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    BasicDeriv PDF

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    Frederick Heisenberg
    This document discusses basic derivatives of volume (V) with respect to temperature (T) and pressure (P). It defines the isobaric thermal expansivity (α) and isothermal compressibility (κ) which describe how V changes with T at constant P, and with P at constant T, respectively. It then shows that the total change in V (dV) can be expressed as a function of α, κ, dT and dP. The document questions whether α and κ fully describe the mechanical behavior and derives an expression for the derivative of P with respect to T at constant V.

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    BasicDeriv PDF

    Uploaded by

    Frederick Heisenberg
    14 views1 page
    This document discusses basic derivatives of volume (V) with respect to temperature (T) and pressure (P). It defines the isobaric thermal expansivity (α) and isothermal compressibility (κ) which describe how V changes with T at constant P, and with P at constant T, respectively. It then shows that the total change in V (dV) can be expressed as a function of α, κ, dT and dP. The document questions whether α and κ fully describe the mechanical behavior and derives an expression for the derivative of P with respect to T at constant V.

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    This document discusses basic derivatives of volume (V) with respect to temperature (T) and pressure (P). It defines the isobaric thermal expansivity (α) and isothermal compressibility (κ) which describe how V changes with T at constant P, and with P at constant T, respectively. It then shows that the total change in V (dV) can be expressed as a function of α, κ, dT and dP. The document questions whether α and κ fully describe the mechanical behavior and derives an expression for the derivative of P with respect to T at constant V.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    14 views1 page

    BasicDeriv PDF

    Uploaded by

    Frederick Heisenberg
    This document discusses basic derivatives of volume (V) with respect to temperature (T) and pressure (P). It defines the isobaric thermal expansivity (α) and isothermal compressibility (κ) which describe how V changes with T at constant P, and with P at constant T, respectively. It then shows that the total change in V (dV) can be expressed as a function of α, κ, dT and dP. The document questions whether α and κ fully describe the mechanical behavior and derives an expression for the derivative of P with respect to T at constant V.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    Basic Derivatives

    V(T,P)

    V V
    dV = ( T )P dT + ( P )T dP

    1 V
    = V ( )P isobaric thermal expansivity, coefficient of thermal expansion
    T
    1 V
    = = V ( )T isothermal compressibility
    P
    dV = V dT - V dP
    do and give everything we need to know about mechanical behavior?
    (P ) =?
    T V
    V V
    0 = dV = ( ) dT + ( )T dP
    T P P

    (V)
    P T
    dP = (
    V
    ) dT
    T P
    V
    ( ) dT
    T P
    dP =
    (V )
    P T
    V
    ( )
    (P ) =
    T V
    T P
    (V)
    P T
    for small changes V doesn't change much: V Vo
    cst. P dV = V dT
    V2 T2
    dV = V dT V = Vo T
    V1 T1

    cst. T dV = -V dP
    V = -Vo P

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