Product: Hydrogen, Compressed P-4604-G Date: July 2007

Praxair Material Safety Data Sheet

(See section 15, under TSCA, for important restrictions on product use.)

1. Chemical Product and Company Identification

Product Name: Hydrogen, compressed (MSDS No. Trade Names: Hydrogen
P-4604-G)
Chemical Name: Hydrogen Synonyms: Dihydrogen, parahydrogen,
refrigerant gas R702, water gas
Chemical Family: Permanent gas Product Grades: Industrial, 4.5, 4.5-Zero,
4.5 TOC, 5.0-UHP, 5.0-SPG, 5.5-SPG, 6.0-
SPG, 6.0-UHP, and 6.0-Research
Telephone: Emergencies: 1-800-645-4633* Company Name: Praxair, Inc.
CHEMTREC: 1-800-424-9300* 39 Old Ridgebury Road
Routine: 1-800-PRAXAIR Danbury, CT 06810-5113
* Call emergency numbers 24 hours a day only for spills, leaks, fire, exposure, or accidents
involving this product. For routine information, contact your supplier, Praxair sales
representative, or call 1-800-PRAXAIR (1-800-772-9247).

2. Hazards Identification

EMERGENCY OVERVIEW
DANGER! Flammable high-pressure gas.
Can form explosive mixtures with air.
May ignite if valve is opened to air.
Burns with invisible flame.
May cause dizziness and drowsiness.
Self-contained breathing apparatus may be required by rescue workers.
Under ambient conditions, this is a colorless, odorless, tasteless gas.
OSHA REGULATORY STATUS: This material is considered hazardous by the OSHA Hazard
Communications Standard (29 CFR 1910.1200).
POTENTIAL HEALTH EFFECTS:
Effects of a Single (Acute) Overexposure
Inhalation. Asphyxiant. Effects are due to lack of oxygen. Moderate concentrations may
cause headache, drowsiness, dizziness, excitation, excess salivation, vomiting, and
unconsciousness. Lack of oxygen can kill.
Skin Contact. No harm expected.
Swallowing. An unlikely route of exposure; this product is a gas at normal temperature and
pressure.
Eye Contact. No harm expected.
Effects of Repeated (Chronic) Overexposure. No harm expected.

Copyright 1980, 1986, 1992, 1997, 2000, 2004, 2007, Praxair Technology, Inc. Page 1 of 10
All rights reserved.
A vertical line in the left margin indicates revised or new material.
Product: Hydrogen, Compressed P-4604-G Date: July 2007

Other Effects of Overexposure. Hydrogen is an asphyxiant. Lack of oxygen can kill.

Medical Conditions Aggravated by Overexposure. The toxicology and the physical and
chemical properties of hydrogen suggest that overexposure is unlikely to aggravate existing
medical conditions.
CARCINOGENICITY: This product is not listed by NTP, OSHA, or IARC
POTENTIAL ENVIRONMENTAL EFFECTS: None known. For further information, see section
12, Ecological Information.

3. Composition/Information on Ingredients
See section 16 for important information about mixtures.

COMPONENT CAS NUMBER CONCENTRATION

Hydrogen 1333-74-0 >99%*
*The symbol > means greater than.

4. First Aid Measures

INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, qualified personnel may give oxygen. Call a physician.
SKIN CONTACT: An unlikely route of exposure. This product is a gas at normal temperature
and pressure.
SWALLOWING: An unlikely route of exposure. This product is a gas at normal temperature
and pressure.
EYE CONTACT: An unlikely route of exposure. This product is a gas at normal temperature
and pressure.
NOTES TO PHYSICIAN: There is no specific antidote. Treatment of overexposure should be
directed at the control of symptoms and the clinical condition of the patient.

5. Fire Fighting Measures

FLAMMABLE PROPERTIES: Flammable gas. Flame is nearly invisible. Escaping gas may
ignite spontaneously. Hydrogen has a low ignition energy. Fireball forms if gas cloud ignites
immediately after release. Forms explosive mixtures with air and oxidizing agents.
SUITABLE EXTINGUISHING MEDIA: CO2, dry chemical, water spray, or fog
PRODUCTS OF COMBUSTION: Water (H2O)
PROTECTION OF FIREFIGHTERS: DANGER! Flammable high-pressure gas. Evacuate all
personnel from danger area. Immediately deluge cylinders with water from maximum distance
until cool; then move them away from fire area if without risk. Continue cooling water spray
while moving cylinders. Do not extinguish flames emitted from cylinders; allow them to burn out.
Self-contained breathing apparatus may be required by rescue workers. On-site fire brigades
must comply with OSHA 29 CFR 1910.156.
Specific Physical and Chemical Hazards. Heat of fire can build pressure in cylinder and
cause it to rupture. Hydrogen cylinders are equipped with a pressure relief device. (Exceptions
may exist where authorized by DOT.) No part of a cylinder should be subjected to a
temperature higher than 125F (52C). If venting or leaking hydrogen catches fire, do not

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Product: Hydrogen, Compressed P-4604-G Date: July 2007

extinguish flames. Flammable gas may spread from leak, creating an explosive re-ignition
hazard. Vapors can be ignited by pilot lights, other flames, smoking, sparks, heaters, electrical
equipment, static discharge, or other ignition sources at locations distant from product handling
point. Explosive atmospheres may linger. Before entering area, especially confined areas,
check atmosphere with approved explosion meter.
Protective Equipment and Precautions for Firefighters. Firefighters should wear self-
contained breathing apparatus and full fire-fighting turnout gear.

6. Accidental Release Measures

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
DANGER! Flammable high-pressure gas.
Personal Precautions. Forms explosive mixtures with air. (See section 5.) Immediately
evacuate all personnel from danger area. Use self-contained breathing apparatus where
needed. Approach suspected leak area with caution. Remove all sources of ignition if without
risk. Reduce gas with fog or fine water spray. Shut off flow if without risk. Ventilate area or
move cylinder to a well-ventilated area. Flammable gas may spread from leak. Before entering
area, especially confined areas, check atmosphere with an appropriate device.
Environmental Precautions. Prevent waste from contaminating the surrounding environment.
Keep personnel away. Discard any product, residue, disposable container, or liner in an
environmentally acceptable manner, in full compliance with federal, state, and local regulations.
If necessary, call your local supplier for assistance.

7. Handling and Storage

PRECAUTIONS TO BE TAKEN IN HANDLING: Keep away from heat, sparks, and open
flame. Use only spark-proof tools and explosion-proof equipment. Protect cylinders from
damage. Use a suitable hand truck to move cylinders; do not drag, roll, slide, or drop.
Hydrogen is the lightest known gas. It may leak out of systems that are air-tight for other
gases and may collect in poorly ventilated upper reaches of buildings. Leak check system with
soapy water; never use a flame. All piped hydrogen systems and associated equipment
must be grounded. Electrical equipment must be non-sparking or explosion-proof. Do not
crack or open hydrogen cylinder valves unless connected to utilization equipment;
escaping gas may ignite spontaneously. Open valve slowly. If valve is hard to open,
discontinue use and contact your supplier. Close cylinder valve after each use; keep closed
even when empty. Never attempt to lift a cylinder by its cap; the cap is intended solely to
protect the valve. Never insert an object (e.g., wrench, screwdriver, pry bar) into cap openings;
doing so may damage the valve and cause a leak. Use an adjustable strap wrench to remove
over-tight or rusted caps. For other precautions in using hydrogen, see section 16.
PRECAUTIONS TO BE TAKEN IN STORAGE: Store and use with adequate ventilation.
Store only where temperature will not exceed 125F (52C). Separate hydrogen cylinders
from oxygen, chlorine, and other oxidizers by at least 20 ft (6.1 m), or use a barricade of
noncombustible material. This barricade should be at least 5 ft (1.53 m) high and have a fire
resistance rating of at least hour. Always secure cylinders upright to keep them from
falling or being knocked over. Install valve protection cap, if provided, firmly in place by hand
when the cylinder is not in use. Post No Smoking or Open Flames signs in storage and
use areas. There must be no sources of ignition. All electrical equipment in storage areas
must be explosion-proof. Storage areas must meet national electric codes for Class 1

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Product: Hydrogen, Compressed P-4604-G Date: July 2007

hazardous areas. Store full and empty cylinders separately. Use a first-in, first-out inventory
system to prevent storing full cylinders for long periods.
RECOMMENDED PUBLICATIONS: For further information on storage, handling, and use, see
Praxair publication P-14-153, Guidelines for Handling Gas Cylinders and Containers. Obtain
from your local supplier. For further information specific to hydrogen, see NFPA 50A, Standard
for Gaseous Hydrogen Systems at Consumer Sites, published by the National Fire Protection
Association, 1 Batterymarch Park, PO Box 9101, Quincy, MA 02269-9101; 1-800-344-3555;
www.nfpa.org.

8. Exposure Controls/Personal Protection

COMPONENT OSHA PEL ACGIH TLV-TWA (2007)

Hydrogen N.E.* Simple asphyxiant
*N.E.Not Established.
IDLH = Not applicable.
ENGINEERING CONTROLS:
Local Exhaust. An explosion-proof local exhaust system is acceptable. See SPECIAL.
Mechanical (General). Inadequate; see special.
Special. Use only in a closed system.
Other. See special.
PERSONAL PROTECTIVE EQUIPMENT:
Skin Protection. Wear work gloves for cylinder handling and metatarsal shoes for cylinder
handling. Select in accordance with OSHA 29 CFR 1910.132 and 1910.133. Regardless of
protective equipment, never touch live electrical parts.
Eye/Face Protection. Select in accordance with OSHA 29 CFR 1910.133.
Respiratory Protection. None required under normal use. An air-supplied respirator must be
used in confined spaces. Respiratory protection must conform to OSHA rules as specified in 29
CFR 1910.134. Select per OSHA 29 CFR 1910.134 and ANSI Z88.2.

9. Physical and Chemical Properties

APPEARANCE: Colorless gas
ODOR: Odorless
ODOR THRESHOLD: Not applicable.
PHYSICAL STATE: Gas at normal temperature and pressure
pH: Not applicable.
MELTING POINT at 1 atm: -434.56F (-259.2C)
BOILING POINT at 1 atm: -422.97F (-252.76C)
FLASH POINT (test method): Not available.
EVAPORATION RATE (Butyl Acetate = 1): Not applicable.
FLAMMABILITY: Flammable
FLAMMABLE LIMITS IN AIR, % by volume: LOWER: 4.0% UPPER: 75.0%

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Product: Hydrogen, Compressed P-4604-G Date: July 2007

LIQUID DENSITY at boiling point and 1 atm: 4.43 lb/ft3 (70.96 kg/m3)
VAPOR PRESSURE at 68F (20C): Not applicable.
VAPOR DENSITY at 70F (21.1C) and 1 atm: 0.0052 lb/ft3 (0.083 kg/m3)
SPECIFIC GRAVITY (H2O = 1) at 19.4F (-7C): Not available.
SPECIFIC GRAVITY (Air = 1) at 32F (0C) and 1 0.07
atm:
SOLUBILITY IN WATER vol/vol at 60F (15.6C) 0.019
and 1 atm:
PARTITION COEFFICIENT: n-octanol/water: Not available.
AUTOIGNITION TEMPERATURE: 932F (500C)
DECOMPOSITION TEMPERATURE: Not available.
PERCENT VOLATILES BY VOLUME: 100
MOLECULAR WEIGHT: 2.016
MOLECULAR FORMULA: H2

10. Stability and Reactivity

CHEMICAL STABILITY: Unstable Stable

CONDITIONS TO AVOID: None known.

INCOMPATIBLE MATERIALS: Oxidizing agents, lithium, halogens
HAZARDOUS DECOMPOSITION PRODUCTS: None
POSSIBILITY OF HAZARDOUS REACTIONS: May Occur Will Not Occur
Flammable gas. Forms explosive mixtures with air and oxidizing agents.

11. Toxicological Information

ACUTE DOSE EFFECTS: Hydrogen is a simple asphyxiant.

STUDY RESULTS: None known.

12. Ecological Information

ECOTOXICITY: No adverse ecological effects expected.
OTHER ADVERSE EFFECTS: Hydrogen does not contain any Class I or Class II ozone-
depleting chemicals.

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Product: Hydrogen, Compressed P-4604-G Date: July 2007

13. Disposal Considerations

WASTE DISPOSAL METHOD: Do not attempt to dispose of residual or unused quantities.
Return cylinder to supplier.

14. Transport Information

DOT/IMO SHIPPING NAME: Hydrogen, compressed
HAZARD PACKING IDENTIFICATION PRODUCT
CLASS: 2.1 GROUP/Zone: NA* NUMBER: UN1049 RQ: None
SHIPPING LABEL(s): FLAMMABLE GAS
PLACARD (when required): FLAMMABLE GAS
*NA-Not applicable.
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position, in a
well-ventilated vehicle. Cylinders transported in an enclosed, nonventilated compartment of a
vehicle can present serious safety hazards.
Shipment of compressed gas cylinders that have been filled without the owners consent is a
violation of federal law [49 CFR 173.301(b)].
MARINE POLLUTANTS: Hydrogen is not listed as a marine pollutant by DOT.

15. Regulatory Information

The following selected regulatory requirements may apply to this product. Not all such
requirements are identified. Users of this product are solely responsible for compliance with all
applicable federal, state, and local regulations.
U.S. FEDERAL REGULATIONS:
EPA (ENVIRONMENTAL PROTECTION AGENCY)
CERCLA: COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION,
AND LIABILITY ACT OF 1980 (40 CFR Parts 117 and 302):
Reportable Quantity (RQ): None
SARA: SUPERFUND AMENDMENT AND REAUTHORIZATION ACT:
SECTIONS 302/304: Require emergency planning based on Threshold Planning
Quantity (TPQ) and release reporting based on Reportable Quantities (RQ) of
Extremely Hazardous Substances (EHS) (40 CFR Part 355):
TPQ: None
EHS RQ (40 CFR 355): None
SECTIONS 311/312: Require submission of MSDSs and reporting of chemical
inventories with identification of EPA hazard categories. The hazard categories for
this product are as follows:
IMMEDIATE: No PRESSURE: Yes
DELAYED: No REACTIVITY: No
FIRE: Yes
SECTION 313: Requires submission of annual reports of release of toxic chemicals
that appear in 40 CFR Part 372.
Hydrogen is not subject to reporting under Section 313.

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Product: Hydrogen, Compressed P-4604-G Date: July 2007

40 CFR 68: RISK MANAGEMENT PROGRAM FOR CHEMICAL ACCIDENTAL

RELEASE PREVENTION: Requires development and implementation of risk
management programs at facilities that manufacture, use, store, or otherwise handle
regulated substances in quantities that exceed specified thresholds.
Hydrogen is listed as a regulated substance in quantities of 10,000 lb (4536 kg) or
greater.
TSCA: TOXIC SUBSTANCES CONTROL ACT: Hydrogen is listed on the TSCA
inventory.
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION:
29 CFR 1910.119: PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS
CHEMICALS: Requires facilities to develop a process safety management program
based on Threshold Quantities (TQ) of highly hazardous chemicals.
Hydrogen is not listed in Appendix A as a highly hazardous chemical. However, any
process that involves a flammable gas on site in one location in quantities of 10,000
lb (4536 kg) or greater is covered under this regulation unless the gas is used as a
fuel.
STATE REGULATIONS:
CALIFORNIA: Hydrogen is not listed by California under the SAFE DRINKING WATER
AND TOXIC ENFORCEMENT ACT OF 1986 (Proposition 65).
PENNSYLVANIA: Hydrogen is subject to the PENNSYLVANIA WORKER AND
COMMUNITY RIGHT-TO-KNOW ACT (35 P.S. Sections 7301-7320).

16. Other Information

Be sure to read and understand all labels and instructions supplied with all containers of this
product.
OTHER HAZARDOUS CONDITIONS OF HANDLING, STORAGE, AND USE: Flammable
high-pressure gas. Use only in a closed system. Use piping and equipment adequately
designed to withstand pressures and temperatures to be encountered. Use a backflow
prevention device in the piping. Gas can cause rapid suffocation due to oxygen deficiency.
Store and use with adequate ventilation. Never work on a pressurized system. If there is a
leak, close the cylinder valve. Blow the system down in a safe and environmentally sound
manner in compliance with all federal, state, and local laws; then repair the leak. Never place a
compressed gas cylinder where it may become part of an electrical circuit.
Mixtures. When you mix two or more gases or liquefied gases, you can create additional,
unexpected hazards. Obtain and evaluate the safety information for each component before
you produce the mixture. Consult an industrial hygienist or other trained person when you
evaluate the end product. Remember, gases and liquids have properties that can cause serious
injury or death.
HAZARD RATING SYSTEMS:
NFPA RATINGS: HMIS RATINGS:
HEALTH =0 HEALTH =0
FLAMMABILITY =4 FLAMMABILITY =4
INSTABILITY =0 PHYSICAL HAZARD = 3
SPECIAL = None

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Product: Hydrogen, Compressed P-4604-G Date: July 2007

STANDARD VALVE CONNECTIONS FOR U.S. AND CANADA:

THREADED: 0-3000 psig CGA-350
3301-5500 psig CGA-695
5501-7500 psig CGA-703
PIN-INDEXED YOKE: Not applicable.
ULTRA-HIGH-INTEGRITY CONNECTION: CGA-724
Use the proper CGA connections. DO NOT USE ADAPTERS. Additional limited-standard
connections may apply. See CGA pamphlet V-1 listed below.
Ask your supplier about free Praxair safety literature as referred to in this MSDS and on the
label for this product. Further information can be found in the following materials published by
the Compressed Gas Association, Inc. (CGA), 4221 Walney Road, 5th Floor, Chantilly, VA
20151-2923; telephone (703) 788-2700, http://www.cganet.com/Publication.asp.
AV-1 Safe Handling and Storage of Compressed Gases
G-5 Hydrogen
G-5.3 Commodity Specification for Hydrogen
P-1 Safe Handling of Compressed Gases in Containers
SB-2 Oxygen-Deficient Atmospheres
V-1 Compressed Gas Cylinder Valve Inlet and Outlet Connections
Handbook of Compressed Gases, Fourth Edition

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Product: Hydrogen, Compressed P-4604-G Date: July 2007

Praxair asks users of this product to study this MSDS and become aware of product hazards
and safety information. To promote safe use of this product, a user should (1) notify employees,
agents, and contractors of the information in this MSDS and of any other known product
hazards and safety information, (2) furnish this information to each purchaser of the product,
and (3) ask each purchaser to notify its employees and customers of the product hazards and
safety information.

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Product: Hydrogen, Compressed P-4604-G Date: July 2007

The opinions expressed herein are those of qualified experts within Praxair, Inc. We
believe that the information contained herein is current as of the date of this Material
Safety Data Sheet. Since the use of this information and the conditions of use of the
product are not within the control of Praxair, Inc., it is the users obligation to
determine the conditions of safe use of the product.

Praxair MSDSs are furnished on sale or delivery by Praxair or the independent distributors and suppliers
who package and sell our products. To obtain current MSDSs for these products, contact your Praxair
sales representative or local distributor or supplier, or download from www.praxair.com. If you have
questions regarding Praxair MSDSs, would like the form number and date of the latest MSDS, or would
like the names of the Praxair suppliers in your area, phone or write the Praxair Call Center (Phone: 1-
800-PRAXAIR; Address: Praxair Call Center, Praxair, Inc., PO Box 44, Tonawanda, NY 14151-0044).
Praxair and the Flowing Airstream design are trademarks or registered trademarks of
Praxair Technology, Inc. in the United States and/or other countries.

Praxair, Inc.
39 Old Ridgebury Road
Danbury, CT 06810-5113

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