CHEM 2200 CH 1 Worksheet Lewis Structures

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CHAPTER 1- WORSHEET

Guidelines for drawing simple Lewis dot formulas (electron dot formulas):

(1) Calculate the total number of valence electrons


(2) Draw a skeletal structure using single bonds to connect atoms to a central atom (least electronegative
atom)
(3) Deduct one pair of valence electrons (2e- total) for each single bond drawn in Step #1, then use the
remaining pairs to complete octets for the other atoms
(4) If there are not enough electrons to complete an octet for each atom, because the molecule is short 2
e-, then move a nonbonding electron pair (an unshared pair) between two atoms that already share an
electron pair to create a double bond. If the molecule is short 4 e-, then move nonbonding pairs to
create either two double bonds or one triple bond.
(5) Check your work. Make sure all atom have 8 electrons (except for Hydrogen) Octet Rule.

Example 1: Draw the Lewis dot structure formula and build the molecular model of sulfur trioxide, SO3.
(1) Calculate the total number of valence electrons.
(2) Draw a skeletal structure with a central S atom.
(3) Deduct a pair of electrons for each of the single bonds drawn in Step #1. Use the remaining pairs to
complete octets for each of the other atoms.
(4) If there are not enough electrons to provide an octet for each atom, move a nonbonding (unshared)
electron pair between two atoms that already share an electron pair.
(5) Check your work. [Hint: Did you need a double bond?]

# of
Molecule Lewis Structure
valence e-

6 + 3(6)
SO3 = 24e-

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CHEM 2200-Spring2020
Name _________________________
Recitation M / W

CH 1- WORKSHEET – Lewis Structures

Part A – Molecules with single bonds

# of Polar or
Electronic group Molecular Geometry (drawing
Molecule valence Lewis Structure Nonpolar (P or
geometry (name) and name)
e- NP)

2(1) +
H2 O 6 = 8e-
Tetrahedral P

Bent

CH2Cl2

HOOH

Part B – Molecules with double bonds

Electronic group Polar or


# of Shape of the molecule
Molecule Lewis Structure geometry Nonpolar (P or
valence e- (drawing and name)
(name) NP)

6 + 3(6) Trigonal
SO3 = 24e- planar
NP

trigonal planar

O3

C2H4

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CHEM 2200-Spring2020
HONO

SO2

Part C – Molecules with triple bonds

Polar or
# of Electronic group Shape of the molecule
Molecule Lewis Structure Nonpolar
valence e- geometry (name) (drawing and name)
(P or NP)

1+4+
HCN 5 = 10e-
Linear P
Linear

N2

HOCN

Part D – Molecules with two double bonds

Polar or
# of Electronic group Shape of the molecule
Molecule Lewis Structure Nonpolar
valence e- geometry (name) (drawing and name)
(P or NP)

4+
CO2 2(6) = Linear NP
16e-
Linear

CH2CCH2

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CHEM 2200-Spring2020

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