Buffer Solution (Biphthalate), pH 4 10/1/10 1:11 PM

MSDS Number: B5627 * * * * * Effective Date: 09/02/09 * * * * * Supercedes: 03/14/07

Buffer Solution (Biphthalate), pH 4

1. Product Identification
Synonyms: None
CAS No.: 877-24-7
Molecular Weight: Not applicable to mixtures.
Chemical Formula: HOOC-C6H4COOK
Product Codes:
J.T. Baker: 5606
Mallinckrodt: 0029

2. Composition/Information on Ingredients

Ingredient CAS No Percent Hazardous

--------------------------------------- ------------ ------------ ---------

Potassium Acid Phthalate 877-24-7 1 - 2% Yes

Water 7732-18-5 98 - 99% No

3. Hazards Identification
Emergency Overview
--------------------------
CAUTION! MAY CAUSE IRRITATION TO SKIN AND EYES.

SAF-T-DATA (tm) Ratings (Provided here for your convenience)

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Health Rating: 1 - Slight
Flammability Rating: 0 - None
Reactivity Rating: 0 - None
Contact Rating: 2 - Moderate
Lab Protective Equip: GOGGLES; LAB COAT; PROPER GLOVES
Storage Color Code: Green (General Storage)
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---

Potential Health Effects

----------------------------------

Information on the human health effects from exposure to this substance is limited.

Inhalation:
Not expected to be an inhalation hazard. May cause irritation to respiratory tract because of
slight acidity. Symptoms may include coughing and sore throat.
Ingestion:
Large doses may produce nausea, vomiting, and abnormal sensations in hands and feet. Because
of slight acidity, causes irritation to the mucous membranes.
Skin Contact:
Contact may cause irritation, with redness and pain.

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Buffer Solution (Biphthalate), pH 4 10/1/10 1:11 PM

Eye Contact:
May cause eye irritation.
Chronic Exposure:
No information found.
Aggravation of Pre-existing Conditions:
No information found.

4. First Aid Measures

Inhalation:
Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
If large amounts were swallowed, give water to drink and get medical advice.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated
clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention if irritation develops.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Get medical attention if irritation persists.

5. Fire Fighting Measures

Fire:
Not expected to be a fire hazard.
Explosion:
No information found.
Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained
breathing apparatus with full facepiece operated in the pressure demand or other positive
pressure mode.

6. Accidental Release Measures

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in
Section 8. Contain and recover liquid when possible. Collect liquid in an appropriate container
or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical
waste container. Do not use combustible materials, such as saw dust.

7. Handling and Storage

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical
damage. Containers of this material may be hazardous when empty since they retain product
residues (vapors, liquid); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
None established.
Ventilation System:
In general, dilution ventilation is a satisfactory health hazard control for this substance.
However, if conditions of use create discomfort to the worker, a local exhaust system should be
considered.
Personal Respirators (NIOSH Approved):
Not expected to require personal respirator usage.
Skin Protection:
Wear protective gloves and clean body-covering clothing.
Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work
area.

9. Physical and Chemical Properties

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Buffer Solution (Biphthalate), pH 4 10/1/10 1:11 PM

Appearance:
Clear, colorless liquid.
Odor:
Odorless.
Solubility:
Complete (100%)
Specific Gravity:
No information found.
pH:
4
% Volatiles by volume @ 21C (70F):
ca. 99
Boiling Point:
No information found.
Melting Point:
No information found.
Vapor Density (Air=1):
Not applicable.
Vapor Pressure (mm Hg):
Not applicable.
Evaporation Rate (BuAc=1):
No information found.

10. Stability and Reactivity

Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Nitric Acid. Strong oxidizing agents.
Conditions to Avoid:
Heat, ignition sources and incompatibililites.

11. Toxicological Information

No LD50/LC50 information found relating to normal routes of occupational exposure.

--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Potassium Acid Phthalate (877-24-7) No No None
Water (7732-18-5) No No None

12. Ecological Information

Environmental Fate:
No information found.
Environmental Toxicity:
No information found.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and
approved waste disposal facility. Processing, use or contamination of this product may change
the waste management options. State and local disposal regulations may differ from federal
disposal regulations. Dispose of container and unused contents in accordance with federal, state
and local requirements.

14. Transport Information

Not regulated.

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Buffer Solution (Biphthalate), pH 4 10/1/10 1:11 PM

15. Regulatory Information

--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Potassium Acid Phthalate (877-24-7) Yes Yes Yes Yes
Water (7732-18-5) Yes Yes Yes Yes

--------\Chemical Inventory Status - Part 2\---------------------------------

--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Potassium Acid Phthalate (877-24-7) Yes Yes No Yes
Water (7732-18-5) Yes Yes No Yes

--------\Federal, State & International Regulations - Part 1\----------------

-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Potassium Acid Phthalate (877-24-7) No No No No
Water (7732-18-5) No No No No

--------\Federal, State & International Regulations - Part 2\----------------

-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Potassium Acid Phthalate (877-24-7) No No No
Water (7732-18-5) No No No

Chemical Weapons Convention: No TSCA 12(b): No CDTA: No

SARA 311/312: Acute: Yes Chronic: No Fire: No Pressure: No
Reactivity: No (Mixture / Liquid)

Australian Hazchem Code: None allocated.

Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all of the information required by the CPR.

16. Other Information

NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0
Label Hazard Warning:
CAUTION! MAY CAUSE IRRITATION TO SKIN AND EYES.
Label Precautions:
Avoid contact with eyes, skin and clothing.
Keep container closed.
Wash thoroughly after handling.
Label First Aid:
In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes.
Get medical attention if irritation develops or persists.
Product Use:
Laboratory Reagent.
Revision Information:
No Changes.
Disclaimer:
************************************************************************************************
Mallinckrodt Baker, Inc. provides the information contained herein in good faith but
makes no representation as to its comprehensiveness or accuracy. This document is
intended only as a guide to the appropriate precautionary handling of the material by a
properly trained person using this product. Individuals receiving the information must
exercise their independent judgment in determining its appropriateness for a particular
purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR
WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT
LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE
FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS
INFORMATION.
************************************************************************************************
Prepared by: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.)

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