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DATE: 12-12-2018

COURSE JEE-MAIN MOCK TEST-10 TEST CODE

NUCLEUS XII 1 1 2 9 7

IOC OC PC IOC OC PC IOC OC PC IOC OC PC IOC OC PC

Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans 2 3 4 1 4 2 1 4 2 1 2 4 1 4 3
IOC OC PC IOC OC PC IOC OC PC IOC OC PC IOC OC PC
Q.No. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans 2 3 1 1 3 3 1 3 4 4 3 4 4 1 3
Q.No. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans 2 3 1 3 1 3 3 1 3 2 1 4 3 1 2
Q.No. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans 1 3 2 2 3 2 4 2 4 1 4 2 3 1 4
Q.No. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans 4 2 4 2 1 4 4 3 3 3 2 3 3 2 1
Q.No. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans 2 4 3 3 3 1 1 3 3 3 3 4 4 2 2

HINTS & SOLUTIONS

C H E M I S T RY Q.4 Zn(amphoteric) + 2NaOH  Na2ZnO2 + H2 
(c)
Q.1 M(s) (
a)
M(g)  M+(g) O
OMe O H
COOH C
Q.2 + O3 Me
 2S
 O
O
Q.5 
CHOH
2

lH 4 CHOH
2 OH
LiA
+ CO2
COOMe
unstable structure double bond is at
CHO Na bridge head C
B H
4
COOMe
Q.6 (Eq) KMnO4  (Eq) H2O2  (Eq) H 2C2O4
CHOH
2
0.2 × 200 × 5 = (M ×50 × 2) + (0.5×100×2)
 Vn  Z 2 [H2O2] = 1M
Q.3    3  volume strength = 11.2 × 1 V
 2 rn  n = 11.2 V
Z2 12
  2.
43 23
 2
Z = 16
Z=4
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Q.7 1
CaO(s) Ca(OH)2(s) So, 2NO2  2NO + O2 ; KC =
(quick lime) (slaked lime)
144
H2O
Q.13 [Mn(CO)5]
Ca(OH)2 EAN = 25 + 5 × 2
(white turbidity) = 25 + 10 = 35
(milk of lime) [Mn(CO)5] requires 1 more electron to
H2O achieve 36 e– so it act as oxidizing agent.
Ca(OH)2(aq)
(lime water) OH
Q.14 Glycine – CH2
NH2
O
OH
Q.8 * No chiral carbon is present
here therefore optically inactive
O
n=3
2n = 23 = 8 rCs 
Q.15  0.732
Q.9 Process is isochoric rCl
q = qv = n.Cv,m T
3R 1
=2× (200 – 400) Q.16 XeF2 + H2O  Xe + O + 2HF
2 2 2
= – 1200 Cal
1
2XeF4 + 4H2O  Xe + O + 8HF + XeO3
Q.10 C2 +  C2 2 2
B.O. = 1.5 (para) B.O.=2(dia)
* * NO2 NH2
C2+ = 1s2 1s 2  2s2  2s2  2 p x 2   2 p y1
HCl
Nb  Na Q.17 HCl
Sn 
 NaNO
 2 
Bond order =
2
74 N NCl Cl
= =1.5 (Paramagnetic)
2
CuCl
 / HCl

C2 = 1s 2 1*s 2  2s2 *2s2  2 p 2   2 p 2
y y

Nb  Na
Bond order = Q.18 Theory based
2
84 Q.19 PH4+ > OF2 > SF2 > SbH3
= =2 (diamagnetic)
2 3
(sp ) 3
(sp ) 3
(sp )
No hybridisation (Bond angle  90°)
Q.11 Order of basicity   
(C2H5)2NH > (C2H5)3N > C2H5NH2 > NH3 BA EN of CA

Q.12 2NO + 2SO3  2NO2 + 2SO2 ;KC = (3)2

2SO2 + O2  2SO3 ; KC = 16
__________________________________
2NO + O2  2NO2 ; KC = 9 × 16

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H 3C O Q.24 AT 373K, PH0 2O = 760 torr

| ||
Q.20 H 5C 2  CH — C  NH 2 Br / KOH
2    P = P0 . X H 2O

NaNO 2  HCl
H5C2 – CH–NH2    570 = 760 . X H 2O
H O 2
CH3 1
 Xsolute =
(P) 4
H5C2–CH–CH3
Q.25 Smelting -An oxidation process.
OH Smelting is a process of applying heat to ore in
(Q) order to extract out a base metal. It is a form
of extractive metallurgy.Smelting uses heat and
PCC a chemical reducing agent to decompose the
ore, driving off other element as gases or slag
H5C2–C–CH3 leaving the metal base behind.
O
(R) CH(CH3)2
Q.21 Sn2+ + 2e–  Sn ; G° = (–2.F.x)
(
i) O2

Sn4+ + 4e–  Sn ; G° = (–4.F.y) Q.26 (ii ) H  / H 2O
__________________________
Sn2+  Sn4+ + 2e– ; G° = (–2.F.E°)
So, (–2.F.E°) = (–2.F.x) – (–4.F.y) OH O
 E° = (x – 2y)
+ H3C CH3
H (Q)
(P) Major
O Product
B


H
O O Gives violet coloured
H H complex with FeCl 3
H O O H H
O B O
Q.22 [ A ]t 1 1
 n  3 = 1
H H
Q.27 [A ]0 2
B O B
O
2 8
O O H H O
H H 300
H Number of Half lives (n) = =3
100
1 7
Fraction reacted = 1 – =
8 8
Q.23 N–H (
i ) KOH

 C 2 H 5  NH 2
( ii ) C 2 H 5  X
( iii ) aq.NaOH (P)
3
sp
Cl
Q.28 (1) ClO3–1 O
 O
OK CHCl3  NaOH O
+      


2 p - d
0 p - p
C 2 H 5  NC
Bad smelling compound
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 a2 + ab + bc + ca, b2 + ab + bc + ca,
sp
2 c2 + ab + bc + ca AP
(2) SO2 S  (a + b) (a + c), (a + b) (b + c),
O O (b + c) (c + a) AP
1 p - d 1 1 1
1 p - p  , , AP.
bc ca ab
F

Cl F sin 20  cos 20  sin 50

(3) ClF3 Q.33 cos 10 · sin 35 · cos 25
F sin 160   sin 70   sin 130 
= sin 80  · sin 35  · sin 65  = 4
0 p - d
0 p - p
Q.34 f (x) = [x] + x  1
 f –1(x) = g (x) = [ x ] + {x}2 – 1
(4) SO32– S f (0) = 1 and f (2) = 3 then
O O
O 2 3

1 p - d  f (x )dx   g( x)dx  6
0 p - p 0 1

Q.35 (zn – 1) = (z – 0) (z – 1) ….… (z – n–1)

Q.29 Me  C  CH 2  Cl > Me – O – CH2 – Cl > ln (zn – 1) = ln (z – 0) + ln (z – 1) ….…
|| + ln (z – n–1)
O n 1
n · z n 1 1
Cl =  z
zn  1 r 0 r
>
n 1
Cl n · 3n 1 1
 n
3 1
=  3n  
r 0 r
2
Q.30 For AB = Ksp = s1 Now,
n 1 n 1 n
MB2 Ksp = 4 s32   3  n ·3 n
 3  r =   3    1 3n  1 – n = 3n  1 .
  =
5
N3 C 2 Ksp = 108 s3 r 0 r r 0  r 

A3C Ksp = 27 s 44
All have same Ksp, So maximum solubilitywill Q.36 y= 7  7  7  7  .
be of N3C2(s).  y2 = 7 + 7y  y = 3

Q.37 fn2(3) + 2fn(1) = 9fn2(1) + 2fn(1)

M AT H E M AT I C S 2
 10n  1  2 (10 n  1)
ax 2  3x  5 = 9   

Q.31 y =  9  9
5x 2  3x  a
Range is R  a  (– 8, – 2) 102 n  1
= = f2n(1).
a = – 7, – 6, – 5, – 4, – 3. 10  1

Q.32 a2, b2, c2 AP Q.38 2a + 3b + 5c = 2a + (4 – 1)b + (4 + 1)c

 2 2 2
a + 1, b + 1, c + 1 AP = 2a + 4k + (– 1)b + 1

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Case-1: a = 1  b  even and c is any number

number of ways = 10. t ( t  1) t 2
 t2   .  1
Case-2: a  1  b  odd and c is any number = Lim 2! = 2.
number of ways = 4 × 3 × 5 = 60. t 0  t 2 t3 
t   t    .
 2 3 
Q.39 In multinomial, by beggar's method
Total number of distinct terms = n+r–1Cr–1.
So, n+4–1C4–1 = n+3C3 = n+3Cn. Q.45 f '(x) = 3x 2 + 2ax + b – 5sin 2x > 0  x  R
 a2 – 3 (b – 5) < 0  a2 – 3b + 15 < 0.

x 2  3x x  1 x  3 Q.46 Let the point be (2t2, 4t)

Q.40 f(x) = x  1 2  x x  3 Equation of normal is tx + y = 4t + 2t3
 2t3 + 4t + 6 = 0  t3 + 2t + 3 = 0
x  3 x  4 3x  (t + 1) (t2 – t + 3) = 0  t = – 1
f '(0) = point be (2, – 4).
3 1  3 0 1 3 0 1 1
3
1 2  3  1 1  3  1 2 1 x2  x , x0
x,
1 4 0 3 1 0 3 4 3 Q.47 y=  ;y= 
4  x , x  2  3 , x0
= 36 + 3 – 6 + 9 + 6 + 6 + 10 = 60.  x

Q.41
 3 1   3 1 
  
2  = 
1 0
PPT =  2 2  2
0 1 = I
 1 3  1 3  
2
 2 2   2 2 
Hence, required area
 Q = PAP PAP = PA 2PT
2 T T

1 2019 2 3
 PTQ2019P = A2019 = 
1 
.  3  3
0 =   x   dx    (4  x )  x  dx
3
x 2
Q.42 n (A × B) = n(S) = 20.
5  3ln 3
a + b = 9  {(1, 8), (3, 6), (5, 4), (7, 2)} = .
n(E) = 4 2
1
P(E) = . dy dt
5 Q.48 Put x + y = t 1 + =
dx dx
Q.43 f(x) = x3 – x2 + 4x + 2sin–1x  t  1   dt  t 1
    1 =
2  t  2   dx  t  2
f '(x) = 3x2 – 2x + 4 + >0
1 x2 ( t 2  t  2) dt
 x  (0, 1)  = 2dx
( t 2  2)
 Range is [0, 4 + ].
ln | t 2  2 |
 t+ = 2x + C
2
Q.44 Put sin x = 1 + t  if x  t0
2
ln | ( x  y ) 2  2 |
(1 t )
(1  t )  (1  t ) t
(1  t )  1  (y – x) + = C.
Lim = Lim 2
t 0  t  ln (1  t ) t 0 t  ln (1  t )

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   
where OA  a ; OB  b ; OC  c ; OP  p
y=3 2 2 2
PA  PB  PC
 2 
    2,  2
 0,   4     a 
 4     
x – 4y =  = | a  p |2  | b  p |2  | c  p |2 = 6   = 2a2
Q.49  3

Q.56 From theory.

x=0 x=2
Area of quadrilateral = 2 × 3 = 6 n 1
  r 
1  2  2  Q.57 Lim  sin   =   sin x dx
3=   × 2  = – 5. n 
r 1 n n 0
2 4 
1
=  cosx 0 = 2.
sin 4  cos 4  (sin 2   cos 2 )2
Q.50  =
5 1 5 1 Q.58 f(x) = [3 + 11sin x] = 3 + [11sin x]
Number of points at which y = f(x) is not
sin 4  cos4  differentiable is 21.
   tan2 = 5.
5 1
Q.59 f(x) = (sin–1x)4 + (cos–1x)4
Q.51 Let the circle be
x2 + y2 – a2 +  (xcos  + ysin  – P) = 0  f '(x) =

4 (sin 1 x )3  (cos 1 x )3 
   cos    sin   1 x2
Centre is  , .
 2 2   1 
 f(x) is decreasing in   1, 
 = – 2P.  2

Q.52 Let P(h, k), then  1 

and increasing in  , 1 .
 2ax 2ah   2 
ky = 4b    = 0  D = 0
 k k  17 4  1  
4
fmax. = f(– 1) = ; fmin = f   = .
2 16  2  128
 8ab  8ah
  =  xy = constant.
 k  k

Q.53 Centre is point of intersection of cos x  cos3 x 2 dt

Q.60 f(x) =  3
dx = 
2x – y + 1 = 0 and x + 2y – 3 = 0. 1  cos x 3 1 t2

2  1
3

Q.54 Let the tangent be y = mx +

2 f(x) = sin (cos x ) 2  .
m 3 
 
 2 2x
x  mx   = – 1  mx2 + +1=0
 m m
P H YS I C S
4
D = 2 – 4m = 0  m = 1. dW
m Q.61 For W to be maximum ; =0;
dx
i.e. F(x) = 0 x=,x=0
Q.55 R= 3a Clearly for d = l ,the work done is maximum.
   a  Alternate Solution :
|a | = |b| = |c| = = |p| External forceand displacement are in the same
3
direction

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 Work will be positive n

continuosly so it will be maximum when Q.67 n = N =  =
N
displacement is maximum.
0.69 0.69 N
 t1 / 2  =
Q.62 At equilibrium  n

4 3
mg = 6r or  r g = r Q.68 Energy released = (80 × 7 + 120 × 8 – 200 ×
3
6.5) = 220 MeV.
vr (r )2
 v  or v2r = (vr) × 4
2r (2r )2
nh h
= 4 cm/s. Q.69 Angularmomentum = =
2 2
( n = 1)
Q.63 At maximum depth the ray graze the surface
(i.e. the angle made bythe raywith normal will
become 90°) 0A
Q.70 C
Applying Snell's law L

 1   log C  log  0  log A  log L

1  sin 450   2  x  sin 900
 2  dC dA dL
 
C A L
1 1
 2 x or x = 1 m
2 2 dC
 21 dT   2 dT  0
C

 K /r2 
 21   2
  
Q.64 (2) dB = 10 log 


 = 10 log    = 10
 0   0 
Q.71 Since elasticity of balloon is negligible, pres-
[log (K1) – 2 log r] sure inside ballon ~– pressure outside baloon =
dB1 = 10 (log K´ – 2 log r1) Patm.
dB2 = 10 (log K´ – 2 log r2) W = Patm V
r2   Vin = 10 litre.
3 = dB1 – dB2 = 20 log  r 
 1  Vin Vfin 
Vin Tfinal 
Tin = T Vfinal =  T  litre.
 r2 
2
 r1  1 fin  in 
(0.3) = log      =
r 
 1   r2  2 Tfinal 
W = Patm Vin  T  1
 in 
Q.65 Induced emf in the rod   Blv
 58 
Current in the circuit  105 × 10–2  290  = 200 J
 
 Blv  t / RC
I  e  t / RC  e
R R Q.72 Let y-axis be vertically upwards and x-axis be
Since the net force on the rod should be zero, horizontal.
the external force will be equal in magnitude
Vy (real)
but opposite to the magnetic force. Vy (app.) =  1
B2l 2 v  t / RC  
 F Il B e 
R
Vx (app.) = Vx (real)

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Alternate solution
vy(real) v  0    i R R 
B = J  r = 0 2
ĵ ×  î  k̂  =
2 2 R 2 2 

µ0 i
( î  k̂ )
= sin-1(3/5)
4R
vx(real)
Q.76 eE = me r
Vy (app ) 4 4 3 R
tan  =  tan  =   1 m e 2
Vx (app ) 3 3 4   E dr = e 
r dr
0

Q.73 E =  × 10–9 sint

Also E = i × 2.

i = × 10–9 sin t.
2

Q.74 As soon as the field changes, there will be an m e 2R 2

induced current (anticlockwise) in the ring.As  V=
2e
there is always a electromagnetic force acting
on a current carrying element. Hence, there will Q.77 As field is uniform
be a torque on the ring about its axis. Hence
qE 
(2). Acceleration ‘a’ = . E = 2
m 0

1 2s
Using s = at2  t =
2 a

on putting values t = 4 2s

The magnitudeofmagnetic field at P  , y,

R R
Q.75 
2 2 
Q.78 Strain () = = T = (10–5) (200)

is
= 2 × 10–3
µ0 Jr µ0i R µ0i
B= = × = Stress = Y (strain)
2 2R 2 2 2 2R Stress = 1011 × 2 × 10–3 = 2 × 108 N/m2
 Required force = stress × Area = (2 ×
unit vector in direction of magnetic field is 10 ) (2 × 10–6) = 4 × 102 = 400 N
8

î  k̂ 400
B̂ =  Mass to be attached = g = 40 kg
2
Ans.

Q.79 Equivalent circuit is

10 15

A 10 20 30 15 B

20 30

 µ0 i = 37.5 
 B = BB̂ = ( î  k̂ )
4R

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Q.80 The shape of water layer between the two the component of weight along tangential
plates is shown in the figure. direction is mg sin .
Thickness d of the film
= 0.12 mm = 0.012 cm. g
hence tangential acceleration is g sin  =
2

Q.84 When connected in parallel

d Potential difference across each capacitor = v
P.D. when connected in series = N.V.

Q.85 Let the ball collides with the wall after time t.
d Let velocity of ball after collision is v.
Radius R of cylindrical face  .
2
Pressure difference across the surface  u
 v  
 5  1 u u
T 2T
  . u 4 ; v 5 4 ;
R d   u cos 37
5
Area of each plate wetted by water = A.
Force F required to separate the two plates is u u 9u
v  
given by 5 4 20
2T
F = pressure difference × area  A u/5
d
2  75  8
  10 5 dynes 37°
0.012
9u
Q.81 Momentum of the system remains conserved Also, ( u cos 37) t  (T  t )
20
as no external force is acting on the system in
horizontal direction. 4ut 9u  2u 3  54u
   t   t 
 (50 + 100) 10 = 50 × V + 100 × 0 5 20  g 5  125g
 V = 30 m/s towards right, as boat is at rest.
VPboat = 30 m/s
Q.86 The current lags the EMF by /2, so the circuit
should contain only an inductor.
g
Q.82 mg = m2 R ,  =
R 2 A
Q.87 x = A sin t ; for x =
T 2
Q.83 x2 = 4ay A 2
Differentiating w.r.t. y, we get  = A sin t
2 T
dy x T
= Solving t = .
dx 2a 6

rel. v 
Q.88 rod = point =  r  ; v rel. being the
 
velocity of one point w.r.t. other.
3v  v
dy = and ‘r’ being the distance between
 At (2a, a), =1 r
dx
2v
 hence  = 45° them. =
r
XII MT-10 [JEE Main] Page # 9
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Q.89 Acceleration of box = 10 m/s2

Inside the box forces acting on bob are shown
in the figure
T = (mg)2  (ma)2 = 10 2 N

x
CM

Fixed end
Q.90 x
 L  2x
2
L–x

d
(L – 2x) = 1 m/s
dt
dx 1
– = m/s
dt 2
2 L  3x
 rCM =
2
drCM  3 dx 3
= vCM = = m/s
dt 2 dt 4

XII MT-10 [JEE Main] Page # 10