SPE/DOE 27751 Microbial Enhanced Waterflooding Field Tests
SPE/DOE 27751 Microbial Enhanced Waterflooding Field Tests
SPE/DOE 27751 Microbial Enhanced Waterflooding Field Tests
This paper was prepared for presentation at the SPE/DOE Ninth Symposium on Improved Oil Recovery held in Tulsa, Oklahoma, U.S.A., 17-20 April 1994.
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as presented, have not been reviewed by the Society of Petroleum Engineers and are subject to correction by the author(s). The material, as presented, does not necessarily reflect
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159
2 Microbial Enhanced Waterflooding Field Tests SPE 27751
waterflood, which may make this recovery method FIELD TEST DESIGN - MINK UNIT
applicable at low oil prices when more expensive
methods are not economically feasible. The Mink Unit site, which includes both the Candy
and Sallie Mink leases, selected for the project is
Microorganisms most commonly used for MEOR located in Delaware-Childers field in Nowata County,
field processes that rely on improving the efficiency Oklahoma (Figs 2 and 3). This particular part of
of microscopic oil displacement are species of Delaware-Childers field was owned by B & N Oil
Bacillus and Clostridium. These species have a Company when the project was initiated in 1986. The
greater potential for survival under petroleum legal description of the Mink Unit is Section 36,
reservoir conditions than other species because they Township 27N, Range 16 E of Nowata County.
produce spores, which are dormant, resistant forms of
the cells that can survive under stressful The 1,200-acre Sinclair Oil and Gas Company Tanner
environmental conditions. Clostridium species Waterflood, initiated in March 1954, included the
produce surfactants, gases, alcohols and solvents, Mink leases, the site of the microbial field
whereas some Bacillus species produce surfactants, experiment. Surface water from the nearby Verdigris
acids, and some gases. River has continued to be the source water for this
flood since its initiation. The flood has been in
In microbial-enhanced waterflood applications, it is continuous operation, although under various owners,
important that the microbes be capable of moving to the present time.
through the reservoir matrix and producing chemical
products that can mobilize oil. The relative rates of In 1988, as a result of the sale of this oilfield, cores
transport of the nutrient and microorganisms will were drilled on the Mink Unit and Brown leases of
affect the injection strategy and design of the this field, and data from core analyses were provided
microbial system. by the new owners to NIPER. The average
permeability was 90 millidarcies, which was higher
A microbial treatment requires careful design and than that of some of the earlier core analyses, and the
sound reservoir engineering practice, as does any average porosity was 19.1 %.
enhanced oil recovery (EOR) method. A microbial-
enhanced waterflood field project sponsored by the The Mink Unit covered a 160-acre area, of which 110
U. S. Department of Energy (DOE), Microbial acres were productive and contained 21 injection
Systems Corp. (MSC), and INJECTECH, Inc., and wells and 15 production wells drilled on 5-acre
conducted in cooperation with the National Institute spacing (Fig. 3). All wells were flowing, except for
for Petroleum and Energy Research (NIPER) was one which was being pumped. Well completions
initiated in October of 1986. The purpose of the were open-hole. Table 1 lists the average reservoir
project was to determine the feasibility of injecting a properties at the time of the project.
microbial formulation in a mature, ongoing
waterflood, and if such an injection could increase oil TABLEt
production. The microbial formulation was designed
to improve microscopic oil displacement efficiency Reservoir Properties for Mink Unit
by surfactant, gas and acid production from
fermentation of molasses. Molasses was the nutrient
of choice because it was readily available and Formation '" ... ............. ... Bartlesville sandstone
inexpensive ($100/ton). Based on the the favorable Depth, ft........................................ 600
results of the initial pilot, an expanded microbial- Average net pay thickness, ft.... ...... 30
Average permeability, rnD ... ..... ..... 90
enhanced waterflood was initiated in June of 1990. Porosity, % ... ... ....... ... .... ... .... ... ... .... 20
Figure 1 shows the location of the two field projects. Avg formation temperature, OF ....... 75
Number of injection wells.............. 21
These particular field experiments were designed to Number of production wells........... 15
use microorganisms that produced chemicals Avg water injection rate, bbl/d....... 40/well
(surfactants, gases, alcohols, and fatty acids) for Avg injection pressure, psi........... 530
improved oil mobilization, and had the ability to Avg oil production, bbl/d/well ...... ... 0.4
transport through porous media. Detailed information Oil gravity, ° API.... ...... .... ..... ......... 34
about the Mink Unit Project through January 1990 has TDS of injection water, %................ 0.03
Avg IDS of produced water, % ....... 0.5
been published previously. 1 Avg oil saturation, %...................... 33
160
SPE 27751 R.S. Bryant, A.K. Stepp, K. M. Bertus, T.E. Burchfield, M.Dennis 3
161
4 Microbial Enhanced Waterflooding Field Tests SPE 27751
monitoring period through December 1989, the oil assigned for the research and development of the
production never achieved the levels ~ri?r to ~he microbial formulation; (2) The cost for equipment for
drilling activity. Since 1989, all of the ongmal Mmk
Unit wells have been plugged, and a total of 350 new TABLE 2
wells have been drilled.
Predicted and Actual Oil Production Rates
for the Mink Unit
Injection pressures at the microbially treate~ injection
wells did not increase throughout the duratIOn of the Year Production, Production,
microbial treatment. Injection pressure monitoring Pred. avg bbllwk Actual avg bbllwk
was critical to this microbial-enhanced waterflood 1981 50.0 50.5
experiment. In NIPER laboratory core flooding 1982 48.8 46.5
experiments, no facial plugging was ever observed by 1983 47.7 46.8
NIPER Bac 1. Later coreflood experiments with 1984 46.6 46.4
similar microorganisms indicated that 1985 45.6 44.8
microorganisms and their products transport at 1986 44.5 45.1
1987 43.5 48.8
reasonable rates through porous media. 4 Based upon
1988Al 42.6 48.2
laboratory and field results, it was concluded that no
1988B2 42.6 46.5
adverse plugging effects occurred because of the
1989 41.7 36.3
microbial injection. 1990 40.7 26.3
11988A - Jan. 1 - May 31.
The average water-oil ratios (WOR) at all monitored 21988B - Jun. 1 - Dec. 31.
production wells in the Mink Unit decreased when
compared to the averages during the baseline period this particular microbial injection was less than $500;
(Fig. 5). These WORs have high standard. dev.iation and (3) Because the microbial population was not
values, primarily because of gas productIOn m the overfed, the total effect of the microbial injection may
wells, which causes large fluctuations, but the overall not have been attained. Since the chemical tracer
averages have definitely decreased, and in wells S- began to appear only after 1.8 years (22 months) of
P47R and C-CP-3, the decrease is significant. Note injection, based on preliminary data from early
that in the two off-pattern wells, S-AP-4 and breakthrough of tracer, microorganisms should have
C-BP-2, the WOR has not decreased; thus, the begun to appear in the production wells about 0.6 -
microbial treatment has probably affected those wells 0.8 year (7-10 months) after the tracer appearance.
closest to the injectors. Unfortunately, this would have been about the time
that infill drilling near the Mink Unit began, and the
Oil production increased after the microbial injection sampling period for microorganisms ended.
through May 1988 (Fig. 6). After the infill drilling
and hydraulic fracturing occurred, the wellhead During the 14 months of microbial/nutrient injection
pressures at some of the nearest Mink Unit producers before infill drilling and hydraulic fracturing activity,
were much lower, as was the total produced fluid. 577 bbl of incremental oil was obtained when
The MEOR injection had a positive effect on oil compared to the predicted oil recovery by
production until the drilling and hydraulic fracturing waterflooding alone. A total of 18.7 tons of molasses
activity occurred. Since that time, actual oil was injected during this period. Using a nutrient cost
production has dropped significantly below the of $100/ton, this is equivalent to $3.24/bbl of
predicted decline curve. incremental oil. This does not take into account any
other injection costs, although for this particular
Economic Analysis - Mink Unit project, the costs were fairly minimal. Field
personnel were used for the daily injection of the
molasses. However, this analysis also does not
Limited economic analyses of the Mink Unit field include any projected recoveries beyond the time of
pilot showed that the major cost of a microbial- infill drilling. Detection of fluorescein in the Mink
enhanced waterflood would be the nutrient support Unit producing wells after the infill drilling in the
for the microorganisms. When determining the cost Tanner lease, indicates that the microbial treatment
per incremental barrel of oil for the Mink Unit, the had not yet transported through the formation matrix;
following assumptions were made: (1) No cost was thus, the complete effect on incremental oil
162
SPE 27751 R.S. Bryant, A.K. Stepp, K. M. Bertus, T.E. Burchfield, M.Dennis 5
production that may have occurred would have been fluorescein response seemed to follow the same trend
masked. as that observed during the monitoring of the Mink
Unit. There was an initial quick response of tracer
from some of the nearest production wells; the
FIELD TEST DESIGN - PHOENIX SITE response then leveled out to very low values.
Fluorescein values seemed to peak at 145 days and
In May 1988, Comdisco Resources, Inc. purchased were monitored for 599 days post-injection.
property in the Delaware-Childers oilfield from B &
N Oil company. The Mink Unit leases were a part of Selected producers were monitored for tracer
this purchase. After much negotiation, an agreement concentrations. The tracer concentrations observed in
was executed on April 18, 1989, by Microbial the selected producing wells indicated a very quick
Systems Corporation (MSC) and Comdisco show in some wells, probably from very low-volume,
Resources, Inc. (Comdisco) that financially high-permeability stringers in the formation. This
compensated the project for relocating the planned very quickly decreased to baseline levels. These data
expansion of the project in three nearby leases in the were corroborated by our observations of tracer
B & N property of Delaware-Childers field to an response in the Mink Unit. 1 Both the Mink Unit and
alternate site. With DOE's approval, MSC and the Phoenix reservoirs are very mature fields that
NIPER beg'an to search for the new site; which ideally have been waterflooded for many years. The
would have the same or similar properties to that of operators of the fields had indicated that channeling
Delaware-Childers field. of fluids was never a major problem. The
measurements of fluorescein tracer in both fields
Compatibility tests were conducted with reservoir indicates that fluid flow patterns were similar.
fluids from three nearby waterfloods and selected
microorganisms from the NIPER microbial culture TABLE 3
bank. Based upon these studies, a new field site was
selected. The site selected for the ME OR project site Reservoir Properties for Phoenix Site
is in Section 8, Township 24 North, Range 17E of
Rogers County, Oklahoma. This site is part of
Chelsea-Alluwe field in the Bartlesville formation and Formation ......... ... ... .... ... Bartlesville sandstone
was initially developed soon after Delaware-Childers Depth, ft........................................ 400
field. The site, owned by Phoenix Oil and Gas, Ltd, Average net pay thickness, ft... .... 18-23
was being waterflooded. This field is in an isolated Average permeability, roD ..... ... ..... 16
Porosity, % .. .......... ....... ....... ....... .... 20
area, with virtually no other oil-producing leases A vg formation temperature, 0F....... 66
nearby. Number of injection weBs.............. 19
Number of production weBs ........... 47
Estimates of original oil saturation from core analyses A vg water inj rate/well, bbl/d.. 111
and from Delaware-Childers field were used to Avg injection pressure, psi........... 350
estimate the oil currently in place for each individual A vg oil production, bbIldlweII .... ..... 1
lease. Figure 7 shows a map of the Phoenix site, and Oil gravity, 0 API.... .......... ...... ........ 34
Table 3 lists the reservoir properties. TDS of inj. and prod. water, %........ 3.0
Avg oil saturation, %...................... 30
FIELD OPERATIONS - PHOENIX SITE The objective of the expanded Phoenix project was to
determine how the process could be expanded for a
Figure 8 shows the sequence of events for the whole field, and to determine whether microbial-
Phoenix field project. Fluorescein was injected as a enhanced waterflooding is economically feasible.
tracer on June 6, 1990. Eighty-five barrels of a The monitoring for this field site was designed to be
solution containing 126 ppm fluorescein was injected. minimal; including only those field parameters that
Samples were collected from all 19 injection wells at would affect oil production. In addition to oil
2-hr intervals the first day. Twenty-one producers production from the field, individual injection
were sampled 24 hr after injection of tracer, sampled pressures and volumes were monitored. Since this
daily, then weekly, once a month, and finally, was a recycled flood, produced volumes could not be
intermittently. Since the second day of sampling, the monitored; thus no water-oil ratios were available.
tracer response has only been higher than 0.30 ppm
for one (WM-13-1O) of the wells. The pattern of the
163
6 Microbial Enhanced Waterflooding Field Tests SPE 27751
To determine the commercial feasibility of microbial- decline curve, which corresponds to approximately
enhanced waterflooding, a method of microbial and 19.6% improvement in oil production.
molasses injection had to be designed for the entire
field. Figure 9 shows a schematic of the centralized Economic Analysis - Phoenix Site
injection station used for the Phoenix field site. After
the initial injection of the microbial formulation, The total amount of molasses injected was 104 tons.
molasses was injected continuously from the station. From the oil production data above, an incremental
4,440 bbl of oil was obtained through May 1993.
The microbial formulation consisting of NIPER 1A Using $151bbl as the cost of oil, this amounts to
and NIPER 6 was selected for this field injection. $66,600 gross income. At a cost of $l00/ton, $10,332
NIPER 1A is a variation of the same strain that was was spent for injected nutrient, indicating a cost of
used in the Mink Unit project, and produces $2.33/incremental bbl of oil compared to that of the
surfactant and acid from molasses. 1 However, its Mink Unit which was $3.24/incremental bbl. The
growth in the reservoir brine from the Phoenix field cost of the centralized injection station facilities was
site was never as optimal as that from the Mink Unit. $2,500. Thus, a total of $12,832 was spent for the
There are two potential reasons for this: (1) the Mink microbial-enhanced flooding.
Unit injection water was fresh; thus, the fluids for
cultivation of NIPER 1A had always been relatively CONCLUSIONS
low (0.5%) in salinity. The Phoenix brine is recycled
produced water and has a salinity of about 2.9%. (2) These microbial-enhanced waterflood field projects
There is a higher concentration of iron in the Phoenix demonstrated the feasibility of microbial EOR
brine that may be inhibiting the growth of NIPER 1A. technology in a manner that an independent operator
Another Clostridium, NIPER 6, was selected to be could implement. It is noteworthy that no operating
injected with NIPER 1A. NIPER 6 was smaller in problems were encountered before or during either
size than NIPER 3 Clostridium that was used in the project. No corrosion problems were experienced; in
Mink Unit. Since the Phoenix had a lower average fact, the sulfate-reducing bacterial populations
permeability, it was determined that this would be a remained. relatively low compared to the baseline
better microbial species for injection. After counts. There were no problems with injectivity. The
conducting several corefloods, observations showed Phoenix project demonstrated the commercial
that the other two microorganisms used in the Mink applicability of microbial-enhanced waterflooding,
Unit had relatively little effect in terms of improved and showed an improvement in oil production of
oil production, so they were not injected into this site. 19.6%. Although these two pilots have shown the
potential for microbial waterflooding technology,
On June 20, 1990, approximately 100 bbl of NIPER there are many other MEOR processes and types of
1A and NIPER 6 was injected in a solution of 4% applications that merit further field testing.
molasses. This injection was followed by continuous Development of microbial waterflooding and single
injection of 40 gal/d of molasses, which was well stimulation techniques for a wide variety of
increased after 1 year, to 80 gal/d until December 31, reservoirs is critical, both for the United States and
1991. other oil-producing nations.
164
SPE 27751 R.S. Bryant, A.K. Stepp, K. M. Bertus, T.E. Burchfield, M.Dennis 7
165
STATE OF OKLAHOMA
PHOENIX PILOT
•
CoBp·, •
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pJ'
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WEll.
Jli'
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WEll.
•
c.cp.,
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CANDY MINK
• -
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8
------------------------
SITE OF NEW WATERFLOOD PROJECT TANNER
166
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SEQUENCE OF EVENTS
167
MINK UNIT WATER/OIL RATIOS
160
140
0 OFF PATTERN WELLS
t=
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FIGURE 6. - Predicted and actual average oil production/or Mink Unit during 1981 -1990.
168
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SEQUENCE OF EVENTS
169
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