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    Aldian Ghani Rahman
    This document summarizes boundary work for polytropic processes of gases in a closed system where mass is constant. It defines polytropic processes where PV^n is constant for different values of n, including isobaric (n=0), isothermal (n=1), and isochoric (n=infinity) processes. It provides equations to calculate the work done during these processes in terms of initial and final pressure, volume, and temperature.

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    15 PDF

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    Aldian Ghani Rahman
    25 views1 page
    This document summarizes boundary work for polytropic processes of gases in a closed system where mass is constant. It defines polytropic processes where PV^n is constant for different values of n, including isobaric (n=0), isothermal (n=1), and isochoric (n=infinity) processes. It provides equations to calculate the work done during these processes in terms of initial and final pressure, volume, and temperature.

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    This document summarizes boundary work for polytropic processes of gases in a closed system where mass is constant. It defines polytropic processes where PV^n is constant for different values of n, including isobaric (n=0), isothermal (n=1), and isochoric (n=infinity) processes. It provides equations to calculate the work done during these processes in terms of initial and final pressure, volume, and temperature.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    25 views1 page

    15 PDF

    Uploaded by

    Aldian Ghani Rahman
    This document summarizes boundary work for polytropic processes of gases in a closed system where mass is constant. It defines polytropic processes where PV^n is constant for different values of n, including isobaric (n=0), isothermal (n=1), and isochoric (n=infinity) processes. It provides equations to calculate the work done during these processes in terms of initial and final pressure, volume, and temperature.

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    4-1 BOUNDARY WORK FOR POLYTROPIC PROCESS OF GASES closed system, m=const

    P n n,C are constants


    PV
    1 1 = C
    ln P
    1 ⇒
    PV n = C n=0 P = const isobaric
    C ln P = −n ⋅ lnV + C n=1 ⇒ T = const isothermal ideal gas
    P=
    Vn n=k ⇒ s = const isentropic
    n
    PV = P V n n=∞ ⇒ v = const isochoric
    2 P2V2n = C 1 1 2 2
    lnV

    W
    V
    V1 V2

    2 2
    n≠1 PV n = C polytropic process W = ∫ PdV = C ∫ V − n dV
    1 1

    1
    =
    1− n
    ( CV21− n − CV11− n ) ⇐ C = P1V 1n = P2V 2n

    P2V2 − PV
    1 1
    W =
    1− n
    ( 4.9 )

    ideal gas 1
    1− n −1
    PV
    1 1 PV T2 P  n V 
    PV = mRT = 2 2 = 2  = 1 
    T1 T2 T1  P1   V2 
    PV
    1 1 = mRT1

    mR
    P2V2 = mRT2 W = (T2 − T1 ) ( 4.10 )
    1− n

    2
    C V
    n=1 PV = C process W =∫ dV = C ln 2
    1
    V V1

    P V2 V2 P1
    W = PV
    1 1 ln = P2V2 ln = PV
    2 2 ln ( 4.7 )
    PV
    1 1 = C V1 V1 P2
    1
    C
    P=
    V
    For ideal gas: PV = mRT = C ⇒ T = const (isothermal process)
    2
    P2V2 = C V2 P1
    W W = mRT ln = mRT ln PV
    1 1 = P2V2
    V1 P2
    V
    V1 V2

    n=0 P=C isobaric process (constant pressure process)

    W = P ⋅ (V2 − V1 ) = P ⋅ m ⋅ ( v2 − v1 ) ( 4.6 )
    1 2
    P = const
    W
    V
    V1 V2

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