cleaning Guide (on board of all
managed Vessels) reports what preparation is necessary to load the products. Two
sections of the Guide give the cleaning procedures (e.g. only cargo line and pump
stripping or butterworth with cold water for two hours, etc.). Ships Command has to follow
this Guide and consider it as Company procedure. Technical procedures for cleaning are
the same described in sections of this Manual.
For those Vessels in TC Charterers/Shippers/Receivers may request not to clean before
new loading operations. In this case, request should be a formal request and Company
Ops Dept. should be contacted for information/confirmation.
12.
BALLASTING OPERATIONS
The Chief Officer is responsible for the ballast operation during the cargo handling (ballast
is concurrently with cargo operations) so when making the loading/unloading plan the
ballast/deballast plan is to be inserted accordingly.
See Company BALLAST MANAGEMENT MANUAL.
Typical Procedures for Ballasting and the Method of Preventing Hydrocarbon
emission (for Aframax Class vessel type)
This Section is not applicable to this vessel as being a SBT tanker.
However, if it becomes necessary to ballast empty cargo tanks due to severe weather
conditions such ballast is only allowed to be carried in tanks which have been crude oil
washed during the last discharge of cargo. Any such ballast must be treated and
discharged in accordance with the requirements in Section 16. In case the vessel has
carried a cargo or a part cargo that is not suitable for crude oil washing arrangements
must be made to wash the tank with a lighter crude oil or with hot water before it can be
used for carriage of heavy weather ballast.
Heavy weather ballast can, when necessary, be loaded over top into cargo tank #4 via a
spool piece connection on deck from the port side ballast line.
13.
Officers shall familiarise themselves with the content of the cargo pump manufacturers'
instruction manual.
The following general operational points shall be observed:
Notify the engine room in good time before the pump is required, and ask them to start
warming through;
Check that the discharge valve is shut and the suction valve fully open;
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Prime the pump by opening the air vent valve on top of the pump casing: shut it when
liquid appears. If the tank level is lower than the pump then the air vent valve must be
kept closed and the pump primed using the stripping pump, or vac-strip equipment if
fitted;
Check that the pump speed governor is in manual control and set at minimum, and
ask the engine room to start the pump turbine and bring the pump up to slow speed.
Do not adjust the pump speed before the engine room indicate that control has been
passed to the cargo control room (CCR);
Increase pump speed gradually and as the discharge pressure rises slowly open the
discharge valve to its maximum;
Check the pump for normal operation;
Notify the engine room before making large alterations in pump speeds;
Keep a close check on tank levels so that the pump never runs dry or loses suction:
cavitation and allowing the pump to draw air can damage it;
Check the MCP casing and bearing temperatures, and if necessary stop the pump
and vent air/gas from the pump casing;
Reduce pump speed to maintain pumping capacity when cavitation starts. When
cavitation occurs after pump speed has been reduced to a minimum, shut in the
discharge valve to maintain pumping: if this response is unsuccessful, stop the pump.
Exercise particular caution when using a self-priming MCP for stripping operations;
Give the engine room at least 30 minutes notice before stopping cargo pumps. Slowly
reduce the pump speed and shut in the discharge valve. When the pump is on
minimum control rpm, stop it and shut down the system;
In an emergency press the emergency stop button to stop the cargo pump(s), and
then inform the engine room.
When pumps are being used in parallel adjust individual pump speeds as necessary to
keep their discharge pressures equal. If the speed of one pump decreases and its shut-off
pressure drops below the discharge pressure of the other pump(s), it will cease to
discharge and the pump casing will rapidly overheat. All pump speed alterations must be
made slowly.
To prevent surge pressures on cargo and COW lines, cargo pump speed must be reduced
to a minimum before changing the valve lineup or pressure testing the COW line during
discharge operations. Surge pressures can easily damage cargo and COW lines.
14.
Before using a stripping pump notify the engine room in good time and ask them to be
ready to start warming through. Open the drain, exhaust, suction and discharge valves.
Lubricate moving parts as necessary, and check that all bolts and nuts are tight. Crack
open the steam supply valve to move the pump very slowly and drain off water in the
system. Shut the drain valve when all water has been displaced and drained. Open the
test valve on the valve box cover to vent any air in the system.
With all water drained off and the pump warmed through, gradually open up the steam
supply valve until the required steam pressure and pump speed is reached. Check the
operation of the pump for leaks or any indication of malfunction. The pump should be
started from the local control position so that the pumpman can monitor its initial operation.
If this is satisfactory, control of the pump can then be transferred to the CCR. The
discharge side of the pump must be kept fully open at all times, while the suction valve
setting and pump speed should be adjusted as necessary to maintain good suction.
The pump must be checked and oiled at intervals not exceeding one hour. The
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pumpman's checks must include an inspection of steam gland packing, which must be
tightened up evenly if there is steam leakage. The stripping pump gauges must be
monitored closely for any indication that the pump has become vapour- or air-locked.
This will result in the loss of suction and short stroking of the pump, which can cause
damage if prolonged: the pump must not be run dry. To recover the suction reduce
pump speed, close in on the suction side, and prime from another tank with a greater
head of oil if necessary. On completion of stripping operations, the pump should be
slowed down and stopped. Close the steam valves and open the drain valve. Close the
exhaust, suction and discharge valves, and inform the engine room that stripping steam
is no longer required.
15.
Eductors can be used alone or in parallel. When used in parallel total stripping capacity
is greatly increased. The drive for eductors is taken from a MCP, which may also be used
to drive COW machines. When tank washing ensure that the eductor capacity
substantially exceeds the delivery of the COW machines. All eductor inlet and outlet
valves must be opened fully before starting. Monitor the suction pressure gauge to ensure
that there is a good vacuum before opening up the suction valves to the tank.
For optimum performance of the eductors the drive pressure must be as specified by the
makers. Ensure that this drive pressure is known and maintained by all operators. For best
effect operate the eductors on stripping rather than main cargo lines and valves.
Keep a close check on slop tank levels when using the eductors.To stop eductor
operations shut the tank and eductor suction valves, reduce the drive-pump speed, and
then shut the eductor drive and discharge valves.
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16.
Premuda
The incorrect operation of pumps and valves can produce pressure surges or water
hammer in a pipeline system. These surges may be sufficiently severe to cause damage
to the pipeline, hoses or hardarms. One of the most vulnerable parts of the system is the
ship to shore connection. Pressure surges are produced upstream of a closing valve and
may become excessive if the valve is closed too quickly. They are more likely to be severe
where long pipelines and high flow rates are involved.
Where the risk of pressure surges exists, information should be exchanged and written
agreement reached between the tanker and the terminal concerning the control of flow
rates, the rate of valve closure, and pump speeds. This should include the closure period
of remote controlled and automatic shutdown valves. These arrangements should be
included in the ship's cargo plan.
A pressure surge and/or water hammer may result from the following actions:
1. Shutting a valve against the flow of liquid in a line;
2. The sudden stopping of MCPs or large and sudden changes of pump speed;
3. Abrupt or incorrect changeover of valves or pumps during cargo operations;
4. Introducing liquid under pressure into an empty pipeline;
5. Moving a mixture of liquid and vapour under pressure through a cargo pipeline, or a
mixture of water and steam through a steam line;
6. Failure to drain steam lines of water before opening the steam supply valve.
Pressure surges and water hammer can cause serious damage to cargo lines and steam
lines, and may also lead to personal injury. They must be avoided.
17.
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Where p 1
y
d
= Measured dip
= Distance from measuring point to aft bulkhead of tank
= Tank ref height
= Trim angle in degrees ( Tan-1 Trim )
LBP
This formula assumes that the liquid is free flowing and that the vessel is upright at the
time of measurement.
Worked Example
VLCC, LBP 320m, Breadth of Tank 20m, y = 4m, ref height d = 30.5m, measured dip, p 1 =
40 cm. Trim = 8m. Calculate the volume of liquid remaining in tank.
Trim angle = 1.432 degrees
p
= (0.4 x cosec 1.432 + (4 - 30.5 tan 1.432))tan 1.432
=
0.48m
V
= (320 x 20 x 0.482)/16
= 92.2m3
18.
Static Electricity
There are three basic stages leading up to a potential static hazard: charge separation,
charge accumulation and electrostatic discharge. All three are necessary for an
electrostatic ignition.
Certain operations can give rise to accumulations of electric charge, which may be
released suddenly in electrostatic discharge with sufficient energy to ignite flammable
hydrocarbon gas/air mixtures. The minimum amount of energy thought necessary to ignite
petroleum gas is about 0.2 mJ.
There is of course no risk of ignition without the presence of a flammable mixture. The
phenomenon of charge separation occurs at the interface of two dissimilar materials. At
the interface a positive charge, say, moves from one material to the other so that the
two materials become respectively negatively and positively charged.
While the materials stay in contact and immobile relative to each other the charges are
very close together and the voltage difference between the two oppositely-signed
charges is small, so that no hazard exists.
However, charges can be widely separated by many processes, for example:
1. The ejection of droplets from a nozzle, as in the case of high pressure jets of sea
water or oil from tank cleaning machines, or the injection of steam under pressure;
2. The flow of petroleum or water/petroleum mixtures through pipes or fine filters;
3. The settling of a solid or an immiscible liquid through a liquid, such as rust or water
through petroleum;
4. The splashing or agitation of a liquid against a solid surface, such as the impact of
high pressure water or oil jet during tank cleaning;
5. Friction and the subsequent separation of synthetic polymers, for example the sliding
of a nylon rope through PVC-gloved hands.
When the charges are separated a large voltage difference develops between them, and
an electrostatic field or voltage gradient is established in the neighbouring space. For
example, the charge on a water mist caused by tank washing produces an electrostatic
field throughout the tank.
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Electrical breakdown between any two points (electrodes) which gives rise to a
discharge is dependent on the strength of the electrostatic field in the space
between the two points.
Examples of a discharge between two adjacent electrodes are:
1. Between sampling apparatus in a tank, and the surface of a charged petroleum liquid;
2. Between unearthed equipment suspended in a tank, and the adjacent tank structure.
A two-electrode discharge may be incentive if the following conditions are met:
The discharge gap is short enough to allow the discharge to take place, but not so
short that the resulting flame is quenched.
There is sufficient electrical energy to supply the minimum amount of energy to initiate
combustion.
The release of this energy into the discharge gap is nearly instantaneous. Electrostatic
discharges can occur as a result of accumulations of charge on:
1. Liquid or solid non-conductors, for example a static accumulator oil such as kerosene
pumped into a tank, or a polypropylene rope;
2. Electrically isolated liquid or solid conductors, for example mists, sprays or particulate
suspensions in air, or a metal rod suspended on the end of a synthetic fibre rope.
During tank cleaning the risk of electric charge accumulation and subsequent electrostatic
discharge is high when:
1. The wash-liquid pressure is high;
2. The temperature of the washing medium is high;
3. The washing medium is crude oil contaminated by water;
4. The washing medium is sea water contaminated with oil;
5. A detergent is added to the washing liquid;
6. A large number of machines are in use;
7. The wash-liquid flow rate is high;
8. The last cargo was refined white product, rather than black oil;
9. The capacity of the tank being washed is large.
Measures to Prevent Static Electricity Generation and/or Discharge:
The most important countermeasure that must be taken to prevent an electrostatic hazard
is to bond all metal objects together. Bonding eliminates the risk of discharges between
metal objects, which can be very energetic and dangerous.
Earth all rods, detectors and equipment before introduction into a tank;
Prohibit the free fall of water or slops into tanks;
Thoroughly flush and strip any tank having carried accumulator oil before water
washing, if not inerted;
Prohibit steam injection into any tank;
Ensure that the tank-washing liquid is either clean crude oil free of water, or clean
water free of oil;
When loading products such as petroleum or kerosene restrict the pipeline flow-rate to
one m/sec or less, until the bottom longitudinals are covered. The flow rate must then
be restricted to 3 to 4 m/sec in the case of rubber loading hoses, and to 12 m/sec in
the case of metal hardarms;
Avoid pumping mixtures of refined oil and water. A mixture of oil and water may occur
during the initial stages of loading a refined product, and the flow rate must be
restricted to less than one m/sec;
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Strainers, fittings and other obstructions should be located as far from tanks as
possible;
Ensure the strict use of anti-static clothing and personal protection equipment on deck.
Ground all conductors;
Check tanks for debris after repairs, maintenance or inspection;
Ensure the proper maintenance of float gauge guide wires, if fitted;
Avoid structural protrusions inside tanks as far as is practicable;
Impose a delay of at least 30 minutes after completion of loading, before
ampling/ullaging refined oil cargoes such as petroleum or kerosene;
Whenever possible ensure that transfer pipelines are of metal and that all metal parts
are grounded.
19.
Crude Oil
Although rudimentary oils differ considerably depending on their place of origin, they are
generally made up of the following elements:
Carbon
83 to 87%
Hydrogen
11 to 14%
Sulphur
5% or less
Nitrogen
0.4% or less
Oxygen
0.5% or less
Metal
0.5% or less
Crude Oil Gas
Crude oil contains gases such as methane and ethane, hydrogen sulphide.
Toxic Hazards of Crude Oil Gas
General
The inhalation of crude oil gas leads to a feeling of light headedness, drunkenness or
dizziness. If large quantities of gas are inhaled, death may occur.
These symptoms manifest themselves at a density well below the lower flammable limit.
The physiological effects of petroleum gas on human beings can differ widely, according to
individual levels of tolerance.
Even if a certain exposure to gas can be sustained with no apparent adverse effect, it
must not be assumed that the gas concentration is in the safe range.
The odour of crude oil gas mixtures is not uniform and can paralyse the sense of smell.
Hydrogen sulphide gas is a prime example, and is very dangerous.
Never assume that toxic gas is absent because there is no odour.
Gases released from oil are composed of various hydrocarbons, whose toxicity is
almost the same.
Generally the toxicity of a gas is more severe when the number of carbon atoms is large.
The toxicity of crude oil gas is acute but it does not accumulate in the human body.
Methane (CH 4 ) has no toxicity, but if its concentration is high then death from lack of
oxygen may occur.
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0.1%
1,000 ppm
0.2%
2,000 ppm
0.7%
7,000 ppm
1.0%
10,000 ppm
2.0%
20,000 ppm
Flammability and toxicity of a gas are not related. Measurement of a gas concentration
below the LEL does not imply that it is safe to enter a tank.
Toxic Hazards of Hydrogen Sulphide
Most crude oils contain hydrogen sulphide (H 2 S), and some grades contain very high
concentrations of it.
Crude oils containing 50 ppm H 2 S or over are called sour crudes. Although hydrogen
sulphide is usually removed from crude oil before shipment, some grades of crude oil are
loaded containing substantial residues of H 2S.
Loading terminals, which export oil with a high concentration of hydrogen sulphide gas
usually, notify the vessel of analysis results and the degree of concentration. Because
hydrogen sulphide has a low boiling point it evaporates in the tank in the early stages of
loading and accumulates in the upper part of the ullage space. It is highly concentrated
because of its low density (relative to propane and butane for example).
As shown in the following table hydrogen sulphide is very toxic and if inhaled at
concentrations of 1000 ppm or more, natural breathing is paralysed immediately.
At a concentration of around one ppm it can be recognised by its odour of rotten eggs.
However, H 2 S quickly impairs the sense of smell, which can prove fatal in
conditions of increasing concentration.
The absence of smell must never be taken to indicate the absence of gas.
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Concentration
(ppm)
50-100
200-300
Marked eye and respiratory tract irritation after exposure of one hour.
500-700
700-900
1000-2000
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10 ppm
0.0025%
2,000 ppm or
over
0.2% or
over
7,500 ppm
0.75%
20,000 ppm
2.00%
Death in 5 to 10 minutes.
Effect
0.03%
Slight odour.
0.07 to 0.28%
Dizziness in 14 to 15 minutes
1.13 to 2.22%
Dizziness in 3 minutes
2.2 to 2.6%
Many hydrocarbon gases and others of crude oil origin have carcinogenic or other long
term adverse medical effects.
Inhalation, even of concentrations considered safe in the short term, must be
avoided.
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20.
Premuda
Shortages
Shortage claims arise from a discrepancy between the quantity of cargo stated in the bill of
lading and the outturn quantity determined by the receivers at the discharge port.
Both figures are frequently derived from shore-tank or meter-measured data.
The most common arguments cited in support of the shipper/receiver's case are that:
1. The ship is jump by the figure stated in the bill of lading;
2. The shore tank calibrations are more accurate than the ship's tank calibrations;
3. The oil has become contaminated by water after loading;
4. Some oil remains on board the ship.
The owner's defence is usually based on the accuracy of the ship's cargo figures and
seeks to demonstrate that the cargo quantity discharged was comparable with the cargo
quantity loaded, that there was no significant in-transit loss, that any on board quantity
(OBQ) prior to loading has been taken in to consideration and that all the cargo has been
discharged with nothing remaining on board (nil ROB).
The following practices shall be included in the Chief Officer's loading/discharging plan:
1. The hourly recording of tank ullages and corresponding loading/discharging rates;
2. Careful documentation of any delays to operations which are the responsibility of the
terminal or any other party, detailing the cause of the delay and all relevant
communications with the terminal.
3. Ensuring tank survey agreement on ullage, temperature, and water cut measurements
etc. by all concerned. The methods used by the ship and shore representatives to
calculate the cargo quantity from agreed tank measurements may differ, but should
produce results which are closely in accord. The Chief Officer and any surveyor
attending on the ship's behalf should check that there are no inconsistencies in the
calculations. The new petroleum measurement tables are generally more accurate
than the old tables, but it must be remembered that they are based on the average
characteristics of average oil and are extrapolated from a relatively narrow band.
Ship's tanks may be calibrated using imperial, US or metric units of volume and the
quantity of cargo may be expressed in various units including long tons, tonnes or barrels.
Comparison of standard volume is preferable as it does not involve the application of
conversion factors based on density data, which may differ between two observers or
laboratories.
Measurement Accuracy
To calculate cargo quantities vessels rely on the Terminal for the API gravity of the cargo.
Samples taken from the shore pipeline may not be representative of the cargo loaded.
Clean and clearly labelled bottles shall be used for taking individual samples from the top,
middle and bottom of each of the ship's tanks. Sampling must not be effected by using a
standard sampling can and then decanting the three samples into a single larger can.
Volatile fractions can be lost to the atmosphere during this process and the density
established from the final mix may not represent the true density of the cargo in each tank.
This may later have a significant effect upon the calculation of weight and bottom sediment
and water.
Once the calculation of the ship's figure has been completed the terminal will provide the
shore figure, which normally appears on the bill of lading. It is unlikely that the shore and
ship figures will be identical, but usually the discrepancy is small and there will be no
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impediment to signing the bills of lading. In every case it is the gross figures, which should
be compared, and the ship's experience factor should also be taken into consideration.
The Master must decline to sign the bills of lading if there is an abnormal difference
between the bill of lading figure and the ship's figure. He must insist on a thorough check
of all measurements and calculations, both on board and ashore. Difficulties may arise
because measurements taken of the shore tanks before loading cannot be verified once
the cargo has been transferred. The accuracy of shore figures will then depend upon the
accuracy of the records kept by the terminal.
If the figures cannot be reconciled, the Master must then decline to sign the bills of lading
and seek instruction from the Company/Owners, who may require the charterers to
provide a letter of indemnity before authorising the Master to sign.
It is essential for the defence of cargo claims that the ship maintains a complete
documentary record of cargo operations. Time charterers will place on board their own
documentation, the prompt return of which they will require at the end of each voyage.
These will include:
1. Deck and engine voyage abstracts;
2. Notice of Readiness
3. Port log
4. Pumping/loading record
5. Stowage plan
6. Loading and discharge port calculations
7. Records of any cargo transfers
Loading and Discharging Operations
Records of all oil transfers, loading, discharging, internal, and including bunkering
operations, will also be required. Such records will assist not only with the defence of
shortage and contamination claims but also with the handling of other possible disputes.
Internal transfer of cargo shall be avoided unless absolutely necessary: The Company
must be consulted before any internal transfers take place unless the Master considers it
urgent or otherwise essential. Such action must be reported and properly recorded in the
Oil Record Book. Charter Parties also usually require the Master to notify the charterers of
any internal transfer of cargo.
The owners have no liability for measurements taken once the cargo has left the vessel.
Claims are frequently presented on the basis of shore outturn figures which can be
inaccurate.
The effective stripping of the tanks is important since claims will undoubtedly be made
against the Company for any cargo remaining on board. Crude oil washing can be
expected to minimise the ROB of most types of crude oil cargoes.
It will be necessary to demonstrate that ship's valves, lines and pumps were in good
condition at the time of discharge, because of its relevance to the question of pumpability.
If any ROB is in liquid form it must first be decided if it was reachable, and if so whether it
could be pumped by the vessel's equipment. If this is the case, then it should be pumped
ashore.
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The Master must call in a local P & I surveyor and notify the Company if he experiences
difficulty in obtaining a suitable ROB certificate. If pressure is applied to the ship to sail
before the surveyor can attend, the Master shall protest to the receivers and to the
receivers' surveyor. If the surveyors are not prepared to certify cargo remaining on board
as unpumpable/unreachable, they must be invited to inspect the ship's pumps. The
receivers must be informed that if they consider the cargo to be pumpable, the ship will
continue to attempt to pump it until the P & I surveyor arrives.
It is essential that maintenance records for the cargo pumps are preserved and that they
are available if such disputes arise. Surveyors who certify cargo as pumpable must be
required to prove that they have assessed the physical characteristics of the cargo and
have ascertained that it is within reach of the cargo pumps.
ROB claims can arise for many different reasons, for example:
The alleged inadequacy of the vessel's cargo heating capability, often coupled with
low ambient temperatures at the time of discharge;
Because of the physical properties of a particular crude, and consequent pumping
difficulties;
Because of an accumulation of sediment or scale in the cargo tanks, restricting the
free flow of oil to tank suctions;
Trim restrictions in the berth;
The alleged poor condition of the vessel and its equipment.
After discharge an ROB certificate will be issued signed by an appropriate shore
representative and, ideally, describing any remaining cargo as unpumpable residue.
Any alleged contamination could have taken place ashore before loading. It is therefore
Company policy that ship's staff routinely takes cargo samples from each tank after
loading, and if feasible at the ship's manifold during loading, in order to refute claims of this
kind. Sample bottles must be labelled and retained for three voyages. This sampling shall
ideally be witnessed and acknowledged by an independent cargo inspector. Apart from
cargo contamination resulting from leakages between cargo pipelines or cargo tanks, the
most likely cause of cargo being off specification is a failure to prepare appropriately the
tanks and associated pipelines to load a cargo which is incompatible with the previous
cargo with the previous cargo.
21.
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
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