Marketing Bulletin

Optical Effects of Particles

SPECIALTY FLUIDS - PERSONAL CARE

An aging global population and the Key Features and Typical Benefits Potential Applications
desire of consumers to maintain a „ Imperfections are minimized – „ Color cosmetics
youthful appearance have created soft focus effect „ Anti-aging
a growing anti-aging market „ Skin’s appearance is improved – „ Daily wear skin creams and lotions
glow and radiance
segment in the health and beauty „ Serums
„ Natural appearance with sheer
industries. Skincare product „ Anti-acne
radiance
manufacturers have responded „ Moisturizers
„ Natural appearance with sparkle
with a growing number of „ Cleansers
„ Even distribution of light
treatments aimed at reviving „ Skin imperfection correctors
„ Instant brightening
or preserving skin health. While
„ Sunscreens
„ Coverage
„ After tanning products
many of the products have proven
successful in revitalizing skin,
the results are not instantaneous
Soft Focus Effect with Tospearl* Microspheres
and have only been achieved by
Optical Property Skin Appearance Benefit Tospearl Microspheres
consistent and ongoing application. More than 50% diffused
Minimize Skin Imperfection
Human nature demands results be High Diffused Transmission transmission with
Natural Appearance
Tospearl 150KA Microspheres
immediate and visible, presenting
a significant challenge to the Optical Effects with Softouch* Boron Nitride Platelets
formulator. Sensory enhancer Momentive Softouch Boron
Optical Property Skin Appearance Benefit
Nitride Platelets
particles from Momentive Momentive Softouch CCS102J –
Radiance, glow
Performance Materials enable High Total Transmission Natural Appearance
Momentive Softouch CCS402 –
the formulation designer to Sparkle/shimmer
Momentive Softouch CC6097 –
simulate instantly the appearance High Diffused Transmission Minimize Skin Imperfection
Soft focus
of flawless, bright, luminescent Momentive Softouch CC6097 &
High Scattered Reflection Even Light Distribution
Velvesil* Mul-T Gel – Matte finish
skin, encouraging the consumer
to reapply and eventually realize
skin vitality.
Typical Physical Properties
Refractive Particle Size
INCI Particle Shape
Index (microns)
Tospearl
Polymethylsilsesquioxane 1.42 2 - 11 Spherical
Microspheres
Momentive Softouch
Boron Nitride 2.10 5 - 50 Platelets
Boron Nitride Platelets
Typical properties are average data and are not to be used as or to develop specifications.

*Momentive, Tospearl and Softouch are trademarks of Momentive Performance Materials Inc.
Performance Data: Optical Effects of Particles

Overview Soft Focus: Reduce the contrast by blurring

Momentive Performance Materials offers cosmetic particles the imperfection
with a wide range of morphology and surface properties used Two different imperfections, wrinkles and pigmentation
to provide a variety of optical effects in cosmetic formulations. marks have to be treated differently. Wrinkles affect the
distribution of particles as the particles tend to segregate
Light interacts with skin by either being reflected or transmitted in them. Such particle segregation is not observed in case
through the cosmetic film. Both the transmitted and reflected of pigmentation marks.
light has two components; direct and diffused. Introducing
light scattering particles into cosmetic preparations affects Other factors affecting the optical effects of cosmetic
these properties and impacts skin appearance by hiding skin formulations are the thickness of the applied formulation,
imperfections and improving glow and radiance of skin. particle size distribution within it, and its texture. Formulators
also need to take into consideration the properties of particles
being used such as the refractive index difference between
Light Interaction with Skin
Glow
the medium and the particle, as well as the particles’ size,
shape, morphology, and concentration.
Radiance
Specular
reflection
GOAL: to maximize diffused transmission and scattered
Scattered Surface reflection Subsurface reflection reflection for better soft focus effect.
reflection (Direct or Diffused T ) (Direct or Diffused T )

Optical Property Skin Appearance Benefit

High Total Transmission Natural Appearance
Particles Soft Focus High Diffused Transmission Minimize Skin Imperfection
High Scattered Reflection Even Light Distribution

CREAM
Measuring Optical Properties of Films
Optical properties of cosmetic films are measured using
ColorEye 7000 A and goniospectrophotometer.
SKIN
125 micron
Hiding Skin Imperfections by “Soft Focus Effect”
Skin imperfections are perceived due to the contrast created
either by the light trapped in wrinkles or absorbed by skin
pigments. Reducing the contrast between wrinkles and
imperfections and the skin will minimize the visual appearance Direct
of these imperfections. This phenomenon is commonly referred Transmission
Light
to as “Soft Focus effect”. source

Hiding the Imperfections due to wrinkles Diffused

Transmission

After measuring the total and direct transmission of dried films,

diffused transmission is calculated as
Diffused transmission = Total transmission – Direct transmission

Model Formulation
Model formulation used for demonstrating optical properties of
Tospearl* and Boron nitride particles contains 1% of particles.
Hiding the Imperfections due to hyperpigmentation
Ingredient % w/w
Cyclopentasiloxane 79
Dimethicone (500 cst) 10
SilForm* Flex resin 10
Particles 1

Product formulations are included as illustrative examples only. Momentive makes

no representation or warranty of any kind with respect to any such formulations, After the film is completely dried, it will constitute of
including, without limitation, concerning the efficacy or safety of any product approximately 5% of particles in it.
manufactured using such formulations.

Note: Test results. Actual results may vary. *Tospearl and SilForm are trademarks of Momentive Performance Materials Inc.
Page 2 of 8
 Performance Data: Optical Effects of Particles

Silicone Spheres Line Blurring with Silsoft E-Pearl PF Emulsion

Momentive Performance Materials offers solid, spherical Silsoft E-Pearl PF emulsion, which is a non-ionic emulsion of
T-resin particles as dry powders (Tospearl*) and as oil-in-water Tospearl microspheres, also improved the wrinkle hiding effects
emulsion (Silsoft* E-Pearl PF emulsion). for aqueous formulations. After applying the Silsoft E-Pearl PF
emulsion to arm, wrinkles were practically hidden even at a
Tospearl Microspheres microscopic level.
„ 100% active
„ Variety of particle sizes (2 - 12 micron)
„ Refractive index 1.42

The image analysis of similar images of model formulation

Tospearl 120A Tospearl AQ Tospearl 145A applied to arm is used to calculate the wrinkle index.

Wrinkle index is an easy way to determine contrast of the

image. Lower the wrinkle index lower is the contrast and thus
Tospearl 1110A Tospearl 150KA better is the wrinkle hiding.

Model Formulation Comparison with Other Microspheres

Silsoft E-Pearl Emulsion 30
„ O/W emulsion with Tospearl Ingredient
%
w/w
„ Easily water dispersdible
Wrinkle Index
Sepigel 1 20
Glycerine 7
Butylene glycol 4
Incr
Diffused Transmission with Tospearl* Microspheres eas
Silsoft E-Pearl 10 ed S
5 oft F
It was demonstrated that a boost in soft focus may be Emulsion ocu
s Ef
fect
achieved by increasing the surface roughness of the particle q.s.
Water
100
as in the case of Tospearl 150KA. 0
Before Silica PMMA E-Pearl
Diffused Transmission Direct Transmission
100 Product formulations are included as illustrative examples only. Momentive makes
no representation or warranty of any kind with respect to any such formulations,
including, without limitation, concerning the efficacy or safety of any product
manufactured using such formulations.
80
% Transmission

60 t Silsoft E-Pearl PF emulsion provided better wrinkle hiding for

Effec
cus aqueous formulations than silica and PMMA microspheres.
Soft Fo
ased
40
Incre

20 Summary of Tospearl Microspheres Technology

for Soft Focus
0
Blank Talc 3000A 145A 120A 2000B 150KA Skin Appearance
4-7 μm 4.5 μm 2 μm 4-6 μm 5 μm Optical Property Tospearl Microspheres
Benefit
High Total Natural 90% transmission with 6%
Key Highlights: Transmission Appearance Tospearl Microspheres
More than 50% diffused
„ 90% total transmission High Diffused Minimize Skin
transmission with
„ Less loss in reflection (Less RI difference) Transmission Imperfection
Tospearl 150KA Microspheres
„ Increased diffused transmission by surface roughness High Scattered Even Light Low reflection due to RI
Reflection Distribution match with medium

Note: Test data. Actual results may vary. *Tospearl and Silsoft are trademarks of Momentive Performance Materials Inc.
Page 3 of 8
Performance Data: Optical Effects of Particles

Boron Nitride Platelets Reflectance with Momentive Softouch Boron

Momentive Performance Materials offers boron nitride platelets Nitride Powders
as dry powders (Momentive Softouch* BN powder) and Model Formulation
formulated gels (Velvesil* Mul-T gel).
Ingredient % w/w
Momentive Softouch Boron Nitride Powder Silicone gel 96
„ Arrays of crystal morphologies (5 – 50 micron) Momentive Softouch
Boron Nitride platelets 4
„ More lubricious than talc and nylon beads
„ Refractive index = 2.1

Velvesil Mul-T gel Because of higher refractive index difference between the
medium and the particles, boron nitride platelets reflect light.
„ Synergistic blend of Silicone gel and Momentive Softouch
Reflectance is an essential for improving radiance, glow and
Boron Nitride shine. Reflectance study of a model formulation is carried
„ Ease of formulating boron nitride out. The following figure shows visual appearance of total and
diffused transmittance when the model formulation was applied
Diffused Transmission with Momentive Softouch to transparencies. As seen in images, Momentive Softouch
Boron Nitride Powder CC6097 powder provided excellent diffused transmission
It was found that Momentive Softouch CC6097 powder with required for soft focus and the Momentive Softouch CCS402
its small particle size and crystal imperfections was the best and CCS102J powders maintained high total transmission
for soft focus. Momentive Softouch CCS402 and CCS102J required for natural skin appearance, radiance and glow.
powders preserved the natural appearance of skin due to
higher transmission than the other boron nitride powders.
Momentive
Diffused transmission Direct transmission Softouch CC6097
100
Sparkly Pearlescent Line Blurring

80 Momentive
Increas Softouch CCS102J
ed Tran
% Transmission

smissio
n
60

Momentive
40 Softouch CCS402

fect
20 Focus Ef
Soft Radiance and sparkle with Momentive Softouch Boron
ased
Incre Nitride Powders
The Momentive Softouch CCS402 powder provided highest
0 reflectance and when applied to skin provided sparkly powder
Blank Talc CCS402 CCS102J CC6058 CC6069 CC6059 CC6004 CC6097
optical effect. Contrary to Momentive Softouch CCS402
Key Highlights: powder, the Momentive Softouch CC6097 powder demon-
strated scattered reflectance which is necessary for soft focus
„ Total transmission: Crystal structure dependent
and uniform coverage. The reflectance properties of Momentive
„ Higher loss in reflection (High RI difference) Softouch CCS102J powder were between those of the other
„ Increased diffused transmission by crystal imperfections two platelets and is evident by application to the skin provided
a seamless natural looking glow and radiance.
Note: Test data. Actual results may vary.
*Momentive, Softouch and Velvesil are trademarks of Momentive Performance Materials Inc.
Page 4 of 8
Performance Data: Optical Effects of Particles

Velvesil* Mul-T gel: Even Light Distribution The plot below demonstrates that the Tospearl 150KA and
Velvesil Mul-T gel, which is a synergistic blend of silicone Momentive Softouch CC6097 provided optimal soft fo-
gel and Momentive Softouch* Boron Nitride platelets, was cus. Also, the Momentive Softouch CCS402 and CCS102J
found to provide an even distribution of light so that the maintained higher transmission which is necessary for natural
skin imperfections due to pigmentation were significantly appearance of skin.
diminished by the soft focus effect. Following figure illustrates
the transmission and reflectance from a 125 micron thick film Direct Transmission Diffused Transmission
of the Velvesil Mul-T gel. 100
100
80
80

% Transmission
Direct
60
60
us
Foc
cus
%

ft
So t Fo
40 40 sed of
ncrea ed
S
Diffused
I
creas
Specular In
20 20
Scattered

0
Transmission Reflection 0
Tospearl Tospearl Momentive Momentive Momentive
Summary of Momentive Softouch Boron Nitride platelets 2000B 150KA Softouch Softouch Softouch
for Soft Focus CCS402 CCS102J CC6097

Optical Skin Appearance Momentive Softouch

Property Benefit Boron Nitride Powders
Moisturizing Cream: Reflectance
Momentive Softouch CCS102J -
High Total Natural Radiance, glow Using the same moisturizing cream to measure reflectance,
Transmission Appearance Momentive Softouch CCS402 - it was observed that Momentive Softouch CC6097 powder had
Sparkle/shimmer
the most even distribution of light (high scattered reflection)
High Diffused Minimize Skin Momentive Softouch CC6097 - while Momentive Softouch CCS402 powder had the highest
Transmission Imperfection Soft focus
specular reflection, which correlates to a sparkly effect on
High Scattered Even Light Momentive Softouch CC6097 &
Reflection Distribution Velvesil Mul-T Gel - Matte finish the skin. Momentive Softouch CCS102J powder was again
between the two other platelets studied and whose optical
Moisturizing Cream: Transmittance
effects could be described as bright, radiant, and pearlescent.
For a transmittance study, a basic moisturizer cream Once again, more scattered reflection due to surface rough-
formulation was employed to examine the optical properties ness was observed in case of Tospearl 150KA microspheres.
of a cosmetic film containing Tospearl* microspheres and
Momentive Softouch Boron Nitride platelets.
Specular Reflection Scattered Reflection
Part INCI Name % w/w 25
Deionized Water 83.07
Disodium EDTA 0.05
A 20
Carbomer 0.2
% Reflection

Preservative q.s.
Momentive Softouch BN 1.00 15
B
Butylene Glycol 2.5
Cetyl Ethylhexanonate 5.00
10
Sorbitan Stearate 1.5
Polysorbate 60 1.0
C
Cetearyl alcohol (and) Ceteareth-20 1.5 5
Cyclopentasiloxane (and) Dimethicone
1.5
Phenoxyethanol (and) Preservative
Deionized Water 1.00 0
D Tospearl Tospearl Momentive Momentive Momentive
Aminomethyl Propanol 0.18 2000B 150KA Softouch Softouch Softouch
Polyacrylate-13 (and) Polyisobutene (and) CCS402 CCS102J CC6097
E 0.5
Polysorbate-20
Product formulations are included as illustrative examples only. Momentive makes
no representation or warranty of any kind with respect to any such formulations, Note: Test data. Actual results may vary.
including, without limitation, concerning the efficacy or safety of any product
manufactured using such formulations.
*Momentive, Tospearl, Softouch and Velvesil are trademarks of Momentive Performance Materials Inc.
Page 5 of 8
Performance Data: Optical Effects of Particles

Summary of Tospearl* and Momentive Softouch* Product

Optical Effects Options
Tospearl microspheres and Momentive Softouch Boron Nitride
platelets can offer flexibility in achieving a range of optical
properties including the masking of skin defects such as
hyperpigmentation and fine lines and wrinkles. They can
also be a very useful tool for the formulator to achieve optical
effects including instant radiance, luminosity, and a means to
counteract dull lifeless skin.

Positioning of Momentive Particles

Momentive Softouch CC6097 Tospearl 150KA

Diffused Transmission

Soft focus for Soft focus for

hyperpigmentation wrinkle hiding
Refractive
Index
Particle size,
shape
Crystal
Momentive Momentive
morphology
Softouch Softouch
CCS102J CCS402

Radiance, glow Sparkle

Total Transmission

Note: Test results. Actual results may vary.

*Momentive, Tospearl and Softouch are trademarks of Momentive Performance Materials Inc.
Page 6 of 8
Performance Data: Optical Effects of Particles

Patent Status
Nothing contained herein shall be construed to imply the
nonexistence of any relevant patents or to constitute the
permission, inducement or recommendation to practice any
invention covered by any patent, without authority from the
owner of the patent.
Product Safety, Handling and Storage 
Customers should review the latest Material Safety Data
Sheet (MSDS) and label for product safety information,
safe handling instructions, personal protective equipment if
necessary, emergency service contact information, and any
special storage conditions required for safety. Momentive
Performance Materials (MPM) maintains an around-the-clock
emergency service for its products. MSDS are available at
www.momentive.com or, upon request, from any MPM
representative. For product storage and handling procedures
to maintain the product quality within our stated specifications,
please review Certificates of Analysis, which are available in
the Order Center. Use of other materials in conjunction with
MPM products (for example, primers) may require additional
precautions. Please review and follow the safety information
provided by the manufacturer of such other materials.
Limitations 
Customers must evaluate Momentive Performance Materials
products and make their own determination as to fitness of use
in their particular applications.

Page 7 of 8
Customer Service Centers

Email
4information@momentive.com

Telephone
Americas Europe, Middle East, Asia Pacific
+1 888 443 9466 Africa and India China
+1 614 986 2497 +00 800 836 43581 +800 820 0202
+40 212 534754
Japan
+81 276 20 6182

All Other Countries

+60 3 9206 1543

To find a specific language, visit the Contact Us page at Momentive.com. You may select a country to view additional languages and the corresponding
telephone numbers.

For email inquiries, we will make every attempt to respond in the incoming written language. If that is not possible, we will respond in English.

DISCLAIMER:
THE MATERIALS, PRODUCTS AND SERVICES OF MOMENTIVE PERFORMANCE MATERIALS INC. AND ITS SUBSIDIARIES AND AFFILIATES
(COLLECTIVELY “SUPPLIER”), ARE SOLD SUBJECT TO SUPPLIER’S STANDARD CONDITIONS OF SALE, WHICH ARE INCLUDED IN THE APPLICABLE
DISTRIBUTOR OR OTHER SALES AGREEMENT, PRINTED ON THE BACK OF ORDER ACKNOWLEDGMENTS AND INVOICES, AND AVAILABLE UPON
REQUEST. ALTHOUGH ANY INFORMATION, RECOMMENDATIONS, OR ADVICE CONTAINED HEREIN IS GIVEN IN GOOD FAITH, SUPPLIER MAKES
NO WARRANTY OR GUARANTEE, EXPRESS OR IMPLIED, (i) THAT THE RESULTS DESCRIBED HEREIN WILL BE OBTAINED UNDER END-USE
CONDITIONS, OR (ii) AS TO THE EFFECTIVENESS OR SAFETY OF ANY DESIGN INCORPORATING ITS PRODUCTS, MATERIALS, SERVICES,
RECOMMENDATIONS OR ADVICE. EXCEPT AS PROVIDED IN SUPPLIER’S STANDARD CONDITIONS OF SALE, SUPPLIER AND ITS REPRESENTATIVES
SHALL IN NO EVENT BE RESPONSIBLE FOR ANY LOSS RESULTING FROM ANY USE OF ITS MATERIALS, PRODUCTS OR SERVICES DESCRIBED
HEREIN. Each user bears full responsibility for making its own determination as to the suitability of Supplier’s materials, services, recommendations, or advice for its own
particular use. Each user must identify and perform all tests and analyses necessary to assure that its finished parts incorporating Supplier’s products, materials,
or services will be safe and suitable for use under end-use conditions. Nothing in this or any other document, nor any oral recommendation or advice, shall be deemed
to alter, vary, supersede, or waive any provision of Supplier’s standard Conditions of Sale or this Disclaimer, unless any such modification is specifically agreed to
in a writing signed by Supplier. No statement contained herein concerning a possible or suggested use of any material, product, service or design is intended, or should
be construed, to grant any license under any patent or other intellectual property right of Supplier covering such use or design, or as a recommendation for the use of
such material, product, service or design in the infringement of any patent or other intellectual property right.

*Tospearl, Softouch, SilForm, Silsoft and Velvesil are trademarks of Momentive Performance Materials Inc.

Momentive and the Momentive logo are trademarks of Momentive Performance Materials Inc.

260 Hudson River Road

Waterford, NY 12188 USA
momentive.com

Copyright 2008-2014 Momentive Performance Materials Inc. All rights reserved. MPM 131-179-00E-GL 05/14 Printed in U.S.A.
Page 8 of 8