Chemical and Ionic Equilibrium: Chapter - 08

LT-2023(JEE ADV NOTE) Part-II-CHEMISTRY
CHAPTER - 08
CHEMICAL AND IONIC EQUILIBRIUM
WORK BOOK
1. C  2NO 2
N 2 O 4 
Initial 1 0
Final (1  x) 2x
1  x  0.2 mole
2x  0.02 mole
0.2
 N 2O4    0.1 M
2
0.02
 NO2    0.01M
2
 NO2    0.01
2 2
K  103
 N 2 O4   0.1
2. A  AB5
B2  AB3 
5 2 4
10 10 10
Kc 
 AB5 

 4 
10
 AB3  B2   5    2   4
   
 10   10 
3. A A  B  2C

Initial 3 1 0
Final  3  x  1  x  2x
At equilibrium  C   1.5
ie 2x  1.5 x  0.75
 C 1.5 
2 2
Kc   4
 A   B  2.25  0.25
4. B  2CO g 
C s   CO 2(g) 
K p  63
 
2
P2 10PCO2
K p  CO 
PCO2 PCO2
100 PCO2  63
PCO2  0.63 atm
PCO  10PCO3  10  0.63  6.3
Ptot  PCO2  PCO  0.63  6.3  6.93 atm
5. B 
2AB2(g )  A 2(g)  2B2(g)
t  0 5 mole 0 0
t  eq 5  2x x 2x
but 2x  2mole
 at equilibrium
Mole of AB2  3
Mole of B2  2
Mole of A 2  1
3 1 2
 AB2  ;  A2  ;  B2 
6 6 6
Ptotal  12
3
PAB2  Pt   AB2  12   6 atm
6
PA2  12  1  2 atm
6
2
PB2  12   4 atm
6
 
2
2.  4 
2
PA 2 PB2
Kp    0.9
P  AB2 
2
62
6. C Kc = 61
 2 103 
2
 NH3  
2
QC =  1.48  106 ; QC  K C
 N 2  H 2  1103    3 103 
3 2
 A g   B(g)
AB 
7. A
t0 C 0 0
t  eq C(1  )  C
1
Number of moles 
VD
1
n initial 
80
1
n final 
50
1
C
80
1
C 1    
50
C 1    80

C 50
80
H 
50
  0.6
% d  60%
8. C
9. A K a  C 2
%d
 C112  C 2  22 ;  
100
2 2
 1   n 
0.1    0.025   
 100   100 
0.1  0.025  n 2
0.1
n  2%
0.025
10. C K sp  S2
S  0.376 g / L
0.376
S
188
2
 0.376  6
K sp     4 10
 188 
11. A
12. D  Ag   Br 
AgBr 
K sp   Ag    Br  
5  1013  0.05  Br 1 
5  1013
 Br 1   2
 11011  moles of KBr
5 10
Weight of KBr  120  1011 g
13. B
14. C
15. C
16. D 
AB g   A (g)  B(g)
2P
Kp   2.56  102 atm
1  2
 2 1
 2.56  102
1  2
  0.16 ;   16%
17. A At equilibrium A, B, C and D are equal.  K c  1
A  C  D
 B 
Initial 1 2 0 0
1  x  2  x x x
x.x
K 1
1  x  2  x 
x 2  1  x   2  x 
x 2  2  x 2  x  2x
3x  2
x  2  66.66
3
66.66
 % B converted   33.33%
2
18. D  2NO2  1 O 2

N 2 O5 
2
Pi 600 0 0
Pf 600  P 2P P
2
Ptotal  600  P  2P  P  960
2
P  240 mm Hg
240
 N 2 O5   0.4
600
19. A  Hg 22  2I 

Hg 2 I 2 
S 2S
K sp  4S3
1.2  1023  4S3
S  3.1 1010 M
 Hg 22    3.1 1010 M
 I   2  S  6.2  1010 M
20. C
21. D KCN, K 2 CO3 & LiCN are basic in nature
22. D  H    K a .C
K a1 C1  K a 2 C2
1.8  104  0.001  1.8  105  C2
C2  0.01 M
23. A At 100°C ; Kw = 55 × 10–14
 H    OH    55  1014
pH  1   log 55  1014   6.13

2
24. C
25. C Ist dissociation 100%
 H    2  104 M
1
Second dissociation 50%

 H     H     H    2  104  1 104  3 104
2 1 2
pH   log 3 104   3.53
26. A pH  8;  pOH  6
OH    106
OH    K b .C
106  K b  0.01
K b  1010
But K a . K b  K w
K w 1014
Ka   10  104
K b 10
27. B
28. B 300  0.134

 Pb 2    1.005 101 M
400
100  0.4
Cl     101
400
PbCl2   Pb 2   Cl 
2
Qsp   Pb 2   Cl   1.005 103  K sp
29. B
30. A SO2 in atmosphere = 10 ppm = 10g in 106 mL H2O
 H 2SO3
SO 2  H 2 O 
10
mol in 106 ml H 2 O  1.5625  104 M
64
 H   HSO3
H 2SO 4 
 H    HSO3 
Ka 
 H 2SO3 
From the above equation [H+] can be calculated
31. D  NH3(g )  H 2S(g )

NH 4 HS s  
Before eq 0.5 0
After eq. 0.5  P P
Pt  0.84  0.5  P  .  P  0.17 atm
K p  PNH3  PH3   0.5  0.17  0.17  0.11atm 2
 2X  P1
2
32. A  2Y
X  K P1 
1  X  1  x 
 P  Q K P  X 2  P1 
Z   
2
1 X  1 X 
P1 1
 
P2 36
33. C  C  D
A  B 
I 1 1 0 0
C x x x x
E 1 x 1  x x x 1
KC 
 C D  x 2 0
 A  B 1  x 2
x
3
1 x
x  3  3x
4x  3
x  3  0.75
4
H
34. C log K  log A 
2.303 RT
1  D  d  46  30 16
    0.533
35. A  n  1  d  30 30
 in %  53.3%
2
36. A K sp   Mg 2  OH  
2
11011  101 OH  
2 1014
OH    1010  H    5  109
10
OH   10 ; pH  9
 5
37. D Refer Levelling effect

38. C Henderson-Hasselbach equation
p OH  p K b  log
salt 
 base
39. A 1 103  2 104  3   H     H    4  104 ; pH  3.4
40. B
41. D
42. B
48  2SO3
43. B n SO3   0.6 2SO 2  O 2 
80
 SO3 
2
12.8 0.62
n SO2   0.2 Kc  
SO 2   O 2  0.22  0.3
2
64
9.6
n O2   0.3
32
44. D PV = nRT
3170 × 1 × 10–3 = n H2 O  8.314  300
A  C 
B  D
45. B
 C  D  1  x 
2
I 1 1 1 1 KC    100
 A  B 1  x 2
C x x x y
E 1  x  1  x  1  x  1  x  1  x  10  10x
119 20 9
 D   HX    1.818 11x  9; x 
11 11 11
46. D [H+] = 10–1 [H+] = 10–2

V1 = 1L V2 = ?
M1V1 = M2V2 10–1 × 1 = 10–2 × V2
101
V2 =  10 ; So volume of water added = 9L
102
 PA q  PBp

47. A A p Bq 
ps qs
K sp   Aq    Bq    Ps   qs 
p q p q
Ls  pPq q s p  q
48. D
49. A A-PRS, B-PQRS, C-PQRS, D-Q
50. B
51. A
52. D
53. D
54. A
55. A
56. C Precipitation occurs when the ionic product is greater than the solubility product. For the similar formula
if the solubility product is smaller, precipitation must occur earlier.
Of the given choices, HgS has the least value of the solubility product so its precipitation occurs earlier.
57. A
58. B a  p; b  r; c  s; d  q
59. A a  q; b  r; c  s; d  p
60. A a  q; b  p; c  s; d  t
61. A
62. C
63. B
64. 64ml
65. 3.30 - 3.50 range
66. 8.32
pK a1  pK a 2
HCO3 is amphiprotic ion pH =
2
67. 2.40 - 2.80
N1V1  N 2 V2
acid base
N A  25  0.1850  17.10
N A  0.131
 H 3O   A  ; K a  5.56 10 5
HA  H 2 O 
pK a  4.255
1
2 a
pH  1 pK  log C    4.255  log 0.131  2.57
2
68. 4 K p  PNH3 .PH2S  0.265  0.265

K p  K c  RT   K c  RT 
n 2
0.0702
Kc   1.2 104
 0.0821 295 
2
69. 100  2Ag   CrO24

Ag 2 CrO4 
2S1 S1
2S2 (0.6  S2 )
 2Na  CrO 42
Na 2 CrO 4  
2  0.6 0.6
K sp   2S2    0.6  S2 
2
S2  6  107 mol / L
S1
 100
S2
70. B, C
71. A, C
pH1  pK a  log y
x
pH 2  pK a  log y solving x  3.162
x y
 y  log  y x  pK  4.95
pH 2  pH1  log x a
After dilution,  H    102 pH  2

72. A,B, C, D
102  10  V 102
 H     10 2  Re sult is independent of volume 
10  V 
73. A, B, C
74. B, C, D
75. A, C, D

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LT-2023(JEE ADV NOTE) Part-II-CHEMISTRY

18. D  2NO2  1 O 2

19. A  Hg 22  2I 

23. A At 100°C ; Kw = 55 × 10–14

pH  1   log 55  1014   6.13

Second dissociation 50%

pH   log 3 104   3.53

28. B 300  0.134

From the above equation [H+] can be calculated

31. D  NH3(g )  H 2S(g )

37. D Refer Levelling effect

39. A 1 103  2 104  3   H     H    4  104 ; pH  3.4

3170 × 1 × 10–3 = n H2 O  8.314  300

46. D [H+] = 10–1 [H+] = 10–2

68. 4 K p  PNH3 .PH2S  0.265  0.265

69. 100  2Ag   CrO24

After dilution,  H    102 pH  2

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