Replacement of Cement With Rice Husk Ash RHA
Replacement of Cement With Rice Husk Ash RHA
Replacement of Cement With Rice Husk Ash RHA
A Project Report
Of
Bachelor of Technology
In
CIVIL ENGINEERING
BY
APRIL, 2015
1
CERTIFICATE
We hereby certify that the work which is being presented in the B.Tech. Major Project Report
The matter presented in this thesis has not been submitted by me for the award of any other
degree elsewhere.
Signature of Candidate
Praveer Bhriguvanshi (110107140)
Anshuman Mani (110107038)
Amitesh Kumar (110107032)
Pal Shweta Prakash (110107127)
This is to certify that the above statement made by the candidate is correct to the best of my
knowledge.
Signature of Supervisor(s)
Date: 24-04-2015 PRASHANT KUMAR
ASSISTANT PROFESSOR
Head of Department
CIVIL Engineering Department
Sharda University, Greater Noida
2
ACKNOWLEDGEMENT
Our sincere Thanks to all the lab attendant who helps us in doing our project. Last
but not the least we express our sincere thanks to all our friends who have patiently
extended all kind of help for accomplishing this undertaking. Finally we extend our
gratitude to one and all who are directly or indirectly involved in the successful
completion of this project work.
3
ABSTRACT
The optimized RHA, by controlled burn or grinding, has been used as a pozzolanic material in
cement and concrete. Using it provides several advantages, such as improved strength and
durability properties, and environmental benefits related to the disposal of waste materials and to
reduced carbon dioxide emissions. Up to now, little research has been done to investigate the use
of RHA as supplementary material in cement and concrete production .The main objective of
this work is to study the suitability of the rice husk ash as a pozzolanic material for cement
replacement in concrete. However it is expected that the use of rice husk ash in concrete improve
the strength properties of concrete. Also it is an attempt made to develop the concrete using rice
husk ash as a source material for partial replacement of cement, which satisfies the structural
properties of concrete like compressive strength.
From the entire experimental work & studies it is concluded that mix M20 with the replacement
of 20% is the best combination among all mixes, which gives the maximum compressive
strength.
4
List of Figures
5
List of Tables
6
List of Abbreviations
7
CONTENTS
3 Methodology 21-22
3.1 General 21
3.2 Flow chart 22
8
CHAPTER NO NAME OF TOPIC PAGE NO
9 Reference 43
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CHAPTER-1
Introduction
RHA produced after burning of Rice husks (RH) has high reactivity and pozzolanic property.
Chemical compositions of RHA are affected due to burning process and temperature. Silica
content in the ash increases with higher the burning temperature.The effect of partial replacement
of cement with different percentages of ground RHA on the compressive strength and durability
of concrete is examined.
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Fig 1 : Rice husk ash (R.H.A)
(Ref. thailand.ipm-info.org)
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Table 1: Physical Properties of R.H.A
(B) Cement
Ordinary Portland cement (OPC) of 43 grade was used in which the composition and
properties is in compliance with the Indian standard organization.
Cement can be defined as the bonding material having cohesive & adhesive properties which
makes it capable to unite the different construction materials and form the compacted assembly.
Ordinary/Normal Portland cement is one of the most widely used type of Portland Cement. The
name Portland cement was given by Joseph Aspdin in 1824 due to its similarity in color and its
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quality when it hardens like Portland stone. Portland stone is white grey limestone in island of
Portland, Dorset.
1. Calcium
2. Silica
3. Alumina
4. Iron
Calcium is usually derived from limestone, marl or chalk while silica, alumina and iron come
from the sands, clays & iron ores. Other raw materials may include shale, shells and industrial
by products.
Contents %
i. CaO 60-67
v. MgO 0.5-4.0
vii. SO 3 2.0-3.5
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3. Tricalcium aluminates (3CaO.Al2O3)
1. Durable
2. Corrosion resistance
4. Volume stability
Cement sets when mixed with water by way of a complex series of chemical reactions still only
partly understood. The different constituents slowly crystallize and the interlocking of their
crystals gives cement its strength. Carbon dioxide is slowly absorbed to convert
the portlandite (Ca(OH)2) into insoluble calcium carbonate. After the initial setting, immersion
in warm water will speed up setting. Gypsum is added as an inhibitor to prevent flash setting.
The most common use for Portland cement is in the production of concrete. Concrete is a
composite material consisting of aggregate (gravel and sand), cement, and water. As a
construction material, concrete can be cast in almost any shape desired, and once hardened, can
become a structural (load bearing) element. Concrete can be used in the construction of
structural elements like panels, beams, road furniture, or may make cast-in situ concrete for
building superstructures like roads and dams. These may be supplied with concrete mixed on
site, or may be provided with "ready-mixed" concrete made at permanent mixing sites. Portland
cement is also used in mortars(with sand and water only) for plasters and screeds, and
in grouts (cement/water mixes squeezed into gaps to consolidate foundations, road-beds, etc.).
When water is mixed with Portland cement, the product sets in a few hours and hardens over a
period of weeks. These processes can vary widely depending upon the mix used and the
conditions of curing of the product, but a typical concrete sets in about 6 hours and develops
a compressive strength of 8 MPa in 24 hours. The strength rises to 15 MPa at 3 days, 23 MPa at
1 week, 35 MPa at 4 weeks and 41 MPa at 3 months. In principle, the strength continues to rise
slowly as long as water is available for continued hydration, but concrete is usually allowed to
dry out after a few weeks and this causes strength growth to stop.
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(C) CONCRETE
Concrete is a composite material composed mainly of water, aggregate, and cement. Often,
additives and reinforcements (such as rebar) are included in the mixture to achieve the desired
physical properties of the finished material. When these ingredients are mixed together, they
form a fluid mass that is easily molded into shape. Over time, the cement forms a hard matrix
which binds the rest of the ingredients together into a durable stone-like material with many
uses.
C (i) HISTORY
Famous concrete structures include the Hoover Dam, the Panama Canal and the
Roman Pantheon. The earliest large-scale users of concrete technology were the ancient
Romans, and concrete was widely used in the Roman Empire. The Colosseum in Rome was built
largely of concrete, and the concrete dome of the Pantheon is the world's largest unreinforced
concrete dome.
1. Workability
4. Strength
5. Durability
6. Appearance
(D) AGGREGATES
The inert mineral materials such as sand, gravel, etc used for manufacture of concretes are
known as aggregates. Requirements Of Good Aggregates
2. It should be hard
3. It should be durable.
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4. It should have rough surface.
1. Coarse Aggregates
2. Fine Aggregates
Coarse aggregates –
The aggregates which pass through 75mm IS sieve and retain on 4.75mm IS sieve are known as
coarse aggregates.
Fine aggregates –
The aggregates which pass through 4.75 mm IS sieve and retain on 75 micron IS sieve are
known as fine aggregates.
*The research work is restricted to sand collected from the river. The sand was collected to
ensure that there was no allowance for deleterious materials contained in the sand and the size of
5mm. In this research, granite of 20mm maximum size was used.
(E) Water
Water plays an important role in concrete production (mix) in that it starts the reaction
between the cement, pozzolan and the aggregates. It helps in the hydration of the mix. In this
research, the water used was distilled water.
1.4 Objective
The main objective of this work is to study the suitability of the rice husk ash as a pozzolanic
material for cement replacement in concrete. However it is expected that the use of rice husk ash
in concrete improve the strength properties of concrete. Also it is an attempt made to develop the
concrete using rice husk ash as a source material for partial replacement of cement, which
satisfies the various structural properties of concrete like compressive concrete like compressive
strength.
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1. Effect of Rice Husk Ash on workability.
2. Effect on Compressive strength of concrete.
3. Comparison of result of different tests with varying proportion of RHA.
It is also expected that the final outcome of the project will have an overall beneficial effect on
the utility of rice husk ash concrete in the field of civil engineering construction work. Following
parameters influences behavior of the rice husk ash concrete, so these parameters are kept
constant for the experimental work. Thus the scope of the project can be summarized as:
B. To perform the specific gravity test, sieve analysis and slump test under Indian Standard
methods.
C. To conduct Compression test on RHA and Control concrete on standard IS specimen size
150 x 150 x 150 mm.
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CHAPTER 2
Literatures of Review
Ryan (1999)
Investigated on Concrete durability. He in his paper through QCL group addresses two
aspects of concrete serviceability, which has been the subject of extensive recent
discussion and research: sulphate attack and chloride ion penetration. The basic
chemistry involved in each of these processes is outlined by him and differentiated and
their effects on concrete and reinforcing steel are described. His paper relied for actual
test data, showing relative performance of binder options, on experimental work carried
out by researchers at the CSIRO Division of Building, Construction, and Engineering.
Skalny et al (2002)
Researched on Concrete subject to sulfate attack undergoes a progressive and profound
reorganization of its internal microstructure. These alterations have direct consequences
on the engineering properties of the material. As seen from his studies, concrete
undergoing sulphate attack is often found to suffer from swelling, spalling and cracking.
There is overwhelming evidence to show that the degradation also contribute to
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significantly reduce the mechanical properties of concrete. He studied the behaviour of
hydrated cement systems tested under well-controlled laboratory conditions is also
distinguished from the performance of concrete in service. He stated that Sulphate attack
has significant consequences on the microstructure and engineering properties of
concrete. Marked expansion and loss in the mechanical properties of the material often
accompany sulphate-induced micro structural alterations.
Prasad et al (2006)
Investigated on Cement concrete which continues to be the pre-eminent construction
materials for use in any type of civil engineering structure He concluded in his
investigation the blended cements, particularly are better in Sodium Sulphate
environment. The blended cement mixes show more deterioration in Magnesium
Sulphate exposure in compared to plain cement mixes. The Magnesium Sulphate
environment is more severe than Sodium Sulphate environment. The performance of low
water/binder ratio mixes is inferior in Sulphate resistance. The little initial air curing of
mixes is beneficial for Sulphate resistance. He also stated that The deterioration of
cement mixes increases with increase in the concentration of Sulphate. The presence of
Chloride ions with Sulphate ions reduces the rate of Sulphate attack on cement mixes.
The deterioration rate of mixes due to Sulphate attack is higher at high temperature with
alternate wetting and drying cycles.
Abdullahi et al (2006)
Investigated on the compressive strength of some commercial sandcrete blocks in
Minna, Nigeria was investigated. Rice Husk Ash (RHA) was prepared from burning
firewood. Preliminary analysis of the Constituent materials of the ordinary Portland
Cement (OPC) / Rice Husk Ash (RHA) hollow sandcrete blocks were conducted to
confirm their suitability for block making. He conducted physical test of the freshly
prepared mix. 150mm×450mm hollow sandcrete blocks were cast cured and crushed for
1, 3, 7, 14, 21, and 28 days at 0, 10, 20, 30, 40 and 50 percent replacement levels. He
concluded the results of test and indicated compressive strength of the OPC/RHA
sandcrete blocks increases with age at curing and decreases as the percentage of RHA
content increases.
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CHAPTER 3
METHODOLOGY
3.1 GENERAL
It is also expected that the final outcome of the project will have an overall beneficial effect on
the utility of rice husk ash concrete in the field of civil engineering construction work. Following
parameters influences behavior of the rice husk ash concrete, so these parameters are kept
constant for the experimental work.
Also from the literature survey, it is observed that the parameters suggested by different
researchers and their results are not matching with each other. It was due to variation in
properties of different materials considered in the work. Therefore the percentage replacement of
cement by rice husk ash and method of mix design is fixed after preliminary investigation.
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3.2 FLOW CHART
CONTROLLE
D CONCRETE
CASTING
PARTIAL
REPLACEMENT OF
CEMENT WITH
RHA(20%)
COMPRESSIO
CONCLUSION RESULTS N TEST AT 7th
AND 28th DAY
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CHAPTER -4
Preliminary Test
Purpose:
This test is performed to determine the percentage of different grain sizes obtained within a soil.
The mechanical or sieve analysis is performed to determine the distribution of the coarser,
larger-sized particles, and the hydrometer method is used to determine the distribution of the
finer particles.
Standard Reference:
ASTM D 422 - Standard Test Method for Particle-Size Analysis of Soils
Significance:
The distribution of different grain sizes affects the engineering properties of soil. Grain size
analysis provides the grain size distribution, and it is required in classifying the soil.
Equipment:
Balance, Set of sieves, Cleaning brush, Sieve shaker, Timing device.
Test Procedure:
Sieve Analysis:
(1) Write down the weight of each sieve as well as the bottom pan to be used in the analysis.
(3) Make sure that all the sieves are clean, and assemble them in the ascending order of sieve
numbers (4 sieve at top and 200 sieve at bottom). Place the pan below 200 sieve. Carefully pour
the soil sample into the top sieve and place the cap over it.
(4) Place the sieve stack in the mechanical shaker and shake for 10 minutes.
(5) Remove the stack from the shaker and carefully weigh and record the weight of each sieve
with its retained soil. In addition, remember to weigh and record the weight of the bottom pan
with its retained fine soil.
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Table:3 Sieve Analysis of sand
20 0 100
13 4 0.3 99.7
10 18 1.2 98.5
6.3 119 8 90.5
4.7 70 4.7 85.8
2.36 234 15.8 70.0
PAN 40 2.70 67.3
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CHAPTER-5
MIX DESIGN
Max water content for 20mm aggregate = 186 litre (for 20 to 50mm slump range)
Water content for 100mm slump = 186 + 6/100*186
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= 186 + 11.1
= 197.1 ~ 197L
Assuming 29%
W.C = 197 – 197*29/100
= 140 (approx)
From table No.5 of IS456 minimum cement content for severe exposure conditions
= 320kg/m3
350kg/m3 > 320kg/m3 Hence ok
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(a) VOLUME OF CONCRETE = 1 m3
= [1-(0.98+0.0337+0.14)]
= 0.7293 m3
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TOTAL CUBE IN 1 M3 = 296.2 ~ 297
Calculation:-
Density= mass/volume
Mass= (0.15)3*2400
= 8.1 kg
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Table: 5 Similarly all the following values given in the table are calculated as
above
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CHAPTER-6
Experimental work
Mixing:
Mix the concrete either by hand or in a laboratory batch mixer
Hand mixing:
(i)Mix the cement and fine aggregate on a water tight none-absorbent platform until the mixture
is thoroughly blended and is of uniform color
(ii)Add the coarse aggregate and mix with cement and fine aggregate until the coarse aggregate
is uniformly distributed throughout the batch
(iii)Add water and mix it until the concrete appears to be homogeneous and of the desired
consistency
(i) The internal surface of the mould is thoroughly cleaned and applied with a light coat of oil.
(ii) The mould is placed on a smooth, horizontal, rigid and nonabsorbent surface.
(iii) The mould is then filled in four layers with freshly mixed concrete each approximately to
one-fourth of the height of the mould.
(iv) Each layer is tamped 25 times by the rounded end of the tamping rod (strokes are
distributed evenly over the cross section).
(v) After the top layer is rodded, the concrete is struck off the level with a trowel.
(vi) The mould is removed from the concrete immediately by raising it slowly in the vertical
direction.
(vii) The difference in level between the height of the mould and that of the highest point of the
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subsided concrete is measured.
(viii) This difference in height in mm is the slump of the concrete.
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Fig:5 slump height being checked after removal of mould
Result:
The value of the slump test i.e, the height of the slump cameout to be 26 cm.
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Fig 6: MOUDLS OF SIZE 150mm*150mm
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Fig.8,9 Tamping of concrete being done.
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6.3. Casting:
(ii) Fill the concrete in the molds in layers approximately 5cm thick
(iii) Compact each layer with not less than 35strokes per layer using a tamping rod (steel bar
16mm diameter and 60cm long, bullet pointed at lower end)
6.4: Curing:
The first batch of 12 test specimens are stored in moist air for 24hours and after this
period the specimens are marked and removed from the molds and kept submerged in
clear fresh water until taken out prior to test.
The next batch of 12 test specimen are casted and stored in moulds for 24hrs after
demoulding the first batch. After this the specimen are removed from the moulds and
kept submerged in clear water until taken out prior to test.
Precautions:
The water for curing should be tested every 7days and the temperature of water must be at
27+-2oc. We should make sure that the water should be free from any deleterious material.
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6.5. Compression Test
Aim:
To find out the compressive strength of 24 test specimens.
Apparatus:
Compression testing machine
Specimen:
12 cubes of 15 cm size mix. M20
Procedure:
(i) Remove the specimen from water after specified curing time and wipe out excess water from
the surface.
(iv) Place the specimen in the machine in such a manner that the load shall be applied to the
opposite sides of the cube cast.
(v) Align the specimen centrally on the base plate of the machine.
(vi) Rotate the movable portion gently by hand so that it touches the top surface of the specimen.
(vii) Apply the load gradually without shock and continuously at the rate of 140KG/cm2/minute
till the specimen fails
(viii) Record the maximum load and note any unusual features in the type of failure.
Note
Minimum three specimens should be tested at each selected age. If strength of any specimen
varies by more than 15 per cent of average strength, results of such specimen should be rejected.
Average of there specimens gives the crushing strength of concrete. The strength requirements of
concrete.
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Calculations
Size of the cube =15cm x 15cm x 15cm
Area of the specimen (calculated from the mean size of the specimen ) =225cm
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Fig 11: Compressive test being done at 28 days
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CHAPTER-7
40
35
30
25
20 0% RHA
20% RHA
15
10
0
7 DAYS 14 DAYS 21 DAYS 28 DAYS
38
CHAPTER -8
39
(B) DISADVANTAGE OF RHA
Effective consumption of following RHA in cement or concrete has a great importance regarding
strength, durability and cost effectiveness of concrete up to a certain replacement percent.
Having the more benefits using RHA in cement or concrete, it shows a few disadvantages that
are mentioned below
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(C) Conclusion
Based on the limited study carried out on the strength behaviour of Rice Husk ash, the following
conclusions are drawn
At all the cement replacement levels of Rice husk ash; there is gradual increase in
compressive strength from 3 days to 7 days. However there is significant increase in
compressive strength from 7 days to 28 days followed by gradual increase from 28 days.
By using this Rice husk ash in concrete as replacement the emission of greenhouse gases
can be decreased to a greater extent. As a result there is greater possibility to gain more
number of carbon credits.4.
The technical and economic advantages of incorporating Rice Husk Ash in concrete
should be exploited by the construction and rice industries, more so for the rice growing
nations of Asia.
RHA based sand cement block can significantly reduce room temperature. Hence air
conditioner operation is reduce resulting in electric energy saving.
Moreover with the use of rice husk ash, the weight of concrete reduces , thus making the
concrete lighter which can be used as light weight construction material.
The pozzolonic activity of rice husk ash is not only effective in enhance the concrete
strength, but also in improving the impermeability characteristics of concrete
As the Rice Husk Ash is waste material, it reduces the cost of construction.
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CHAPTER -9
References
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