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Assignment 3
(Due date 05 March 2019)
Grand Canonical Ensemble
Problem 1. For a system in grand canonical ensemble:
i, Find the expression for the grand probability distribution function, p(E, NV), and the grand
partition function, Qy(T,V, 1).
ii. Find the following relations:
a. Average number of particles: (z = eM is the fugacity term)
a a
W) = ke? 5 In Qu = 251m Qy
b. Average energy:
a
(8) = spin Qn + ul)
cc. Pressure:
Pak, ren
= kel 3510 Oy
4. Grand potential energy:
Dy (TV, we) =
‘aT In Qu (TVs)
Problem 2. For a system in grand canonical ensemble show the following relations:
i, Fluctuation in the number of particles of the system:
‘GN) 2
(2 = B((AN)’)
MH lye
root-mean square fluctuation in the number of particles of the system:
VGN -o(4)
) oy
iii, Relate mean-square fluctuation in the particle density (n = N/V) of the system to
isothermal compressibility (ir):
(Gan?) _
mm ~V
ii, Rek
Kr
Problem 3: Consider a system in grand canonical ensemble
i. Evaluate the mean-square fluctuation in energy:
ae) ate)
((QE)*) = kT? Gr), + wkyT @),,
ii, Relative root-mean square fluctuation in the energy of the system:
GE) (4)
8) ia)
Problem 4: Consider a classical ideal gas of N particles in grand canonical ensemble. Evaluate
the following thermodynamic quantities: Qu, Qy,{N), {E), P,S, F, Cy. Show that the relative root-
mean square fluctuations in the energy (Prob. 2(ii)) and the number of particles (Prob. 3(ii)) of
the system hold true.
Bias oe : inear classical harmonic
Parasol open system of N non-interacting, independsns, dineat fe the frequency of
oscillators, each of mass m, in thermal equilibrium at nl
oscillation. The Hamiltonian of any one of them is then gi’
HG) = 3
Evaluate the following thermodynamic quantities Qu
matq? + peri = ts N)-
é Oy, (N) {EY SF, and Cy in one dimension
f an
(b) Consider the Quantum mechanical situation of the above problem where the enerBy ©
oscillator is expressed as
o).
1
ey = (n +5) ho (n= 0112,
i. Evaluate the following thermodynamic quantities Qy, %y,(N), (E),S, F,and Cy. ;
ii, Discuss the limiting cases: Pha > 1 (low temperature limit) and Bhw «1 (high
temperature limit) for S, £ and Cy. Aasynment 's
ne peeve te energy (Eset
ao eect GP
ports, wedlunrn (WV), deweponaborel)
egy ee eek
® System re Yonge yt a
Be pee) eth te
e compote a Yer We atguered Ae
oe : Tsolobed!
fy > Ee
@ wre tern
ee eke ae age
eucauansen gescnecinten he
© een) + ameganens eT ine qe
= D ay qrneres ees
ew
rien) 2 vers ect we
= Ee foreah, PEM)
a geben ie | ise! A, eH)
RU ER€, raw) 2 Sine, ss
= Glee, y ers e Paces
a
Tegflevin semen, exemesen ——
0 Fea) F Fld + FO + aesie wear
ger) =E aia e cle - ve - y Ligh ote
GR)
a ~ £ oh 2 Ong
a a 5 oe waa *
= ae be).
welt el? Ged Ce
tg)
Use
7 ef sn]
Ba :
Sn QUE) © On G+ Sn [1- eet)
eae
er tally
= PEP) 5 tnlen) = ead
> [ey =
Treverlors, ta prokall rn disteibubion AT for @ grand Comoniesl)
emeemble is given
(6) <= co te
Pl sem) = >®
ee
On
= nermalligkin dacker
= harlhien 27
Que Sheedy
-©®
77 Summation 18 ever oll Ha
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