Fiitjee: Solutions To JEE (Main) - 2019
Fiitjee: Solutions To JEE (Main) - 2019
Fiitjee: Solutions To JEE (Main) - 2019
Solutions to JEE(Main)-2019
Test Date: 8th April 2019 (First Shift)
2. This Test Paper consists of 90 questions. The maximum marks are 360.
3. There are three parts in the question paper A, B, C consisting of Physics, Chemistry and Mathematics
having 30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for correct
response.
4. Out of the four options given for each question, only one option is the correct answer.
5. For each incorrect response 1 mark i.e. ¼ (one-fourth) marks of the total marks allotted to the question
will be deducted from the total score. No deduction from the total score, however, will be made if no
response is indicated for an item in the Answer Box.
6. Candidates will be awarded marks as stated above in instruction No.3 for correct response of each
question. One mark will be deducted for indicating incorrect response of each question. No deduction
from the total score will be made if no response is indicated for an item in the answer box.
7. There is only one correct response for each question. Marked up more than one response in any
question will be treated as wrong response and marked up for wrong response will be deducted
accordingly as per instruction 6 above.
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-2
PART –A (PHYSICS)
1. If 10 22 gas molecules each of mass 10 26 kg collide with a surface (perpendicular to it)
elastically per second over an area 1 m2 with a speed 10 4 m/s, the pressure exerted by
the gas molecules will be of the order of:
N N
(A) 108 2 (B) 103 2
m m
4 N 16 N
(C) 10 2 (D) 10
m m2
a ˆ ˆ
(C)
5
ij (D) a ˆi ˆj
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-3
5. Two identical beakers A and B contain equal volumes of two different liquids at 60o C
each and left to cool down. Liquid in A has density of 8 10 2 kg / m3 and specific heat of
2000 Jkg1 K 1 while liquid in B has density of 103 kgm3 and specific heat of
4000JKg1K 1 . Which of the following best describes their temperature versus time
graph schematically? (assume the emissivity of both the beakers to be the same)
(A) (B)
(C) (D)
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-4
8. A wire of length 2L is made by joining two wires A and b of same lengths but different
radii r and 2r and made of the same material. It is vibrating at a frequency such that the
joint of the two wires forms a node. If the number of antinodes in wire A is p and that in B
is q then the ratio p : q is:
(A) 1 : 4 (B) 1 : 2
(C) 3 : 5 (D) 4 : 9
9. A steel wire having a radius of 2.0 mm, carrying a load of 4 kg, is hanging from a ceiling.
Given that g 3.1 ms2 , what will be the tensile stress that would be developed in the
wire?
(A) 6.2 10 6 Nm2 (B) 4.8 106 Nm2
6 2
(C) 5.2 10 Nm (D) 3.1 106 Nm2
10. Voltage rating of a parallel plate capacitor is 500V. Its dielectric can withstand a
V
maximum electric field of 106 . The plate area is 10 4 m2 . What is the dielectric
m
constant if the capacitance is 15 pF? (given 0 8.86 10 12 C2 / Nm2 )
(A) 3.8 (B) 6.2
(C) 4.5 (D) 8.5
11. An alternating voltage v t 220 sin100l volt is applied to a purely resistive load of
50 . The time taken for the current to rise from half of the peak value of the peak value
is:
(A) 2.2 ms (B) 3.3 ms
(C) 5 ms (D) 7.2 ms
12. The wavelength of the carrier waves in a modern optical fiber communication network is
close to:
(A) 1500 nm (B) 600 nm
(C) 2400 nm (D) 900 nm
13. Water from a pipe is coming at a rate of 100 litres per minute. If the radius of the pipe is
5 cm, the Reynolds number for the flow is of the order of : (density of water = 1000
kg/m3, coefficient of viscosity of water = 1 mPa s)
(A) 103 (B) 10 6
2
(C) 10 (D) 10 4
14. A boy’s catapult is made of rubber cord which is 42 cm long, with 6 mm diameter of
cross – section and of negligible mass. The boy keeps a stone weighing 0.02 kg on it
and stretches the cord by 20 cm by applying a constant force. When released, the stone
flies off with a velocity of 20 ms–1. Neglect the change in the area of cross section of the
cord while stretched. The Young’s modulus of rubber is closest to:
(A) 103 Nm2 (B) 10 6 Nm2
(C) 108 Nm2 (D) 10 4 Nm2
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-5
15. Two particles move at right angle to each other. Their de Broglie wavelengths are 1
and 2 respectively. The particles suffere perfectly inelastic collision. The de Broglie
wavelength , of the final particle, is given by:
2
(A) 1 2 (B) 1
2
2 1 1 1 1 1
(C) (D) 2 2 2
1 2 1 2
17. In figure, the optical fiber is l 2m long and has a diameter of d = 20 m. If a ray of
light is incident on one end of the fiber at angle 1 40o , the number of reflection it
makes before emerging from the other end is close to:
18. A circular coil having N turns and radius r carries a current. It is held in the XZ plane in a
magnetic field Biˆ . The torque on the coil due to the magnetic field is:
Br 2 1
(A) (B) zero
N
Br 2 1
(C) (D) Br 2IN
N
19. Ship A is sailing towards north – east with velocity 30 ˆi 50ˆj km/hr where î points
east and ĵ , north. Ship B is at a distance of 80 km east and 150 km north of Ship A and
is sailing towards west at 10 km/hr. A will be at minimum distance from B ins:
(A) 2.2 hrs. (B) 4.2 hrs.
(C) 2.6 hrs. (D) 3.2 hrs.
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-6
20. A plane electromagnetic wave travels in free space along the x – direction. The electric
field component of the wave at a particular point of space and time is E Vm1 along
y – direction. Its corresponding magnetic filed component, B would be:
(A) 2 10 8 T along z – direction (B) 6 10 8 T along x – direction
(C) 6 10 8 T along z- direction (D) 2 10 8 T along y – direction
21. A thermally insulted vessel contains 150 g of water at 0o C . Then the air from the vessel
is pumped out a adiabatically. A fraction of water turns into ice and the rest evaporates
at 0o C itself. The mass of evaporated water will be closes to:
(Latent heat of vaporization of water = 2.10 10 6 Jkg1 and Laten heat of Fusion of water
3.36 105 Jkg1 )
(A) 35 g (B) 150 g
(C) 130 g (D) 20 g
22. Radiation coming from transition n = 2 to n = 1 of hydrogen atoms fall of He ions in n =
1 and n = 2 states. The possible. Transition of helium ions as they absorb energy from
the radiation is:
(A) n 2 n 4 (B) n 2 n 5
(C) n 2 n 3 (D) n 1 n 4
23. A 200 resistor has a certain color code. If one replaces the red color by green in the
code, the new resistance will be:
(A) 500 (B) 400
(C) 300 (D) 100
24. The reverse breakdown voltage of a Zener diode is 5.6 V in the given circuit .
25. A thin circular plate of mass M and radius R has its density varying as p r p0 r with P0
as constant and r is the distance from its center. The moment of Inertia of the circular
plate about an axis perpendicular to the plate and passing through its edge is I aMR2 .
The value of the coefficient a is:
8 1
(A) (B)
5 2
3 3
(C) (D)
5 2
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-7
0
26. In SI units, the dimensions of is:
0
(A) AT 3ML3/2 (B) A 1TML3
(C) A 2 T 3M1L2 (D) AT 2M1L1
27. For the circuit shown, with R1 1.0 , R 2 2.0 ,E1 2 V and E2 E 3 4 V, the potential
difference between the points ‘a’ and ‘b’ is approximately (in V):
a1 1
29. In an interference experiment the ratio of amplitudes of coherent waves is . The
a2 3
ratio of maximum and minimum intensities of fringes will be:
(A) 9 (B) 4
(C) 18 (D) 2
30. The bob of a simple pendulum has mass 2g and a charge of 5.0 C . It is at rest in a
V
uniform horizontal electric field of intensity 2000 . At equilibrium, the angle that the
m
m
pendulum makes with the vertical is: (take g 10 2 )
s
(A) tan 1 2.0 (B) tan 1 0.2
(C) tan 1 5.0 (D) tan 1 0.5
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-8
PART –B (CHEMISTRY)
31. Element ‘B’ forms ccp structure and ‘A’ occupies half of the octahedral voids, while
oxygen atoms occupy all the tetrahedral voids. The structure of bimetallic oxide is
(A) A 2B 2 O (B) AB 2 O 4
(C) A 4B 2 O (D) A 2BO 4
32. Coupling of benzene diazonium chloride with 1 – naphthol in alkaline medium will give:
(A) (B)
(C) (D)
33. The size of the iso-electronic species CI , Ar and Ca2+ is affected by
(A) Principal quantum number of valence shell
(B) Azimuthal quantum number of valence shell
(C) electron – electron interaction in the outer orbitals
(D) nuclear charge
34. In the following compounds, the decreasing order of basic strength will be:
(A) C 2H5NH2 NH3 C2H5 2 NH (B) NH3 C 2H5NH2 C2H5 2 NH
(C) C2H5 2 NH C 2H5NH2 NH3 (D) C2H5 2 NH NH3 C2H5NH2
35. The correct order of the spin only magnetic moment of metal ions in the following low
4 4 3 2
spin complexes, V CN6 , Fe CN6 , Ru NH3 6 , and Cr NH3 6 , is:
(A) Cr 2 Ru3 Fe2 V 2 (B) V 2 Cr 2 Ru3 Fe2
2 2 3 2
(C) Cr V Ru Fe (D) V 2 Ru3 Cr 2 Fe2
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-9
36. An organic compound ‘X’ showing the following solubility profile is:
(A) (B)
(C) (D)
40. 100 mL of a water sample contains 0.81 g of calcium bicarbonate and 0.73 g of
magnesium bicarbonate. The hardness of this water sample expressed in terms of
equivalents of CaCO3 is:
(molar mass of calcium bicarbonate is 162 gmol1 and magnesium bicarbonate is 146 g
mol1 )
(A) 10, 000 ppm (B) 1, 000 ppm
(C) 5,000 ppm (D) 100 ppm
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-10
41. An organic compound neither reacts with neutral ferric chloride solution nor with Fehling
solution. It however, reacts with Grignard reagent and gives positive iodoform test. The
compound is:
(A) (B)
(C) (D)
42. For the reaction 2A B C, the values of initial rate at different reactant concentrations
are given in the table below: The rate law for the reaction is:
A molL1
B molL1
Initial Rate (mol L1s1 )
0.05 0.05 0.045
0.10 0.05 0.090
0.20 0.10 0.72
(A) Rate = k[A]2[B]2 (B) Rate = k[A][B]2
(C) Rate = k[A][B] (D) Rate = k[A]2[B]
(A) (B)
(C) (D)
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-11
44. Which is wrong with respect to our responsibility as a human being to protect our
environment?
(A) Restricting the use of vehicles
(B) Using plastic bags
(C) Setting up compost tin in gardens
(D) Avoiding the use of floodlighted facilities.
(A) (B)
(C) (D)
46.
For silver CP JK 1 mol1 23 0.01T . If the temperature (T) of 3 moles of silver is
raised from 300 K to 1000 K at 1 atm pressure, the value of H will be close to:
(A) 13 kJ (B) 62 kJ
(C) 16 kJ (D) 21 kJ
47. The correct order of hydration enthalpies of alkali metal ions is:
(A) Li Na K Cs Rb (B) Na Li K Rb Cs
(C) Na Li K Cs Rb (D) Li Na K Rb Cs
48. Adsorption of a gas follows Freundlich adsorption isotherm. x is the mass of the gas
x
adsorbed on mass m of the adsorbent. The plot of log versus log p is shown in the
m
x
given graph, is proportional to:
m
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-12
49. The vapour pressures of pure liquids A and B are 400 and 600 mm Hg, respectively at
298 K. On mixing the two liquids, the sum of their initial volumes is equal to the volume
of the final mixture. The mole fraction of liquid B is 0.5 in the mixture. The vapour
pressure of the final solution, the mole fractions of components A and B in vapour
phase, respectively are:
(A) 500 mmHg, 0.4, 0.6 (B) 500 mmHg, 0.5, 0.5
(C) 450 mmHg, 0.5, 0.5 (D) 450 mmHg, 0.4, 0.6
50. Given that E0O2 /H2O 1.23V; E0S O2 /SO2 2.05 V;EBr
0
1.09 V;E0Au3 /Au 1.4V . The
2 8 4 2 /Br
52. If solubility product of Zr3 PO 4 4 is denoted by K SP and its molar solubility is denoted by
S, then which of the following relation between S and K SP is correct?
1/7 1/6
K K
(A) S SP (B) S SP
6912 144
1/9 1/7
K Sp K
(C) S (D) S SP
929 216
53. Which of the following amines can be prepared by Gabriel phthalimide reaction?
(A) t – butylamine (B) n – butylamine
(C) neo – pentylamine (D) triethylamine
54. Which one of the following equations does not correctly represent the first law of
thermodynamics for the given processes involving an ideal gas? (Assume non –
expansion work is zero)
(A) Adiabatic process: U w (B) Isochoric process: U q
(C) Cyclic process: q w (D) Isothermal process: q w
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-13
57. In order to oxidize a mixture of one mole of each of FeC 2 O4 , Fe2 C2 O 4 3 ,FeSO 4 and
Fe2 SO 4 3 in acidic medium, the number of moles of KMnO4 required is:
(A) 1 (B) 1.5
(C) 2 (D) 3
60. With respect to an ore, Ellingham diagram helps to predict the feasibility of its
(A) Electrolysis (B) Thermal reduction
(C) Vapour phase refining (D) Zone refining
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-14
PART–C (MATHEMATICS)
61. The magnitude of the projection of the vector 2iˆ 3 ˆj kˆ on the vector perpendicular to
the plane containing the vectors ˆi ˆj kˆ and ˆi 2ˆj 3kˆ , is:
3
(A) 3 6 (B)
2
3
(C) 6 (D)
2
62. The shortest distance between the line y x and the curve y 2 x 2 is:
11
(A) (B) 2
4 2
7 7
(C) (D)
4 2 8
63. If and be the roots of the equation x 2 2x 2 0 , then the least value of n for
n
which 1 is:
(A) 4 (B) 2
(C) 5 (D) 3
64. All possible numbers are formed using the digits 1, 1, 2, 2, 2, 2, 3, 4, 4 taken all at a
time. The number of such numbers in which the odd digits occupy even places is:
(A) 180 (B) 175
(C) 162 (D) 160
5x
sin
65. 2x dx is equal to:
sin
2
(where c is a constant of integration).
(A) x 2 sin x 2 sin 2x c (B) 2x sin x 2 sin 2x c
(C) x 2 sin x sin 2x c (D) 2x sin x sin 2x c
66. Let O (0, 0) and A (0, 1) be two fixed points. Then the locus of a point P such that the
perimeter of AOP , is 4, is:
(A) 9x 2 8y 2 8y 16 (B) 8x 2 9y 2 9y 18
(C) 9x 2 8y 2 8y 16 (D) 8x 2 9y 2 9y 18
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-15
3 5
67. If cos ,sin and 0 , , then tan 2 is equal to:
5 13 4
63 33
(A) (B)
52 52
63 21
(C) (D)
16 16
1 x 2x
69. If f x loge , x 1, then f 2
is equal to:
1 x 1 x
2
(A) 2f x (B) f x
(C) 2f x 2 (D) 2f x
2
3 cos x sin x dy
70. If 2y cot 1 , x 0, then is equal to
cos x 3 sin x 2 dx
(A) x (B) x
6 3
(C) x (D) 2x
6 3
sin2 x
72. lim equals
x 0
2 1 cos x
(A) 2 (B) 4 2
(C) 4 (D) 2 2
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-16
2 dy
74. Let y y x be the solutions of the differential equation, x 2 1 dx
2x x 2 1 y 1
such that y 0 0 . If ay 1 , then the value of ‘a’ is
32
1
(A) (B) 1
2
1 1
(C) (D)
16 4
2 x cos x
75. If f x and g x loge x, x 0 then the value of the integral
2 x cos x
/4
g f x dx is:
/ 4
77. The mean and variance of seven observations are 8 and 16, respectively. If 5 of the
observations are 2, 4, 10, 12, 14, then the product of the remaining two observations is:
(A) 40 (B) 45
(C) 49 (D) 48
78. The length of the perpendicular from the point (2, –1, 4) on the straight line,
x3 y2 z
is:
10 7 1
(A) greater than 2 but less than 3 (B) less than 2
(C) greater than 4 (D) greater than 3 but less than 4
79. The contrapositive of the statement “If you are born in India, then you are a citizen of
India”, is:
(A) If you are a citizen of India, then you are born in India
(B) If your are not a citizen of India, then you are not born in India
(C) If you are no born in India, then you are not a citizen of India
(D) If you are born in India, then you are not a citizen of India
80. The sum of all natural numbers ‘n’ such that 100 n 200 and H.C. F (91, n) > 1 is:
(A) 3221 (B) 3303
(C) 3203 (D) 3121
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-17
81. If S1 and S 2 are respectively the sets of local minimum and local maximum points of the
function. f x 9x 4 12x 3 36x 2 25, x R, then
(A) S1 2, 1 ;S 2 0
(B) S1 2,0 ;S2 1
(C) S1 2; S2 0,1
(D) S1 1 ;S2 0,2
82. The sum of the co – efficient of all even degree terms in x in the expansion of
6 6
x x3 1 x x3 1 , x 1 is equal to:
(A) 26 (B) 24
(C) 32 (D) 29
83. A point on the straight line, 3x 5y 15 which is equidistant from the coordinate, axes
will lie only in:
(A) 4th quadrant (B) 1st , 2nd and 4th quadrants
(C) 1st quadrant (D) 1st and 2nd quadrants
84. If the tangents on the ellipse 4x 2 y 2 8 at the points (1, 2) and (a, b) are
perpendicular to each other, then a 2 is equal to:
2 4
(A) (B)
17 17
64 128
(C) (D)
17 17
3 1
85. If cos1 , tan1 , where 0 , , then is equal to:
5 3 2
9 9
(A) sin1 (B) cos1
5 10 5 10
9 9
(C) tan 1 (D) tan 1
5 10 14
86. The equation of a plane containing the line of intersection of the planes 2x y 4 0
and y 2z 4 0 and passing through the point (1, 1, 0) is:
(A) x 3y z 4 (B) 2x z 2
(C) x 3y 2z 2 (D) x y z 0
87. The sum of the squares of the lengths of the chords intercepted on the circle,
x 2 y 2 16, by the lines, x y n,n N , where N is the set of all natural numbers is:
(A) 320 (B) 160
(C) 105 (D) 210
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-18
88. The greatest value of c R for which the system of linear equations
x cy cz 0
cx y cz 0
cx cy z 0
has a non – trivial solution, is:
1
(A) –1 (C)
2
(B) 2 (D) 0
89. Let f : 0,2 R be a twice differentiable function such that f " x 0, for all x 0,2 . If
x f x f 2 x , then is:
(A) increasing on (0, 2)
(B) decreasing on (0, 2)
(C) decreasing on (0, 1) and increasing on (1, 2)
(D) increasing on (0, 1) and decreasing on (1, 2)
90. Let A and b be two non – null events such that A B . Then, which of the following
statements is always correct?
(A) P A B 1 (B) P A B P A
(C) P A B P B P A (D) P A B P A
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-19
PART B – CHEMISTRY
PART C – MATHEMATICS
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-20
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-21
m 2
6. T0 2
k 10
A = A0e–1/
A0
for A , t=
e
2m 2m
t== 2 2 = 104 s
b B
R
t 10 4
No of oscillation 5000.
T0 2 / 10
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-22
7. LIDI = I2R
E 1 E
L ( e t / 2 ) (1 e t / 2 ) 10
10 2 10
e 1/ 2 1 e1/ 2 ; t = 2n2
10. A = 10–4 m2
Emax = 106 V/m
C = 15 F
k A Cd
C 0 ; k
d 0 A
15 1012 500 10 6 15 5
k = = 8.465
8.86 1012 10 4 8.86
k 8.5
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-23
15.
h h ˆ
P1 ˆi and P2 j
1 2
Using momentum conservation
h ˆ h ˆ
P P1 P2 = i j
1 2
2 2
h h
P
1 2
2 2
h h h
1 2
1 1 1
2
2 2
1 2
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-24
17. If we approximate the angle 2 as 30° initially then answer will be closer to 57000. but if
we solve thoroughly, answer will be close to 55000.
So both the answers must be awarded. Detailed solution as following.
Exact solution
By Snell’s law 1.sin 40° = (1.31) sin 2
.64 64
sin 2 .49
1.31 131
64 64 64 d
Now tan 2
(131)2 (64)2 13065 114.3 x
Now number of reflections
2 64 64 105
=
114.3 20 10 6 114.3
55991 55000
Approximate solution
By Snell’s law 1.sin 40° = (1.31)sin 2
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-25
0.64 64
Sin 2 = 0.49
1.31 131
If assume 2 30°
d
Tan 300 = x 3d
x
Now number of reflections
2 105
=
3d 3 20 10 6 3
57735 57000
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-26
23. When red is replace with green 1st digit changes to 5 so new resistance will be 500 .
24. 9 = Vz + VR1
VZ = 5.6 V
VR1 9 5.6
VR1 3.4
VR1 3.4
IR1 ; IR1 = 17 mA
R 200
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-27
5.6
IR2 ; IR2 7 mA
800
Iz = (17 – 7) mA = 10 mA
R
0 2 R 3
25. M 0r(2rdr)
0 3
R
0 2 R 5
I0 0r(2rdr) r 2
(MOI about COM) 0 5
By parallel axis theorem
I = I0 + MR2
0 2R5 0 2R3 8
= R2 0 2R5
5 3 15
2 8
= MR
5
0
26. Dimension of
0
[0] = [M–1L–3T4A2]
[0] = [MLT–2A–2]
1
0 M1L3 T 4 A 2 2
Dimension of
0 MLT 2 A 2
= [M–2L–4T6A4]1/2
= [M–1L–2T3A2]
E1 E2 E3
2R1 R 2 2R1
27. Eeq
1 1 1
2R1 R 2 2R1
2 4 4
2 2 2 5 10 = 3.3
1 1 1 3 3
2 2 2 2
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-28
1 1
= kQ V
r1 r2
Hence, we also obtain that potential difference does not depend on charge of outer
sphere.
P. d. remains same.
a1 1
29. Given
a2 3
2
I a 1
Ratio of intensities, 1 1
I2 a2 9
2
2
Imax I1 I2 1 3
Now, 4
Imin I1 I2 1 3
qE 5 10 6 2000
30. tan
mg 2 10 3 10
1
tan = tan1 (0.5)
2
PART B – CHEMISTRY
31. For cubic unit cell, only FCC has octahedral and tetrahedral voids.
1
ZB = 4, ZA = 4 2,Zo 8
4
Formula = A2B2O8 = AB 2 O 4
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-29
35. Since CN– and NH3 are strong field ligands, low spin complexes are formed.
Complex Configuration No. of unpaired electrons
[V(CN)6]4– 3
t e 0 3
2g g
2+
[Cr(NH3)6] t 42g eg0 2
[Ru(NH3)6]3+ t52g eg0 1
[Fe(CN)6]4– t 62g eg0 0
Magnetic moment is directly proportional to number of unpaired electrons.
36.
38. Sm3+(4f5) = yellow colour, other ions have stable electron configurations with half filled or
full-filled electron configuration.
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-30
39. H
OCH3 O - CH3
Br
Conc.HBr
SN 2
excess
CH = CH2 CH = CH2
OH OH
HBr
CH3Br
CH - CH3 CH = CH2
Br
OH
Br
41. OH Neutral
FeCl
ve phenolic group is absent
3
RMgX
CH3
Grignard
vereaction Acidic H
Re agent C are present
NaOH I O
C - C2H5
Iodoform
2
vereaction
Test
O Fehling' s solution
ve no CHO group ispresent
x y
42. r = K[A] [B]
0.045 = K(0.05)x (0.05)y . . . . (1)
0.090 = K(0.10)x (0.05)y . . . . (2)
0.72 = K(0.20)x (0.10)y . . . . (3)
Dividing (1) by (2) we get
x
0.045 0.05
x 1
0.090 0.10
Dividing (2) by (3)
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-31
x y
0.090 0.10 0.05
y2
0.720 0.20 0.10
Hence, r = K[A][B]2
43.
45.
T2 1000
46. H n Cp.m dT 3
T1
23 0.01T dT
300
0.01
3 23 1000 300
1000 2 300 2
2
= 61950 J 62 kJ
47. Hydration enthalpy depends upon ionic potential (charge/size). As ionic potential
increases hydration enthalpy increases.
q
hydH0
r
x
48. Kp1/n
m
Taking log from both sides
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-32
x 1
log logK logP
m n
1 2
slope
n 3
x
Kp2/3
m
49. Ptotal= X A PA0 XB PB0 0.5 400 0.5 600 500 mmHg
Now, mole fraction of A in vapour
P 0.5 400
YA A 0.4 and mole fraction of B in vapour
Ptotal 500
YB = 1 – 0.4 = 0.6
50. For strongest oxidising agent, standard reduction potential should be highest. Peroxy
oxygen (–O – O–) is reduced to oxide (O 2–) in the change
52.
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-33
3-Hydorxy-4-methylpentanoic acid
58. The upper stratosphere consists of ozone (O3), which protect us from harmful
ultraviolet (UV) radiations coming from sun. The layer get depleted by CFC’s
59.
60. Ellingham diagram which are the curves of the graph between G and T helps in
predicting the feasibility of thermal reduction of ores.
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-34
PART C – MATHEMATICS
61. Vector perpendicular to plane containing the vectors ˆi ˆj kˆ d ˆi 2ˆj 3kˆ is parallel to
vector
ˆi ˆj kˆ
1 1 1 ˆi 2ˆj kˆ
1 2 3
Required magnitude of projection
2iˆ 3 ˆj kˆ . ˆi 2ˆj kˆ
ˆi 2ˆj kˆ
2 6 1 3 3
6 6 2
62. We have
dy dy 1
2y 1 1
dx dx P 2 t 2 , t 2t
1
t
2
9 1
P ,
4 2
So, shortest distance
9 2
4 4 7
2 4 2
2
63. x 1 1 0 x 1 i, 1 i
n
n
1 i 1
n (least natural number) = 4
64.
4th place 8th place
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-35
5x 5x x
sin 2 sin cos
65. 2x dx 2
x x
2 dx
sin 2 sin cos
2 2 2
sin3x sin 2x
dx
sin x
3 sin x 4 sin3 x 2 sin x cos x
dx
sin x
3 4 sin2 x 2cos x dx
3 2 1 cos 2x 2cos x dx
1 2cos 2x 2cos x dx
x sin 2x 2 sin x c
66. AP OP AO 4
2
h2 k 1 h2 k 2 1 4
2
h2 k 1 h2 k 2 3
2
h2 k 1 9 h2 k 2 6 h2 k 2
2k 8 6 h2 k 2
k 4 3 h2 k 2
k 2 16 8k 9 h2 k 2
2 2
9h 8k 8k 16 0
Locus of P is 9x 2 8y 2 8y 16 0
67. 0 and
2 4 4
3 4 5 5
If cos then tan and if sin then tan
5 3 13 12
(since here lies in the first quadrant)
Now tan 2 tan
4 5
tan tan
63
3 12
1 tan .tan 4 5 16
1 .
3 12
cos sin
68. A
sin cos
cos sin cos sin
A2
sin cos sin cos
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-36
cos 2 sin 2
sin 2 cos 2
cos 2 sin 2 cos sin
A3
sin 2 cos 2 sin cos
cos 3 sin 3
sin 3 cos 3
cos 32 sin 32 0 1
Similarly A 32
sin 32 cos 32 1 0
cos 32 0 and sin32 1
32 4n 1 , n I
2
4n 1 , n I
64
for n 0
64
1 x
69. f x loge , x 1
1 x
2x
2x 1 1 2x 2
f 2
n
1 x 1 2x
1 x2
x 12 1 x
n 2n 2f x
x 12 1 x
3 1
cos x sin x
70. Consider cot 1 2 2
1 3
sin x sin x
2 2
sin x
3
cot 1
cos x 3
cot 1 tan x tan1 tan x
3 2 3
x x ; 0 x
2 3 6 6
x 7 x ; x
2 3
6
6 2
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-37
2
x ; 0 x
6 6
2y 2
7
6 x ; 6x2
2 6 x . 1 ; 0 x 6
dy
2
dx 7
2 x . 1 ; x
6 6 2
71. x 2 x x 4 20
2
x 2 x 4 x 20
2
x 2 x 2 20
x 2 2 (not possible) or x 2 1
x 2 1, 1
x 3,1
x 9, 1
Sum = 10
sin2 x
2 2 1 cos x
x
72. lim
x 0 1 cos x
x2
1
2
. 2 2 4 2
1
2
dy 2x 1
74. 2 y 2
dx x 1 x2 1
(Linear differential equation)
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-38
x2 1
n x 2 1
I.F. e
So, general solution is y. x 2 1 tan1 x c
As y 0 0 c 0
1
tan x
y x
x2 1
As, a, y 1
32
1 1
a a
4 16
2 x.cos x
75. g f x n f x n
2 x.cos x
/4
2 x.cos x 2 x.cos x
I n dx
0 2 x.cos x 2 x .cos x
/2
0 dx 0 log 1
0
e
x 2 3x dx Area of
0
rectangle PQRS
11 59
8
6 6
Also 2 16
1 7 2
16 xi2 x
7 i1
1 7 2
16 xi 64
7 i1
7
xi2 560 ……..(2)
i1
Now, x1 2, x 2 4, x 3 10, x 4 12, x 5 14
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-39
78.
Now, MP. 10iˆ 7ˆj kˆ 0
1
2
Length of perpendicular
1 49
PM 0
4 4
50 25 5
,
4 4 2
which is greater than 3 but less
than 4.
80. S A sum of numbers between 100 and 200 which are divisible by 7.
S A 105 112 ..... 196
14
SA
2
105 196 2107
SB Sum of numbers between 100 and 200 which are divisible by 13.
8
SB 104 117 ..... 195 104 195 1196
2
SC Sum of numbers between 100 and 200 which are divisible by 7 and 13.
SC 182
H.C. F. (91, n) > 1 S A SB SC 3121
6 6
82. x x3 1 x x3 1
2 3
2 6 C0 x 6 6C2 x 4 x3 1 6C4 x 2 x 3 1 6C6 x3 1
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-40
2 6 C0 x 6 6C2 x7 6 C2 x 4 6C4 x 8 6C4 x 2 2 6C4 x5 x 9 1 3x 6 3x3
Sum of coefficient of even powers of x
2 1 15 15 15 1 3 24
15 3t
83. Now, t
5
15 3t 15 3t
t or t
5 5
15 15
t or t
8 2
15 15 st
So, P , 1 quadrant
8 8
15 15 nd
or P , II Quadrant
2 2
3 1
85. cos , tan
5 3
4
tan
3
4 1
9
tan 3 3
4 1 13
1 ,
3 3
9
sin
5 10
9
sin1
5 10
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JEE-MAIN-2019 (8th Apr-First Shift)-PCM-41
n n
87. p , but 4 n 1,2,3, 4,5
2 2
n2
Length of chord AB 2 16
2
64 2n2 (say)
For n 1, 2 62
n 2, 2 56
n 3, 2 46
n 4, 2 32
n 5, 2 14
Required sum
= 62 + 56 + 46 + 32 + 14 = 210
89. x f x f 2 x
' x f x f ' 2 x ………(1)
Since f " x 0
f x is increasing x 0,2
Case – I : When x 2 x x 1
' x 0 x 1,2
x is increasing on 1, 2
Case – II : When x 2 x x 1
' x 0 x 0, 1
x is decreasing on (0, 1)
P A B PA
90. P A B
P B P B
(as A B P A B P A )
P A B P A
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