110 West Beaver Creek Road, Richmond Hill,

Ontario, L4B 1J9 CANADA

101 Glasgow Street, Kitchener, Ontario, N2G 4X8
Tel: 905-707-3433 · Fax: 905-707-3433
Email: karen@sunboss.ca

Safety Data Sheet

TMTD
1. IDENTIFICATION OF SUBSTANCE / COMPANY INFORMATION

Chemical Name Tetramethyl thiuram disulfide

Synonyms Accelerator TMTD, THIURAD, THIRAM,Bis(dimethyldithiocarbamoy) disulfide
CAS # 137-26-8
Formula C6H12N2S4
Chemical Family Accelerator
Supplier SunBoss Chemicals Corp.
Address 8-110 West Beaver Creek Road
Richmond Hill, ON L4B 1J9
Telephone 905-707-3433
Fax 905-707-7393
Emergency Information After normal hours call Chemtrec at 1-800-424-9300

2. COMPOSITION / INFORMATION ON INGREDIENTS

Component CAS - No Weight % UN No.

Tetramethylthiuram Disulfide 137-26-8 > 97 205-286-2
Ethoxylated Alcohols [-3mm-grs ONLY] 68439-50-9 ≤2 500-213-3
White Mineral Oil (powder only) 8042-47-5 1-2 232-455-8

Symbol(s) Risk Phrase(s)

Xn, N R20/22, R36/37/38,
R48/22, R51/53

3. HEALTH HAZARDS INFORMATION

EMERGENCY OVERVIEW
Signal Word: WARNING!
Harmful by inhalation and if swallowed!
Inhalation and ingestion may cause alcohol intolerance (Antabuse Effect).
Irritating to eyes, respiratory system and skin.
Harmful: danger of serious damage to health by prolonged exposure if swallowed.
Toxic to aquatic organisms may cause long-term adverse effects in the aquatic environment.

Potential Health Effects

Inhalation Exposure to dust particles generated from this material may cause irritation of
the respiratory tract. Inhalation may cause alcohol intolerance.
 Ingestion May cause alcohol intolerance (Antabuse Effect). May cause headache,
dizziness, nausea, vomiting and gastrointestinal irritation.

Skin contact May cause an allergic skin reaction. May be absorbed through the skin and
produce effects similar to those caused by inhalation and/or ingestion.

Eye Contact Causes mild eye irritation. Signs/symptoms can include redness, swelling,
pain and tearing.

4. EMERGENCY FIRST AID PROCEDURES

Inhalation Remove person to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, get immediate attention.

Ingestion If swallowed, call a physician immediately. Only induce vomiting at the

instruction of a physician. Never give anything by mouth to an unconscious
person.

Skin Immediately flush skin with plenty of water and soap for at least 15 minutes
and get medical attention if irritation persists. Remove contaminated clothing
and launder before reuse.

Eyes Immediately flush with plenty of water for at least 15 minutes and get medical
attention if irritation persists.

Note to Physician Treat symptomatically. Exposure by ingestion, inhalation or skin absorption

may cause alcohol intolerance (Antabuse Effect).

5. FIRE AND EXPLOSION HAZARD MEASURES

Flammability Not determined

Flash Point 280°F / 138°C

Flash Point Method Pensky-Martens Open Cup

DOT Category RQ, UN 3077, Environmentally Hazardous Substance, Solid, N.O.S.,

(Tetramethylthiruam Disulfide), 9, III

Extinguishing Media Use water fog, carbon dioxide, foam or dry chemical.

Auto Ignition Temperature Not determined

Flammable Limits Not determined

Special Fire Fighting Procedures Fight fire from a safe distance and from a protected location. Use water spray
to cool fire exposed surfaces. Decomposition in fire may produce toxic gases.
Do not allow runoff to enter waterways.

Special Protective Equipment Full protective clothing and approved self-contained breathing apparatus
required for fire- fighting personnel

Unusual Fire and Explosion Hazards Toxic emissions may result if product is involved in a fire.

Sunboss Chemicals Corp. / MSDS for TMTD Page 2

 6. ACCIDENTAL RELEASE MEASURES

Procedures Isolate the area. Turn off/remove all potential sources of ignition. Work only
with non-sparking tools and equipment. Wear gloves.

Clean up Methods Scoop up and remove solids. Place spilled material in a closable container
for hazardous waste disposal. Do NOT spread spilled product with water.

7. HANDLING AND STORAGE

Handling Avoid contact with eyes, skin and clothing. Avoid generation of breathing
dust. Wash thoroughly with soap and water after handling. Wash hands
before eating, drinking, chewing of gum, using tobacco or using the toilet.
Reclose containers of unused product. Keep containers tightly closed when
not in use. Do not reuse this container.

Storage Store closed containers in a cool, dry, well-ventilated area. Store away from
strong oxidizing materials. Avoid exposure to direct sunlight.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering Controls Avoid dust generation. Ensure good ventilation and local exhaustion of the
working area as necessary to control any air contaminants to within their
exposure limits. Eliminate ignition sources.

Exposure Limits ACGIH (TWA) OSHA (TWA)

Tetramethyl thiruam Disulfide 1 mg/m3 (total dust) 5 mg/m3 (8H OEL)
White Mineral Oil 5 mg/m3 5 mg/m3

Respiratory Use in a well-ventilated area. Use approved NIOSH respiratory protection if

TLV exceeded or if overexposure is likely. Appropriate respiratory protection
shall be worn when applied engineering controls are not adequate to protect
against inhalation exposure.

Eyes Wear safety glasses or goggles to protect against exposure.

Skin Normal work coveralls. Launder contaminated clothing before reuse.

Gloves Use gloves as a standard industrial handling procedure. Appropriate chemical

resistant gloves should be worn.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance White powder or granules

Odour Very slight

Specific Gravity 143 kg/m³ @ 20°C

Sunboss Chemicals Corp. / MSDS for TMTD Page 3

 Density 1.29 g/cm³

Bulk Density 1425 kg/m³ @ 20°C

Solubility in water INSOLUBLE

pH Not applicable

Other Solubility Soluble in chloroform, acetone and benzene - slightly soluble in carbon
tetrachloride and ethyl alcohol

Boiling point Not determined

Melting Point 142°C min

Molecular Weight 240.41

Molecular Formula C6H12N2S4

10. STABILITY AND REACTIVITY

Chemical Stability This material is stable when stored at room temperature in closed, original
container. Stable under normal conditions of handling, use and
transportation.

Conditions to avoid Keep away from heat, sparks, flame and exposure to heat and humidity.

Incompatibility Avoid contact with acidic, basic or oxidizing agents.

Hazardous Polymerization Will not occur

Hazardous Decomposition Products Carbon monoxide, Oxides of nitrogen and sulphur.

Additional Guidelines None

11. TOXICOLOGICAL INFORMATION

Acute oral LD 50 (mg/kg) 1080 mg/kg - Rat

Acute Dermal LD 50 (mg/kg) >7940 mg/kg - Rabbit

Acute Inhalation LC50 (mg/l) 500 mg/m3 - Rat

Principle routes of Exposure Dermal - skin. Inhalation.

Ingestion May cause alcohol intolerance (Antabuse Effect). May cause headache,
dizziness, nausea, vomiting and gastrointestinal irritation.

Skin contact May cause an allergic skin reaction. May be absorbed through the skin and
product effects similar to those caused by inhalation and/or ingestion.

Inhalation Exposure to dust particles generated from this material may cause irritation of
the respiratory tract. Inhalation may cause alcohol intolerance

Eye Contact Causes mild eye irritation. Signs/symptoms can include redness, swelling,
pain and tearing.

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 Aggravated Conditions Alcohol consumption problems. Dermal ailments.

Carcinogenicity Both negative and positive results have been found in standard tests using
bacteria. Negative, positive and equivocal results in have been found in
standard in vitro and in vivo tests using animals, animal and bacterial cells.
This product or one of its ingredients present at 0.1% or more, is NOT listed
as a carcinogen or suspected carcinogen by NTP, IARC or OSHA.

Primary Irritation Effect Practically non-irritating to skin and eyes. Probable skin sensitizer.

Genotoxicity Both positive and negative effects have been reported in standard tests using
animals and animal cells.

Reproductive/Developmental Toxicity Animal studies have shown some adverse effects - low birth weight of pups,
maternal toxicity - on female animals. Chronic animal studies have shown this
material to cause reproductive effects, blood effects and organ weight
changes. Some animal studies have shown adverse effects on fetal
development.

12. ECOLOGICAL INFORMATION

Acute Fish Toxicity 96Hr LC50 Rainbow Trout 0.13 mg/l

96Hr LC50 Bluegill Sunfish 0.13 mg/l
96Hr LC50 Guppy 0.27 mg/l

Acute Crustacean Toxicity 48Hr LC50 Daphnia Magna 0.21 mg/l

Octonal/Water Coefficient 1.82 log P

Chemical Fate Information Hydrolysis Half-life: 9.5 hrs @ pH 3.5 108 hrs @ pH 5.7 1123 hrs @ pH 7.0
3316 hrs @ pH 8.0

Other Information Tests indicate this material will not bio-accumulate or persist in the
environment.

13. DISPOSAL CONSIDERATIONS

Waste Disposal This product, if disposed as received, is a listed hazardous waste. Bury in a
licensed landfill or burn in an approved incinerator according to federal, state
and local regulations. Treatment, storage, reuse and disposal of the waste
material must conform to all applicable federal, state and local laws and
regulations.

Contaminated Packaging This bag may contain residue of a hazardous material. Some authorities may
regulate such containers as hazardous waste. Dispose of container according
to national or local regulations.

Sunboss Chemicals Corp. / MSDS for TMTD Page 5

 14. TRANSPORT INFORMATION

DOT

UN/IN No. 3077

Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.,
(Tetramethy lthiruam Disulfide)
Hazard Class 9
Packing Group III
Reportable Quantity (RQ) 10 lbs
Note: The (RQ) for this product is 10 lbs. Any package containing 10 lbs or more, must be labelled, marked and
shipped as hazardous material. Single packages under 10 lbs are considered non-hazardous for transport.

IATA

UN/IN No. 3077

Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.,
(Tetramethy lthiruam Disulfide)
Hazard Class 9
Packing Group III
Special Markings Symbol (fish and tree)
Note: EFFECTIVE 01/01/2009: Subject to ICAO/IATA ENVIRONMENTALLY
HAZARDOUS SUBSTANCE marking requirement [IATA 7.1.6.3] Passengers:
Packaging instruction 911 (No restricted quantity by package),
Cargo: Packaging instruction 911 (No restricted quantity by package)

IMDG

UN/IN No. 3077

Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.,
(Tetramethy lthiruam Disulfide)
Hazard Class 9
Packing Group III
Marine Pollutant Yes
Special Markings: Symbol (fish and tree)

TDG (Canada) See DOT

Sunboss Chemicals Corp. / MSDS for TMTD Page 6

 15. REGULATORY INFORMATION

LABELLING ACCORDING TO DIR 67/548 EEC

EC Number: 205-286-2
Classification based on: TESTS

HARMFUL (Xn) DANGEROUS FOR THE ENVIRONMENT (N)

CLASSIFIED ACCORDING TO DIRECTIVE 199/45/EC

Risk Phrases: R20/22 - Harmful by inhalation and if swallowed.

R36/37/38 – Irritating to skin, eyes and respiratory system.
R48/22 – Harmful: danger of serious damage to health by prolonged
exposure if swallowed.
R50/53 – Very toxic to aquatic organisms, may cause long term adverse
effects in the aquatic environment.

Safety Phrases: S24/25 – Avoid contact with skin and eyes.

S26 – In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36/37 – Wear suitable protective clothing and gloves.
S60 – This material and its container must be disposed of as a hazardous
waste.
S61 – Avoid release to the environment. Refer to Special Instructions/Safety
Data Sheet.

FDA Status 21 CFR TMTD is regulated for use under the following sections of FDA 21 CFR:
175.105 - Components of adhesives.
177.2600 - Rubber articles intended for repeated use in food contact.

TSCA Listed

Canadian DSL Listed

EINECS/ELINCS Listed

US Regulations
SARA Section 302 Not Applicable/None
SARA 311/312 Hazard Categories Immediate Delayed
SARA 313 Chemical Listed as “Thiram”
RCRA Status RCRA Hazardous Waste U244 (Reportable Quantity is 10 lbs (40 CFR 302))

Canadian Regulations
WHMIS Hazard Class

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 D2A VERY TOXIC MATERIALS; D2B TOXIC MATERIALS/Materials Causing
Other Toxic Effects

NPRI Not Listed [Canada]

16. HAZARD RATING SYSTEM

NFPA Rating (Scale 0-4)

HEALTH 2
0 - Minimal Hazard
1 - Slight Hazard FIRE 1
2 - Moderate Hazard
3 - Serious Hazard
REACTIVITY 0
4 - Severe Hazard

HMIS Classification (Scale 0-4)

HEALTH 2
0 - Minimal Hazard
1 - Slight Hazard FIRE 1
2 - Moderate Hazard
3 - Serious Hazard
REACTIVITY 0
4 - Severe Hazard

17. OTHER INFORMATION

Although reasonable precautions have been taken in the preparation of the data contained herein, it is offered solely for
your information, consideration and investigation. SunBoss Chemicals Corp. extends no warranty and assumes no
responsibility for the accuracy or sufficiency of the content and expressly disclaims all liability for reliance thereon. This
material safety data sheet provides guidelines for the safe handling of this product; it does not and cannot advise on all
possible situations, therefore, your specific use of this product should be evaluated to determine if additional
precautions are required. It is the responsibility of the user to comply with all Federal, State and local laws and
regulations. Individuals exposed to this product should read and understand this information and be provided pertinent
training prior to working with this product.

Abbreviations and Acronyms

ACGIH: American Conference of Governmental Industrial Hygienists Inc.
CAS: Chemical Abstracts Service (Division of American Chemical Society)
DOT: Department of Transportation (USA)
EINECS: European Inventory of Existing Commercial Chemical Substances
HMIS: Hazardous Materials Identification System (USA)
IARC: Internal Agency for Research on Cancer
IATA: International Air Transport Association
IMDG: International Marine Code for Dangerous Goods
LD50: Lethal Dose Medium
LC50: Lethal Concentration Medium
EC50: Effective Concentration Medium
NIOSH: National Institute for Occupational Safety and Health
NFPA: National Fire Protection Association (USA)
NPRI: National Pollutant Release Inventory (Canada)
NTP: National Toxicology Program
OSHA: Occupational Safety and Health Administration (USA)
TDG: Transportation of Dangerous Goods (Canada)
TLV: Threshold Limit Value
TWA: Time Weighted Average
WHMIS: Workplace Hazardous Materials Information Systems (Canada)

Sunboss Chemicals Corp. / MSDS for TMTD Page 8

 18. REVISION DATE

Revision number: 5
Date of Issue: September 3, 2014
Changes: Number and format of headings changed; Updates to Sections 1: Identification of Substance - EC
information added; 2: Health Hazards Information; 8: Specific Personal Protection Equipment - pictograms added; 14:
Transport information - pictograms added; 15: Regulatory information - EC information added; 16: Hazard Rating
System - table added; 17: Abbreviations and Acronyms added

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