REPORT OF CHEMISTRY I LABORATORY

ACIDIMETRY - ALKALIMETRY

By:
Group: 5

Name / NRP: Andreas Njotoprajitno / 5503018006

Name / NRP: Kevan Alvian Hartono / 5503018015

ANALYTICAL CHEMISTRY AND INSTRUMENT LABORATORY

CHEMICAL ENGINEERING DEPARTMENT

ENGINEERING FACULTY

WIDYA MANDALA CATHOLIC UNIVERSITY SURABAYA

2019
 FEEDBACK FORM

ACIDIMETRY – ALKALIMETRY

Day, date of experiment: Thursday, February 14th 2019

by:
Group 5
Name / NRP: Andreas Njotoprajitno / 5503018006
Name / NRP: Kevan Alvian Hartono / 5503018015

Assistant:
Maria Yuliana, S.T., Ph.D.
Dra. Adriana Anteng Anggorowati, M.Si.

FEEDBACK RECORD

Submission Feedback Date of Assistant

Date Return Signature
 CONTENT

REPORT COVER.................................................................................................
FEEDBACK FORM.................................................................................................
CONTENT.................................................................................................
CHAPTER I. INTRODUCTION.................................................................................................
A. Objective.................................................................................................
B. Literature review.................................................................................................
Chapter II. Experimental Method.................................................................................................
A. Material and apparatus.................................................................................................
B. Experimental procedure.................................................................................................
C. Solution preparation.................................................................................................
CHAPTER III. RESULT AND DISCUSSION.......................................................................
A. Result.................................................................................................
B. Calculation.................................................................................................
C. Discussion.................................................................................................
CHAPTER IV. CONCLUSION.................................................................................................
REFERENCES.................................................................................................
APPENDIX.................................................................................................
 CHAPTER I
INRODUCTION

I.1. Objective
Students are able to:
1. Prepare primary and secondary standard solution for acidimetry-alkalimetry
titration.

2. Perform acidimetry-alkalimetry titration and observe the changes that occur at the
end of the titration.

3. Calculate the secondary solution concentration at the end of titration.

4. Determine pH solution at the end of titration.

I.2. Literature Review

<Mboh sek gak ero>

 CHAPTER II
EXPERIMENTAL METHOD

II.1. Materials and Apparatus

II.1.1 Materials
1. H2C2O4 ∙ 2H2O
2. NaOH
3. Phenolphtalein Indicator (pp)
4. Na2B4O7 ∙ 10H2O
5. Solution of Concentrated HCl
6. Methyl Red Indicator (mm)
7. Universal pH

II.1.2 Apparatus
1. Weighing Bottle
2. Beaker glass
3. Mixing Glass
4. Funnel
5. Volumetric flask
6. Measuring cup
7. Watch glass
8. Volumetric pipette
9. Erlenmeyer
10. Burette
11. Statif and clam
12. Spray Bottle
 II.2. Experimental Procedure and Preparation of Solution

II.2.1 Acidimetry
a) Standard solutions of H2C2O4.2H20 ± 100 mL

Valence=2

Molecular Weight = 126 gr/mol

Volume 100 mL = 0,1 L

The formula equation

N = M x Valence

𝑀𝑜𝑙
N= 𝑉𝑜𝑙𝑢𝑚𝑒(𝐿) 𝑥 𝑉𝑎𝑙𝑒𝑛𝑐𝑒

𝑚𝑜𝑙
0,1 = 𝑥2
0,1

𝑚𝑜𝑙 = 5 𝑥 10−3

𝑚𝑎𝑠𝑠(𝑔𝑟𝑎𝑚)
𝑚𝑜𝑙 =
𝑀𝑊
𝑚𝑎𝑠𝑠(𝑔𝑟𝑎𝑚)
5 𝑥 10−3 = 126

𝑚𝑎𝑠𝑠 = 0,63 𝑔𝑟𝑎𝑚

Tolerance ± 10 %

0,63 x 10% = 0,063 gram

0,63 + 0,063 = 0,693 gram

0,63 – 0,063 = 0,567 gram

Preparing Oxalic acid (H2C2O4.2H20) solution :

1. Using the analyitc balance, oxalic acid was weighed within the range of 0,567-0,693
gram
2. Using aquadest, oxalic acid was dissolved in beaker glass below 100 mL
3. Using funnel, the oxalic acid was poured from beaker glass into the volumetric
flask(100 mL)
4. Adding aquadest into the volumetric flask(100 mL) until it reached the limit sign.
5. The oxalic acid in the volumetric flask was shaked until it dissolved completely.
6. The oxalic acid was poured from the volumetric flask into the beaker glass.

b) Solution of NaOH ±0,1N

Valence = 1

Molecular weight = 40 gr/mol

Volume = 100mL = 0,1 L

The Formula equation :

N = M x Valence
𝑀𝑜𝑙
N = 𝑉𝑜𝑙𝑢𝑚𝑒(𝐿) 𝑥 𝑉𝑎𝑙𝑒𝑛𝑐𝑒
𝑚𝑜𝑙
0,1 = 𝑥1
0,1

𝑚𝑜𝑙 = 10−2
𝑚𝑎𝑠𝑠(𝑔𝑟𝑎𝑚)
𝑚𝑜𝑙 =
𝑀𝑊

𝑚𝑎𝑠𝑠(𝑔𝑟𝑎𝑚)
10−2 =
40

𝑚𝑎𝑠𝑠 = 0,4 𝑔𝑟𝑎𝑚

Preparing Sodium Hydroxide (NaOH) solution:

1. Using hard balance, sodium hydroxide was weighed around 0,4 gram
2. The sodium hydroxide was dissolved in the beaker glass using aquadest until the
volume is 100ml
3. The sodium hydroxide was poured into the burrete until the volume is 100 ml
c) Titration of Acidimetry

1. 10 mL of Standard oxalic acid(H2C2O4.2H20) solution is moved into the Erlenmeyer

using the volumetric pipette
2. 2 drops of phenolphthalein(pp) are added into the Erlenmeyer
3. Titrating the oxalic acid(H2C2O4.2H20) solution with sodium hydroxide(NaOH)
solution ±0,1N until the (H2C2O4.2H20) solution’s color changes.
4. Note the amount of sodium hydroxide(NaOH) needed to titrate the oxalic acid
(H2C2O4.2H20) solution
5. Meeasuring the pH of solution in the erlenmeyer at the end of titrating.
6. Repeating the experiment one more time

II.2.2 Alkalimetry
a) Standard solution of Na2B4O7.10H2O ± 𝟎, 𝟏𝑵 , 100 mL
N = M x Valence

𝑁 𝑥 𝑀𝑊𝑥 𝑉𝑜𝑙𝑢𝑚𝑒
Mass = 𝑉𝑎𝑙𝑒𝑛𝑐𝑒

0.1𝑥 381,37𝑥 0.1

Mass = 2

Mass = 1,90685 gram

Tolerance ± 10 %

1,90685 x 10% = 0,190685 gram

1,90685 + 0,190685 = 2,097535 gram

1,90685 – 0,190685= 1,716165 gram

Preparing Sodium Borax (Na2B4O7.10H2O) solution :

1. Using the analyitc balance, Sodium Borax (Na2B4O7.10H2O) was weighed within the
range of 1,716165-2,097535 gram
2. Using aquadest, Sodium Borax (Na2B4O7.10H2O) was dissolved in beaker glass
below 100 mL
3. Using funnel, the Sodium Borax (Na2B4O7.10H2O) was poured from beaker glass into
the volumetric flask(100 mL)
4. Adding aquadest into the volumetric flask(100 mL) until it reached the limit sign.
5. The Sodium Borax (Na2B4O7.10H2O) in the volumetric flask was shaked until it
dissolved completely.
6. The oxalic acid was poured from the volumetric flask into the beaker glass.

b) Solution of HCl ±0,1N

Valence = 1

Molecular weight = 36 gr/mol

Volume = 100mL =0,1 L

Density = 1,19 gr/mL

Purity = 37%

𝑁𝑥𝑀𝑊𝑥𝑉𝑜𝑙𝑢𝑚𝑒
Mass = 𝑉𝑎𝑙𝑒𝑛𝑐𝑒

0.1𝑥36𝑥0.1
Mass = 2

Mass = 0,36 gram

Volume of HCl:
mass
volume =
density x purity(%)
0,36
volume =
1,19 x 37%
volume = 0,8280 ≈ 0,85 mL
Preparing Hydrochloric Acid (HCl) Solution :
1. Using a meacuring cup, 0,83 mL of concentrated HCl was taken
2. The concentrated HCl was dissolved in beaker glass using aquadest until 100 mL
3. The HCl solution was poured into the burette until 50 mL

C) Titration of Alkalimetry
1. Using volumetric pipette to get 10 mL of standard sodium borax solution and
moving into the erlenmeyer
2. Expelling 2 drops of mm into the Erlenmeyer which has the standard sodium
borax solution inside
3. Titrating sodium borax solution with HCl solution ±0,1N until the sodium borax
solution’s color changes
4. Note the amount of HCl solution needed to titrate the sodium borax solution.
5. Measuring the pH of the solution in the Erlenmeyer at the end of the titration
6. Repeating the experiment one more time
 CHAPTER III
RESULT AND DISCUSSION
III.1. Results

Experimental Result.
a. Acidimetry
1) Standard solution was prepared by weighing 0,6216 gram of oxalic
acid, dissolved and diluted with distilled water until 100 mL
Chemical formula of oxalic acid = H2C2O4.2H20
Molecular weight of Oxalic acid =126,07 g/mol
2) Titration result
Indicator : Phenolpthalein (pp)
V of oxalic acid V of NaOH Color Change pH of Solution
solution(mL) solution(mL)
10 9,6 Colorless-Pink 9
10 10 Colorless-Pink 9
Average = 10 9,8 Colorless-pink 9

b. Alkalimetry

1) Standard solution was prepared by weighing 1,9664 gram of

sodium borax, dissolved and diluted with distilled water until 100
mL
Chemical formula of oxalic acid = Na2B4O7.10H2O
Molecular weight of Oxalic acid =381,37 g/mol
2) Titration Result
Indicator : Methyl red(mm)
V of oxalic acid V of NaOH Color Change pH of Solution
solution(mL) solution(mL)
10 11,2 Yellow-Pink 5
10 11,1 Yellow-Pink 5
Average = 10 11,15 Yellow-Pink 5
The result of the reaction that occurs :

 Acidimetry
H2C2O4 + 2NaOH Na2C2O4 + 2H2O
Oxalic acid + sodium hydroxide Sodium oxalate + water

(William Thomas Hall, 1952)

 Alkalimetry
Na2B4O7 + 2 HCl + 5H2O 2NaCl + 4H3BO3
Sodium Borax + hydrochloric acid + Water Sodium Chloride+ Boric Acid
(William Thomas Hall, 1952)

III.2. Calculation

a) Calculation of the concentration of H2C2O4 solution (normality)

The first calculation is the normality of oxalic acid:

N = M x valence
𝑚 𝑥 1000 𝑥 𝑣𝑎𝑙𝑒𝑛𝑐𝑒
𝑁=
𝑀𝑊 𝑥 𝑉
0,6216 𝑥 1000 𝑥 2
𝑁=
126 𝑥 100
𝑁 = 0,09866 𝑁 (𝑜𝑥𝑎𝑙𝑖𝑐 𝑎𝑐𝑖𝑑)

The second calculation is the concentration of sodium hydroxide :

Equivalent of H2C2O4 = Equivalent of NaOH
(N x V) H2C2O4 = (N x V ) NaOH
0,09866 x 10 = N x 9,8
0,9866 = N x 9,8
NNaOH = 0,1006 N
So the normality of NaOH at equivalent point is 0,1006 N
b) Calculation of the concentration of HCl solution (normality)

The first calculation is the normality of sodium borax

N = M x valence
𝑚 𝑥 1000 𝑥 𝑣𝑎𝑙𝑒𝑛𝑐𝑒
𝑁=
𝑀𝑊 𝑥 𝑉
1,9664 𝑥 1000 𝑥 2
𝑁=
381,37 𝑥 100
𝑁 = 0,1031 𝑁 (𝑜𝑥𝑎𝑙𝑖𝑐 𝑎𝑐𝑖𝑑)

The second calculation is the concentration of hydrochloric acid :

Equivalent of Na2B4O7 = Equivalent of HCl
(N x V) Na2B4O7 = (N x V ) HCl
0,1031 x 10 = N x 10,9
1,031 = N x 10,9
NHCl = 0,0945 N
So the normality of NaOH at equivalent point is 0,0945 N

III.3. Discussion
 CHAPTER IV
CONCLUSION AND SUGGESTION

REFERENCES...
APPENDIX...

Andreas : Literature review & Discussion & TOC

Kevan: Procedure & calculation