SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY

UNDERTAKING
Trade name ARMOHIB 28
Chemical description/Application Corrosion inhibitor.

Supplier Akzo Nobel Surface Chemistry AB

SE 444 85 Stenungsund
SWEDEN
Tel: +46 303 850 00
Fax: +46 303 813 06
Emergency telephone + 31 570679211 (Fax. +31 570679801)
Akzo Nobel Chemicals, Deventer, NL

2. COMPOSITION/INFORMATION ON INGREDIENTS

This product is to be considered as a preparation according to EU-legislation.

Substance name EU number CAS number Concentration Symbols Risk phrases
Tallowalkylamine ethoxylate 68213-26-3 35-45 % Xn R-22, 52/53
propoxylate
Formaldehyde, reaction products 295-051-0 91782-77-3 30-40 % C R-22, 34
with oleylamine
Prop-2-yn-1-ol 203-471-2 107-19-7 2-10 % T ,N R-10, 23/24/25,
34, 51/53
Butan-1-ol 200-751-6 71-36-3 5-10 % Xn R-10, 22, 37/38,
41, 67
Acetic acid 200-580-7 64-19-7 5-10 % C R-10, 35
Formaldehyde 200-001-8 50-00-0 <1 % T R-23/24/25, 34,
40, 43, 40
Water 231-791-2 7732-18-5 1-3 % -

Other information All components are registered in EINECS. For explanation of riskphrases, see section 16.

3. HAZARDS IDENTIFICATION

Flammable. Corrosive. Harmful.

Above the flash point an explosive mixture can be formed. Causes burns. Harmful by
inhalation, in contact with skin and if swallowed. May cause sensitisation by skin contact.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.

4. FIRST AID MEASURES

General Get medical attention.

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Inhalation Provide fresh air, warmth and rest, preferably in a comfortable upright sitting position. If
breathing stops, provide artificial respiration. Obtain medical attention.
Skin Remove contaminated clothing. Wash the skin with soap and water. Seek medical advice
if symptoms appears.
Eyes In case of contact with eyes, rinse immediately with 0.5% acetic acid in water for a few
minutes, followed by rinsing with plenty of water for as long as possible. Eyelids should be
held away from the eyeball to ensure thorough rinsing. Get medical attention immediately.
Continue to rinse during transport.
Ingestion Only when conscious, rinse mouth, give plenty of water to drink (approx. 500 ml). Obtain
medical attention immediately.

5. FIRE FIGHTING MEASURES

Extinguishing media Water spray, fog or mist, alcohol resistant foam, powder, carbon dioxide.

Unsuitable extinguishing media Waterjet, foam.

Special fire fighting procedures Treat as an oil fire. Water spray may be ineffective unless used by experienced fire
fighters. Wear self contained breathing apparatus.
Unusual fire hazards Above the flash point an explosive mixture can be formed. If involved in a fire it will support
combustion and may decompose to give off toxic materials. In case of fire and/or explosion
do not breathe fumes.
Hazardous combustion products No typical hazardous decomposition products known.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions For personal protection see Section 8.

Environmental precautions Should not be allowed to enter drains or water courses. Dispose of this material and its
container at hazardous or special waste collection point.
Methods for cleaning up Contain spill with inert material. Place in container for disposal according to local
regulations. Cover the remainder with inert absorbent (e.g. vermiculite) for disposal. In
case of large spillages contact the local authority.

7. HANDLING AND STORAGE

Handling The usual precautions for flammable liquids should be observed. When using do not eat,
drink or smoke. Avoid spilling, skin and eye contact. No sparking tools should be used.
Storage The usual precautions for flammable liquids should be observed. Keep away from heat,
sparks and open flame. No smoking. Keep container tightly closed in a cool,
well-ventilated place. For further information see product information sheet.
Other information Do not use with concentrated hydrochloric acid.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limits
Ingredient name Exposure limit 8 Short term References
hours exposure
Prop-2-yn-1-ol 1 ppm 3 ppm OEL,s
Butan-1-ol 50 ppm OEL,s
Formaldehyde 2 ppm 2 ppm OEL,s
Acetic acid 10 ppm 15 ppm OEL,s
Comments OELs = EH40/2002 Occupational Exposure Limits 2002.
Comments OELs = EH40/2002 Occupational Exposure Limits 2002.

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Comments OELs = EH40/2002 Occupational Exposure Limits 2002.
Comments OELs = EH40/2002 Occupational Exposure Limits 2002.

Engineering controls Provide eyewash station. Provide shower facilities near the work place. Mechanical
ventilation or local exhaust ventilation may be required. Keep solutions of 0.5% acetic acid
in water at hand.
Personal protection

Respiratory If ventilation is insufficient, suitable respiratory protection must be provided. Wear full face
mask supplied with: Combination filter ABEKP.

Hand Use protective gloves made of: Neoprene or nitrile.

Eyes Wear tightly fitting safety goggles.

Skin and body Use suitable protective clothing as protection against splashing or contamination.
Dry-clean contaminated clothes before reuse.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Liquid.

Colour Brown.

Odour Mild, fatty, sweet.

Boiling point/range (ºC) 100 Pressure (kPa)

Melting point/range (ºC) *< -10

Flash point (ºC) 47 Method

Autoignition temperature (ºC) 440

Density (kg/m3) 1024 Temperature (°C) 15

Viscosity 116 mPas Temperature (°C) 5

Solubility in water Soluble.

Other physical data * Pour point.

(These data are typical for the product and not a specification)

10. STABILITY AND REACTIVITY

Stability Avoid elevated temperatures. Stable under recommended storage and handling
conditions (see section 7).
Hazardous decomposition No typical hazardous decomposition products known.
products

11. TOXICOLOGICAL INFORMATION

Toxicological data

Acute toxicity. LD50. oral Rat. 950 mg/kg

Health effects

Respiratory The inhalation of aerosols may cause irritation of the respiratory tract. Contains solvent.
Emits vapours during heating. High concentrations may cause stupor, dizziness, nausea,
vomiting.
Skin Causes burns. May cause transient redness and pain. Harmful in contact with skin.
Repeated contact may cause skin sensitization.

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Eyes Causes burns. Risk of serious and permanent damage to eye.

Ingestion Causes burns. Harmful if swallowed.

Component Prop-2-yn-1-ol

Toxicological data LD50. oral Rat. 50-70 mg/kg

LD50. dermal Rabbit. 88 mg/kg

LC50. 2 hours. Inhalation. Rat. 850 ppm

LC50. 2 hours. Inhalation. Mouse. 2000 mg/m3

12. ECOLOGICAL INFORMATION

Ecotoxicological data

Ecotoxicology The product contains a substance considered harmful to aquatic organisms.

Degradation The product is considered not readily biodegradable. Primary biodegradation > 90%.

Component Tallowalkylamine ethoxylate propoxylate

Ecotoxicological data LC50 96 hours fish 10-100 mg/l ¹)

EC50 48 hours Daphnia 10-100 mg/l ¹)

Ecotoxicology Harmful to aquatic organisms.

Degradation Inherently biodegradable. Not readily biodegradable. <70% DOC, 28 days, Modified
OECD Screening Test (OECD 301E). (The data are estimated from tests on similar
products.)
Other information ¹) The data are estimated from tests on similar products.

Component Prop-2-yn-1-ol

Ecotoxicological data LC50 96 hours Pimapheles promelas (fish) 1,53 mg/l

Ecotoxicology Toxic to aquatic organisms.

Partition coefficient (log -0,38

Pow)

13. DISPOSAL CONSIDERATIONS

Disposal methods Incineration is recommended. Dispose of in accordance with local authority requirements.
Nitrous gases may be formed by incineration.

14. TRANSPORT INFORMATION

Proper shipping name FLAMMABLE LIQUID, CORROSIVE, N.O.S.(Butanol/amine derivate)

Land transport

UN number 2924 RID-class 3

ADR class 3 RID packing group III

ADR packing group III

Classification code FC

CEFIC number 30GFC-III Tremcard internal code 380

Sea transport

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UN number 2924

IMDG class 3(8) EmS F-E, S-C

IMDG packing group III Marine pollutant No.

Air transport

UN number 2924 Subsidary risk 8

IATA/ICAO class 3 Packing group III

15. REGULATORY INFORMATION

Substance name Tallowalkylamine ethoxylate propoxylate

Formaldehyde, reaction products with oleylamine

Prop-2-yn-1-ol

Formaldehyde

Symbols

Risk phrases R-10 Flammable.

R-34 Causes burns.
R-20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R-43 May cause sensitisation by skin contact.
R-52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety phrases S-25 Avoid contact with eyes.
S-24 Avoid contact with skin.
S-26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S-28 After contact with skin, wash immediately with plenty of 0.5% acetic acid in water,
followed by washing with soap and water.
S-36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S-45 In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).
S-57 Use appropriate containment to avoid environmental contamination.
EU directive Safety Data Sheet according to EC-directive 2001/58/EC

Water hazard classification WGK: 2 (Germany).

16. OTHER INFORMATION

This information only concerns the above mentioned product as supplied and may not be valid if used with other product(s) or in any process. It
remains the user´s own responsibility to make sure that the information is appropriate and complete for his special use of this product.

Important changes were made in 3,11,14,15

section
Composed by Kristina Sterky

Eva Cassel
Explanations to R-phrases in R-22 Harmful if swallowed. R-52/53 Harmful to aquatic organisms, may cause long-term
section 2 adverse effects in the aquatic environment.R-34 Causes burns.R-10
Flammable.R-23/24/25 Toxic by inhalation, in contact with skin and if swallowed.R-51/53
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

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environment.R-37/38 Irritating to respiratory system and skin.R-41 Risk of serious damage
to eye.R-67 Vapours may cause drowsiness and dizziness.R-35 Causes severe
burns.R-40 Limited evidence of a carcinogenic effect.R-43 May cause sensitisation by
skin contact.R-40 Limited evidence of a carcinogenic effect.
Date of major revision 2006-03-24

Date of printing 2006-08-10

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