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    Full Length Model Paper Wbut 2 Semester Chemistry - 1 CH 201 GROUP A (Multiple Choice Type Questions)

    Uploaded by

    Soumodip Chakraborty
    This document is a model chemistry exam paper containing multiple choice and short answer questions covering various topics: 1) The first section contains 10 multiple choice questions testing topics like internal energy, polymers, calorific values, hybridization, reaction order, conductivity units, and crystal defects. 2) The second section contains 3 short answer questions about the ideal gas law, LPG as a fuel and its octane number, and polymerization and examples. 3) The third section contains 4 long answer questions about electrolyte conductivity, Gibbs free energy, entropy, adiabatic and isothermal processes, transport numbers, reaction kinetics, and mechanisms.

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    Full Length Model Paper Wbut 2 Semester Chemistry - 1 CH 201 GROUP A (Multiple Choice Type Questions)

    Uploaded by

    Soumodip Chakraborty
    60 views3 pages
    This document is a model chemistry exam paper containing multiple choice and short answer questions covering various topics: 1) The first section contains 10 multiple choice questions testing topics like internal energy, polymers, calorific values, hybridization, reaction order, conductivity units, and crystal defects. 2) The second section contains 3 short answer questions about the ideal gas law, LPG as a fuel and its octane number, and polymerization and examples. 3) The third section contains 4 long answer questions about electrolyte conductivity, Gibbs free energy, entropy, adiabatic and isothermal processes, transport numbers, reaction kinetics, and mechanisms.

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    Chemistry 1st sem Model Paper

    Original Title

    Chem Model Paper

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    This document is a model chemistry exam paper containing multiple choice and short answer questions covering various topics: 1) The first section contains 10 multiple choice questions testing topics like internal energy, polymers, calorific values, hybridization, reaction order, conductivity units, and crystal defects. 2) The second section contains 3 short answer questions about the ideal gas law, LPG as a fuel and its octane number, and polymerization and examples. 3) The third section contains 4 long answer questions about electrolyte conductivity, Gibbs free energy, entropy, adiabatic and isothermal processes, transport numbers, reaction kinetics, and mechanisms.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    60 views3 pages

    Full Length Model Paper Wbut 2 Semester Chemistry - 1 CH 201 GROUP A (Multiple Choice Type Questions)

    Uploaded by

    Soumodip Chakraborty
    This document is a model chemistry exam paper containing multiple choice and short answer questions covering various topics: 1) The first section contains 10 multiple choice questions testing topics like internal energy, polymers, calorific values, hybridization, reaction order, conductivity units, and crystal defects. 2) The second section contains 3 short answer questions about the ideal gas law, LPG as a fuel and its octane number, and polymerization and examples. 3) The third section contains 4 long answer questions about electrolyte conductivity, Gibbs free energy, entropy, adiabatic and isothermal processes, transport numbers, reaction kinetics, and mechanisms.

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    FULL LENGTH MODEL PAPER

    WBUT 2nd SEMESTER

    CHEMISTRY - 1

    CH 201

    GROUP A (Multiple Choice Type Questions)

    1. Choose the correct alternatives for the following :


    (i) The change internal energy of a system depends on
    (a) Initial and final states of the system
    (b) The reversible path
    (c) The initial state of the system only
    (d) The irreversibility in the process

    om
    (ii)Cellulose acetate is a

    (a) Natural polymer (c) synthetic polymer


    (b) Semi synthetic polymer (d) thermosetting polymer
    t.c
    (iii)The relation between HCV and LCV will be

    (a) HCV = LCV (c) HCV < LCV


    bu
    (b) HCV > LCV (d) no relation exits

    (iv)For an ideal gas undergoing free expansion


    yw

    (a) T = 0 and S > 0 (c) T < 0 and S > 0


    (b) T = 0 and S = 0 (d) T < 0 and S = 0

    (v)The calorific value is highest for


    m

    (a) water gas (c) producer gas

    (b) LPG (d) Bakelite

    (vi)The hybridization of Xe in XeF2 is

    (a) Sp (c) sp3


    (b) Sp3d2 (d) sp3d

    (vii)The half-life period of a reaction is found to be directly proportional to the initial


    concentration. The order of the reaction is

    (a) Zero (c) Two


    (b) One (d) Three
    (vii)The time required to reduce the concentration of a reactant from 0.02 m to 0.01 M is 15
    sec and from 0.01 M to 0.005 M is also 15 sec. The order of reaction is

    (a) Zero (c) Two


    (b) One (d) Three

    (viii) The unit of equivalent conductance is

    (a) Ohm-1cm2/gm-eqv (c) ohm-1m2/gm-eqv


    (b) Ohm-1m-1 (d) ohm-1m-1

    (ix)Which one of the following has largest bond angle?

    (a) H2O (c) NH3


    (b) H2S (d) PH3

    (x) Which of the following defect arises due to misplace of ions in a crystal lattice

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    (a) Schotty effect (c) Metal excess defect

    (b) Frenkel defect t.c (d) Non-stiochiometric defect

    GROUP B (Short Answer Type Questions)


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    Answer any three questions

    2. Show that for an ideal gas undergoing reversible adiabatic expansion or compression PV =
    yw

    constant. A diatomic ideal gas ( = 1.4), initially at 600 K and 10 atm undergoes reversible
    adiabatic expansion till the final pressure becomes 2 atm. Find out its final volume.
    3. What is LPG? Why is it used as a domestic fuel? Define octane number of fuel and explain
    how the octane number can be improved.
    m

    4. What do you understand by polymerization? What is the degree of polymerization? Write


    down the structure and use of Nylon-66 and PVC.
    5. Deduce Gibbs-Helmholtz equation in any of its standard forms.
    6. Discuss the shapes of NH3 and H2O molecules on the basis of VSEPR theory.
    7. What is the effect of temperature on the conductivity of p-type and n-type semiconductors?

    GROUP C (Long Answer Type Question)

    Answer any three of the following

    8. (a) Explain the variation of equivalent conductances of strong and weak electrolyte with
    concentration.
    (b)State and explain Kohlrauschs law of independent migration of ions.
    (c)Differentiate between electrolytic cell and galvanic cells.
    (d) Calculate the EMF of the following cell:
    Ni | Ni2+ (1M) | Pb2+ (1M) Pb at 250 C
    Given: standard electronic potentials of Ni and Pb are -0.24 V and -0.13 V respectively at 250
    C.
    9. (a) Define Gibbs free energy and work function.
    (b)At N.T.P., 3 dm3 of oxygen were mixed with 21 dm3 of hydrogen. Calculate the increase in
    entropy.
    (c) Prove that adiabatic P-V curve would be steeper than the isothermal P-V curve.

    10. What is meant by inversion temperature? Derive an expression for inversion temperature
    of a gas obeying Vander Walls equation.
    11. (a) What is meant by transport number of an ion? How is it related with ion conductance?
    The ionic radius of Li+ is less than that of K+. However, in aqueous solution Li+ ions are less
    mobile than K+ ions. How can you explain this observation?

    om
    (b)Rate constant of a reaction at 300K and 310K are 4.5 10-5 s-1 and 9 10-5 s-1
    respectively. Evaluate the activation energy and the pre-exponential factor (frequency
    factor) of the reaction. What is order of the reaction?
    (c) Distinguish between SN1 and SN2 mechanisms with suitable examples. Discuss the role
    of solvents in SN1 reactions.
    t.c
    12. Write short notes on any three of the following
    (a) First Law of Thermodynamics
    bu
    (b) Entropy
    (c) Stiochiometric Defects
    (d) NMR and Mass spectrometry
    yw

    (e) Rubber

    This model paper has been prepared for reference of students and should not be referred as Original WBUT paper.
    m

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