Mass Balance Fix
Mass Balance Fix
Mass Balance Fix
C3H4O2 +
M 58.49709706
R 57.32715511
S 1.169941941
Reactor
C3H4O2
C2H5OH
C5H8O2
H2O
comp
C3H4O2
C2H5OH
C5H8O2
H2O
Decanter
component
C3H4O2
C2H5OH
C5H8O2
H2O
comp
C3H4O2
C2H5OH
C5H8O2
P
T
comp
C3H4O2
C2H5OH
C5H8O2
mol ET D
ln (Di/Bi)
ln (i)
mol EA D
comp
C3H4O2
C2H5OH
C5H8O2
y=ax+b
(1) 5,293305 = 0,771638 a
(2) -8,844532 = 0 a + b
b
a
AA
ln (Di/Bi)
(Di/Bi)
(1) Di = 4,78E-16 x Bi
(2) Di + Bi = 0,761251
4,78E-16Bi + Bi = 0,76
mol AA D
Colomn 1
component
C3H4O2
C2H5OH
C5H8O2
comp
C3H4O2
C2H5OH
C5H8O2
P
T
comp
C3H4O2
C2H5OH
C5H8O2
mol EA D
ln (Di/Bi)
ln (i)
mol AA D
comp
C3H4O2
C2H5OH
C5H8O2
y=ax+b
(1) 5,293305 = 1,422524 a
(2) 0,051017 = 0 a + b
b
a
ET
ln (Di/Bi)
(Di/Bi)
(1) Di = 3524,637 x Bi
(2) Di + Bi = 0,017616
3524,637Bi + Bi = 0,01
mol ET D
Colomn 2
C3H4O2
C2H5OH
C5H8O2
mass (kg) purity kmol
4211.79099 99.70% 58.4970971 2959.953111
12.6733931 0.30% 0.7040774
input output
mol mass mol mass
58.4970971 4211.790988 1.16994194 84.23581976
64.3468068 2959.953111 7.01965165 322.9039757
0 0 57.3271551 5732.715511
7.02219584 126.3995251 64.349351 1158.288317
129.8661 7298.143624 129.8661 7298.143624
305 = 0,771638 a + b
4532 = 0 a + b
-8.3138027
16.9418319
-32.755235
5.951E-015
4,78E-16 x Bi
Bi = 0,761251
-16Bi + Bi = 0,761251
4.571E-015 mol AA B 0.76806244
305 = 1,422524 a + b
017 = 0 a + b
-1.7050262
5.76817141
10.9994169
59839.2366
3524,637 x Bi
Bi = 0,017616
637Bi + Bi = 0,017616
0.03021471 mol ET B 5.049E-007
TT-01
Ethanol Storage Tank (TT-01)
ET ET1
X 98%
C2H5OH C5H8O2 + H2O solubility in H2O data at 298,15 K
64.45932 0 7.034474 component kg/kg H2O
57.42739 57.42739 57.427391 C3H4O2 0.024981
7.031925 57.42739 64.461866 C2H5OH 0.137605
C5H8O2 0.052504
H2O 1
DC-02 input o
to heavy key from DC-01 to distillate (TT-03)
mass (kg) component mol mass (kg) mol
28.98592 C3H4O2 0.7694054 55.397189 0.118342
159.6650 C2H5OH 0.0302680 1.3923303 0.030268
60.92096 C5H8O2 56.804259 5680.4259 56.71905
1160.314 H2O 0 0 0
1409.885 total 57.603932 5737.2154 56.86766
310.90440743341 BALANCE 57.603932 5737.2153761445
FL-01
Decanter (FL-01)
component mol (kmol) mass (kg)
C3H4O2 0.7694054 55.39719
C2H5OH 3.5609470 163.8036
ata at 298,15 K C5H8O2 56.818182 5681.818
H2O 0 0
LIGHT OUTPUT
HEAVY OUTPUT
output
to distillate (MP-01) to bottom (DC-02)
mass (kg) mol mass (kg)
0 0.7694054 55.397189
162.41123 0.0302680 1.3923303
1.3923303 56.804259 5680.4259
0 0 0
163.8036 57.603932 5737.2154
61.148534 5901.01893931120
output
to distillate (TT-03) to bottom (MP-02)
mass (kg) mol mass (kg)
8.5206388 0.6510632 46.876550
1.3923070 0 0
5671.9052 0.0852064 8.5206388
0 0 0
5681.8182 0.7362701 55.397212
57.603932 5737.2153761445
DC-01
Distillation Colomn 1 (FL-01)
vapor pressur
component
C3H4O2
C2H5OH
C5H8O2
C5H8O2
mol EA D 0.0139233 mol EA B 56.80426
ln (Di/Bi) -8.313803
ln (i) 0
component ln(D/B) [y] ln () [x]
C3H4O2 -1.4426676
C2H5OH 4.7591528 0.771638
C5H8O2 -8.31380267 0
y=ax+b
eq (1) 5,293305 = 0,771638 a + b
eq (2) -8,844532 = 0 a + b
b -8.31380267
a 16.941832
C3H4O2
ln (Di/Bi) -32.7552347
(Di/Bi) 5.951E-15
eq (1) Di = 4,78E-16 x Bi
eq (2) Di + Bi = 0,761251
4,78E-16Bi + Bi = 0,761251
mol AA D 4.579E-15 mol AA B 0.769405
component mol (kmol) mass (kg)
C3H4O2 0 0
C2H5OH 3.5306790 162.41123
C5H8O2 0.0139233 1.3923303
to mixed point 1
P DC-02
T
component
C3H4O2
C2H5OH
C5H8O2
C5H8O2
mol EA D
ln (Di/Bi)
ln (i)
C3H4O2
mol AA D
component
C3H4O2
C2H5OH
C5H8O2
y=ax+b
eq (1) 5,293305 = 0,771638 a +
eq (2) -8,844532 = 0 a + b
b
a
C2H5OH
ln (Di/Bi)
(Di/Bi)
eq (1) Di = 4,78E-16 x Bi
eq (2) Di + Bi = 0,761251
4,78E-16Bi + Bi = 0,7612
mol ET D
component
C3H4O2
C2H5OH
DC-01 C5H8O2
Distillation Colomn 2 (FL-02)
305 = 0,771638 a + b
4532 = 0 a + b
-1.70502624
5.7681713
10.999417
59839.227
4,78E-16 x Bi
Bi = 0,761251
-16Bi + Bi = 0,761251
0.0302675 mol ET B 5.058E-07
mol (kmol) mass (kg)
0.1183422 8.5206388
0.0302675 1.3923070 Ethyl Acrylate Storage Tank (TT-03)
56.719052 5671.9052
TT-03
EA
ta of each component
vpc vpd vpe
-4.8813 0.0004369 -4.916E-013
-5.0474 3.7448E-011 2.736E-007
-17.694 0.008051 -4.886E-013
to mixed point 2
vapor pressure data of each component
component vpa vpb vpc vpd
C3H4O2 23.0607 -3134.7 -4.8813 0.0004369
C2H5OH 23.8442 -2864.2 -5.0474 3.7448E-011
C5H8O2 55.0109 -3590.4 -17.694 0.008051
input C2H5OH
component mol mass (kg) mol ET D
C3H4O2 0.7694053982 55.3971887 ln (Di/Bi)
C2H5OH 3.5609470254 163.803563 ln (i)
C5H8O2 56.8181818748 5681.81819
C5H8O2
mol EA D
component
C3H4O2
C2H5OH
C5H8O2
y=ax+b
eq (1) 5,293305 = 0,771638 a + b
eq (2) -8,844532 = 0 a + b
b
a
C3H4O2
ln (Di/Bi)
(Di/Bi)
eq (1) Di = 4,78E-16 x Bi
eq (2) Di + Bi = 0,761251
4,78E-16Bi + Bi = 0,761251
mol AA D
Dew Point Temperature
P DC-01 1 atm
T 351.6938714287 K
component mol yi Pi (atm) K = Pi/P
C3H4O2 4.57865290E-015 1.2917E-015 0.0981291 0.098129099
C2H5OH 3.5306789756 0.99607197 1.00392694 1.003926936
C5H8O2 0.0139233029 0.00392803 0.50217517 0.50217517
99.15% P DC-01 1
99.15% T 373.0449938715
i = Ki/Kb component xi
0.2362965757 C3H4O2 0.0133568208
2.1633061137 C2H5OH 0.0005254511
1 C5H8O2 0.9861177281
input
3.5306789756 mol ET B 0.03026805 component mol
4.7591527845 C3H4O2 0.7694053982
0.7716376597 C2H5OH 0.0302680497
C5H8O2 56.8042585719
305 = 0,771638 a + b
4532 = 0 a + b
-8.313802675
16.941831823
-32.75523429
5.95090E-015
4,78E-16 x Bi
Bi = 0,761251
-16Bi + Bi = 0,761251
4.57865E-015 mol AA B 0.7694054
Dew Point Temperature
P DC-01 1
T 372.9365591154
xi = yi/Ki i = Ki/Kb component mol
1.31635E-014 0.19540811 C3H4O2 0.1183422054
0.99217576 1.99915686 C2H5OH 0.0302675439
0.0078220308 1 C5H8O2 56.719052184
0.9999977908
C5H8O2
mass (kg) mol EA D 56.719052184 mol EA B 0.08520639
55.3971887 ln (Di/Bi) 6.5007890447
1.39233029 ln (i) 0
5680.42586
C3H4O2
mol AA D 0.1183422054 mol AA B 0.651063
ln (Di/Bi) -1.705026
ln (i) -1.4226027
y=ax+b
eq (1) 5,293305 = 0,771638 a + b
eq (2) -8,844532 = 0 a + b
b 6.5007890447
a 5.7681708767
C2H5OH
ln (Di/Bi) 10.999416133
(Di/Bi) 59839.193393
eq (1) Di = 4,78E-16 x Bi
eq (2) Di + Bi = 0,761251
4,78E-16Bi + Bi = 0,761251
mol ET D 0.0302675439 mol ET B 5.058E-007
atm
K
yi Pi (atm) K = Pi/P xi = yi/Ki i = Ki/Kb
0.00208101 0.24235363 0.242353627 0.0085866698 1
0.00053225 2.19403541 2.194035408 0.0002425874 9.0530331
0.99738674 1.00627084 1.006270839 0.9911712684 4.15207666
1.0000005256
atm
K
xi Pi (atm) K = Pi/P yi = Ki xi i = Ki/Kb
0.00208101 0.24068514 0.240685143 0.0005008683 1
0.00053225 2.18099552 2.180995523 0.0011608245 9.06161259
0.99738674 1.00095349 1.000953492 0.9983377445 4.15876726
0.9999994374
atm
K
xi Pi (atm) K = Pi/P yi = Ki xi i = Ki/Kb
0.88427223 0.80162286 0.801622859 0.7088528346 0.3186394
6.8700E-007 6.13873119 6.138731189 4.21728E-006 2.44010212
0.11572708 2.51576815 2.515768151 0.2911425043 1
0.9999995561
Heat Capacity Components
component A B C D
C3H4O2 84.154 0.52899 -0.0013617 1.7294E-006
C2H5OH 59.342 0.36358 -0.0012164 0.000001803
C5H8O2 102.928 0.55475 -0.0016152 2.3569E-006
H2O 92.053 -0.039953 -0.00021103 5.3469E-007
Tref 298.15 K yaws
TT-01
Ethanol Storage Tank (TT-01) Heat Exchanger (E-01)
E-01
ET ET1
steam
AA AA1
at Exchanger (E-02)
E-01
steam
reaction
C3H4O2 + C2H5OH C5H8O2 + H2O
Enthalpy of Formation Component HF
component A B C Hf
C3H4O2 -325.0380 -0.044058 2.093E-05 -336.313709
C2H5OH -216.9610 -0.069572 3.174E-05 -234.882059
C5H8O2 -327.0440 -0.089230 4.497E-05 -349.650387
H2O -238.4100 -0.012256 2.766E-06 -241.818283
output COOLING
to FL-01
mol Q (kJ) Q (kJ)
1.1719876 979.24594
7.0319255 3786.7054
57.427391 53914.809
64.461866 24333.476
130.09317 83014.236
130.09317 83014.236 -676732.6
Q (kJ)
9009.7674
34930.461
497599.19
218207.44
759746.86 Heat Exchanger (E-03)
CWS E-01
CWR
component
C3H4O2
C2H5OH
Q (kJ) C5H8O2
979.24594 H2O
3786.7054 T
53914.809
24333.476
83014.236 HEAVY OUTPUT
output DC-01
to E-04 to heavy key
Q (kJ) mol Q (kJ) component
642.87124 0.4025822 336.37470 C3H4O2
1917.5768 3.4709785 1869.1286 C2H5OH
53342.862 0.6092096 571.94692 C5H8O2
0 64.461866 24333.476 H2O
55903.310 68.944636 27110.927 total
130.09317 83014.236 BALANCE
component
C3H4O2
C2H5OH
C5H8O2
H2O
T
input output
from E-04 to E-05 to DC-02
mol Q (kJ) mol Q (kJ) mol
0.7694054 9718.4036 0 0 0.7694054
3.5609470 29168.437 3.5306790 20970.561 0.0302680
56.818182 811412.92 0.0139233 144.24202 56.804259
0 0 0 0 0
61.14853 850299.76 3.544602 21114.803 57.603932
61.14853 850299.76 61.14853 867903.430
input output
from DC-01 to E-06 to E-07
mol Q (kJ) mol Q (kJ) mol
0.769405 10018.77 0.6510632 12471.295 0.1183422
0.030268 255.68 0 0 0.0302675
56.804259 836514.18 0.0852064 1854.673 56.719052
0 0 0 0 0
57.60393 846788.6 0.7362701 14325.975 56.867662
57.60393 846788.6 57.60393 848059.201
eq (1)
eq (2)
DC-01
Distillation Colomn 1 (D
steam
mol H Q (kJ)
0.7694054 12631.057 9718.4036
3.5609470 8191.2021 29168.437
56.818182 14280.867 811412.92
0 5472.7078 0
370.89437 K 850299.76
STEAM
to E-07
Q (kJ) Q (kJ)
1534.9241
254.66110
831943.64
0
833733.23
848059.201 1270.574
component mol H Q (kJ)
C-01 C3H4O2 0 9183.4055 0
C2H5OH 3.5306790 5939.5263 20970.561
tion Colomn 1 (DC-01) C5H8O2 0.0139233 10359.756 144.24202
H2O 0 4023.1925 0
T 351.64429 K 21114.803
to mixed point 1
output COOLING
to TT-03
mol Q (kJ) Q (kJ)
0.118342 98.879993
0.030268 16.299130
56.71905 53249.796
0 0
56.86766 53364.975
56.86766 53364.975 -780368.3
component mol
C3H4O2 0.1183422
DC-01 C2H5OH 0.0302675
Distillation Colomn 2 (DC-02) C5H8O2 56.719052
H2O 0
T 372.763137
component mol
C3H4O2 0.6510632
C2H5OH 0
C5H8O2 0.0852064
H2O 0
T 406.0447241
H Q (kJ)
12970.218 1534.9241
8413.6693 254.66110
14667.799 831943.64
5613.8157 0
K 833733.23
Heat Exchanger (E-03)
CWS E-01
to mixed point 2
H Q (kJ)
19155.276 12471.295
12507.864 0
21766.836 1854.6735
8146.7365 0
K 14325.975
TT-03 Tank (TT-03)
Ethyl Acrylate Storage
EA
CWR
input C2H5OH
component mol mass (kg) mol ET D
C3H4O2 0.7679872307 55.2950806 ln (Di/Bi)
C2H5OH 3.5540775720 163.487568 ln (i)
C5H8O2 56.818125230 5681.81252
C5H8O2
mol EA D
component
C3H4O2
C2H5OH
C5H8O2
y=ax+b
eq (1) 5,293305 = 0,771638 a + b
eq (2) -8,844532 = 0 a + b
b
a
C3H4O2
ln (Di/Bi)
(Di/Bi)
eq (1) Di = 4,78E-16 x Bi
eq (2) Di + Bi = 0,761251
4,78E-16Bi + Bi = 0,761251
mol AA D
Dew Point Temperature
P DC-01 1 atm
T 351.6938095675 K
component mol yi Pi (atm) K = Pi/P
C3H4O2 4.54901098E-015 1.2858E-015 0.09812882 0.098128823
C2H5OH 3.5238679126 0.99607197 1.00392449 1.003924488
C5H8O2 0.0138964433 0.00392803 0.50217408 0.50217408
99.15% P DC-01 1
99.15% T 373.0444353511
i = Ki/Kb component xi
0.23630358 C3H4O2 0.0133325576
2.1633325632 C2H5OH 0.0005244515
1 C5H8O2 0.9861429909
input
3.5238679126 mol ET B 0.03020966 component mol
4.7591527845 C3H4O2 0.7679884946
0.771649886 C2H5OH 0.0302097114
C5H8O2 56.804290370
305 = 0,771638 a + b
4532 = 0 a + b
-8.315733122
16.944065104
-32.75988438
5.92329E-015
4,78E-16 x Bi
Bi = 0,761251
-16Bi + Bi = 0,761251
4.54901E-015 mol AA B 0.76798723
Dew Point Temperature
P DC-01 1
T 372.9366140177
xi = yi/Ki i = Ki/Kb component mol
1.31036E-014 0.19540798 C3H4O2 0.1183422716
0.992178179 1.99915632 C2H5OH 0.0302092059
0.0078220478 1 C5H8O2 56.7190839349
1.0000002268
C5H8O2
mass (kg) mol EA D 56.719083935 mol EA B 0.08520644
55.29517 ln (Di/Bi) 6.5007890447
1.389647 ln (i) 0
5680.429
C3H4O2
mol AA D 0.1183422716 mol AA B 0.649646
ln (Di/Bi) -1.702847
ln (i) -1.4226078
y=ax+b
eq (1) 5,293305 = 0,771638 a + b
eq (2) -8,844532 = 0 a + b
b 6.5007890447
a 5.7666179517
C2H5OH
ln (Di/Bi) 10.998192704
(Di/Bi) 59766.02916
eq (1) Di = 4,78E-16 x Bi
eq (2) Di + Bi = 0,761251
4,78E-16Bi + Bi = 0,761251
mol ET D 0.0302092059 mol ET B 5.055E-007
atm
K
yi Pi (atm) K = Pi/P xi = yi/Ki i = Ki/Kb
0.00208101 0.24235416 0.242354157 0.0085866598 1
0.00053122 2.19403955 2.194039546 0.0002421195 9.05303038
0.99738777 1.00627253 1.006272526 0.9911706239 4.15207455
0.9999994032
atm
K
xi Pi (atm) K = Pi/P yi = Ki xi i = Ki/Kb
0.00208101 0.24068573 0.240685732 0.0005008701 1
0.00053122 2.18100013 2.181000131 0.0011585901 9.06160955
0.99738777 1.00095537 1.000955372 0.9983406436 4.15876488
1.0000001039
atm
K
xi Pi (atm) K = Pi/P yi = Ki xi i = Ki/Kb
0.88404902 0.80129418 0.801294183 0.708383341 0.31860886
6.8784E-007 6.13657379 6.136573787 0.000004221 2.44001118
0.11595029 2.51497773 2.514977733 0.2916123909 1
0.9999999528
Heat Capacity Components
component A B C D
C3H4O2 84.154 0.52899 -0.0013617 1.7294E-006
C2H5OH 59.342 0.36358 -0.0012164 0.000001803
C5H8O2 102.928 0.55475 -0.0016152 2.3569E-006
H2O 92.053 -0.039953 -0.00021103 5.3469E-007
Tref 298.15 K yaws
TT-01
Ethanol Storage Tank (TT-01)
CWR
R-01
Reactor (R-01)
component mol (kmol) H
C3H4O2 1.1699459 7687.5963
C2H5OH 7.0196753 4967.4106
C5H8O2 57.426451 8664.8405
H2O 64.361822 3385.0625
T 343.15 K
reaction
C3H4O2 + C2H5OH C5H8O2 + H2O
T 343.15 K
Enthalpy of Formation Component HF
component A B C Hf
C3H4O2 -325.0380 -0.044058 2.093E-05 -337.692426
C2H5OH -216.9610 -0.069572 3.174E-05 -237.096715
C5H8O2 -327.0440 -0.089230 4.497E-05 -352.367971
H2O -238.4100 -0.012256 2.766E-06 -242.289992
Q (kJ)
8994.0716
34869.609
497591.04
217868.79
759323.51 Heat Exchanger (E-03)
E-01
CWS
H Q (kJ)
19152.895 12442.61
7676.6334 654.0986
K 13096.70
E-04 input
from FL-01
component mol Q (kJ)
C3H4O2 0.7679885 641.68736
C2H5OH 3.5540837 1913.8809
C5H8O2 56.818187 53342.867
H2O 0 0
total 61.140259 55898.435
BALANCE 61.140259 55898.435
FL-01
Decanter (FL-01)
component
C3H4O2
CWR C2H5OH
C5H8O2
Q (kJ) H2O
977.54001 T
3780.1086
53913.926 LIGHT OUTPUT
24295.711
82967.286 HEAVY OUTPUT
output
to E-04 to heavy key
mol Q (kJ) mol Q (kJ)
0.7679885 641.68736 0.4019574 335.85265
3.5540837 1913.8809 3.4655916 1866.2277
56.818187 53342.867 0.6082641 571.05927
0 0 64.361822 24295.711
61.140259 55898.435 68.837635 27068.851
129.97789 82967.286
output STEAM
to DC-01
mol Q (kJ) Q (kJ)
0.7679885 9700.9463
3.5540837 29113.552
56.818187 811450.09
0 0
61.140259 850264.59
61.140259 850264.59 794366.16
mol H Q (kJ)
0.7679885 835.54293 641.68736
3.5540837 538.50192 1913.8809
56.818187 938.83437 53342.867
0 377.48638 0
303.15 K 55898.435
steam
LIGHT OUTPUT
component
C3H4O2
C2H5OH
C5H8O2
H2O
T
steam
mol H Q (kJ)
0.7679885 12631.630 9700.9463
3.5540837 8191.5775 29113.552
56.818187 14281.520 811450.09
0 5472.9462 0
370.89752 K 850264.59
component mol H
C3H4O2 0.6496462 19152.895
C2H5OH 0 12506.273
C5H8O2 0.0852064 21764.086
H2O 0 8145.7748
T 406.0322075 K
Q (kJ)
12442.606
0
1854.4402
0
14297.053
COOLING
Q (kJ)
-780369.0
Ethyl Acrylate TT-03
Storage Tank (TT-03)
EA
Tdecanter 298.15 K
P 1 atm
4. Decanter sizing
4.1 Calculating Liquid Volume
decanter 10 minutes
Vl 1.312560108 m3
1.04551222
0.78730435
0.9177816
1.02745291
1.13755266
1.05688598
0.53512993
0.91129952
component MW
C3H4O2 72
C2H5OH 46
C5H8O2 100
H2O 18 component
Aspen Databanks TT-01 C2H5OH
Ethanol Storage Tank (TT-01) C5H8O2
ET ET1
mixed point 1
component
C3H4O2
C5H8O2
R-01
mixed point 1 Reactor (R-01)
reaction X 98%
C3H4O2 + C2H5OH C5H8O2 +
mixed point 2 M 58.49729 64.34702 0.099103
R 57.32735 57.32735 57.32735
mol (kmol) mass (kg) S 1.169946 7.019675 57.42645
58.497294 4211.8052
0.0852064 8.5206436
0.7053085 12.695553
LIGHT OUTPUT
HEAVY OUTPUT
input output
from FL-01 to distillate (MP-01) to bottom (DC-02)
mass (kg) mol mass (kg) mol mass (kg)
55.29517 4.549E-15 3.275E-13 0.767988 55.29517
163.4878 3.5238740 162.09820 0.030210 1.389647
5681.819 0.0138965 1.3896467 56.80429 5680.429
0 0 0 0 0
5900.602 3.5377704 163.48785 57.60249 5737.114
5900.60170530468 61.140259 5900.60170530468
input output
from DC-01 to distillate (TT-03) to bottom (MP-02)
mass (kg) mol mass (kg) mol mass (kg)
55.29517 0.1183423 8.5206436 0.649646 46.77453
1.389647 0.0302092 1.3896235 5.05E-07 2.33E-05
5680.429 56.719084 5671.9084 0.085206 8.520644
0 0 0 0 0
5737.114 56.867635 5681.8187 0.734853 55.29519
5737.1138553759 57.602489 5737.1138553759
component
C3H4O2
DC-01 C2H5OH
C5H8O2
Distillation Colomn 1 (FL-01)
C2H5OH
mol ET D 3.5238740 mol ET B 0.030210
ln (Di/Bi) 4.7591528
ln (i) 0.7716486
C5H8O2
mol EA D 0.0138965 mol EA B 56.80429
ln (Di/Bi) -8.315732
ln (i) 0
y=ax+b
eq (1) 4,7591528 = 0,7716486 a + b
eq (2) -8,315732 = 0 a + b
b -8.315732
a 16.944092
C3H4O2
ln (Di/Bi) -32.75997
(Di/Bi) 5.923E-15
eq (1) Di = 5,923E-15 x Bi
eq (2) Di + Bi = 0,767988
5,923E-15 Bi + Bi = 0,767988
mol AA D 4.549E-15 mol AA B 0.767988
mol mass (kg)
0 0
3.5238740 162.0982
0.0138965 1.389647
ta of each component
DC-01
vpc vpd vpe Distillation Colomn 2 (FL-
-4.8813 0.0004369 -4.916E-013
-5.0474 3.745E-011 2.736E-007
-17.694 0.008051 -4.886E-013
P DC-02 1 atm
T 373.04447 K
component xi Pi (atm)
C3H4O2 0.0133326 0.243397
C2H5OH 0.0005245 2.202181
C5H8O2 0.9861430 1.009591
C5H8O2
mol EA D 56.719084 mol EA B
ln (Di/Bi) 6.5007890
ln (i) 1.4226075
C3H4O2
mol AA D 0.1183423 mol AA B
ln (Di/Bi)
ln (i)
y=ax+b
eq (1) 6,500789 = 1,422608 a + b
eq (2) -1,702847 = 0 a + b
b -1.702847
a 5.7666192
C2H5OH
ln (Di/Bi) 10.998194
(Di/Bi) 59766.128
eq (1) Di = 59766,128 x Bi
eq (2) Di + Bi = 0,030210
59766,128 Bi + Bi = 0,030210
mol ET D 0.0302092 mol ET B
component mol
C-01 C3H4O2
C2H5OH
0.11834
0.03021
ation Colomn 2 (FL-02) C5H8O2 56.7191
component mol
C3H4O2 0.64965
C2H5OH 0
C5H8O2 0.08521
0.649646
-1.702847
0
5.055E-07
mass (kg)
8.520644 Ethyl Acrylate Storage Tank (TT-03)
1.389623 TT-03
5671.908 component mol
C3H4O2 0.11834
EA C2H5OH 0.03021
C5H8O2 56.7191
vpe
-4.916E-013
2.736E-007
-4.886E-013
mass (kg)
46.77453
0
8.520644
mass (kg) purity
8.5206436 0.14996%
1.3896235 0.02446%
5671.9084 99.8256%
5681.8187
component mass (kg) kmol Xmol
C3H4O2 55.295172 0.7679885 0.013
C2H5OH 163.48785 3.5540837 0.058
C5H8O2 5681.8187 56.818187 0.929
H2O 0 0 0
5900.6017 61.1403
1. operation condition
1.1 feed key component
light key C2H5OH
heavy key C5H8O2
1.2 recovery
each key 99.15%
y=ax+b
eq (1). 4,7676891 = 0,7716486 a + b
eq (2). -8,315732 = 0 a + b
b -8.315732
a 16.955127
C3H4O2
ln (Di/Bi) -32.77584
(Di/Bi) 5.830E-15
eq (1). Di = 5,830E-15 x Bi
eq (2). Di + Bi = 0,7679885
5,830E-15 Bi + Bi = 0,7679885
Tboiling 351.64365 K
Pt 1 atm
component kmol xi Puap Ki
C3H4O2 0 0 0.097905 0.098
C2H5OH 3.5238740 0.9960719703 1.001942 1.002
C5H8O2 0.0138965 0.0039280297 0.501291 0.501
Total 3.53777045 1
3. minimum reflux
3.1 Underwood constant
2.024896435
component Xf f i -
C3H4O2 0.012561093 0.2363035776 0.236 -1.789
C2H5OH 0.058130007 2.1633325543 2.163 0.138
C5H8O2 0.9293089 1 1.000 -1.025
Total 1 3.3996361319
i = Ki / Kb
0.236
2.163
1.000
xi = yi / Ki i = Ki / Kb
0 0.195407997
0.992 1.999156389
0.008 1
0.9999999307
yi = Ki xi i = Ki / Kb
0 0.195305902
0.9980058487 1.998720587
0.0019690876 1
0.9999749363
xi = yi / Ki i = Ki / Kb
0.0526206146 0.243
0.0002280848 2.190
0.9471505439 1.000
0.9999992433
i - / xF/B
-7.569 -0.001659534
0.064 0.908393978
-1.025 -0.906734444
-1.0436E-014
i Xi / i -
0
-76.0574973312
-0.0038326113
-76.0613299425
ponent
n
1.25
1.22
1.13
0.96
C D
0.03438 -2.77E-05
0.01372 -1.55E-05
0.01300 -1.43E-05
0.01773 -1.26E-05
ent
n
0.351
0.079
0.306
0.321