3M Brand Fire Barrier CP-25WB+ 02/22/19

Safety Data Sheet

Copyright,2019,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 09-5451-1 Version Number: 26.05

Issue Date: 02/22/19 Supercedes Date: 07/26/18

SECTION 1: Identification
1.1. Product identifier
3M Brand Fire Barrier CP-25WB+

Product Identification Numbers

42-0016-4710-8, 42-0016-4715-7, 42-0016-4716-5, 98-0400-5380-7, 98-0400-5381-5, 98-0400-5382-3, 98-0400-5383-1, 98-
0400-5406-0, 98-0400-5456-5, 98-0400-5562-0, 98-0400-5573-7, 98-0400-5610-7, 98-0400-5629-7
7100006311, 7000006379, 7000059394, 7000145569, 7100025518, 7000006383, 7010353050, 7100137423

1.2. Recommended use and restrictions on use

Recommended use
Fire Protection, Used as Firestop in buildings.

1.3. Supplier’s details

MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number

1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classification
Serious Eye Damage/Irritation: Category 2A.
Reproductive Toxicity: Category 2.

2.2. Label elements

Signal word
Warning

Symbols
Exclamation mark | Health Hazard |

Pictograms

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Hazard Statements
Causes serious eye irritation.
Suspected of damaging fertility or the unborn child.

Precautionary Statements
General:
Keep out of reach of children.

Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.

Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF exposed or concerned: Get medical advice/attention.

Storage:
Store locked up.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt
Water 7732-18-5 10 - 30 Trade Secret *
Zinc Borate 2335 138265-88-0 10 - 30 Trade Secret *
Polymer (NJTS Reg. No. 04499600-7270) Trade Secret* 10 - 30 Trade Secret *
Sodium Silicate 1344-09-8 10 - 19 Trade Secret *
Ethylhexyldiphenyl phosphate 1241-94-7 3 - 7 Trade Secret *
Iron oxide 1309-37-1 1 - 5 Trade Secret *
Oxide glass chemicals 65997-17-3 1 5 Trade Secret *
Polyethylene Glycol 25322-68-3 1 - 5 Trade Secret *
Quartz Silica 14808-60-7 < 1 Trade Secret *

NJTS or NJTSRN: New Jersey Trade Secret Registry Number.

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

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Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Wash with soap and water. If signs/symptoms develop, get medical attention.

Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media
Non-combustible. Use a fire fighting agent suitable for surrounding fire.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Oxides of Phosphorus During Combustion

5.3. Special protective actions for fire-fighters

Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus,
bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and
health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate
authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible in accordance with
applicable local/regional/national/international regulations.

SECTION 7: Handling and storage

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7.1. Precautions for safe handling

Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Avoid breathing
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this
product. Wash thoroughly after handling. Avoid release to the environment. Use personal protective equipment (gloves,
respirators, etc.) as required.

7.2. Conditions for safe storage including any incompatibilities

Keep cool. Store away from heat. Store away from areas where product may come into contact with food or
pharmaceuticals. Store in a dry place.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
DUST, INERT OR NUISANCE 1309-37-1 OSHA TWA(as total dust):15
mg/m3;TWA(as total dust):50
millions of particles/cu. ft.(15
mg/m3);TWA(respirable
fraction):15 millions of
particles/cu. ft.(5
mg/m3);TWA(respirable
fraction):5 mg/m3
Iron oxide 1309-37-1 ACGIH TWA(respirable fraction):5 A4: Not class. as human
mg/m3 carcin
Iron oxide 1309-37-1 OSHA TWA(as fume):10 mg/m3
ROUGE 1309-37-1 OSHA TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Quartz Silica 14808-60-7 ACGIH TWA(respirable A2: Suspected human
fraction):0.025 mg/m3 carcin.
Quartz Silica 14808-60-7 OSHA TWA Table Z-
1(respirable):0.05
mg/m3;TWA Table Z-
3(respirable):0.1 mg/m3
Polyethylene Glycol 25322-68-3 AIHA TWA(as particulate):10
mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

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Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl Rubber
Neoprene
Nitrile Rubber

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
General Physical Form: Solid
Specific Physical Form: Paste
Odor, Color, Grade: Red with negligible odor
Odor threshold No Data Available
pH 7.5 - 8
Melting point No Data Available
Boiling Point 100 ºC
Flash Point No flash point
Evaporation rate 0.33 [Ref Std:BUOAC=1]
Flammability (solid, gas) Not Classified
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure 17.5 mmHg [@ 20 ºC]
Vapor Density No Data Available
Density No Data Available
Specific Gravity 1.35 [Ref Std:WATER=1]
Solubility in Water Complete
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature Not Applicable
Decomposition temperature No Data Available
Viscosity No Data Available
Molecular weight No Data Available
Volatile Organic Compounds <=0.5 % weight [Test Method:tested per EPA method 24]
VOC Less H2O & Exempt Solvents <=6 g/l [Test Method:tested per EPA method 24]

SECTION 10: Stability and reactivity

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10.1. Reactivity
This material is considered to be non reactive under normal use conditions.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

None known.

10.5. Incompatible materials

None known.

10.6. Hazardous decomposition products

Substance Condition
None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.

Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.

Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

May cause additional health effects (see below).

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Additional Health Effects:

Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Carcinogenicity:

Ingredient CAS No. Class Description Regulation

SILICA, CRYS AIRRESP 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens
Quartz Silica 14808-60-7 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE >5,000 mg/kg
Overall product Ingestion No data available; calculated ATE2,000 - 5,000 mg/kg
Zinc Borate 2335 Dermal Rabbit LD50 > 5,000 mg/kg
Zinc Borate 2335 Inhalation- Rat LC50 > 4.95 mg/l
Dust/Mist
Zinc Borate 2335 Ingestion Rat LD50 > 5,000 mg/kg
Polymer (NJTS Reg. No. 04499600-7270) Dermal LD50 estimated to be > 5,000 mg/kg
Polymer (NJTS Reg. No. 04499600-7270) Ingestion Rat LD50 > 2,000 mg/kg
Sodium Silicate Dermal Rabbit LD50 > 4,640 mg/kg
Sodium Silicate Ingestion Rat LD50 500 mg/kg
Ethylhexyldiphenyl phosphate Dermal Rabbit LD50 > 7,940 mg/kg
Ethylhexyldiphenyl phosphate Ingestion Rat LD50 > 24,000 mg/kg
Iron oxide Dermal Not LD50 3,100 mg/kg
available
Iron oxide Ingestion Not LD50 3,700 mg/kg
available
Polyethylene Glycol Dermal Rabbit LD50 > 20,000 mg/kg
Polyethylene Glycol Ingestion Rat LD50 32,770 mg/kg
Oxide glass chemicals Dermal LD50 estimated to be > 5,000 mg/kg
Oxide glass chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Quartz Silica Dermal LD50 estimated to be > 5,000 mg/kg
Quartz Silica Ingestion LD50 estimated to be > 5,000 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name Species Value

Zinc Borate 2335 Rabbit No significant irritation

Polymer (NJTS Reg. No. 04499600-7270) Rabbit Minimal irritation
Sodium Silicate Rabbit Corrosive
Iron oxide Rabbit No significant irritation
Polyethylene Glycol Rabbit Minimal irritation
Oxide glass chemicals Professio No significant irritation
nal
judgeme
nt
Quartz Silica Professio No significant irritation
nal
judgeme
nt

Serious Eye Damage/Irritation

Name Species Value

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Zinc Borate 2335 Rabbit Severe irritant

Polymer (NJTS Reg. No. 04499600-7270) Professio Mild irritant
nal
judgeme
nt
Sodium Silicate Rabbit Corrosive
Iron oxide Rabbit No significant irritation
Polyethylene Glycol Rabbit Mild irritant
Oxide glass chemicals Professio No significant irritation
nal
judgeme
nt

Skin Sensitization
Name Species Value
Zinc Borate 2335 Guinea Not classified
pig
Sodium Silicate Mouse Not classified
Iron oxide Human Not classified
Polyethylene Glycol Guinea Not classified
pig

Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity

Name Route Value

Zinc Borate 2335 In Vitro Some positive data exist, but the data are not
sufficient for classification
Sodium Silicate In Vitro Not mutagenic
Sodium Silicate In vivo Not mutagenic
Iron oxide In Vitro Not mutagenic
Polyethylene Glycol In Vitro Not mutagenic
Polyethylene Glycol In vivo Not mutagenic
Oxide glass chemicals In Vitro Some positive data exist, but the data are not
sufficient for classification
Quartz Silica In Vitro Some positive data exist, but the data are not
sufficient for classification
Quartz Silica In vivo Some positive data exist, but the data are not
sufficient for classification

Carcinogenicity
Name Route Species Value
Iron oxide Inhalation Human Some positive data exist, but the data are not
sufficient for classification
Polyethylene Glycol Ingestion Rat Not carcinogenic
Oxide glass chemicals Inhalation Multiple Some positive data exist, but the data are not
animal sufficient for classification
species
Quartz Silica Inhalation Human Carcinogenic
and
animal

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test Result Exposure
Duration
Zinc Borate 2335 Ingestion Toxic to male reproduction Rat NOAEL 100 92 days
mg/kg/day
Zinc Borate 2335 Ingestion Toxic to development Rat LOAEL 100 during

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mg/kg/day gestation
Sodium Silicate Ingestion Not classified for development Mouse NOAEL 200 during
mg/kg/day gestation
Polyethylene Glycol Ingestion Not classified for female reproduction Rat NOAEL 1,125 during
mg/kg/day gestation
Polyethylene Glycol Ingestion Not classified for male reproduction Rat NOAEL 5699 5 days
+/- 1341
mg/kg/day
Polyethylene Glycol Not Not classified for reproduction and/or NOEL N/A
Specified development
Polyethylene Glycol Ingestion Not classified for development Mouse NOAEL 562 during
mg/animal/da gestation
y

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Zinc Borate 2335 Inhalation respiratory irritation Some positive data exist, but the similar NOAEL Not
data are not sufficient for health available
classification hazards
Sodium Silicate Inhalation respiratory irritation May cause respiratory irritation official NOAEL Not
classifica available
tion
Polyethylene Glycol Inhalation respiratory irritation Not classified Rat NOAEL 2 weeks
1.008 mg/l

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Zinc Borate 2335 Inhalation immune system | Not classified Rat NOAEL 0.15 2 weeks
respiratory system | mg/l
heart | endocrine
system |
hematopoietic
system | liver |
nervous system |
kidney and/or
bladder
Zinc Borate 2335 Ingestion endocrine system | Not classified Rat NOAEL 375 92 days
liver | kidney and/or mg/kg/day
bladder | heart | skin
| bone, teeth, nails,
and/or hair |
hematopoietic
system | immune
system | nervous
system | eyes |
respiratory system |
vascular system
Sodium Silicate Ingestion kidney and/or Some positive data exist, but the Dog LOAEL 4 weeks
bladder data are not sufficient for 2,400
classification mg/kg/day
Sodium Silicate Ingestion endocrine system | Not classified Rat NOAEL 804 3 months
blood mg/kg/day
Sodium Silicate Ingestion heart | liver Not classified Rat NOAEL 8 weeks
1,259
mg/kg/day
Iron oxide Inhalation pulmonary fibrosis | Not classified Human NOAEL Not occupational
pneumoconiosis available exposure
Polyethylene Glycol Inhalation respiratory system Not classified Rat NOAEL 2 weeks
1.008 mg/l
Polyethylene Glycol Ingestion kidney and/or Not classified Rat NOAEL 13 weeks
bladder | heart | 5,640
endocrine system | mg/kg/day

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hematopoietic
system | liver |
nervous system
Oxide glass chemicals Inhalation respiratory system Not classified Human NOAEL not occupational
available exposure
Quartz Silica Inhalation silicosis Causes damage to organs through Human NOAEL Not occupational
prolonged or repeated exposure available exposure

Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information
Test Organism Test Type Result
Water flea, Daphnia magna 48 hours Aquatic Toxicity - Acute 27 mg/l
Green algae, Pseudokirchneriella subcapitata 72 hours Aquatic Toxicity - Chronic 2.6 mg/l

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste
incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty
drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations
classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes
unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the
available treatment and disposal facilities.

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations

Contact 3M for more information.

EPCRA 311/312 Hazard Classifications:

Physical Hazards
Not applicable

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Health Hazards
Reproductive toxicity
Serious eye damage or eye irritation

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt
Zinc Borate 2335 (ZINC COMPOUNDS) 138265-88-0 10 - 30

15.2. State Regulations

15.3. Chemical Inventories

The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification
and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information.

The components of this product are in compliance with the new substance notification requirements of CEPA.

The components of this material are in compliance with the China "Measures on Environmental Management of New
Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information.

The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain
restrictions may apply. Contact the selling division for additional information.

The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.

15.4. International Regulations

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 09-5451-1 Version Number: 26.05

Issue Date: 02/22/19 Supercedes Date: 07/26/18

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for
user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of
which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine
whether it is fit for a particular purpose and suitable for user's method of use or application.
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3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic
transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its
completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the
SDS available directly from3M

3M USA SDSs are available at www.3M.com

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