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2.
Explain the following terms :
(a) State of a System
(b) Extensive Properties
(c) Closed System
(d) Isothermal Process
4. State the first law of thermodynamics in as many ways as possible. Obtain the mathematical
expression for the law with sign conventions.
6. (a) What do you understand by thermodynamic system and surroundings?
(b) Which of the following are intensive properties :
(i) Density
( ii) Surface Tension
(iii) Volume
(iv) Entropy
8. (a) State and explain First law of Thermodynamics
(b) Prove that QV = 'E and QP = 'H and discuss the relation amongst heat, internal energy and
work.
10. Explain heat capacity at constant volume thermodynamically.
12. How would the energy of an ideal gas change if it is made to expand into vacuum at
constant temperature.
14. (a) Explain the term enthalpy. (b) State the first law of thermodynamics. (c) Define CP and
CV. State their relation.
16. (a) Describe open, closed and isolated systems.
(b) What do you understand by the terms : Extensive properties and Intensive properties. Give
two examples of each category.
(c) Calculate the work of expansion of one mole of an ideal gas at 25°C under isothermal
conditions, the pressure being changed from 1 to 5 atmosphere. Answer. (c) –3988.2 J
18. (a) Under what conditions 'E = 'H for a chemical reaction? (b) One mole of an ideal gas
expands isothermally and reversibly from 1 litre to 100 litres at 27°C. Calculate w, q, 'E, 'H and
'S for the process. Answer. (b) 2745.63 cal; 2745.63 cal; zero; 596.1 cal, 9.152 cal K–1
20. Explain the difference between isothermal and adiabatic processes.
22. (a) Prove that the value of Joule Thomson coefficient is zero for an ideal gas.
(b) Explain First law of Thermodynamics. Calculate the work done in an isothermal and
reversible expansion process of an ideal gas.
24. Calculate the work done in expanding 2 moles of an ideal gas from 2L to 5L at 273°C.
Answer. –5683.5 J (Andhra BSc, 2002)
26. (a) Write short notes on following :
(i) Enthalpy
(ii) Internal Energy
(iii) Free Energy
(b) Heat supplied to a Carnot engine is 453.6 kcal. How much useful work can be done by the
engine between 0°C and 100°C? Answer. (b) 1.216 × 105 cal (HS Gaur BSc, 2002
28. Calculate q, w, 'H, 'Ssystem, 'Ssurr and 'Suniverse for one mole of an ideal gas which
expands from V1 to 10V1 at 300 K isothermally under reversible conditions (Use R = 8.314 J K–
1 mol–1) Answer. 5744.14 J, 5744.14 J, 0, 0, 19.147 J K–1, –19.147 J K–1, 0 (Delhi BSc, 2003)
30. Calculate maximum amount of heat withdrawn from a hot reservoir at 410 K to obtain
work equivalent to 15 kJ per cycle. The temperature of the sink is 290 K. Answer. 512.50 kJ
(Sambalpur BSc, 2003)
32. What is the basic principle of Joule-Thomson effect? (Nagpur BSc, 2003)
34. Distinguish between : (a) Isothermal and adiabatic process (b) Reversible and Irreversible
process (Panjab BSc, 2003)
36. How many calories of heat are required to heat 18 grams of Argon from 40°C to 100°C at (i)
constant volume and (ii) constant pressure Molar heat capacity of Argon at constant volume is
3 cal/degree and molar heat capacity of Argon at constant pressure is 5 cal/degree. Answer.
180 cals; 300 cals (Meerut BSc, 2004)
38. (a) Explain the following : Heat capacity, Thermodynamic state, Isolated state, Intensive
properties.
(b) Calculate the maximum work obtained when 2 moles of nitrogen were expanded
isothermally and reversibly from 10 litres to 20 litres at 25°C.
Answer. (b) 3434.9 J (Sri Venkateswara BSc, 2004)
40. Calculate w and ' E for the conversion of 1 mole of water into l mole of steam at a
temperature of 373 K and 1 atm pressure. Latent heat of vaporisation of water 540 cal g–1.
Answer. 8.979 kcal (Delhi BSc, 2005)
42. When one mole of liquid Br2 is converted to Br2 vapour at 25 ºC and 1 atm pressure, 7.3
kcal of heat is absorbed and 0.59 k cal of expansion work is done by the system. Calculate ' E
for this process. Answer. + 6.7 kcal (Nagpur BSc, 2005)
44. What is the maximum work which can be obtained by the isothermal reversible expansion
of two moles to three moles of an ideal gas at 273 K from 1.12 litre to 11.2 litres ? Answer.
1627.35 cal

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2.

Explain the following terms :

(a) State of a System

(b) Extensive Properties

(c) Closed System

(d) Isothermal Process

6. (a) What do you understand by thermodynamic system and surroundings?

(b) Which of the following are intensive properties :

( ii) Surface Tension

8. (a) State and explain First law of Thermodynamics

10. Explain heat capacity at constant volume thermodynamically.

16. (a) Describe open, closed and isolated systems.

20. Explain the difference between isothermal and adiabatic processes.

26. (a) Write short notes on following :

(ii) Internal Energy

(iii) Free Energy

Answer. (b) 3434.9 J (Sri Venkateswara BSc, 2004)

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