Potassium Thiocyanate

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MSDS Number : 1268

RESEARCH-LAB FINE CHEM INDUSTRIES


An ISO 9001:2008 certified company

MATERIAL SAFETY DATA SHEET


Section 1 - Chemical Product and Company Identification

Product Name : POTASSIUM THIOCYANATE


Synonyms: Potassium sulfocyanate; Potassium thiocyanide; Thiocyanic acid, potassium salt; Potassium
isothiocyanate
CAS No.: 333-20-0
Molecular Weight: 97.18
Chemical Formula: KSCN
Product Codes: 1268, 1268A
Brand : RESEARCH-LAB
Company Identification :-
MARKETING OFFICE :
1, Devkaran Mansion, 3rd Floor, 79, Princess Street,
MUMBAI-400 002. (Maharashtra, India)
●Telefax : (022) 2206 2623/2203 5501.
e-mail : researchlab.salunkhe@gmail.com, info@researchlab.in

Section 2 - Composition, Information on Ingredients


Ingredient CAS No Percent Hazardous
--------------------------------------------------------------------- ---------------------------------------------------------------
Potassium Thiocyanate 333-20-0 90 - 100% Yes

Section 3 - Hazardous Identification


Emergency Overview
--------------------------
WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES
AND RESPIRATORY TRACT.

SAF-T-DATA(tm) Ratings (Provided here for your convenience)


-----------------------------------------------------------------------------------------------------------
Health Rating: 2 - Moderate (Life)
Flammability Rating: 0 - None
Reactivity Rating: 1 - Slight
Contact Rating: 2 - Moderate
Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
Storage Color Code: Green (General Storage)
-----------------------------------------------------------------------------------------------------------
Potential Health Effects
----------------------------------

Inhalation:
Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath.
Ingestion:
May cause psychosis, vomiting, disorientation, weakness, low blood pressure, convulsions and death which
may be delayed. The probable lethal dose is between 15-30 grams.
Skin Contact:
Causes irritation to skin. Symptoms include redness, itching, and pain.
Eye Contact:
Causes irritation, redness, and pain.
Chronic Exposure:
Prolonged or repeated skin exposure may cause dermatitis. Repeated ingestion of small amounts may cause
weakness, confusion, central nervous system effects, nausea and skin eruptions.
Aggravation of Pre-existing Conditions:
No information found.
Section 4 - First Aid Measures
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an
unconscious person. Get medical attention.
Skin Contact:
Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes.
Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean
shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids
occasionally. Get medical attention immediately.

Section 5 - Fire Fighting Measures


Fire:
Not considered to be a fire hazard.
Explosion:
Not considered to be an explosion hazard.
Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus
with full facepiece operated in the pressure demand or other positive pressure mode. May emit toxic and
flammable fumes of cyanide if involved in a fire.

Section 6 - Accidental Release Measures


Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust
dispersal.

Section 7 - Handling and Storage


Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate
from oxidizing materials. Store in the dark. Containers of this material may be hazardous when empty since
they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
Section 8 - Exposure Controls, Personal Protection
Airborne Exposure Limits:
None established.
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial
Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a
particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting
fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the
exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-
purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to
prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain
eye wash fountain and quick-drench facilities in work area.

Section 9 - Physical and Chemical Properties


Appearance:
Colorless, deliquescent crystals.
Odor:
Odorless.
Solubility:
Very soluble in water.
Density:
1.89
pH:
No information found.
% Volatiles by volume @ 21C (70F):
0
Boiling Point:
500C (932F)
Melting Point:
173C (343F)
Vapor Density (Air=1):
No information found.
Vapor Pressure (mm Hg):
No information found.
Evaporation Rate (BuAc=1):
No information found.

Section 10 - Stability and Reactivity


Stability:
Stable under ordinary conditions of use and storage. Slowly decomposes on exposure to light.
Hazardous Decomposition Products:
Burning may produce nitrogen oxides, sulfur compounds, and possibly cyanides.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Strong oxidizers, active halogen compounds.
Conditions to Avoid:
Light and incompatibles.

Section 11 - Toxicological Information


Oral rat LD50: 854 mg/kg. Investigated as a mutagen, reproductive effector.
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Potassium Thiocyanate (333-20-0) No No None

Section 12 - Ecological Information


Environmental Fate:
No information found.
Environmental Toxicity:
No information found.

Section 13 - Disposal Considerations


Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste
disposal facility. Processing, use or contamination of this product may change the waste management options.
State and local disposal regulations may differ from federal disposal regulations. Dispose of container and
unused contents in accordance with federal, state and local requirements.

Section 14 - Transport Information


Not Regulated

Section 15 - Regulatory Information


--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Potassium Thiocyanate (333-20-0) Yes Yes Yes Yes

--------\Chemical Inventory Status - Part 2\---------------------------------


--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Potassium Thiocyanate (333-20-0) Yes Yes No Yes

--------\Federal, State & International Regulations - Part 1\----------------


-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Potassium Thiocyanate (333-20-0) No No Yes No

--------\Federal, State & International Regulations - Part 2\----------------


-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Potassium Thiocyanate (333-20-0) No No No

Chemical Weapons Convention: No TSCA 12(b): No CDTA: No


SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
Reactivity: No (Pure / Solid)

Section 16 - Additional Information


NFPA Ratings: Health: 3 Flammability: 0 Reactivity: 0
Label Hazard Warning:
WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND
RESPIRATORY TRACT.
Label Precautions:
Avoid contact with eyes, skin and clothing.
Wash thoroughly after handling.
Avoid breathing dust.
Keep container closed.
Use only with adequate ventilation.
Label First Aid:
If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to
an unconscious person. In case of contact, wipe off excess material from skin then immediately flush eyes or
skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing
before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. In all cases, get medical attention.
Product Use:
Laboratory Reagent.
Revision Information:
No Changes.

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