Etanhol Belending Siystem
Etanhol Belending Siystem
Etanhol Belending Siystem
Blending Solutions
Technical Paper
Issue/Rev. 0.1 (12/07) Bulletin TP0A015
Billion Liters
20
of legislation for Americas renewable fuels industry.
To achieve the agreement a compromise was made 15
between the refiners and renewable fuels producers
that the EPA would waive the 2% requirement for re- 10
formulated gasoline. This means refiners are no longer
5
required to use any oxygenate if they can continue to
meet the clean air standards. The elimination of oxy- 0
genate was effective May 5, 2006. 1980 1985 1990 1995 2000 2005 2010 2015
(Source: Worldwatch Institute)
While this may sound like oxygenates are a thing of Figure 1 Ethanol Growth World Market
the past, it could not be further from the truth. The Bill
H.R. 3081 dated June 28, 2005 was passed to amend
the Clean Air Act to increase the production and use of 3.0
renewable fuels in the United States. The bill calls for
specific volumes of renewable fuel in each year 2006 2.5
through 2012 and reviewable each year within the time
frame. The following table illustrates:
Billion Liters
2.0
Volume in 1.5
Calendar Year Billions of Gallons
2006 4.0 1.0
2007 4.7
0.5
2008 5.4
2009 6.1
1993 1995 1997 1999 2001 2003 2005 2007
2010 6.8 (Source: Worldwatch Institute)
2011 7.4 Figure 2 Biodiesel Growth World Market
2012 8.0
Any blending components derived from renewable fuel,
BioFuels Facts
except that only the renewable portion of any such
blending component shall be considered part of the Ethanol Production B100 Production
(billions of liters)
applicable volume under the renewable fuel program.
The blend equivalency is 1 gallon of ethanol or B100 Brazil 15.2 USA 0.3 (53 plants)
shall be considered as 2.5 gallons of renewable fuel. USA 14.9 (81 plants) World 1.8
Ethanol and biodiesel were two key renewable fuels World 32.5
listed. Not only has the United States enforced renew-
able fuels but it has become a global issue and several Figure 3 Biofuels Facts
Sample No. et-OH Vol. Gas Vol. et-OH Temp. Gas Temp. Mix Temp. Final Temp. Mix Vol. Final Vol.
1 100.00 ml 900.00 ml 64.5 F 64.5 F 60.0 F 64.5 F 1000.3 ml 1000.5 ml
2 100.00 ml 900.00 ml 64.5 F 64.5 F 59.9 F 64.5 F 1000.5 ml 1000.7 ml
3 100.00 ml 900.00 ml 62.2 F 62.2 F 57.4 F 62.2 F 1000.4 ml 1000.6 ml
4 100.00 ml 900.00 ml 62.2 F 62.1 F 57.4 F 62.2 F 1000.5 ml 1000.6 ml
Figure 6 90/10 Ethanol/Gasoline Blend Endothermic Reaction Lab Test Results
SideStream Blending
Prover or Truck Prover or Truck
1,000 Gallon Batch Delivery Meter Blended Volume
Instantaneous Affect Recovered Temp./Volume
Gross Volume Preset
Temp. Gv Nv Temp. Gv Nv Temp. Gv Nv
90% Gasoline, 10% Ethanol
60 1000.3 1000.3 60 1000.3 1000.3 64.4 1000.5 997.37
A simple lab test was devised to measure the instanta- Biodiesel Fuel Blend Stock (B100)
neous and final growth of the blended 90/10 ethanol and ASTM D 6751 06
at the same time record temperatures. Figure 6 shows Performance requirements
the results of the lab test. (When blended with middle distillates)
Figure 7 is a simulated example of what a 1000 gallon Grade S15 and S500 limits
proving run or transaction might show when using the
data from Figure 6. This example shows the net result Flash Point, degrees C, min. 130.0
using two different methods of blending. Splash Blend-
ing, Sequential Blending and Ratio Blending will all give Water & Sediment, volume %, max. 0.050
similar results as the mixing occurs after the metering. Kinematic Viscosity, at 40 degrees C, mm2/s 1.9-6.0
The two methods for the example are; Ratio and Side-
Stream. The example assumes 60 API gasoline with a Sulfated ash, mass %, max. 0.020
C of E of 0.00069, denatured ethanol in accordance with
Sulfur, mass %, ppm, max. 0.0015 (15) Grade S15
the ASTM standard with a C of E of 0.00063, and of C
0.050 (500) Grade S500
of E for blended product of 0.00071.
It should be noted that these tests were conducted at Copper strip corrosion, max. No. 3
near 60 degrees F. In other tests performed the mo- Cetane no., min. 47
lecular change showed a much lower molecular volume
increase when the product temperatures were near 30 Cloud point See report
degrees F. Other affects such as pressure, different
percentages of each product, and ambient affects may Carbon residue, mass %, max. 0.050
have an impact on the amount of growth. Acid No., mg. KOH/g, max. 0.500
For the purpose of these tests and in order to determine
the real growth, the blended product was allowed to re- Free Glycerin, mass % 0.020
cover to its original temperature. This took place in less Total Glycerin, mass% 0.240
than 12 minutes. This brought out a primary concern and
that being that as soon as the product was mixed and Phosphorus content, mass %, max. .0010
delivered to a vessel it began a recovery in temperature.
Distillation Temperature, degrees C, max. 360
This means the net volume transferred is unstable for
some period of time. This can have serious affects on Atmospheric Equivelent
meter factor calculations and actual consumer deliver- Temperature 90% recovered Sodium
able volumes, both of which could be issues with the and Potassium combined 5 ppm (ug/g), max.
Departments Weights and Measures.
The conclusion is one that the user must decide what is See Figure 5 Biodiesel Production Process-B100
the best method to use for custody transfer in the spirit Process.
of Fair Trade and accurate inventory reconciliation of Not unlike ethanol, B100 has some unique issues as
inventories. well.
Sequential 92
87 Products
92 92/92 ETH
87/87 ETH
ETH 89/89 ETH
87
Products
Hybrid/Ratio
ETH 92/92 ETH
87/87 ETH 92
89/89 ETH
Ratio 87 92/92 ETH
87/87 ETH
92 89/89 ETH
ETH
87
92/92 ETH
87/87 ETH Hybrid/Sidestream
ETH
89/89 ETH 92
87
92/92 ETH
87/87 ETH
ETH 89/89 ETH
Ratio
Diesel
Products
B100 Diesel
B100, B2-20 Typical
Sidestream
Diesel
Diesel
B100 B2-20 Typical
#2
Diesel
(B2 to B20)
2" 3-130 GPM
B100
(B20 to B50)
3" 30-300 GPM
The specifications contained herein are subject to change without notice and any user of said specifications should verify from the manufacturer that the specifications are currently
in effect. Otherwise, the manufacturer assumes no responsibility for the use of specifications which may have been changed and are no longer in effect.
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