Colla 2016
Colla 2016
Colla 2016
Key words: Abstract – In the international steel market, competitiveness is crucial since the market is
Steel making; smelting reduction; increasingly complex and dynamic. The steel companies face ever more stringent environ-
direct reduction; EAF; BF/BOF mental regulations pushing toward process improvements focused on increasing resource
efficiency while keeping economic sustainability. Investing in new and promising technolo-
gies when the current equipment and machinery become obsolete or unproductive is a task
of utmost importance although not always easy to achieve. In Italy a steelwork located in
Piombino produces high steel quality products but is currently undergoing an important
revamping and renovation process. The case of the Piombino steelwork is an interesting
example of the opportunities faced nowadays by European steel industry in the challenge
of increasing global competition. An overview of some combinations among the possible
and fruitful commercialized technologies that can be implemented in the specific situa-
tion and location of Piombino are presented and analysed. Each alternative technology is
Received 10 July 2015
briefly depicted as well as some economic and environmental aspects of the possible mix
Accepted 9 March 2016
combination.
last Furnace (BF)-Basic Oxygen Fur- it is at the end of its operative life and within
Western Europe. The steelworks that instead in order to mantain the market share of high
have preserved the sinter plants thanks to quality products. According to [5], the pres-
investments in technological improvement sure to restructure and reduce production
acquired a great competitive advantage in capacity will remain one of the main chal-
the market. Moreover, if appropriate mate- lenges for the steelmaking industry in the
rial is used, sinter plants are in compliance foreseeable future. The creation of a center
with environmental regulation on air emis- in Lucchini spa for disposal of military ships
sions as demonstrated by several examples and handling of large cruise ships is another
in Europe [2]. In Lucchini spa, part of the pro- essential element in view of the reorganiza-
cess gases coming from the BF and coke oven tion planning of Piombino steelplant. The
plant is sold to the three power plants (one is recovered steel scrap from the ship disman-
currently being closed) producing an impor- tling can maintain a stable flow estimated
tant source of income. This is a benefit also approximately 100–200 kt per year. The steel
in terms of CO2 allowance saving as they scrap to be purchased on the market for
are considered as avoided emissions. In this some technical reasons can be imported by
article, an overview of the possible and reli- ship through the available port instead of
able steelmaking alternative technologies al- by truck and this can be considered as an
ready used at industrial scale which could be alternative and additional supply channel
implemented in Lucchini spa in place of the with respect to some Italian and European
current facilities will be presented and anal- steelworks.
ysed. In the literature, several studies can be Section 2 presents a general overview
found where different steelmaking technolo- of the ironmaking technologies that are al-
gies have been compared. Barella et al. [3] ternative to the traditional BF/BOF route.
have analyzed new innovative steelmaking Section 3 depicts some case studies, which
activities in order to increase competitive- will be analysed and compared from eco-
ness while complying with environmental nomic and environmental points of view. Fi-
regulations. Hasanbeigi et al. [4] describe nally, the main conclusions of the work are
and compare the most important emerging summarized in Section 4.
alternative technologies in terms of energy
and environmental benefits as well as infor- 1 Alternative ironmaking
mation on costs and commercialization sta- technologies
tus. The revamping of Lucchini is and must
remain fully consistent with the environ- 1.1 Direct reduction processes
mental regulation of the Integrated Pollution
Prevention and Control authorization duly There are several processes for direct re-
issued by the Environmental Minister [2]. At duction (DR) of iron ore which use coal or
the same time, Lucchini’s sustainable com- natural gas as fuel. Table 1 summarizes all
petitive position on the international and the most important commercial technolo-
global steel market should be preserved. gies for direct reduction as well as emerging
For such purposes, a technological restruc- technologies.
turation, which allows for a highly flexible The product of direct reduction is a
production with respect to the consumed spongy spheric iron pellet, called Cold Di-
raw materials ensuring the continuation of rect Reduced Iron (CDRI) or a solid ingot
high quality special steel production (i.e. for called Hot Briquetted Iron (HBI), which is
railway use) should be adopted. In such a denser than CDRI. CDRI worldwide pro-
way the considerable know-how achieved duction is about 8 times greater than the
through the years will not be lost, but rather HBI production, but HBI production covers
the economic sustainability and the future 45% of the traded market, due to less restric-
of such facility in the European steel mar- tive regulations for shipping [7]. DRI/HBI
ket will be guaranteed. The steel production is a flexible raw material because it can be
which is currently 1.6 Mt/year has to be re- charged hot in the EAF with significant en-
duced to approximately 1 Mt/year: this is the ergy saving or in the BOF as coolant sub-
minimum steel production level to be kept stituting steel scrap without affecting the
chemical quality of steel [3,8]. Natural gas as
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V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
reducing agent is used by MIDREX NGTM , of all forms of DRI products. It often consists
r r r
HyL /ENERGIRON and FINMET pro- of four stages: (1) reduction gas; (2) reform-
r
cesses. MIDREX Process Technology is ing; (3) heat recovery; and (4) briquette mak-
the world’s leading technology and cur- ing. DRI is produced by reacting iron oxide
rently it has evolved in two main configu- with a hot reducing gas containing mainly
rations: MIDREX NGTM (using natural gas) hydrogen (H2 ) and carbon monoxide (CO).
r
and MXCOL (using coal) [9]. MIDREX H2 and CO reduces Fe2 O3 into metallic iron
plants produce about 60% of the entire (Fe) and the by-products of this reaction are
r r
world’s DRI, HyL /Energiron accounts CO2 and H2 O [13, 14]. Iron oxide is reduced
r
for 15% and the remaining 25% accounts in the MIDREX Shaft Furnace by the re-
r
for the coal-based technologies [10, 11]. In ducing gas generated in the MIDREX Re-
r
order to achieve a better environmental former [9]. In the MIDREX Reformer natu-
performance, this analysis considers only ral gas is heated and catalytically reformed
the processes exploiting natural gas. Cir- along with recycled CO2 and H2 O from the
cored process uses pure hydrogen as re- reduction process to generate a rich reduc-
r
ductant and since hydrogen is not natu- ing gas to make DRI [13]. MIDREX Re-
rally available, it has to be obtained through former also provides the energy needed for
r
some processes consuming energy [12]. In the reduction reactions within the MIDREX
the case of Circored, the EAF melting has Shaft Furnace [13]. DRI yield can be up
to be adapted as there is no transfer of coal to 99%. Some MIDREX plant/EAF facilities
in the iron during the reduction. The Cir- emit only one-third of the CO2 per tonne of
cored process is not operating anymore and steel of a BF/BOF complex [15, 16]. The high
in the present analysis it will not be consid- simplicity using natural gas and agglomer-
ered. Finmet too is not widely spread: there ated iron ore and flexibility about iron ore
is only one plant in Venezuela [12] and, like reducing gas sources are the main benefits
Circored, it will not be included in this study. of this technology. Unfortunately, the need
to use a large amount of natural gas approx-
imately between 260–280 Nm3 /t DRI is the
1.1.1 MIDREX NGTM process main obstacle to its diffusion in the European
MIDREX NGTM , the natural gas-based con- Union [6]. An annual production of 500 kt
figuration of MIDREXr
process, is the most of DRI would require a supply of natural
widely-used technology for the production gas (with a calorific value of 8490 kcal/Nm3 )
401-page 3
V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
between 130 and 140 million Nm3 /year. The ENERGIRON ZR. H2 O and CO2 are re-
only DRI-making plant in Europe is located moved through top gas scrubbing and CO2
in Germany near Hamburg and operates removal systems, respectively [22]. The CO2
since 1971. In 2013 DRI production was absorption system captures even the sulfur,
nearly 500 kt [17, 18]. According to [19], DRI whenever present in the process gas stream,
worldwide production increased from less reducing the overall SO2 emissions from
than one million tonnes per year in 1971 to the plant around 99% [24]. Some significant
over 70 million tonnes forty years later and achievements have been reached also in the
it is expected to continue this rapid increase reduction of NOx emissions. By adopting
for years to come. ultra-low NOx burners, the NOx emissions
can be reduced to values below 25 ppmv
(50 mg/Nm3 as NO2 ) [26]. Table 2 compares
1.1.2 ENERGIRON
R
process MYDREX r
and ENERGIRON r
ZR in terms
of facilities, type of feedstock, operating con-
r
ENERGIRON process uses a H2 -CO re- ditions and related flexibility [6].
r
ducing gas as in the MIDREX process. Midrex and HYL Energiron are the lead-
r r
ENERGIRON is the innovative HyL
di- ing technologies in shaft furnace direct re-
rect reduction technology developed jointly duction, and they account for about 76%
by Techint and Danieli, which merged of worldwide production [27]. They are the
their knowledge and previous technolo- most competitive ways to obtain high qual-
r
gies (Danarex and HyL ). Very recently ity direct reduced iron (DRI) for steelmaking.
r
ENERGIRON has introduced a reformer-
r
less version called ENERGIRON ZR (Zero
Reformer) [20] which uses a combination 1.1.3 ULCORED process
of partial oxidation of natural gas with
ULCORED is a breakthrough technology
oxygen and in situ reforming [10, 21].
r identified within the ULCOS consortium
ENERGIRON ZR provides a self (auto/in
and, like MIDREX and HyL, it produces di-
situ)-reforming of natural gas which directly
rect reduced iron from direct reduction of
occurs within the Vertical Shaft Furnace
iron ore (in form of lumps or pellets) by
(VSF) using DRI as catalyst. The reducing
gas-based direct reduction in a shaft fur-
gases are generated by “in-situ” reforming
nace [28]. An experimental direct reduction
within the reduction reactor, feeding nat-
pilot is planned to be erected in Lulea, but
ural gas as make up to the reducing gas
it is not yet confirmed [28–30]. This process
circuit and injecting oxygen at the inlet of
uses oxygen instead of air and the concept
the reactor [22]. Other reducing agents such
includes also a POX (partial oxidation) in-
as hydrogen gas, coal, pet-coke and similar
stead of reformers, shifter for production of
fossil fuel and coke oven gas, among oth-
CO2 free reduction/excess gas and the reduc-
ers, are also potential sources of reducing
ing agent being either natural gas or syn-
gas depending on the particular situation
gas from coal/biomass [31]. With respect to
and availability. HBI and DRI with a low r
MIDREX , it is able to reduce natural gas
or high carbon content are the main prod-
r consumption by 20–25% and CO2 emissions
ucts of ENERGIRON [23]. A high reduc-
by 15–20% [32]. There is also some signif-
tion temperature (above 1050 ◦ C), “in-situ”
icant savings in terms of electrical energy
reforming inside the shaft furnace and the
consumption [33, 34], even if its industrial
various energy recovery units in the plant
scale and feasibility are yet to be proved.
are the most important features in order
r This process needs to be supplied with iron
to optimize ENRGIRON ZR’s overall en-
ore of high quality [35].
ergy efficiency [24]. Therefore, DRI prod-
uct takes most of the energy supplied to
the process, with minimum energy losses 1.2 Smelting reduction processes
to the environment [25]. The selective re-
moval of both by-products, water and car- The Smelting Reduction (SR) process is an
bon dioxide, generated from the reduction alternative to BF route and to DRI produc-
process is one of the distinctive feature of tion. The final product is liquid pig iron or
401-page 4
V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
r r
Table 2. Comparison between MIDREX and ENERGIRON ZR.
in some cases, liquid steel [16]. It omits coke (2) a stage of gasification of coal and
production by combining the gasification of smelting reduction in the melter-gasifier,
r
non-coking coal with the reduction of iron which is the main reactor of the COREX
ore in a liquid bath [36]. SR includes several technology.
processes, some of which have been com- In the first step, lump iron ore and/or pel-
r
mercially proven e.g. COREX (where pel- lets and additives are loaded into the top of
lets and lump ores are reduced in a shaft), a reduction shaft. In the second stage, the
r
FINEX (where fines ore are reduced in a reduced iron is melted in a melter-gasifier
series of fluidized bed reactor) and ITmk3 unit using the energy generated from the
while others are still under development gasification (and partial combustion) of coal.
r
(e.g. Hismelt). However COREX , among Reducing gas (CO and H2 ) from the melter-
SR technologies, appears to be the most ma- gasifier is injected into the lower part to re-
ture one [4]. duce the iron ore to sponge iron. Hot metal
and slag are tapped at the bottom through
a similar procedure used in the BF conven-
1.2.1 COREX R
process
tional tapping [39]. The two stages allow to
r use a wide range of low cost coals (steam
COREX is a promising alternative emerg-
coal) directly (if the particle size is greater
ing ironmaking technology currently com-
than 8 mm) or in briquettes (if the parti-
mercially proven [37], even if there is a
cle size is less than 8 mm). As an alterna-
low adoption rate in the steel industry
tive to the coal, a 5% maximum amount
worldwide [4]. It allows for cost-efficient
of rigid plastics can also be fed directly
and environmental friendly production of r
into COREX . The process takes place at
hot metal directly from iron ore and non-
high pressure up to 5 bar and the reducing
coking coal [4,38]. SIEMENS VAI develops it.
r gas composition is 65–70% CO, 20–25% H2
COREX process is a two-stage direct smelt-
and 2–4% CO2 . The hot gas leaving from
ing processes:
the melter-gasifier unit is cooled to 800–
(1) a pre-reduction stage; 900 ◦ C and cleaned in a hot cyclone to recycle
401-page 5
V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
r
entrained fines [40]. COREX export gas can lump form and the rest (35%) is fed as pul-
be utilized in several ways: verized coal along with oxygen in the lower
part of the melter-gasifier. The conversion of
(a) directly within the cycle;
coal into char and its gasification is similar
(b) DRI production; r
to the COREX processs [44]. The hot DRI is
(c) electric energy generation;
compacted and charged into a melter gasi-
(d) heating;
fier unit [45].
(e) steam production;
(f) chemical processes [41]. HIsarna (“HI” from HIsmelt and “sarna”
r
from the Celtic for iron isarna) is one of
COREX uses approximately one tonne of the different processing methods selected
coal per tonne of hot metal with approxi- within the ULCOS project [28, 29, 46]. The
mately 45% of the total energy input used HIsarna process produces liquid hot metal
in ironmaking while the rest goes to the ex- from iron ore fines using non-coking coal as
port fuel gas [42]. The produced hot metal reductant. There is no need for ore agglom-
has carbon and silicon content similar to BF eration or coking. It is a two-step process: a
hot metal, while the sulfur content is much cyclone where the fine ore is prereduced and
higher [40,42]. The coal particle size used by melted and an iron bath reactor where the
r
COREX is moderately higher than BF, gen- ore is finally reduced. The reactor uses the
erating a 30–35% of discard with respect to heat generated by degassing the coal [47].
the standard coal supply. There is a negative It requires considerably less carbon than a
impact on the production costs if the inter- conventional BF with a significant CO2 emis-
nal re-use or the selling of this coal is not sions reduction. It is also a flexible process
possible [43]. A comparison between a con- allowing a partial substitution of coal by
r
ventional BF and a COREX process shows biomass, natural gas or hydrogen [32]. A
r
that COREX uses more additives and more HIsarna pilot plant with a nominal capacity
oxygen (from 12 to 24 times more) and it of 60 000 t/year (8 t/h) is located in the Tata
consumes more nitrogen (3.6 times more). It Steel site of Ijmuiden (The Netherlands) [32].
consumes less iron ore (–6%) and less electri- This pilot plant has been constructed by a
cal energy (–11%) than the BF/BOF route. As Consortium of European steelmakers united
r
far as the process gas is concerned, COREX in the ULCOS project with the support of Rio
generates the same amount as the BF, but Tinto [48].
with a higher calorific value (approximately
2.2 times). With regard to CO2 emissions, a The REDSMELTTM process can treat
total reduction is generated, as some plants most iron-bearing materials such as iron ore
i.e. the sinter plant and coke oven plant are fines, iron and steel mill solid and liquid
missing. wastes to produce hot metal [49]. It cou-
ples a Rotary Hearth Furnace (RHF) and
an EAF smelter to convert recycle iron ore
1.2.2 FINEX, HIsarna and REDSMELT fines into hot metal or alloys and slag. Re-
duction takes place in a RHF which can
r r
Like the COREX process, FINEX is a two- use a variety of carbon-containing materi-
stages melting reduction method of iron- als such as anthracite, pet coke and ground
making. It is based on direct use of non- electrodes as reductant to produce DRI for
coking coal and fine ore and with respect recycling or smelting in a submerged arc fur-
r
to COREX it can directly use iron ore sin- nace. This technology has been developed
ter feed (up to 0.012 m) without agglomera- to meet a growing demand of low-cost and
tion [4]. A series of successive fluidised bed environment-friendly production process of
pre-reduction reactors in which ore fines are hot metal due to its low emission levels, but
reduced in three or four stages to DRI and a it has not yet reached the necessary consoli-
melter-gasifier are the main units of this iron- dation of its economic viability [50, 51]. Cur-
making system. The iron ore passes through rently this process has a range of production
4 reactors where it is heated and reduced by of 0.3–1.0 Mt/year of hot metal and may be
a reduction gas also produced by coal gasifi- used to treat a wide range of fine iron ores
cation. The major part of coal (65%) is fed in and steelmaking residues [52].
401-page 6
V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
crisis. Such economic crisis has then led to stall more plants can negotiate the invest-
a marked downturn in steel manufacturing ment cost. The analysis of very specific situ-
and to an associated steel demand which re- ations deriving e.g. from particular commer-
mains 27% below pre-crisis levels [5]. cial framework agreements requires ad-hoc
data and information and is thus out of the
scope of the present paper.
2.1 Economic analysis
Table 3. CAPEX expressed in Mc. and reduction technologies. All the calcula-
CAPEX Mc tion have been carried out considering as the
BF+BOF 295 final output a ton of liquid steel. In particu-
Sinter plant 40 lar, in order to have an idea of the unitary
SR process 132 cost of each scenario, the cost analysis has
DR process 92 been carried out estimating the consumed
Brownfield Greenfield raw materials, energy consumption as well
EAF scenarios 60 300
as labor cost. The EAF main raw materials
and consumed energy taken into consider-
should be minimized [56]. According to the ation are electrical energy, oxygen, fluxes,
above assumptions and hypothesis, Table 3 graphite and refractories. In the direct re-
shows the estimated CAPEX for the consid- duction technology, the amount of iron ore
ered technologies. is estimated as 1.42 t/t DRI. Natural gas, air
The above estimated CAPEX for each compressed and water have been estimated
technology have then been merged in order too. In the smelting reduction technology,
to find the CAPEX of each above depicted the estimated coal consumption is 1.30 t/t
scenario. Figure 1 shows the total CAPEX hot metal, while estimates for iron ore and
for the five production scenarios. The over- additives are 1.51 t/t hot metal and 0.24 t/t hot
all implementation of the Greenfield 5th sce- metal, respectively. Other elements, i.e. oxy-
nario has the highest CAPEX with 524 Mc gen, water, nitrogen, air compressed have
whereas the lowest one is observed at the been taken into account. As far as the unit
brownfield 2nd scenarios with 60 Mc. EAF prices values are concerned, raw materials
greenfield requires more CAPEX than EAF and energy have been estimated according
brownfield scenarios since all the necessary to [32,57]. In the estimation of labor cost, the
equipment and facilities for the steel produc- workers in all five scenarios are subdivided
tion have to be acquired. BF/BOF requires as follows: 69% workers, 30% employees and
less CAPEX with respect to the EAF Green- 1% managers. The following average hourly
field scenarios due to the fact that CAPEX in- costs for each category have been consid-
cludes a new BF/BOF plant and a new sinter ered: 20 c/h for workers, 35 c/h for employ-
plant, but it does not take into consideration ees and 55 c/h for managers. An EAF steel
a coke plant and the rest of the necessary scrap load of about 1.1 k/t LS [2] has been
equipment since they are in a good working considered, in accordance to the BREFs, and
condition. Nevertheless BF/BOF CAPEX is its composition on all scenarios is as follows:
higher than EAF Brownfield scenarios. The (i) 70% shredded steel scrap (E40 Cate-
Brownfield 2nd scenario seems the most fea- gory);
sible from a CAPEX point of view: this is (ii) 30% steel scrap coming from ships dis-
clearly due to the fact that only the EAF has mantling.
to be built but in a long term vision such sce-
In case of the steel scrap coming from
nario is strictly connected to the DRI prices
ships dismantiling, a reduction of 20% on
and its variations in the market.
the scrap prices with respect to the shred-
ded scrap prices has been assumed. Table 4
2.1.2 OPEX summarizes the details of hypothesis and
assumptions taken into consideration for
After an estimation of the CAPEX of each OPEX calculation. In both “SR+EAF” and
scenario, a simple preliminary cost analysis “SR+DR+EAF” scenarios a power reduction
for all five scenarios has been performed by as well as a reduction on the refractory and
estimating OPEX. Each scenario was based graphite consumption have been assumed
on a plant capacity of 1 Mt/year of liquid due to the fact that hot metal is charged.
steel and operating working hours were as- According to the above assumptions, the
sumed to be 2080 h/y. In EAF scenarios, the breakdown of OPEX for each scenario is
OPEX calculation has been carried out con- shown in Figure 2.
sidering the main component of EAF cou- There is a significant increase in OPEX
pled with the main factors of the smelting of BF/BOF scenario with respect to EAF
401-page 9
V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
401-page 10
V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
scenarios: about 40% more with respect to adopted technology and the annual produc-
“SR+DR+EAF” scenario. According to the tion costs. The obtained values are shown in
Figure 2, the scenarios associated to an EAF Table 5.
are the most convenient. In “50% EAF” sce- The Greenfield scenarios obtain lower
nario the main cost component is the pur- values with respect to the Brownfield scenar-
chasing of DRI (about 40%): the DRI price ios: this is due as the CAPEX of Greenfield
has been retrieved in reference [62] and, ob- scenarios is higher than the brownfield
viously, if different prices are used, OPEX ones causing a reduction on the values.
result will change. In the scenarios where In the Greenfield scenario, the combination
smelting reduction is implemented, an im- of smelting and reduction technologies ob-
portant assumption is the sales of the dis- tains a better value than the “DR+EAF” and
carded coal. In fact such sales and the recov- “SR+EAF” ones since the plant obtains addi-
r
ery of COREX gas in place of natural gas tional revenues from the selling of hot metal
reduce OPEX about 4% in “SR+EAF” and and DRI surplus.
8% in “SR+DR+EAF” with respect to “50%
EAF”. From an economic point of view, it
seems that “SR+DR+EAF” is the most con- 2.1.3 Sensitivity analysis
venient due to the combination of savings
of smelting and direct reduction technology. In this section, the effect of influence of vari-
However, a complete economic estimation ous parameters on the convenience to invest
of OPEX and CAPEX depends on many in some scenarios is discussed. In the first
factors which may also change from loca- sensitivity analysis, which compares “50%
tion to location as, for instance, energy and EAF” vs. “SR+EAF” scenario, the effects that
raw materials prices [38]. A profitability in- the fluctuations of DRI/hot metal prices in
dicator called Return On Investment (ROI) “50%EAF” scenario have on the convenience
which is the percentage of the money re- to invest in “SR+EAF” scenario in terms of
covered annually from the plant (ROI% = payback period are investigated. DRI and
Profit/CAPEX) has also been estimated ac- hot metal prices varied in a limit range in
cording to the above assessed CAPEX and order to understand when it becomes more
OPEX. The annual profit has been computed profitable to purchase DRI or hot metal in the
as the difference between a rough estimation market than to produce them. The cost re-
of the annual revenues produced from the lated to DRI or hot metal purchasing would
401-page 11
V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
be saved if “SR+EAF” scenario would be projects [63]. The results of Simple and Ac-
implemented, but the convenience to invest tualised PBP are shown in Figures 3a and 3b.
in “50%EAF” scenario is strictly related to According to the above assumptions,
DRI/hot metal market price. According to Figures 3a and 3b demonstrate that the
the approach adopted for OPEX calculation, higher the hot metal or DRI price, the shorter
the following additional assumptions have the time to recover the “SR+EAF” invest-
been made: ment as more savings would be cumulated
through the years. If the DRI market price
– source of Financing: 100% Equity is higher than 370 c/t the Actualised PBP to
Capital; recover the “SR+EAF” investment would be
– investment depreciation (years): 20; lower than 10 years as shown in Figure 3a.
– DRI to be purchased (kt/year): 510; When the variations are applied to the hot
– hot Metal to be purchased (kt/year): 510; metal prices, PBP is more sensible as it can
– DRI market basic price (c/t): 291 [15]; be seen from Figure 3b: in order to get a
– hot metal market basic price (c/t): short actualised PBP (i.e. less than 10 years),
358 [15]; the hot metal market price should exceed c
– interest rate: 4%; 370/t, which is not very far from the current
– hot metal cost estimation (c/t): 328; market price according to [15]. However,
– DRI cost estimation (c/t): 273; in terms of profitability, the “SR+EAF” sce-
– steel production (Mt/year): 1; nario becomes profitable and cost-effective
– surplus hot metal to sell (kt/year): 135; when simple or actualised PBP is shorter
– surplus DRI to sell (kt/year): 131; than 5 years. The second sensitivity analysis
– taxes: 40%. considers the “50% EAF” vs. “DR+SR+EAF”
scenarios. In this case, not only DRI and hot
Mortgage and financial charges are not in- metal savings, but also the selling of DRI
cluded as the capital equity is supposed and hot metal surplus not used in EAF (as-
to finance all the investment amount. The suming that the steel production is fixed to 1
discounted cash flows have been estimated Mt) have been considered. In this case, DRI
starting from the net operating result (differ- and hot metal prices variations have been
ence between revenues and operating costs, combined among them in order to deter-
but after the taxes) and considering the de- mine the trend of the actualised PBP of the
preciation as a positive variation. In this “DR+SR+EAF” scenario (Fig. 4). Not only
analysis, the taxes were set at 40% which can DRI and hot metal prices variations af-
is an average value representing the Italian fect the PBP, but also the amount of invest-
tax system, but it can change according to ment: for instance, if a 20% reduction is ap-
the value adopted in the considered coun- plied on CAPEX of both Smelting and Direct
try. Obviously the lower the tax value the Reduction process, PBP results decrease fur-
higher the net operating result. The cash ther as shown in the Figure 4b. Any variation
flows are discounted with an interest rate in the input data as well as in the estimated
of 4% according to the Net Present Value assumptions can affect the final results of the
(NPV) method. The interest rate, in such analysis and obviously the results of PBP.
cases, usually corresponds to the Minimum All the above assumptions, especially the
Acceptable Rate of Return (MARR), i.e. the decisions on how to finance CAPEX (debt or
minimum rate of return on a project that equity capital) are an important weight on
a manager or company are willing to ac- the final results obtained as they affect the
cept before starting a project, given its risk investment recovery time and therefore the
and the opportunity cost of forgoing other simple or actualised PBP duration.
401-page 12
V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
Fig. 3. Sensitivity Analysis in terms of Simple and Actualised PBP: sensitivity with respect to DRI prices (a) and
sensitivity with respect to hot metal prices (b).
Fig. 4. Actualised PBP Results: CAPEX without any reduction (a) and CAPEX with a reduction of 20% (b).
mance with respect to the current situation. of natural products such as vegetable oil and
A particular importance should be given to animal fats. The iso-butilene is very impor-
atmospheric emissions, especially the ones tant in the petrochecmical sector for the pro-
related to greenhouse gases (GHG Gas), due duction of fuels, plastics materials, organic
to the ambitious targets set in Europe (–20% glass and elastomers. Lanzatech process is
by 2020 and –87% in 2050 compared with already applied in the steel industry claim-
1990) [71]. However, other types of emis- ing that CO2 emissions are reduced by one
sions, e.g. particulate matter and dioxins, are third with respect to using the process gases
r
extremely important, especially considering as fuel [73]. LanzaTech company claims
the impact at local level and the potential ef- that globally up to 150 million tonnes of CO2
fects on the workers’ health as well as on the emissions could potentially be avoided by
community living in the surroundings of the re-using available steel mill gas residues us-
steelmaking plant. ing LanzaTech’s process [74].
power plant could be completely collected in order to implement new measures to in-
and used for the preparation of conglom- crease the energy efficiency and the reduc-
erates by a local company which is already tion of specific consumptions. In the 4th sce-
a partner of Piombino steelwork for wastes nario it is necessary to consider not only the
and by-products management. Moreover, a time and costs related to the implementation
portion of the electrical energy produced but also the construction and the impact of
could be sold in an internal network system the external related infrastructures to sup-
to several companies located in the vicinity ply and guarantee a large amount of natural
of the Piombino industrial area possibly at gas. It is important to point out that in an
favourable conditions, with a considerable Italian scenario the natural gas has a high-
competitive advantage for them. If all the volatility price due to a great dependence
above assumptions are feasible, the 3rd sce- from two important supplier countries, i.e.
nario could be considered self-sustainable Libya and Russia, which held respectively
from an energy point of view. The energy a 9% and 38% share on 2013 imports. Rus-
interactions among the various plants in the sia became the main supplier in 2013 [75].
industrial area is very important as well as DRI production process has been success-
the introduction of advanced technologies fully implemented where there are large iron
and the research for energy recovery solu- ore mines and natural gas reserves.
tions and for re-use of off-gas and other sec-
ondary energy sources, by improving the
environmental sustainability of the selected 2.2.3 Comparison summary among
steelmaking production route. For instance, the different options
a series of innovative technologies for recov-
ery and reuse of waste heat can be deployed Table 6 shows the final overall compari-
both inside and outside the industrial area son among the five alternatives considered
401-page 15
V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
for Piombino steelwork according to the as- worldwide are considered. This case-study
sumptions and hypothesis previously de- and the considered factors as well as the re-
picted. As far as the economic indicators are sults obtained are related to the steelwork
concerned, the assumptions related to the operating in Piombino and its particular col-
EAF location (i.e. close to the hot area or in location in Italy. For instance, the factors re-
a different area) can greatly affect CAPEX in lated to the needs to continue to produce
the EAF-based scenarios. The highest OPEX a certain amount of high quality steel for
is associated to the BF/BOF scenario and the railway products and, simultaneously, to ex-
highest reduction with respect to BF/BOF is ploit the steel scrap flow coming from the
obtained in the 5th scenario. The 5th sce- ship dismantling could be a significant crite-
nario allows savings of about 26% with re- ria which the investor should not neglect. In
spect to the 4th scenario due to the fact any case, the selected steel production pro-
r r
that MIDREX process is fed by COREX cesses will need to be flexible enough to meet
gas and not by natural gas. From an envi- not only the fluctuation on the prices of the
ronmental point of view, SO2 and NOx are raw materials market but also those related
significantly lower than in a conventional to the sale of finished products.
BF/BOF route: this is primaly based on the
fact that the coke oven plant and the sinter
plant in all the 4 scenarios are definetely dis- Acknowledgements
mantled. The best results in terms of CO2
emissions are achieved in the 2nd scenario,
The authors gratefully acknowledge Eng.
although the 3rd one obtains better results C.Motto and Eng. S.Simoni of Lucchini Spa for
in terms of PCCD/PCFD and SO2 emissions. their helpful and valuable comments on a draft
However, the environmental impact of all version of the manuscript. The sole responsibility
the alternative scenarios appear significantly of the issues treated in the present paper lies with
advantageous with respect to the conven- the authors.
tional BF/BOF route. The results shown in
the 5th scenario are an average estimation of
the values obtained in the 3rd and 4th sce- References
narios, since this scenario couples a smelting
reduction with a direct reduction technol-
[1] World Steel Association. Steel Statistical
ogy. According to the table below, the tech- Yearbook; 2014. Available from: http://
nologies depicted in the 3rd (SR+EAF), 4th www.worldsteel.org/statistics/statistics-
(DR+EAF) and 5th (SR+DR+EAF) scenario archive/yearbook-archive.html (last access:
seem to represent an innovative way to pro- 05/11/2015)
duce steel. [2] European Integrated Pollution Prevention
and Control Bureau (EIPPCB), Best
Available Techniques (BAT) Reference
3 Conclusions Document for Iron and Steel Production.
Industrial Emissions Directive 2010/75/EU,
2010
An overview of the alternative and possi-
[3] S. Barella, E. Bondi, C. Di Cecca, A.F.
ble routes to BF/BOF which could be imple- Ciuffini, A. Gruttadauria, C. Mapelli,D.
mented in a particular company located in Momebelli, La Metallurgia Italiana 11-12
Piombino has been presented in this paper. (2014) 31-40
The case study of the steelwork located in Pi- [4] A. Hasanbeigi, M. Arens,L. Price, Renew.
ombino has been analysed and investigated. Sustain. Energy Rev. 33 (2014) 645-658
An economic and environmental point of [5] European Commission. Action Plan for a
view has been analyzed, but a deeper re- competitive and sustainable steel industry
search on the technical aspects has to be pur- in Europe (COM2013); 2013. Available
from: http://eur-lex.europa.eu/legal-
sued in the future by the investors in order to content/IT/TXT/?uri=CELEX:52013DC0407
reach a final solution. All the environmental (last access: 02/11/2015)
and economic factors taken into considera- [6] A. Chatterjee, Sponge iron production by di-
tion and the obtained results can change if rect reduction of iron oxide, PHI Learning
different data are used or different location Pvt Ltd., 2010
401-page 16
V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
[7] F. Reddemann, Cooling and transport [20] C.E. Baukal Jr., Oxygen-Enhanced
of hot briquetted iron (HBI), 2012. Combustion, CRC Press Taylor & Francis
Available from: http://millennium- Group, Boca Raton, FL, 2013
steel.com/archives/article-category/2012- [21] P.E. Duarte, A. Tavano, E. Zendejas,
international (last access: 14/10/2015) Achieving carbon-free emissions via the
[8] MIDREX. DRI Products & Applications Energiron DR processes in: AISTech 2010
Providing flexibility for steel- Proceedings of the iron and steel technology
making, 2015. Available from: conference, Warrendale PA, 2010, pp. 165-
http://midrex.com/assets/user/media/DRI_ 173.
Products_Brochure_1.29_.15_ 2.pdf (last [22] T.H. P. Duarte, Mexico; A. Martinis,
access: 01/10/2015) Danieli, C., Italy, High-Carbon DRI with
[9] MIDREX, The MIDREXr Process, 2015. ENERGIRON DR Technology presented at
Available from: http://www.midrex.com/ the METEC & 2nd ESTAD 2015, Düsseldorf,
process-technologies/the-midrex-process 15–19 June 2015
(last access: 14/10/2015) [23] P.E. Duarte, Energiron Direct Reduction
[10] International Energy Agency (IEA), Technology – Economical, Flexible,
Overview of the current state and devel- Environmentally Friendly. Available from:
opment of CO2 capture technologies in http://www.tenovagroup.com/pdf/exhibi
the ironmaking process, 2013. Available tion/ENERGIRON%20Direct%20Reducti
from: http://ieaghg.org/docs/General_ on%20Technology%20-%20Economical%
Docs/Reports/2013-TR3.pdf (last access: 20Flexible%20and%20Environmentally%
14/10/2015) 20Friendly.pdf (last access: 25/07/2015)
[11] M. Kirschen, K. Badr,H. Pfeifer, Energy 36 [24] T. Scarnati, D. Masoero, The JSPL DR
(2011) 6146-6155 project: a pratical example of flexibility of
ENERGIRON DR technology for using any
[12] F. Schuler, N. Voigt, T. Schmidt, M. Woertler,
energy source without requiring scheme
P. Dahlmann, J.-T. Ghenda, H.B. Luengen,
change, presented at the International
Stahl Und Eisen 133 (2013) 61-63
Conference “Resurgent India – Vision 2020
[13] H. Gaines, V. Chevrier, C. Ravenscroft,
in Metals and Minerals Sector”, New Delhi,
Developing the MIDREXr Direct Reduction
28-30/09/ 2012.
process – Technological innovations and
[25] C. Raggio, La Metallurgia Italiana 10 (2012)
process enhancements presented at the
[26] D.C. Metallics, Energiron Direct Reduction
METEC&2nd ESTAD 2015, Dusseldorf, 15-
Plant. Available from: http://www.danieli.
19/06/2015.
com/Products-Technologies/Ironmaking/
[14] A. Von Starck, A. Muhlbauer,C. ENERGIRON-ZR/ENERGIRON-ZR/Envi
Kramer, Handbook of Thermoprocessing ronmental (last access: 07/08/2015)
Technologies – Fundamentals, Processes, [27] X. Jiang, L. Wang, F.M. Shen, Adv. Mater. Res.
Components, Safety, Vulkan-Verlag Gmbh, 805-806 (2013) 654-659
Essen, 2005 [28] Ulcos, Ultra Low Carbon Dioxide (CO2 )
[15] International Energy Agency (IEA), Energy Steelmaking. Available from: http://www.
Technology Transitions for Industry; ulcos.org (last access: 18/09/2015)
2009. Available from: http://www.iea.org/ [29] K. Meijer, M. Denys, J. Lasar, J.-P. Birat, G.
publications/freepublications/publicati Still, B. Overmaat, Ironmak. Steelmak. 36
on/energy-technology-transitions-for-i (2009) 249-251
ndustry.html (last access: 14/10/2015) [30] J.-P. Birat, ULCOS II has been shaping
[16] IEA ETSAP, Technology Brief I02 – Iron and up; 5/3/2009. Available from: ftp://ftp.cordi
Steel – 2010, Available from: http://www. s.europa.eu/pub/estep/docs/ulcos_ii_sc_
etsap.org/E-techDS/PDF/I02-Iron\&Steel- estep_en.pdf (last access: 18/09/2015)
GS-AD-gct.pdf (last access: 12/11/2015) [31] K. Knop, M. Hallin, E. Burström, Metall. Res.
[17] MIDREX, 2013 World Direct Reduction Technol. 106 (2009) 419-421
Statistics, 2014. Available from: http:// [32] N. Pardo, J.A. Moya, K. Vatopoulos,
www.midrex.com/assets/user/news/ Prospective Scenarios on Energy Efficiency
MIDREX_World_DRI_Stats.pdf (last access: and CO2 Emissions in the EU Iron & Steel
24/02/2015) Industry, Joint Research Center, Institute for
[18] A. Sawada, T. Miyamoto, Kobelco Technol. Energy and Transport, Luxembourg, 2012
Rev. 29 (2010) [33] J.-P. Birat, Update on the ULCOS
[19] T. Battlea, U. Srivastavaa, J. Kopfleb, R. Programme, 2011. Available from: http://
Hunterb, J. McClellanda, Chapter 1.2 – The erc-online.eu/wp-content/uploads/2014/04/
Direct Reduction of Iron, in Treatise on 2011-00612-E.pdf (last access: 14/10/2015)
Process Metallurgy: Industrial Processes, [34] N. Pardo, J.A. Moya, Energy 54 (2013) 113-
Seshadri Seetharaman, 2014, Vol. 3 128
401-page 17
V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
[35] Centro Studi Ilva, Emissioni di CO2 . [52] Paul Wurth SMS Group, REDSMELT.
Available from: http://www.centrostudii Available from: http://www.paulwurth.
lva.com/items/391/allegati/1/Emissioni% com/Our-Activities/Recycling-technologi
20CO2.pdf (last access: 23/07/2015) es/RedSmelt (last access: 26/10/2015)
[36] L. Price, J. Sinton, E. Worrell, D. Phylipsen, [53] D.S. Remer, A.P. Nieto, Int. J. Production
H. Xiulian, L. Ji, Energy 27 (2002) 492-446 Economics 42 (1995) 101-129
[37] A. Eberle, D. Siuka, C. Böhm, W. Schiffer, [54] H. Bierman Jr, S. Smidt, The capital budget-
Revue de Métallurgie 100 (2003) 297-306 ing decision: economic analysis of invest-
ment projects, Routledge Taylor & Francis
[38] J. Shibu, W. Sterrer, J. Wurm, COREX-An an-
Group, New York and London, 2007
swer for hot metal production in a changing [55] Metals Consulting International, Capital
environment presented at the METEC&2nd investment costs for plant and equip-
ESTAD, Dusseldorf, 15-19 June 2015 ment in iron and steelmaking Available
[39] S. Seetharaman, Treatise on Process from: http://cdn.steelonthenet.com/pdf/
Metallurgy, Industrial Processes, Elsevier, commerce/capex_examples.pdf (last access:
Oxford, UK, 2014, Vol. 3 12/11/2015)
[40] J. Feinman, Direct Reduction and Smelting [56] A. Mukherjee, A. Adak, M.N. Dastur, A
Processes, in The Making, Shaping and Model for Sequencing and Optimizing
Treating of Steel, T. A. S. Foundation, Steel Melt Shop Operations using Discrete
Pittsburgh, PA, 1999, pp. 741-777 Event System Simulation presented at the
[41] K. Lampert, A. Ziebik, W. Stanek, Energy 35 METEC&2nd ESTAD, Düsseldorf, 15–19
(2010) 1188-1195 June 2015
[42] F.J. Fruehan, The Making, Shaping and [57] Lucchini Spa, Private communication with
Treating of Steel: Ironmaking Volume, The experts of Lucchini, 2014
AISE Steel Foundation, Pittsburgh, PA, 1998 [58] Siemens VAI, Competence in iron mak-
ing – The future of manufacturing,
[43] Siemens VAI, Profitable and environ-
2015. Available from: https://www.i
mentally friendly ironmaking, 2015.
ndustry.siemens.com/datapool/industry/i
Available from: http://www.industry.si
ndustrysolutions/metals/simetal/en/
emens.com/verticals/metalsindustry/en/
Competence-in-Ironmaking-en.pdf (last
metals/ironmaking/corex/pages/home.aspx
access: 14/10/2014)
(last access: 03/07/2015)
[59] Siemens VAI. Simetal Corex technology
[44] R.C. Gupta, Energy and Environmental – The profitable and environmentally
Management in Metallurgical Industries friendly direct smelting reduction pro-
PHI Learning Private Limited, New Delhi, cess, 2011. Available from: https://www.i
2012 ndustry.siemens.com/datapool/industry/i
[45] Siemens VAI, Environmentally safe iron- ndustrysolutions/metals/simetal/en/
making, 2015. Available from: http://www.i SIMETAL-Corex-technology-en.pdf (last
ndustry.siemens.com/verticals/metalsi access: 12/11/2015)
ndustry/en/metals/ironmaking/finex/ [60] D.J. Poveromo, Iron ore and DRI – An old
pages/home.aspx (last access: 03/07/2015) and new conference topic, http://www.
[46] D. Kumar, D. Kumar, Management of coking steeltimesint.com/contentimages/features/i
coal resources, Elsevier, 2015 ron_ore_joe_web_res.pdf
[47] W.J. Rankin, Minerals, Metals and [61] Industrial Efficiency Technology Database.
Sustainability: Meeting Future Material Midrex Process. Available from: http://i
Needs, CSIRO Publishing, 2011 etd.iipnetwork.org/content/midrex%C2%
[48] K. Meijer, C. Zeilstra, C. Treadgold, J. Van A9-process (last access: 12/11/2015)
der Stel, T. Peeters, J. Borlée, M. Skorianz, [62] Company United Raw Materials, Direct-
C. Feilmayr, P. Goedert, P. Wurth,R. Dry, reduced iron. Available from: http://www.
The HIsarna ironmaking process presented urm-company.com/production/dri (last ac-
at the METEC&2nd ESTAD, Dusseldorf, 15- cess: 11/11/2015)
19/06/2015 [63] W.G. Sullivan, E.M. Wicks, J. Luxhoj,
Engineering Economy, Prenctice Hall, 2006
[49] R. Degel, O. Metelmann, Steel Times Int. 30 [64] World Steel Association, Climate change.
(2000) 32-33 Available from: http://www.worldsteel.
[50] J.A. de Araújo, V. Schalch, J. Mater. Res. org/steel-by-topic/sustainable-steel/envi
Technol. 3 (2014) 274-279 ronmental/climate-change.html (last access:
[51] Department of Energy USA, Ironmaking 27/10/2015)
Process Alternative Screening Study, [65] T.A. Branca, M. Vannucci, V. Colla, Revue de
Volume 1, 2000. Available from: http:// Métallurgie 106 (2009) 373-381
www1.eere.energy.gov/industry/steel/ [66] V. Colla, B. Fornai, A. Amato, Revue de
pdfs/ironmaking_process.pdf Métallurgie 106 (2009) 363-372
401-page 18
V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
[67] J.-P. Birat, J.-P. Lorrain, Y. De Lassat, Revue giant signs 10-year partnership with
de Métallurgie 106 (2009) 325-336 LanzaTech to commercialise gas to fuel
[68] K. Huitu, M. Helle, H. Helle, M. Kekkonnen, technology, 2013. Available from: http://
H. Saxén, Steel Res. Int. 86 (2015) 56-465 www.businessgreen.com/bg/news/2276284/
[69] Federacciai, Rapporto Ambientale 2011, siemens-to-develop-biofuel-from-steel-i
L’acciaio è sostenibilità (in Italian language), ndustry-gases (last access: 16/02/2016)
2012. Available from: http://www.federacci [74] F. Burton, China Steel Corporation
ai.it/Pdf/RapportoAmbientale/Rapporto_ Approves Investment in LanzaTech
Ambientale_2011.pdf. Commercial Project, 2015. Available
[70] J.-P. Birat, Revue de Métallurgie 100 (2003) from: http://www.marketwired.com/press-
339-348 release/china-steel-corporation-approves-i
[71] European Commission. EU greenhouse nvestment-in-lanzatech-commercial-
gas emissions and targets. Available project-2012180.htm (last access: 09/10/2015)
from: http://ec.europa.eu/clima/policies/g- [75] Autorità per l’energia elettrica il gas e il sis-
gas/index_en.htm (last access: 09/07/2015) tema idrico, Relazione annuale sullo stato
[72] LanzaTech, 2015. Available from: http:// dei servizi e sull’attività svolta (in Italian
www.lanzatech.com/company/ (last access: language), Presidenza del Consiglio dei
12/11/2015) Ministri, Dipartimento per l’Informazione e
[73] BusinessGreen, Siemens to develop biofuel l’Editoria, 2014
from steel industry gases – Manufacturing
401-page 19