Chapter 7 Evaporation
Chapter 7 Evaporation
Chapter 7 Evaporation
Concentrated liquid, L
T1, xL, hL
• relatively small capacity
• cost of steam relatively cheap
• wasteful as latent heat of vapour is discarded
• TF = Tbp, dilute solution, 1 kg steam = 1 kg vapour
Calculation methods for single-effect evaporator (dilute)
Vapour, V
T1, yV, HV
Feed, F
P1
TF, xF, hF
T1
Steam, S Condensate, S
TS , H S TS, hS
Concentrated liquid, L
T1, xL, hL
Concentrated liquid, L
T1, xL, hL
2. Heat-transfer surface area (A) & no boiling-point rise (BPR) :
Energy balance: FhF + S(HS – hS) = LhL + VHV
Heat transfer equation: q = S = UAT = UA(TS – T1)
where S(HS – hS) = S
h = cP(T – Tref.)
HV = latent heat at T1 (T ref.=T1)
cP of inorganic salt in water cP of water = 4.14 kJ/kg.K
Example 8.4-1 (Geankoplis textbook)
L
T1, xL = 0.015
L = 6048 kg/h
U = 1704 W/m2.K T1, xL = 0.015 kg salt/kg ,hL
L = 6048 kg/h
U = 1704 W/m2.K 100oC, xL = 0.015 kg salt/kg ,hL = 0kJ/kg
Heat transfer equation: q = S=UAT = UA(TS – T1)
From the steam table (A.2-9) at, T1 = 100oC ,H = 2676.1 kJ/kg, h = 419.04 kJ/kg
Tref = 0oC (same as steam table),
Energy balance: FhF + S(HS – hS) = LhL + VHV
9072hF + S(2230.2) = 6048(419.04) + 3024(2676.1)
where hF = 159.22 kJ/kg (after interpolation) from steam table (A.2-9)
9072(157.32) + S(2230.2) = 6048(419.04) + 3024(2676.1)
S = 4125 kg/h (compare to 4108 kg/h)
V = 3024 kg/h
100oC, HV =2676.1kJ/kg
F = 9072 kg/h
P1 = 101.325 kPa
xF = 0.01 kg salt/kg
T1 = 100oC
TF = 311K
S = 4125 kg/h S
PS = 143.3 kPa Ts = 110oC
TS = 110oC, = 2230.2kJ/kg
L = 6048 kg/h
U = 1704 W/m2.K 100oC, xL = 0.015 kg salt/kg ,hL = 419.04kJ/kg
Heat transfer equation: q = S=UAT = UA(TS – T1)
Concentrated liquid, L
T1, xL, hL
2. Heat-transfer surface area (A) & with boiling-point rise (BPR) :
Energy balance: FhF + S(HS – hS) = LhL + VHV
Heat transfer equation: q = S = UAT = UA(TS – T1)
where T1 = Tsat. at P1 + BPR or from fig. 8.4-2
hF and hL from fig. 8.4-3
HV = Hsat. at P1 + 1.884(BPR)
Boiling-point rise (BPR) of solution
90
Figure 8.4-2. Duhring line chart for aqueous solutions of sodium hydroxide
Example 8.4-2 Use of Duhring Chart for BPR
175 79.5
Figure 8.4-2. Duhring line chart for aqueous solutions of sodium hydroxide
Enthapy-concentration chart
enthapy chart – Tref. = liquid water at 0oC
- used together with steam tables
92 214
Concentrated liquid, L
T1, xL, hL
2. Heat-transfer surface area (A) & with boiling-point rise (BPR) :
Energy balance: FhF + S(HS – hS) = LhL + VHV
Heat transfer equation: q = S = UAT = UA(TS – T1)
where T1 = Tsat. at P1 + BPR or from fig. 8.4-2
hF and hL from fig. 8.4-3
HV = Hsat. at P1 + 1.884 (BPR)
Example 8.4-3
V T1
HV
F= 4536 kg/h TF = 60oC
P1= 11.7 kPa
xF = 0.2 kg NaOH/kg
T1
S S
NaOH
PS = 172.4 kPa TS, hS
HS
L T1
xL = 0.5 kg NaOH/kg hL
Given : U = 1560 W/m2.K
120
Example 8.4-3 V = 2722 kg/h T1=89.5oC
HV
F= 4536 kg/h TF = 60oC
P1= 11.7 kPa
xF = 0.2 kg NaOH/kg
T1=89.5oC
S S
(Tsat. = 48.9oC)
PS = 172.4 kPa TS, hS
NaOH
HS
L = 1814 kg/h T1=89.5oC
xL = 0.5 kg NaOH/kg hL
Given : U = 1560 W/m2.K
BPR = T1- Tsat = (89.5 – 48.9)oC = 40.6oC
Tref. = 0oC (same figure 8.4-3),
217
hF at 60oC(140oF) & 20% NaOH from
figure 8.4-3,
hF = 92 btu/Ibm (214 kJ/kg)
92
hL at89.5oC (193oF) & 50% NaOH
from figure 8.4-3,
hL = 217 btu/Ibm (505 kJ/kg)
Example 8.4-3 V = 2722 kg/h T1=89.5oC
HV
F= 4536 kg/h hF = 214 kJ/kg
P1= 11.7 kPa
xF = 0.2 kg NaOH/kg
T1=89.5oC
S S
(Tsat. = 48.9oC)
TS= 115.6oC TS, hS
NaOH
= 2214.87 kJ/kg
L = 1814 kg/h hL=505 kJ/kg
xL = 0.5 kg NaOH/kg hL
Given : U = 1560 W/m2.K
BPR = T1- Tsat = (89.5 – 48.9)oC = 40.6oC
Tsat.= 48.9oC , Hsat. vapour = 2590 kJ/kg
Energy balance: FhF + S(HS – hS) = LhL + VHV
4536(214) + S(2214.87) = 1814(505) + 2722HV
HV = 2590 + 1.884(40.6)= 2667 kJ/kg
4536(214) + S(2214.87) = 1814(505) + 2722(2667)
S = 3255 kg/h
Example 8.4-3 V = 2722 kg/h T1=89.5oC
HV = 2667 kJ/kg
F= 4536 kg/h hF = 214 kJ/kg
P1= 11.7 kPa
xF = 0.2 kg NaOH/kg
T1=89.5oC
S = 3255 kg/h S
NaOH
TS= 115.6oC TS, hS
= 2214.87 kJ/kg
L = 1814 kg/h hL=505 kJ/kg
xL = 0.5 kg NaOH/kg hL
Given : U = 1560 W/m2.K
steam, Ts
TS1 TS2 TS3
L1, T1 L2 , T2 L3 T3
• fresh feed and withdrawal conc. prod. at each effect
• vapour from 1st effect as heating medium for 2nd effect
• almost saturated feed
• solid crystals as product
Triple-effect forward feed evaporators
Assumptions:
• latent heat of condensing steam = latent heat of vapour
• areas in all effects are equal (A1=A2=A3)
• q1 = U1A1T1
• q1 = SS 1
•T1= TS1-T1
•T1= ∑T 1/U1
1/U1 + 1/U2 +1/U3
•T2= TS2-T2
Determine:
1. T3 & BPR3
2. L3 & V1+V2+V3. Assume V1=V2=V3
3. L1,L2,x1 & x2
4. BPR1 & BPR2
5. ∑T, T1, T2 & T3. Readjust if necessary
6. T1, TS1, T2, TS2, T3 & TS3
7. cP, enthalpies, L1, L2,V1 ,V2 ,V3 & S
8. Compare ans. from step7 with ans. from steps 2 & 3. If errors 10%, redo step 3.
9. If errors 10%, calculate q1, q2 , q3 , A1, A2, A3 & Aave. If errors 10%, revise Ts.
Example Ps3 = 9 kPa
F = 22680 kg/h
xF = 0.12
TF = 93oC
Ps1 = 170 kPa
L2 = 4536 kg/h
Total balance: 22680 = (V1+V2) +4536 x2 = 0.6
(V1+V2) = 18 144 kg/h
Assume V1=V2 V1=V2 = 18 144 /2 = 9072 kg/h
Effect 1: Total balance: F = 22680 = V1 +L1
22680 = 9072 +L1
L1 = 13 608 kg/h
Solid balance: FxF = L1x1
22680(0.12) = 13 608x1
x1 = 0.2
Effect 2: Total balance: L1 = V2 +L2 13608 = 9072 +4536 √
V1 = 9072 kg/h V2 = 9072 kg/h
T s3 = 43.66oC
F = 22680 kg/h
xF = 0.12 = 47.52oC
TF = 93oC BPR2 = 3.858oC
Ps1 = 170 kPa
U1 = 2271 W/m2.K
L1 = 13608 kg/h
L2 = 4536 kg/h
U2 = 1420 W/m2.K x1 = 0.2 x2 = 0.6
BPR = 0.63 - 3.62x + 15x2
BPR1 = 0.63 - 3.62(0.2) + 15(0.2)2 = 0.506oC
At 170 kPa, T s = 115oC
∑T= TS1-TS3-(BPR1+ BPR2) = 115 – 43.66 –(3.858 + 0.506) = 66.976oC
T1= ∑T 1/U1 1/2271
= 66.976 = 25.767oC
1/U1 + 1/U2 1/2271 + 1/1420
T1= TS1-T1 25.767 = 115 -T1 T1 = 89.233oC
L1 = 0.1 kg/s
L2 = 0.3167 kg/s (% error = 5.3) S = 0.2933 kg/s
V1 = 0.2167 kg/s(% error = 7.7 ) V2 = 0.1833 kg/s (% error = 9.1)
Given: U1 = 2.0 kW/m2.K, U2 = 1.7 kW/m2.K
q1 = SS1 = U1A1T1 = U1A1(Ts1 - T1)
q1 = SS1 = (0.2933)(2135.82) = 626.436 = 2(A1)( 142.96 - 102.69)
A1 = 7.778 m2
q2 = V1S2 = U2A2T2 = U2A2(Ts2 - T2)
q2 = V1S2 = (0.2167)(2249.84) = 1.7(A2)( 51)
A2 = 5.623 m2 Aave. = Am = 6.7005 m2
V1= 0.2167 kg/s V2= 0.1833 kg/s
L1 = 0.1 kg/s
L1 = 0.1 kg/s
Aave. = Am = 6.7005 m2 A1 = 7.778 m2 A2 =5.623 m2
∑T= TS1-TS3 = 142.96 – 51.69 = 91.27oC
T1A1 (40.27)7.778
T1’ = = = 46.75oC
Am 6.7005
T2’= ΔT-ΔT1 = 91.27 – 46.75 = 44.52oC
T2’= TS2-T2 = TS2-51.69 = 44.52
TS2 = 96.21oC = T1
TS2=96.21 oC ,HS2 = 2670.04 kJ/kg & hS2 = 403.06 kJ/kg.
S2 = (2670.04 - 403.06) = 2266.98 kJ/kg
V1= 0.2167 kg/s V2= 0.1833 kg/s
L1 = 0.1 kg/s
Tref. = 0oC (liquid solution),
S2 = 2266.98 kJ/kg hF = 112.86 kJ/kg h2 = 216.06 kJ/kg
h1 = cP1(T1 – Tref.) = 4.18(96.21 – 0) =402.16 kJ/kg
H1 = HS2 = 2670.04 kJ/kg
H2 = HS3 = 2595.07 kJ/kg
Effect 2: Energy balance: FhF + V1 S2 = L2h2 + V2H2
Material balance: V2 = F - L2 = 0.5 - L2
0.5(112.86) + (L2- 0.1)(2266.98) = L2(216.06) + (0.5-L2)2595.07
L2 = 0.316 kg/s
V1= 0.2167 kg/s V2= 0.1833 kg/s
L1 = 0.1 kg/s
Tref. = 0oC , liquid solution (same as steam table),
hF = 112.86 kJ/kg h1 = 402.16 kJ/kg h2= 216.06 kJ/kg
= 2135.82 kJ/kg S2 = 2266.98 kJ/kg H1 = 2670.04 kJ/kg H2= 2595.07 kJ/kg
S1
L1 = 0.1 kg/s
Given: U1 = 2.0 kW/m2.K, U2 = 1.7 kW/m2.K
L2 = 0.316 kg/s (% error = 0.2), S = 0.257 kg/s, V1 = 0.216 kg/s(% error = 0.32),
V2 = 0.184 kg/s (% error = 0.38),
q1 = SS1 = U1A1T1’
q1 = SS1 = (0.257)(2135.82) = 2(A1)( 46.75)
A1 = 5.871 m2
q2 = V1S2 = U2A2T2’
q2 = V1S2 = (0.216)(2266.98) = 1.7(A2)( 44.52)
A2 = 6.47 m2 A1 = 5.871 m2 (% error = 5.1)
Aave. = Am = 6.1705 m2
A2 =6.47 m2 (% error = 4.86)
Example 8.5-1
T3 =
54.12oC
2. Assume V1=V2=V3
Total balance: 22680 = (V1+V2+V3) +4536
(V1+V2+V3) = 18 144 kg/h
V1=V2=V3 = 18 144 /3 = 6048 kg/h
3. L1,L2,x1 & x2
Effect 1:
T3 =
54.12oC
L1 = 16 632 x1 =
Effect 2: 0.136
Total balance: L1 = 16 632= V2 +L2
16 632 = 6048 +L2
L2 = 10 584 kg/h
Sugar balance: L1x1 = L2x2
16 632(0.136) = 10 584x2
x2 = 0.214
Effect 3 (checking) :
Total balance: L2 = 10 584= V3 +L3 Sugar balance: L2x2 = L3x3
10 584 = 6048 +L3 10584(0.214) = 4536 x3
L3 = 4536 kg/h x3 = 0.5
Example 8.5-1
TS
4
T1 T2 Tsat.=
51.67 o
T3 = C=TS4
54.12oC
TS1=121.1oC
TS
4
A = 104.4 m2