DNV RP-F201
DNV RP-F201
DNV RP-F201
DNV-RP-F201
FOREWORD
DET NORSKE VERITAS (DNV) is an autonomous and independent foundation with the objectives of safeguarding life, property and the environment, at sea and onshore. DNV undertakes classification, certification, and other verification and consultancy
services relating to quality of ships, offshore units and installations, and onshore industries worldwide, and carries out research
in relation to these functions.
DNV Offshore Codes consist of a three level hierarchy of documents:
Offshore Service Specifications. Provide principles and procedures of DNV classification, certification, verification and consultancy services.
Offshore Standards. Provide technical provisions and acceptance criteria for general use by the offshore industry as well as
the technical basis for DNV offshore services.
Recommended Practices. Provide proven technology and sound engineering practice as well as guidance for the higher level
Offshore Service Specifications and Offshore Standards.
DNV Offshore Codes are offered within the following areas:
A) Qualification, Quality and Safety Methodology
B) Materials Technology
C) Structures
D) Systems
E) Special Facilities
F) Pipelines and Risers
G) Asset Operation
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In this provision "Det Norske Veritas" shall mean the Foundation Det Norske Veritas as well as all its subsidiaries, directors, officers, employees, agents and any other acting on behalf of Det
Norske Veritas.
CONTENTS
Sec. 1
General................................................................... 5
A. General.................................................................................... 5
A
A
A
A
A
100
200
300
400
500
Introduction....................................................................... 5
Objectives ......................................................................... 5
Scope and application ....................................................... 5
Other codes ....................................................................... 5
Structure of this RP........................................................... 6
C. Definitions .............................................................................. 6
C 100
C 200
Abbreviations.................................................................... 7
Symbols ............................................................................ 7
Greek letters...................................................................... 7
Sec. 2
E
E
E
E
E
300
400
500
600
700
General............................................................................ 15
Reference ........................................................................ 15
Reference ........................................................................ 15
I. Special Considerations..........................................................15
I
100
Reference ........................................................................ 15
Sec. 6
Materials.............................................................. 16
A. General..................................................................................16
A. General.................................................................................... 8
A
A
A
A
A 100
A 200
Objective........................................................................... 8
References......................................................................... 8
B. Material Properties................................................................16
Sec. 3
Loads...................................................................... 9
A. General.................................................................................... 9
A 100
A 200
Objective........................................................................... 9
References......................................................................... 9
Sec. 4
A. General.................................................................................. 10
A 100
A 200
Objective......................................................................... 10
Reference ........................................................................ 10
Sec. 5
A. General.................................................................................. 11
A 100
Objective......................................................................... 11
B. Material Selection................................................................. 11
B 100
General............................................................................ 11
C. Load Effects.......................................................................... 11
C 100
Reference ........................................................................ 11
D. Resistance ............................................................................. 11
D
D
D
D
100
200
300
400
B
B
B
B
B
B
B
B
B
B
100
200
300
400
100
200
300
400
500
600
700
800
900
1000
Scope............................................................................... 16
Application ..................................................................... 16
Material selection............................................................ 16
Process of manufacture................................................... 16
General............................................................................ 16
Chemical composition .................................................... 16
Metallography................................................................. 16
Mechanical properties..................................................... 16
Fracture toughness properties ......................................... 17
Fatigue properties ........................................................... 17
Corrosion properties ....................................................... 18
Environmental conditions............................................... 19
Wear properties............................................................... 20
Weldability ..................................................................... 20
C. Manufacture..........................................................................20
C 100
C 200
C 300
C 400
C 500
General............................................................................ 20
Linepipe NDT level ........................................................ 20
Manufacturing procedure specification and
qualification .................................................................... 20
Production and qualification testing ............................... 21
Non-destructive testing................................................... 21
Sec. 7
A. General..................................................................................24
A 100
A 200
Objective......................................................................... 24
References....................................................................... 24
Sec. 8
A. General..................................................................................25
A 100
A 200
Objective......................................................................... 25
References....................................................................... 25
E 100
E 200
Sec. 9
References ........................................................... 26
General............................................................................ 13
Bursting........................................................................... 13
SECTION 1
GENERAL
A. General
A 100 Introduction
101 This document provides recommended practice regarding criteria, requirements and guidance on structural design
and analyses for riser systems made of titanium alloys and exposed to static and dynamic loading for use in the offshore petroleum and natural gas industries.
102 The basic design principles and functional requirements
are based on the limit state methodology in compliance with
state-of-the-art industry practice.
A 200 Objectives
201 The main objectives of this recommended practice are
to:
provide an international standard of safety for titanium risers utilised for drilling, completion or workover, production or injection, or transportation of hydrocarbons
(import or export) in the petroleum and gas industries
serve as a guideline for riser design and analysis; and
serve as a technical reference document in contractual
matters.
A 300 Scope and application
301 This RP provides specific aspects related to design criteria, local analyses and material description valid for risers
made of titanium or a mix of titanium and steel. For the latter,
the RP covers only the titanium part of the riser.
302 It shall be pinpointed that the majority of available information discusses results obtained for material group I, described in Sec.5 B, and the calibration of the design
requirements given in Sec.5 will be based on the titanium
grades given in this group.
303 General design philosophy, loads and global analysis aspects valid for all riser materials are covered by DNV-OSF201.
304 The RP is applicable to all new built riser systems and
may also be applied to modification, operation and upgrading
of existing risers.
305 The scope covers design, materials, fabrication, testing
and operation of riser systems. Aspects related to documentation, verification and quality control are also addressed
306 The main purpose is to cover design and analysis of top
tensioned and compliant titanium riser systems operated from
floaters and fixed platforms. The standard applies for permanent operation (e.g. production and export/import of hydrocarbons and injection of fluids), as well as for temporary
operation (e.g. drilling and completion/workover activities).
307 This RP is applicable to structural design of all pressure
containing components that comprise the riser system, with
special emphasis on:
single pipes with a ratio of outside diameter to wall thickness less than 30 (D/t < 30)
riser connectors and other riser components such as tension joints and stress joints.
Sec.6 specifies the requirements for titanium alloys, manufacture, fabrication and documentation of linepipe and components in the riser system in addition to DNV OS-F101.
Sec.7 gives requirements for documentation and verification
of riser systems. The requirements described in DNV OS-F201
Sec.8 apply also to this RP.
Sec.8 provides requirements for operation and in-service inspection in addition to general guidance on structural integrity
assessment of risers to demonstrate fitness for purpose in case
deviations from design appear during operation. The requirements described in DNV OS-F201 apply also to this RP.
B. Normative References
B 100 Offshore Service Specifications
101 The latest version of the following documents applies:
DNV-OSS-301Certification and Verification of Pipelines.
B 200 Offshore Standards
201 The latest version of the following documents applies:
DNV-OS-F101 Submarine Pipeline Systems
DNV-OS-F201 Dynamic Risers
B 300 Other standards
301 The latest version of the following documents applies:
ASTM B861
Figure 1-2 Content of DNV-RP-F201 and links to other
DNV standards
404 The limit state design checks for this RP and DNV-OSF201 and DNV-OS-F101 are similar, but due to difference in
the governing failure modes and prevailing uncertainties, some
difference in safety factors exist.
405 In case of conflict between recommendations of this RP
and a reference document, the recommendations of this RP
shall prevail.
406 Where reference is made to codes other than DNV documents, the valid revision shall be taken as the revision that
was current at the date of issue of this RP, unless otherwise
noted.
A 500
501
Structure of this RP
C. Definitions
C 200 Definitions
201 The general definitions are identical to those in DNVOS-F201.
202 Alpha case (-case): Oxygen (or nitrogen) pickup during heat treatment results in a surface structure composed pre-
Sec.1 contains the objective and scope of the project RP. It further introduces essential concepts, definitions and abbreviations.
Sec.2 contains requirements to the fundamental design philosophy and design principles. The design philosophy and design
principles described in DNV OS-F201 Sec.2 apply also to this
RP.
Sec.3 defines the loads to be considered in the design of riser
systems. The loads are classified into different load categories.
The load definitions and classifications described in DNV OSF201 Sec.3 apply also to this RP.
=
=
=
=
SLS
SML
SMTS
SMYS
TRB
ULS
UO
UO
WSD
D 200 Symbols
201 The following symbols are used:
D
Dfat
Di
Dmax
Dmin
E
F0
fy
fu
Md
Mk
pb
pc
pe
pel
pld
pmin
pp
Rk
t
Ted
Tk
fab
U
A
c
E
F
m
SC
e
i
SECTION 2
DESIGN PHILOSOPHY
A. General
A 100 Objective
101 The purpose of this section is to present the safety philosophy and corresponding limit state design format applied in
this standard.
A 200 References
201 The design philosophy and design principles described
in DNV-OS-F201 Sec.2 applies also to this RP.
SECTION 3
LOADS
A. General
A 100 Objective
101 This section defines the loads to be considered in the design of riser systems. The loads are classified into different
load categories.
A 200 References
201 The load definitions and classification described in
DNV-OS-F201 Sec.3 applies also to this RP.
SECTION 4
ANALYSIS METHODOLOGY
A. General
A 100 Objective
101 The purpose of this section is to provide requirements
for global analysis. Focus is on assessment of global structural
A 200
Reference
SECTION 5
DESIGN CRITERIA
A. General
A 100
Objective
Normal
1.14
B. Material Selection
B 100
Guidance note:
General
C. Load Effects
C 100
High
1.26
Reference
(5.1)
Operational condition
t 1 = t nom t fab t corr
(5.2)
(5.3)
Otherwise
D. Resistance
D 100
t 2 = t nom t corr
Resistance factors
101 The following resistance factors apply, (see DNV-OSF201 Sec.2 C):
Safety class factor SC linked to the actual safety class and
accounts for the failure consequence.
Material resistance factor m to account for material and
resistance uncertainties.
A condition factor c to account for special conditions
specified explicitly at the different limit states where relevant, see e.g. Table 5-11 in DNV-OS-F201.
(5.4)
Guidance note:
t1 is the minimum wall thickness and is relevant for design
checks where failure is likely to occur in connection with a low
capacity. t2 is used for design checks governed by the external
loading and failure is likely to occur in connection with an extreme load effect at a location with average thickness.
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
nominal fatigue stress calculations. The following approximation may be applied for an environment with uniform wall
thinning due to wear and/or erosion:
t 3 = t nom 0.5 t corr
(5.5)
(5.6)
Material strength
f u = (SMTS f u, temp) U
is the Specified Minimum Yield Stress at room temperature based on the engineering stress-strain curve.
is the temperature derating factor for the yield stress;
see 303.
is the Specified Minimum Tensile Strength at room
temperature based on the engineering stress-strain
curve.
is the temperature derating factor for the tensile
strength; see 303.
is the material strength factor, see 306.
fy, temp
SMTS
fu, temp
Guidance note:
For reeling the effect of plastic straining after the pipe mill shall
be evaluated and included in the material property.
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
304 De-rated material properties, i.e. SMYS, SMTS and Emodulus, at design temperatures shall be established as input
to the design and verified under manufacture.
305 If the material shall be used at design temperature
T>50C, the yield strength at Tmax shall be determined according to Sec.6 B405.
Guidance note:
If no other information on de-rating temperature effects of the
strength exists, the recommendations below may be used for a
preliminary design for material Group I, see also Figure 5-1:
For material Group I, the changes in SMYS and SMTS with temperature are given as:
f
f
f
f
y, temp
y, temp
u, temp
u, temp
=
=
=
=
1.44 MPa/C
0.97 MPa/C
1.24 MPa/C
0.83 MPa/C
For material Group I, the change in elasticity modulus with temperature is given as
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
SMYS
E = 0.047 GPa / C
f y = (SMYS f y, temp) U
306 The material selection may include selection of supplementary requirement U according to DNV OS-F101. The supplementary requirement ensures increased confidence in
material strength, which is reflected in a higher material
strength factor U, given in Table 5-4.
Table 5-4 Material strength factor U
Normal
0.96
Supplementary requirement U
1.00
307 A fabrication factor fab applies to the design compressive circumferential yield stress for hoop buckling, local buckling and propagating buckling limit states. This fabrication
factor shall be documented for pipes manufactured by the
UOE, UO or three roll bending (TRB) or similar deforming
processes. Beneficial effect on this reduction factor due to heat
treatment is allowed if documented.
308 c is a parameter accounting for strain hardening and
wall thinning given by:
fu
c = ( 1 ) + ---(5.7)
fy
( 0.4 + q h )
= ( 0.4 + q h ) ( 60 D t 2 ) 45
for D t 2 < 15
for 15 < D t 2 < 60
for ( D t 2 ) > 60
( p ld p e ) 2
----------------------- ------qh = p b ( t2 )
3
pld
Guidance note:
A high degree of compatibility with the DNV-OS-F101 has been
attempted where relevant. In general the same limit states apply
for pipeline systems and dynamic riser systems but the governing
failure modes differ due to different functional requirements between pipelines and risers.
Pressure and functional loads normally govern wall thickness
sizing for pipelines while extreme environmental loads and fatigue govern typical dynamic riser design.
The most important comments that apply to this standard in relation to DNV-OS-F101 are:
- load combination a) in DNV-OS-F101, Sec.5 D300 is not required for dynamic risers. Further, p = 1.0 herein;
- the additional safety class resistance factors for pressure containment for compliance with ISO is not required for dynamic
risers. For compliance, see DNV-OS-F101.
- the hoop buckling (collapse) criterion is formulated in terms
of the wall thickness, t. The minimum (t1) thickness is applied
for pure hoop buckling, whereas the nominal (t2) thickness is
applied for combined loading;
- the propagating buckling criteria is similar but may be relaxed
if the buckle is allowed to travel a short distance;
- anisotropy is not considered explicitly but the effect is implicit in the combined loading criteria for internal overpressure.
for p ld > p e
else
pe
pb
c is not to be taken larger than 1.20. c is for illustration purpose given in Figure 5-2 in case of (fu/fy) = 1.18.
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
E 200 Bursting
201 The local incidental pressure, pli is the maximum expected internal pressure with a low annual exceedance probability, see DNV-OS-F201 Sec.3. Normally the incidental
pressure, pinc is taken 10% higher than the design pressure, pd,
i,e.:
Figure 5-2 c versus D/t ratio and pressure ratio qh for
(fu/fy) = 1.18
D 400
401 Specific material correction factors for titanium are given in Table 5-5.
pb ( t 1 )
( p li p e ) ---------------- m SC
D
tm = 1.1 ------------150t 2
pli
pe
Notes:
1)
E 100
General
(5.9)
1.15
3 Dt
(5.8)
(5.10)
tb
203 The burst criterion is valid if the mill pressure test requirement in DNV-OS-F101 has been met. If not, a corresponding decreased utilisation shall be applied.
103
Guidance note:
The burst criterion is expressed in terms of the resistance for
capped pipe ends. Note that the burst criterion is formulated in
terms of the local incidental pressure rather than a local design
pressure. Hence, the bursting limit state designs explicitly
against the extreme pressure loading condition over the lifetime
in compliance with standard ULS design checks. The allowable
utilisation is however in compliance with recent industry practice
for well-known riser types.
D
t 1 = ------------------------------------------------------------fu
min f y ; -----------
1.15
4
------- ---------------------------------------- + 1
(
p
3 m SC li p e )
pc ( t1 )
( p e p min ) ------------------ SC m
(5.15)
305 The initial ovality shall not be taken less than 0.005
(0.5%). Maximum ovality from fabrication is given in DNVOS-F201 Sec.5 G200. Ovalisation caused during the construction and installation phase is to be included in the ovality. The
ovalisation due to external pressure or moment in the as-installed position shall not be included.
(5.11)
p ld p e 2
T ed
Md
c { SC m } ---------- 1 ------------------ + -------- +
pb ( t2 ) Tk
Mk
D max D min
f0 = -------------------------------D
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
E 300
p ld p e 2
----------------- 1
pb ( t2 )
Md = design bending moment, see DNV-OS-F201 Sec.5
B100
Ted = design effective tension, see DNV-OS-F201 Sec.5
B100
pld = local internal design pressure, see Sec.3 B200
pe = local external pressure
c = condition factor to be taken according to Table 5-6
Mk is the (plastic) bending moment resistance given by:
( p c ( t ) p el ( t ) ) ( p c ( t ) p p ( t ) ) =
(5.16)
(5.12)
D
p c ( t ) p el ( t ) p p ( t ) f 0 ---t
M k = f y tm c ( D t 2 ) t 2
Guidance note:
Solution of the equation above can be found DNV-OS-F101
Sec.12.
(5.17)
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
t 3
2 E ----
D
p el ( t ) = ---------------------- tp
2
1
(5.18)
t
p p ( t ) = 2 ---- f y fab tp
D
Tk = fy c ( D t2 ) t 2
(5.14)
capacity (including the effect of strain hardening and wall thinning) for (Ted/Tk) <<1. It reduces to the traditional wall thickness
Von Mises criterion, see e.g. API RP 2RD, for pressure and effective tension load effects only.
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
{ SC
{ SC
2
p e p min 2
M T e 2
4
------- + ------ + ----------------------
M
T
(
t
)
p
k
k
c 2
(5.21)
T ed 2 2
2 Md
m } ---------- + -------- 13 +
Tk
Mk
2
2 p e p min
m } ---------------------- 1
pc ( t2 )
(5.19)
F 100 General
101 The riser system shall have adequate safety against fatigue within the service life of the system.
102 The design criteria for fatigue of steel riser pipes given
in DNV-OS-F201 Sec.5 E, are assumed to be valid for design
of titanium risers, with the exception of the actual fatigue
curves given in Appendix B E.
103 The fatigue properties valid for titanium pipes are given
in Sec.6 B600.
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
High
0.75
I. Special Considerations
T 2 p ld p e 2
p ld p e 2
M
2
- 1 ----------------- + -----e- + -----------------
------
M
(
t
)
T
(
t
)
p
p
k
b 2
k
b 2
I 100
Reference
101 The content in DNV-OS-F201 Sec.5 H applies also to
this RP.
(5.20)
SECTION 6
MATERIALS
A. General
B. Material Properties
B 100 General
101 Requirements for titanium making in general shall be
according to approved and documented practice.
102 Requirements to pipe manufacturing, type and extent of
mechanical testing and NDT are given in C, and suggested test
programs for both qualification testing and production testing
are given in Table 6-5. All mechanical and corrosion testing
shall be conducted in accordance with relevant parts of DNVOS-F101 Appendix B.
A 100
A 200
Scope
Application
201 This standard applies to risers and riser components fabricated from linepipes and forging made of titanium meeting
internationally recognised codes for titanium alloys, manufacturing, coatings, fabrication and NDT methods and procedures
in general with the exceptions given in DNV-OS-F201 Sec.7
and in B and C of this section.
202 The requirements in this section are applicable for risers
made of titanium only or a mix of titanium and steel. In case of
mixed riser systems, the section only covers the titanium part
of the system.
A 300
Material selection
Process of manufacture
2)
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
(6.1)
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
The default S-N curves are based on data for stress ranges in excess of 250 MPa for base metal and for stress ranges in excess of
175 MPa for welds. The available data indicate a standard deviation in the residuals of log10N of about 0.2.
The default characteristic S-N curves are valid for Material
Group I. For Material Groups II and III, reference is made to Table 6-5. The numbers quoted in Table 6-1 are valid in air or seawater, and for temperatures up to 150C. The numbers quoted for
base metal are valid for machined surfaces. The numbers quoted
for welds arise from test data for fusion welds with ground surfaces, no surface-breaking pores greater than 0.2 mm, and no internal pores greater than 0.5 mm.
No stress concentration factor is incorporated in the default characteristic S-N curves.
When verifying that the fatigue life of a material in question is
equal to or better than that given by a default characteristic S-N
curve, at least three fatigue tests at each of two different stress
ranges should be carried out. The fatigue test data by these tests
should be interpreted with respect to a characteristic S-N curve
defined as the curve with 97.7% survival probability with 95%
confidence. The verification should demonstrate that this characteristic S-N curve gives a fatigue life equal to or higher than that
given by the default characteristic S-N curve.
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
- Selection of S-N curves shall match the weld detail and quality
- The specified default characteristic S-N curve is given as a
one-slope S-N curve, valid for all S values, and thus ignoring
a possible endurance limit. Titanium is traditionally known to
exhibit an endurance limit under constant amplitude loading,
i.e., a value of the stress range S below which the number of
cycles N to failure will approach infinity. It will be conservative to apply the one-slope S-N curve for S values below the
endurance limit. When the endurance limit can be determined
with confidence, contributions to fatigue damage from S values below the endurance limit may be ignored for constant
amplitude loading. For variable amplitude loading the endurance limit may be suppressed and it is recommended to use
the one- slope curve for all S values, unless a two-slope S-N
curve can be established, supported by data or test results.
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
(6.2)
in which
Dfat = the accumulated fatigue damage calculated from the
stress range distribution and the characteristic S-N
curve according to the Miners sum, see DNV-OSF201 Appendix B.
DFF = the design fatigue factor, see DNV-OS-F201 Table 59.
Guidance note:
The stress range distribution used for calculation of the accumulated damage Dfat needs to include a relevant stress concentration
factor, when the characteristic S-N curve it is combined with in
the calculation does not incorporate any stress concentration factor.
Stress concentration factors are usually geometry-dependent. In
cases where stress concentration factors are also stiffness-dependent, extra caution should be exercised as then known stress
concentration factors applicable to for example steel details cannot necessarily be transported to apply to titanium details with
the same geometry.
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
- The fatigue crack growth rate, for similar stress ranges, is normally higher in titanium than in steel. This must be appreciated when assessing situations where fatigue crack growth is
the dominating part of the fatigue life or when in-service
crack inspection is considered (Damage Tolerance Design
Approach).
- When determining crack growth parameters in the near
threshold region it is important that the testing is carried out
with care. E.g. erroneously optimistic crack growth parameters may be obtained due to retardation effects if the load
range is decreased too rapidly during the testing.
- Relevant and realistic initial flow sizes must be determined
taking the capability of the NDT system and other aspects of
the fabrication methods into consideration.
- When calculating the fatigue life based on fatigue crack
growth, the final crack size must be determined based on a
given failure criteria, e.g. leakage or fracture.
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
Corrosion properties
702 Use of line pipe materials not listed for sour service in
NACE MR0175 shall be qualified according to the guidelines
given in the said document.
703 Alloy resistance to chloride crevice corrosion shall be
demonstrated when riser service temperature exceed ~75C
and the alloy is exposed to hot produced brine fluid or/and seawater.
704 To prevent crevice corrosion and mitigate the susceptibility to chloride stress corrosion cracking, Pd/Ru enhanced alloys shall be selected when maximum temperature exceed
~75C and alloys are exposed to seawater or hot produced
brine fluid.
705 Crevice or pitting corrosion testing shall be performed in
external environment. SCC testing shall be performed in internal environment.
706 For specimen containing welds, possible corrosion on
base material will be tested simultaneously.
Guidance note:
- Dependent on the environment and the temperature, no testing might be considered necessary if Pd/Ru-enhanced alloys
are requested.
- Pd/Ru-enhanced titanium alloys as ASTM Grade 28 and
Grade 29 are already fully qualified for high temperature
brine/seawater service up to at least 260C.
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
Galvanic Corrosion
707 The titanium alloys listed in Table 6-4 are generally immune to galvanic corrosion in contact with other structural materials and are compatible with nickel alloys and stainless
steels.
708 When in contact with less noble metals such as aluminium, carbon steel and magnesium alloys, accelerated galvanic
attacks can occur.
B 800 Environmental conditions
Liquid Metal Embrittlement
801 Risk for Liquid Metal Embrittlement (LME) due to liquid mercury from the well stream shall be considered. For temperatures <150C, liquid mercury does not appear to affect
titanium unless wetting of freshly exposed surface occur, e.g.
under wear conditions. For temperatures >150C, low resistance to liquid metal embrittlement from liquid mercury might
be expected.
Guidance note:
- Since mercury is not able to wet titanium surfaces covered
with oxide films, due to low surface tension/high contact angle, larger patches of oxide damage need to be present for this
to be a problem.
- Titanium and its alloys are resistant to solutions of mercury
salts over the pH range 3-11.
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
802 Titanium is inert to most oilfield chemicals, the exceptions are hydrofluoric acid and methanol.
Hydrofluoric Acid
803 Hydrofluoric acid, which may be used for acidising
wells, attacks titanium very quickly. This shall be prevented,
either by preventing hydrofluoric acids from flowing into titanium lines or by use of suitable inhibitors.
Methanol
804 Procedures for use of methanol in conjunction with titanium risers must be established, specifying the minimum water
content in the methanol.
Guidance note:
Methanol, used for dissolving and suppressing hydrates in well
flows, causes stress corrosion cracking of titanium in presence of
chlorides. However, water content above approximately 2-4%
nullifies the deleterious effect of methanol.
A guideline for minimum water content required to prevent
methanolic SCC of different titanium alloys, is given in Table 63.
Table 6-3 Guideline, giving minimum water content
required to prevent methanolic SCC
Minimum water content
DNV
required (wt%)
Titanium alloy
material
Intermittent
Sustained
group
exposure
exposure
ASTM Grade 9
II
2.0
2.0
ASTM Grade 19
III
5.0
10.0
ASTM Grade 23
I
3.0
3.0
ASTM Grade 28
II
2.5
3.0
ASTM Grade 29
I
5.0
10.0
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Hydrogen embrittlement:
805 Hydrogen absorption and long-term damages of titanium alloy components should be prevented by design strategies
that lead to prevention of atomic hydrogen on the titanium surface as;
applying polymeric coatings to seawater-exposed metal
surfaces
shift the impressed cathodic potential to levels positive to
0.850 mV
electrically isolate the titanium alloy component from cathodic protected steel structures via insulating flanges and
couplings.
806 Hydrogen absorption may occur when titanium is cathodically charged for extended periods at potentials more
negative than 850 mV (Ag/AgCl) in seawater imposed by
C.P. systems that protect mating steel structures.
Guidance note:
- Hydrogen damage of titanium alloys is manifested as loss of
ductility (embrittlement) and /or a reduction in the stress-intensity threshold for crack propagation.
- The damage is caused by hydrides, which forms as hydrogen
diffuses into the material during exposure with either gaseous
or cathodic hydrogen.
- The temperature limit where now significant hydrogen absorption is expected for the titanium when exposed to seawater is dependent on the chosen titanium alloy and the amount
of hydrogen present.
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807 In cases where hydrogen absorption can not be prevented, testing shall be carried out in order to characterise the frac-
2)
Titanium alloys resist solids-free seawater erosion to velocities as high as 30m/sec, and silt-laden seawater flow to at
least 5-6m/sec.
Testing simulating wear between a titanium riser and a steel
drill string has shown a relatively high degree of wear of the
titanium surface if not protected by a suitable liner.
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B 1000 Weldability
1001 Welding and repair welding procedures, welding personal, handling of welding consumables, and the execution of
welding shall be based on the requirements given in DNV-OSF101 Appendix C. For welding consumables, titanium specific
recommendations as those given for steel in Appendix C, C100
to C300, shall be agreed upon.
1002 The weld metal shall, as a minimum, have strength,
ductility and toughness meeting the minimum requirements of
the base material.
1003 Weldability of linepipe shall be verified during MPQT.
Requirements for weldability testing and WPQT of longitudinal welded titanium pipes and girth welds are given in Table 65 and Table 6-6.
1004 Weldments with high fatigue loads shall be identified,
and extended NDT of these shall be considered. Extended
NDT can take place in the form of spot checks performed by
other qualified operator.
Post Weld Heat Treatment (PWHT)
1005 A PWHT procedure shall be determined and verified as
part of the procedure qualification program.
1006 The effect of residual stress reduction after PWHT, as
input to Engineering Criticality Analyses, shall be evaluated.
1007 If the PWHT is performed in air and T > 480C, a metallographic examination, carried out subsequent to the PWHT,
may replace a mechanical or chemical removal of the surface
layer if no alpha-case is observed at the surface.
1008 If the PWHT is performed properly in a vacuum furnace or in an inert atmosphere for T > 480C, formation of alpha-case at the pipe surface is not expected.
C. Manufacture
C 100 General
101 The following requirements are applicable to the manufacture of risers and stress joints made of titanium alloys.
102 Linepipe manufacture shall fulfil the requirements of
DNV-OS-F101 Sec. 6 E when appropriate.
C 200 Linepipe NDT level
201 All linepipe shall fulfil the requirements to NDT Level I
310 The validity of the qualification of the MPS shall be limited to the titanium-making, rolling, and manufacturing /fabrication facilities where the qualification was performed.
311 If one or more tests in the qualification of the MPS fail
to meet the requirements, the MPS shall be reviewed and modified as necessary, and a complete re-qualification performed.
C 500
Table 6-4 Titanium alloys for riser applications, general mechanical properties according to ASTM 1)
ASTM and UNS
Common alloy Nominal composition Alloy type
Mechanical properties
grade
name
(wt %)
Minimum
MiniElastic
Elongation
0.2% YS
mum UTS modulus
minimum
(MPa)
(MPa)
(GPa)
(%)
ASTM Grade 9 2)
Ti-3-2.5
Ti-3Al-2.5V
Near-alpha
UNS R56320
ASTM Grade 18 2) Ti-3-2.5-Pd
Ti-3Al-2.5V-0.05Pd Near-alpha
483
620
107
15
UNS R56322
Ti-3Al-2.5V-0.1Ru
Near-alpha
ASTM Grade 28 2) Ti-3-2.5-Ru
UNS R56323
ASTM Grade 32 2) Timetal 5111
Ti-5Al-1ZrNear-alpha
586
689
107
10
1Sn-1V-0.8Mo
2)
ASTM Grade 23
Ti-6-4
Ti-6Al-4V
Alpha-beta
759
828
114
10
UNS R56407
(ELI)
(0.13 max O2)
2)
ASTM
Ti-6-4 Pd
Ti-6Al-4V-0.05Pd
Alpha-beta
759
828
114
10
Grade 23+0.05Pd
(ELI)
(0.13 max O2)
ASTM Grade 29 2) Ti-6-4 Ru
Ti-6Al-4VAlpha-beta
759
828
114
10
UNS R56404
(ELI)
0.1Ru(0.13 max O2)
ASTM Grade 19 2) Ti Beta-C
Ti-3Al-8V
Beta
759 3)
793 3)
93-96 3)
15 3)
UNS R58640
-6Cr-4Zr-4Mo
(1103) 4)
(1138) 4)
102 4)
5 4)
2)
3)
3)
3)
ASTM Grade 20
Ti Beta-C/Pd
Ti-3Al-8V-6CrBeta
759
793
93-96
15 3)
UNS R58645
4Zr-4Mo-0.05Pd
(1103) 4)
(1138) 4)
102 4)
5 4)
Notes
Density
typical
(g/cm3)
4.48
4.43
4.43
4.43
4.43
4.82
4.82
1)
Requirements for the most commonly used titanium grades for riser applications, according to ASTM B861;Standard Specification for Titanium
and Titanium Alloy Seamless Pipe and ASTM B862;Standard Specification for Titanium and Titanium Welded Pipe.
In connection with forgings, the mechanical properties given in ASTM B381 Standard Specification for Titanium and Titanium Forgings shall be
used.
Project specific requirement to mechanical properties may be agreed upon, ref. Sec.6 B401.
2)
Material Group I : ASTM Grade 23, ASTM Grade 23+0.05Pd, ASTM Grade 29
Material Group II: ASTM Grade 9, ASTM Grade 18, ASTM Grade 28, ASTM Grade 32
Material Group III: ASTM Grade 19, ASTM Grade 20
3)
4)
Table 6-5 Seamless and longitudinal welded linepipe - Qualification and production testing of linepipes
Qualification (Q) Samples
Testing
Test conditions
production (P)
Chemical analysis
1 sample representing the BM
Q&P
1 sample representing the WM
Tensile test
OD > 300 mm:
1 sample in longitudinal direction, BM and WM
Q&P
1 sample in transverse direction, BM and WM Test temperature: RT 2)
OD <= 300 mm:
1 sample in longitudinal direction, BM and WM
Metallographic
Q: 2 samples, in two directions, from both pipe
examination
ends 1) in both WM and BM
Q&P
P: 1 sample in both WM and BM
Magnification: 100X and 400X
For WM, a macro examination shall be performed.
Hardness measurement
Hardness profile through the entire weld on one
Q
sample
Fracture toughness test
For BM:
One set equals 8 specimens.
1 set in longitudinal direction
For pipe materials:
(J-R testing, multiple
1 set in transversal direction
Testing shall be performed at min. and max.
specimen method)
Q
For WM:
design temperature.
1 set transversal to weld direction
For welds:
For HAZ:
Testing shall be performed at either min. or
1 set transversal to weld direction
max. design temperature.
S-N fatigue testing 4)
Each set of 3 specimens to be tested at two
2 sets representing BM 3)
3)
2
sets
representing
WM
different stress levels.
Q
Surface: real surface finish
Environment: air
FCG-test 5)
3
specimens
representing
BM
Near threshold regime testing
Q
3 specimens representing WM
Environment to be agreed upon.
Bend test
Q: Wt < 20 mm: 2 root bend and 2 face bend
Q: Wt > 20 mm: 4 side bend
Q&P
Only for WM
P: Wt < 20 mm: 1 root bend
P: Wt > 20 mm: 1 side bend
Corrosion testing
Pitting corrosion
Depends on environment and temperature
Q
Crevice corrosion
Test temperature = Design temperature
SSC
+10C
Wear testing
Depends on environment.
Q
To be agreed on a case to case basis
Notes:
1)
2)
3)
4)
5)
Bend test
Q&P
Corrosion testing
Q
3 specimens WM 2)
Test conditions
Test temperature: RT 1)
Notes:
1)
2)
3)
Qualification (Q) test: If the material shall be used at a design temperature T > 50C, the yield strength at Tmax shall be determined.
Is to be performed at different stress ranges in order to verify the validity of the design curve
The quoted number of tests is valid when verifying an established design curve. For establishing a new design curve for a novel situation,
e.g. use of an alloy of Material Group III or welding method where test data do not exist, relevant and statistically significant testing shall
be agreed upon and performed.
SECTION 7
DOCUMENTATION AND VERIFICATION
A. General
A 100 Objective
101 This section gives requirements for documentation and
verification of riser systems during design, fabrication, installation and operational phases.
A 200 References
201 The requirements to documentation and verification described in DNV-OS-F201 Sec.8 apply also to this RP.
SECTION 8
OPERATION, MAINTENANCE AND REASSESSMENT
A. General
A 100 Objective
101 The objective of this section is to provide requirements
for operation and in-service inspections. This section also provides general guidance on structural integrity assessment of
A 200
References
201 The requirements for operation, maintenance and reassessment described in DNV-OS-F201 Sec.9 apply also to this
RP.
SECTION 9
REFERENCES
/1/ O.Aamlid, K.J.Mrk, K.Aaronsen Combined Loading Criteria
for titanium Risers OMAE2002, Oslo, Norway
/2/ K.Mrk, M.Z.Chen, S.Spolton, C.Baxter Collapse and buckling Design Aspects of titanium Alloy Pipes, OMAE2001, Rio de
Janeiro, Brazil.
/3/ K.O.Ronold, S.Wstberg Characteristic S-N curves for Fatigue
Design of Titanium Risers OMAE2002, Oslo,
Norway