Handout Jacobs Css - Superclaus Process

Download as pdf or txt
Download as pdf or txt
You are on page 1of 1

Comprimo® Sulfur Solutions

APPLICATIONS
The SUPERCLAUS® process recovers elemental sulfur from H2S-containing gases originating from gas treating and sour
SULFUR RECOVERY - SUPERCLAUS® PROCESS

water stripper plants. Yields up to 99.2% overall sulfur recovery, without any further tail gas cleanup, are possible.

DESCRIPTION FEATURES
The SUPERCLAUS® process consists of a thermal stage followed by minimum three » Application in both new and
catalytic reaction stages, with sulfur removed between stages by condensers. existing plants
The first reactors are filled with standard Claus catalyst, while the final reactor is » Sulfur recovery up to 99.2%
filled with selective oxidation catalyst.
» Long catalyst lifetime
In the thermal stage, the acid gas is burned with a sub-stoichiometric amount » Simple continuous operation
of controlled combustion air, such that the tail gas leaving the last Claus reactor
contains typically 0.8-1.0 vol.% of H2S. The selective oxidation catalyst in the final » Low additional investment costs
reactor oxidizes the H2S to sulfur at an efficiency of more than 85%. » NH3 destruction
If a sulfur recovery rate of more than 99% is required, a third Claus reactor stage » High turndown
can be installed upstream of the selective oxidation reactor. » High reliability - less than 1%
unscheduled shutdown time
OPERATING CONDITIONS
Two main principles are applied in operating the SUPERCLAUS® process:
» Operating the Claus plant with excess H2S to suppress the SO2
content in the Claus tail gas
» Selective oxidation of the remaining H2S in the Claus tail gas
by means of special catalyst which efficiently converts the
remaining H2S in the presence of water vapor and excess oxygen
to elemental sulfur only
Other operating features that apply to Jacobs’ Comprimo® Claus
process are applicable for the SUPERCLAUS® process as well. These
include NH3 destruction up to 30 vol.%, the capability to process
heavy hydrocarbons and aromatics (BTX) up to 2 vol.%, turndown
ratios of 100-15% and production of 99.9% pure bright yellow sulfur.

UTILITIES
Basis: 100 t/d, two Claus reactors, one selective oxidation reactor, 71 vol.% H2S REFERENCES
and 11 vol.% NH3 feed gas, thermal incineration with heat recovery, and sulfur Since the first commercial
recovery of 99%. demonstration of the SUPERCLAUS®
process in 1988, more than 215 units
Consumption Production with a total installed capacity of over
4 bar(g) steam t/h – 2.7 48,000 t/d have been licensed. The
40 bar(g) steam t/h – 12.8 biggest single unit in operation has a
Pre-/Reheat 40 bar(g) t/h 1.7 – capacity of 1,500 t/d.
Electricity kW 310 –
Fuel gas t/h 0.28 –
Boiler feed water t/h 16.4 –
Steam for plant heating t/h 0.9 –

LICENSOR
Jacobs Comprimo® Sulfur Solutions, a
member of Jacobs Engineering Group Inc.

Europe, Asia, Pacific, Middle East, FSU, Africa North & South America
Mrs. Karen Hanlon Kinsberg Mr. Mike Smeltink Mr. Dennis Koscielnuk www.jacobscomprimo.com
karen.hanlonkinsberg@jacobs.com mike.smeltink@jacobs.com dennis.koscielnuk@jacobs.com

You might also like