www.nipponsteel.

com

SEAMLESS CASING
Pipes
& Tubes

& TUBING

SEAMLESSCASING
SEAMLESS CASING&&TUBING
TUBING
2-6-1 Marunouchi, Chiyoda-ku,Tokyo 100-8071 Japan P003en_01_201904f
P003en_01_201904p
Tel: +81-3-6867-4111 © 2019 NIPPON STEEL CORPORATION
CONTENTS INTRODUCTION
1 INTRODUCTION For more than five decades, NIPPON STEEL has been serving the needs of the oil and gas industries.
All the supply records for most of the severe drilling environments indicate that NIPPON STEEL is the
2 FACILITIES AND LOCATIONS leader in tubular technologies. Field development where it was impossible to drill yesterday becomes
3 MANUFACTURING SITES a reality with NIPPON STEEL tubular products today. Customer satisfaction and reliability are the key
words for our product development.
4 MANUFACTURING PROCESS OF SEAMLESS STEEL TUBES AND PIPES
6 MATERIAL SELECTION GUIDELINES Our product line covers almost all applications from carbon steel to Ni based alloy steel with conven-
tional API connections or advanced sealing mechanisms such as VAM premium connections. NIPPON
8 AVAILABLE GRADES STEEL has the widest material grades for Casing & Tubing. And as a result of continuous R&D efforts,
10 MECHAN I CAL PROPERTI ES you can find more “fit for purpose” products in this brochure.

12 SM-SERIES GRADE DESCRIPTION

12 1 . CASI N G AN D TUBI N G FOR G EN ERAL AN D DEEP WELL SERV I CE
13 2 . CASI N G AN D TUBI N G FOR SOUR OI L AN D G AS SERV I CE
15 3 . HI G H COLLAPSE CASI N G FOR DEEP WELL SERV I CE
16 4 . CASI N G AN D TUBI N G FOR ARCTI C SERV I CE

17 NEW SM-SERIES
17
22
1 . 1 3 CR, SUPER 1 3 CR, SUPER 1 7 CR AN D DUPLEX STAI N LESS STEEL
2 . H2 S + CO2 + Cl- CORROSI ON ( N i BASE ALLOY S) Principles of NIPPON STEEL
24

25
3 . G UI DELI N ES CON CERN I N G BRI N ES ACCEPTABI LI TY FOR 1 3 CR, 1 7 CRS, 1 3 CRS, 1 3 CRM
DUPLEX STAI N LESS AN D CRA STEEL
4 . MECHAN I CAL AN D THERMAL PROPERTI ES
SEAMLESS CASING & TUBING
26 5 . COST COMPARI SON WI TH 1 3 CHROME

27 FEATURES OF PREMIUM CONNECTIONS

Quality
29 MATERIAL AND CONNECTION DESIGN Quality is the most fundamental element of our Casing & Tubing business. We understand that quality
leads to product reliability, which in turn leads to customer trust and that in the end, quality is the basis
30 API AND NIPPON STEEL PROPRIETRY STEEL GRADES COLOR CODE CHART
of our reputation. We will continue to be dedicated to maintaining and improving our quality standard.
32 I N Q UI RY AN D/ OR ORDER DETAI L

Technology
The more severe the drilling conditions, the greater our customers’ needs for cutting edge products.
We understand that customers rely on the quality of our products when they drill in harsh conditions,
and we are proud of our No. 1 technical position. We will continue to work through our R&D activities
to develop high-end products for the future.

Notice: While every effort has been made to ensure the accuracy of the information contained within this publication, the use of the information is at the Customer Satisfaction
reader’s risk and no warranty is implied or expressed by NIPPON STEEL CORPORATION with respect to the use of the information contained herein.
The information in this publication is subject to change or modification without notice. Please contact the NIPPON STEEL CORPORATION office for the Our goal is to be more than just a superior product supplier. We intend to also be a superior solutions
latest information. provider for our tubular products customers. We place importance not just on managing material sales,
Please refrain from unauthorized reproduction or copying of the contents of this publication. but also on “before” and “after service”. Customer satisfaction drives our constant and growing commit-
The names of our products and services shown in this publication are trademarks or registered trademarks of NIPPON STEEL CORPORATION, affiliated
companies, or third parties granting rights to NIPPON STEEL CORPORATION or affiliated companies. Other product or service names shown may be
ment to the oil and gas industries.
trademarks or registered trademarks of their respective owners.

1
 FACILITIES AND LOCATIONS MANUFACTURING SITES
NIPPON STEEL has almost all kinds of steel pipe manufacturing Amagasak i Steel Tub e Work s
facilities which produce a wide range of seamless and welded
steel pipe and tubes. The Steel Tube Works was established in 1919 as the first inte-
The main facilities are composed of our Amagasaki Steel Tube grated mill in Japan for the production of high quality seamless
Works and Wakayama Steel Works. steel tubes and pipe. Since then, the Works has specialized in
These works are able to produce approximately three million met- high quality steel tubes and pipes. NIPPON STEEL is commit-
ric tons of steel pipe and tubes annually. ted to ongoing research to improve manufacturing methods and
The company also possesses facilities in affiliated companies in. to upgrade quality.
NIPPON STEEL facilities and locations are tabulated below to-
gether with their available size ranges (O.D.).

● Location of Casing and Tubing Mills

Steel Research Laboratories (Amagasaki)

Amagasaki Works

Oita Works (Hikari)

Head Office
Steel Research Laboratories (Futtsu)
Nagoya Works
Wak ay ama Steel Work s
Wakayama Works (Wakayama)
Wakayama Works (Kainan)
Wakayama Steel Works is the integrated supply center for
seamless pipes. The steel billets are produced by a blast
furnace, converter, continuous-casting machine. Then, three
seamless pipe mills roll the billets into seamless pipes. Above
all, the medium-size seamless mill is the most advanced in the
world that is directly connected to a round CCM, combined with
NIPPON STEEL Tub e Mak ing Eq uip ment and Availab le Siz es a cone-type piercer with high cross angle, a mandrel mill and an
Outsid e Diameter in Inch es
in-line heat treatment furnace.
Location of
Tub e Mills
Work s
1 2 3 4 5 6 7 8 9 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 6 0
Mannesmann
K ainan 2 3/8 7
(2 sets)
Seamless (Hot Finished)

Wakayama Plant
1 3
Mannesmann Wakayama 5 /2 1 6 /4

Extrusion Amagasaki 2 3/8 9 5/8

Hollow Forging Amagasaki 8 2 8

ERW (Hot Finished) Cold Finished

Cold Drawn Amagasaki 2 3/8 2 0

ERW Hikari 1 2 2 4

ERW Nagoya 4 1/2 1 6

K ainan Plant

2 3
 MANUFACTURING PROCESS OF
SEAMLESS STEEL TUBES AND PIPES
CARBO N & ALLO Y E D STE E L MAK I NG P RO CE SS

Con ti n u ou s
Casti n g
M achi n e

R ou n d Bi l l et Medium siz e TU BE AND P I P E MAK I NG P RO CE SS

Bl ast F u rn ace Seamless
D esu l p hu ri z ati on D ep hosp hori z ati on D ecarb u ri z ati on P lant
R H -P B

Con e- ty p e P i ercer M an d rel M i l l Si z i n g M i l l

Bl oom Mannesmann
P rocess

Small siz e H ot F i n i shed Seaml ess

Seamless Steel P i p e
STANLE SS STE E L & Ni BASE ALLO Y S P lant
MAK I NG P RO CE SS I n g ot

Con e- ty p e P i ercer M an d rel M i l l Stretch R ed u ci n g M i l l

Bl oom
D ep hosp hori z ati on A O D ( A rg on O x y g en D ecarb u ri z ati on ) E x trusion P rocess

O 2 E x trusion
P rocess

V acu u m
H ot F i n i shed Seaml ess
V erti cal E x p an d i n g P ress H ori z on tal E x tru si on P ress Steel Tu b e an d P i p e
1,200t 4,000t

Hollow F orging P rocess

V O D L ad l e
Con ti n u ou s
Casti n g F orging
E l ectri c M achi n e P rocess
A rc F u rn ace V O D ( V acu u m O x y g en D ecarb u ri z ati on )

H ot F i n i shed Seaml ess

V erti cal P i erci n g P ress H ori z on tal P u sh Ben ch Steel P i p e
3,000t 1,500t / 600t

Col d D raw i n g Ben ch Col d F i n i shed Seaml ess

Bl oomi n g M i l l Bar M i l l Bi l l et
Steel Tu b e an d P i p e

4 5
 MATERIAL SELECTION GUIDELINES
Casing & Tub ing are b asically selected accord ing to PCO2 , PH2 S and temp erature of C steel & Low Alloy steel
th e environment
( M P a)

( b ar)

102 103
SM 25CR W 104
SM 13CR M - 9 5,110 SM 13CR S SM 2535- 110, 125 SM 2550- 110, 125

( p si )
10 102 SM 13CR I - 80 - 9 5,110 - 125 SM 2242- 110, 125 103
2

SM 13CR - 80,85 SM 17CR S SM 25CR SM 2035- 110, 125

2
P arti al P ressu re of CO

1 10 - 110,125 - 110, 125 102

P arti al P ressu re of CO
SM 22CR
10- 1 1 - 110, 125 10

10 -2 10- 1 A P I SM - 110E S A P I SM - 80X S 1

J 55 SM - 125E S L 80- 1 SM - 9 0X S
10- 3 10- 2 N 80Q SM - 125S C9 0 SM - 9 5X S 10- 1
P 110 T9 5- 1 SM - 110X S
10- 4 10- 3 ( Q 125- 1) C110 10- 2

10- 4 10- 3 10- 2 10- 1 1 10 102 103 ( b ar)

10- 5 10- 4 10- 3 10- 2 10- 1 1 10 102 ( M P a)
( p si )
10- 2 10- 1 1 10 102 103 104
P arti al P ressu re of H 2S
10 ( k P a) TE M P

232 ( 450F )

> 10( k P a) TE M P H 2S

> 20( k P a) H 2S

CO 2
10( k P a) TE M P

TE M P

Note : API Sour Service materials* can be applicable for any H2 S and any tem-
TE M P
perature only when performances of those grades are verified.

* : per NACE MR0175/ISO15156,

- Low grades: H40, J55 & K55
or any low alloy steels with HRC<22 and Ni content < 1%
- Medium grades: L80-1
20( k P a) - High grades: C90-1 & T95-1

N ote Cri ti cal temp eratu re of 22CR = 200

6 7
 AVAILABLE GRADES
Min. Yield API SPEC 5 CT SM SERIES / NT SERIES NEW SM SERIES
Strength ( p si)
SEAMLESS & ERW SEAMLESS & ERW SEAMLESS

GROUP 1 GROUP 2 GROUP 3 GROUP 4 GENERAL & HIGH COLLAPSE ARCTIC SOUR SERVICE SOUR SERVICE + COLLAPSE Wet CO2 Wet CO2 - Wet CO2 - SOUR CORROSION
DEEP WELL SERVICE CORROSION MILD SOUR WELL SERVICE
SERVICE General Arctic Mild Sour Enh anced Ex treme Enh anced Ex treme Sour WELL SERVICE CORROSION
Service Mild Sour Sour Mild Sour WELL SERVICE

40,000 H40

55,000 J55
K 5 5 N T- 5 5 HE

65,000 M65

80,000 N80Q L80-1 SM-80T SM-80L SM-80XS SM-80TXS SM13CR-80

L80-13CR NT-80DE NT-80HE NT-80LHE SM-80LL SM13CRI-80

85,000 SM13CR-85

90,000 C90-1 SM-90XS SM-90TXS

95,000 R95 T95-1 SM-95T SM-95L SM-95XS SM-95TXS SM13CR-95 SM13CRS-95

SM-95TT SM-95LL SM13CRM-95
NT-95HE

100,000

110,000 C110 P110 SM-110T SM-110L SM-110ES SM-110XS SM-110TES SM-110TXS SM13CRM-110 SM13CRS-110 SM2535-110 SM2550-110
SM-110TT SM-110LL SM17CRS-110 SM2242-110 SM2050-110
NT-110HE SM22CR-110 SM2035-110 SMC276-110
SM25CR-110

125,000 Q 1 2 5 -1 SM- 1 2 5 TT SM- 1 2 5 S SM- 1 2 5 ES SM- 1 2 5 TES SM1 7 CRS- 1 2 5 SM2 5 3 5 - 1 2 5 SM2550-125
SM2 2 CR- 1 2 5 SM2035-125 SM2050-125
SM2 5 CR- 1 2 5 SMC276-125
SM2 5 CRW- 1 2 5

130,000 SM-130G SM2535-140 SMC276-140

SM-130CY

140,000 SM-140G

Available grade: Black·····Seamless & ERW Blue·····Seamless Red·····ERW (Refer to ERW catalogue for detail information)

8 9
 MECHANICAL PROPERTIES
SPECIFICATION APPLICATION GRADE CHANICAL PROPERTIES REMARK S
Yield Strength Tensile Strength ELONGATION ( % ) HARDNESS HRC
min k si ( MPa) max k si ( MPa) min k si ( MPa)
API 5 CT G ROUP 1 H40 40 (276) 80 ( 552) 60 ( 414) API FORMULA
J55 55 (379) 80 ( 552) 7 5 ( 5 1 7 ) API FORMULA
K 5 5 55 (379) 80 ( 552) 95 ( 655) API FORMULA
N80Q 80 (552) 110 ( 758) 100 ( 689) API FORMULA
R95 95 (655) 110 ( 758) 105 ( 724) API FORMULA
G ROUP 2 M65 65 (448) 85 ( 586) 85 ( 586) API FORMULA HRC 2 2
L80-1 80 (552) 95 ( 655) 95 ( 655) API FORMULA HRC 2 3
L80-13CR 80 (552) 95 ( 655) 95 ( 655) API FORMULA HRC 2 3
C90-1 90 (621) 105 ( 724) 100 ( 689) API FORMULA HRC 2 5 .4 3~6
T95-1 95 (655) 110 ( 758) 105 ( 724) API FORMULA HRC 2 5 .4 3~6
C110 110 (758) 120 ( 828) 115 ( 793) API FORMULA HRC 30 3~6
G ROUP 3 P110 110 (758) 140 ( 965) 125 ( 862) API FORMULA
G ROUP 4 Q 1 2 5 -1 125 (862) 150 (1034) 135 ( 931) API FORMULA 3 ~ 5
SM SERI ES G SM-130G 130 (896) 160 (1103) 135 ( 931) API FORMULA
GENERAL & DEEP SM-140G 140 (965) 170 (1172) 150 (1034) API FORMULA
WELL SERV I CE SM-130CY 130 (896) 140 ( 965) 135 ( 931) API FORMULA 3 ~ 5
T, TT SM-80T 80 (552) 110 ( 758) 100 ( 689) API FORMULA <Collapse test>
HI G H COLLAPSE SM-95T 95 (655) 125 ( 862) 110 ( 758) API FORMULA Refer to Material Data Sheet on web site.
WELL SERV I CE SM-110T 110 (758) 140 ( 965) 125 ( 862) API FORMULA www.tubular.nipponsteel.com
SM-95TT 95 (655) 125 ( 862) 110 ( 758) API FORMULA
SM-110TT 110 (758) 140 ( 965) 125 ( 862) API FORMULA
SM- 1 2 5 TT 125 (862) 155 (1069) 135 ( 931) API FORMULA
S SM- 1 2 5 S 125 (862) 140 ( 965) 130 ( 896) API FORMULA HRC 36
MI LD SOUR
WELL SERV I CE
ES SM-110ES 110 (758) 125 ( 862) 115 ( 793) API FORMULA HRC 30
EN HAN CED MI LD SOUR SM- 1 2 5 ES 125 (862) 140 ( 965) 130 ( 896) API FORMULA HRC 36
WELL SERV I CE
X S SM-80XS 80 (552) 95 ( 655) 95 ( 655) API FORMULA HRC 2 2 <Corrosion Test>
EX TREME SOUR SM-90XS 90 (621) 105 ( 724) 100 ( 689) API FORMULA HRC 2 5 .4 Refer to the table on page 13.
WELL SERV I CE SM-95XS 95 (655) 110 ( 758) 105 ( 724) API FORMULA HRC 2 5 .4
SM-110XS 110 (758) 120 ( 828) 115 ( 793) API FORMULA HRC 30 Refer to Material Data Sheet on web site.
www.tubular.nipponsteel.com
TES SM-110TES 110 (758) 125 ( 862) 115 ( 793) API FORMULA HRC 30
EN HAN CED MI LD SOUR SM- 1 2 5 TES 125 (862) 140 ( 965) 130 ( 896) API FORMULA HRC 36
+ HI G H COLLAPSE
WELL SERV I CE
TX S SM-80TXS 80 (552) 95 ( 655) 95 ( 655) API FORMULA HRC 2 2 <Corrosion Test>
EX TREME SOUR SM-90TXS 90 (621) 105 ( 724) 100 ( 689) API FORMULA HRC 2 5 .4 Refer to the table on page 13.
+ HI G H COLLAPSE SM-95TXS 95 (655) 110 ( 758) 105 ( 724) API FORMULA HRC 2 5 .4
WELL SERV I CE SM-110TXS 110 (758) 120 ( 828) 115 ( 793) API FORMULA HRC 30 <Collapse test>
L, LL SM-80L 80 (552) 110 ( 758) 100 ( 689) API FORMULA
ARCTI C SM-95L 95 (655) 125 ( 862) 105 ( 724) API FORMULA
SERV I CE SM-110L 110 (758) 140 ( 965) 125 ( 862) API FORMULA
SM-80LL 80 (552) 110 ( 758) 100 ( 689) API FORMULA
SM-95LL 95 (655) 125 ( 862) 105 ( 724) API FORMULA
SM-110LL 110 (758) 140 ( 965) 125 ( 862) API FORMULA
N EW SM SERI ES Wet CO2 SM13CR-80 80 (552) 95 ( 655) 95 ( 655) API FORMULA HRC 2 3
CORROSI ON SM13CR-85 85 (586) 100 ( 689) 100 ( 689) API FORMULA HRC 2 4
WELL SERV I CE SM13CR-95 95 (655) 110 ( 758) 105 ( 724) API FORMULA HRC 2 7
SM13CRI-80 80 (552) 95 ( 655) 95 ( 655) API FORMULA HRC 2 5
SM13CRM-95 95 (655) 110 ( 758) 105 ( 724) API FORMULA HRC 28
SM13CRM-110 110 (758) 125 ( 862) 110 ( 758) API FORMULA HRC 3 2
Wet CO2 - MI LD SOUR SM13CRS-95 95 (655) 110 ( 758) 105 ( 724) API FORMULA HRC 28
CORROSI ON SM13CRS-110 110 (758) 125 ( 862) 110 ( 758) API FORMULA HRC 3 2
WELL SERV I CE SM17CRS-110 110 (758) 135 ( 931) 120 ( 828) API FORMULA HRC 36
SM1 7 CRS- 1 2 5 125 (862) 145 (1000) 130 ( 896) API FORMULA HRC 38
SM22CR-110 110 (758) 140 ( 965) 125 ( 862) 1 2 HRC 36
SM2 2 CR- 1 2 5 125 (862) 145 (1000) 130 ( 896) 1 1 HRC 3 7
SM25CR-110 110 (758) 140 ( 965) 125 ( 862) 1 2 HRC 36
SM2 5 CR- 1 2 5 125 (862) 145 (1000) 130 ( 896) 1 1 HRC 3 7
SM2 5 CRW- 1 2 5 125 (862) 145 (1000) 130 ( 896) 1 1 HRC 3 7
Wet CO2 - SOUR SM2535-110 110 (758) 140 ( 965) 115 ( 793) 1 2 HRC 3 2
CORROSI ON SM2 5 3 5 - 1 2 5 125 (862) 145 (1000) 130 ( 896) 10 HRC 3 4
WELL SERV I CE SM2535-140 140 (965) 165 (1138) 145 (1000) 10 HRC 40
SM2242-110 110 (758) 140 ( 965) 115 ( 793) 1 3 HRC 3 2
SM2035-110 110 (758) 140 ( 965) 115 ( 793) 1 1 HRC 3 2
SM2035-125 125 (862) 140 ( 965) 130 ( 896) 9 HRC 3 3
SM2550-110 110 (758) 140 ( 965) 120 ( 828) 1 5 HRC 3 3
SM2550-125 125 (862) 145 (1000) 130 ( 896) 1 3 HRC 36
SM2050-110 110 (758) 140 ( 965) 120 ( 828) 16 HRC 3 4
SM2050-125 125 (862) 145 (1000) 130 ( 896) 1 4 HRC 36
SMC276-110 110 (758) 140 ( 965) 115 ( 793) 20 HRC 38
SMC276-125 125 (862) 145 (1000) 130 ( 896) 1 4 HRC 38
SMC276-140 140 (965) 160 (1103) 145 (1000) 10 HRC 40

10 11
 SM-SERIES GRADE DESCRIPTION
1 . CASING AND TUBING FOR GENERAL AND DEEP WELL SERVICE 2 . CASING AND TUBING FOR SOUR OIL AND GAS SERVICE
SM-G meant for general and deep well service are remarkable for their high yield and tensile strengths while maintaining good ductil- In order to prevent possible sulfide stress corrosion cracking in sour gas and oil wells containing H2 S, it is necessary to use specially
ity and fracture toughness. manufactured tubing and casing. API 5CT Group 2 grade tubing and casing have been developed and used widely for this purpose.
SM-130G and SM-140G offer additional tensile and yield strengths for deep well services. However these may not be adequate in high concentration of H2 S.
To address this, NIPPON STEEL, after years of research and development, has succeeded in developing improved materials with
higher strength and higher corrosion resistance for casing and tubing.
Yield Strength Tensile Strength Imp act Prop erties min Ave Value These are available in our SM-XS for extreme sour service, SM-ES for Enhanced mild sour service series as shown below.
Grad e Elongation min %
min p si ( MPa) max p si ( MPa) min p si ( MPa) At 32˚F (0˚C) Ft-lb (J)
NIPPON STEEL does not recommend SM sour series 100ksi and higher grade for tubing applications.
SM-130G 130,000 ( 896) 160,000 (1103) 135,000 ( 931) Each of these grades is produced with rigid manufacturing controls covering chemical composition, heat treatment (quenching and
API Formula 20 (27) (Specimen: 10 by 10 mm)
SM-140G 140,000 ( 965) 170,000 (1172) 150,000 (1034) tempering), tensile property, hardness and microstructure.

Mech anical Ch aracteristics SSC test

Tensile
Yield Strength HRC NACE TM0 1 7 7 Meth od e- A DCB
CHARACTERISTICS Ty p e Grad e Strength
min k si max k si min k si H2 S Ap p lied Average
1 . Tensile Strength max . Solution
( MPa) ( MPa) ( MPa) ( b ar) stress . K 1 SSC
The resistance to collapse and the longitudinal high strength C90 90 (621) 105 (724) 100 (689) 2 5 .4 1 A 80%SMYS
requirements of well casing is becoming increasingly important API T95 95 (655) 110 (758) 105 (724) 2 5 .4 1 A 80%SMYS
with the drilling of deeper and deeper wells. SM130G and SM-
C110 110 (758) 120 (828) 115 (793) 30.0 1 A 85%SMYS
140G offer the high strength properties.
SM-80XS 80 (552) 95 (655) 95 (655) 22.0 1 A 90%SMYS

Extreme SM-90XS 90 (621) 105 (724) 100 (689) 2 5 .4 1 A 90%SMYS

2 . Mech anical Prop erties
Sour SM-95XS 95 (655) 110 (758) 105 (724) 2 5 .4 1 A 90%SMYS
Mechanical properties of SM-G series are shown in above
Table. SM130G and SM140G offer the required high strength SM-110XS 110 (758) 120 (828) 115 (793) 30.0 1 A 85%SMYS
Yi el d Stren g th ( k si )
properties. 40 60 80 100 120 140 160 180 SM-80XSD 80 (552) 95 (655) 95 (655) 22.0 1 A 90%SMYS 30ksi√in

Extreme SM-90XSD 90 (621) 105 (724) 100 (689) 2 5 .4 1 A 90%SMYS 30ksi√in

Sour +DCB SM-95XSD 95 (655) 110 (758) 105 (724) 2 5 .4 1 A 90%SMYS 30ksi√in
N o SSC SM-110XSD 110 (758) 120 (828) 115 (793) 30.0 1 A 85%SMYS 24ksi√in
150
Ap p lication of High Strength SSC SM-80TXS 80 (552) 95 (655) 95 (655) 22.0 1 A 90%SMYS
Temp eratu re ( ° C)

Grad es for Deep Sour Gas & Oil Wells R . D . K an e et. , al . Extreme SM-90TXS 90 (621) 105 (724) 100 (689) 2 5 .4 1 A 90%SMYS
Sour
The smallest amount of H2 S contamination should always be +Collapse SM-95TXS 95 (655) 110 (758) 105 (724) 2 5 .4 1 A 90%SMYS
100
taken into consideration when looking at high strength material SM-110TXS 110 (758) 120 (828) 115 (793) 30.0 1 A 85%SMYS
applications. SM-80TXSD 80 (552) 95 (655) 95 (655) 22.0 1 A 90%SMYS 30ksi√in
Fig shows the applicability of high strength steels for sour ser- N o SSC SSC Extreme SM-90TXSD 90 (621) 105 (724) 100 (689) 2 5 .4 1 A 90%SMYS 30ksi√in
Sour +DCB
vice integrating the following variables: H2 S concentration, ap- 50 +Collapse SM-95TXSD 95 (655) 110 (758) 105 (724) 2 5 .4 1 A 90%SMYS 30ksi√in
plied stress level and temperature. SM-110TXSD 110 (758) 120 (828) 115 (793) 30.0 1 A 85%SMYS 24ksi√in
Sulfide stress corrosion cracking susceptibility increases with Mild Sour SM- 1 2 5 S 125 (862) 140 (965) 130 (896) 36.0 0.03 B (pH3.5) 85%SMYS
material strength and grades such as SM140G should never be 300 600 9 00 1200 SM-110ES 110 (758) 125 (862) 115 (793) 30.0 0.1 B (pH3.5) 85%SMYS
Enhanced
used if H2 S is present. Yi el d Stren g th ( M P a) Mild Sour SM- 1 2 5 ES 125 (862) 140 (965) 130 (896) 36.0 0.1 B (pH3.5) 85%SMYS
Enhanced SM-110TES 110 (758) 125 (862) 115 (793) 30.0 0.1 B (pH3.5) 85%SMYS
Mild Sour
+Collapse SM- 1 2 5 TES 125 (862) 140 (965) 130 (896) 36.0 0.1 B (pH3.5) 85%SMYS
st
NIPPON STEEL renewed sour service line-up since 1 October, 2012. For detailed information, please check www.tubular.nipponsteel.com

12 13
 CHARACTERISTICS 3 . HIGH COLLAPSE CASING FOR DEEP WELL SERVICE
1 . Materials
NIPPON STEEL High Collapse Casing SM-T grade is a seamless product designed for deep wells where high collapse pressures
The chemical compositions have been carefully determined to 100 *
[ Su p ercri ti cal are anticipated. In order to meet deep well service requirements, SM-T casing has improved collapse properties well in excess of
provide resistance to sulfide stress corrosion cracking as well as en v i ron men t]
N o crack API ratings. These properties are achieved by strict mill control incorporating a unique production technique inclusive of quenching
to insure complete through wall hardening. Cri ti cal p oi n t and tempering. SM-T casing shows a very high resistance to tension load, internal pressure, and collapse. SM-TES, TXS, TXSD
80 series are also highly resistant to sulfide stress corrosion cracking and can be used for deep and sour gas and oil service.
2 . Heat Treatment
Quenching and tempering are conducted under rigid tempera-
ture control to assure homogeneous physical properties Yield Strength Tensile Strength

S p ressu re ( b ar)
60 Grad e Elongation min % Collap se Resistance
and microstructures. min p si ( MPa) max p si ( MPa) min p si ( MPa)
[L iq u id H S]
New Higher Strength Sour Resistant Grades SM-110ES, SM- 2

* SM- 80T 80,000 (552) 110,000 ( 758) 100,000 (689) API Formula
125ES, SM-110XS, SM-110TXS, have been developed.
SM- 95T 95,000 (655) 125,000 ( 862) 110,000 (758) API Formula
40 Refer website
[ G as H S] SM- 95TT 95,000 (655) 125,000 ( 862) 110,000 (758) API Formula

2
2
3 . Micro Structure www.tubular.nipponsteel.com

H
SM-110T 110,000 (758) 140,000 ( 965) 125,000 (862) API Formula or ask Nippon Steel representative
These grades exhibit fully tempered martensite which is con-
SM-110TT 110,000 (758) 140,000 ( 965) 125,000 (862) API Formula
sidered to be the most desirable for resistance to sulfide stress SM - 110X S
20 SM- 1 2 5 TT 125,000 (862) 155,000 (1069) 135,000 (931) API Formula
corrosion cracking.

4 . Tensile Prop erties and Hard ness

Yield strength is limited within a narrow range and hardness is 0
0 20 40 60 80 100 120 140 160
controlled to within the predetermined maximum limit.
Temp l atu re ( )

5. Sulfide Stress Cracking (SSC) Performance Crack ing susceptibility as a function of temperature and H2S As wells are drilled deeper, the external pressures applied to well casings become greater. Thus, a well casing must have adequate
SM sour resistant grades are designed for 85% or 90% SMYS pressure ( M ethod : 4 p oi n t b en d test u n d er ap p l i ed stress of 9 0%
actu al YS, H 2S p ressu re: 10- 100b ar, test temp eratu re: 24- 107° C, collapse strength to withstand these horizontal pressures without deformation. For reasons of economy such casings should also be
in NACE condition. test sol u ti on : 5% N aCl , test d u rati on : 720h, 2160h) * : 2160h test as light-weight as possible while still retaining ample collapse resistance properties.
Excellent SSC resistance has been achieved through rigorous, With this in mind NIPPON STEEL has developed its SM-T High Collapse Casing. This casing was developed from experiments in
chemical composition, heat treatment, microstructure, which NIPPON STEEL studied the critical collapse pressure of a well casing under external pressure in relation to its longitudinal
tensile properties, hardness and so on. tensile strength and the geometry of its cross section.

Sp eci f i ed M i n i mu m Col l ap se P ressu re CHARACTERISTICS

20,000
E x amp l e of
A ctu al D ata 1 . Uniq ue Prod uction Tech niq ue
: SM - 9 5T The material for SM-T casing is carefully selected to insure
: SM - 110T
: SM - 125TT structural homogeneity. Strict control of heat treatment and

SM
dimensional tolerances are adhered to throughout the manufac-

-1
25
15,000
turing process.

TT M - 1
S
Col l ap se p ressu re ( p si )

10
2 . Rigid Dimensional Control

T
SM
-9
Dimensional tolerances, such as roundness, straightness, O.D.

5T
10,000 and wall thickness are strictly controlled.

A P 3. Specified Collapse Value

A P IP
IC -1
10 A collapse test is carried out on each production run of SM-T
-R
5,000
9 5 casing with the same frequency as the tensile test.

12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27
Sustain load type
D /t
Sulfide stress corrosion cracking test
apparatus

14 15
 NEW SM-SERIES
4 . CASING AND TUBING FOR ARCTIC SERVICE 1 . 1 3 CR, Sup er 1 3 CR, Sup er 1 7 CR and Dup lex Stainless Steel
NIPPON STEEL SM-L grades are designed for high impact CHARACTERISTICS 1 .1 Ch emical comp osition
toughness at subzero temperatures, as this is experienced in Ch emical comp osition ( w t % )
1 . Material Grad e
arctic regions. C Si Mn Cu Ni Cr Mo W N
These properties are achieved through tight material chemistry Special steel is used in order to obtain sufficient resistance to 12.0
SM1 3 CR 0.22 1.00 1.00 0.25 0.5
low temperature impact. ~14.0
control and specific heat treatment. 1 .5 10.5 0.2
SM1 3 CRI 0.03 0.50 1.50
The following Tables show tensile and impact toughness prop- ~3.0 ~ 1 2 .5 ~0.4
erties. 2 . Heat Treatment 4.0 11.0 0.2
SM1 3 CRM 0.03 0.50 1.00
Both casing and couplings are quenched and tempered with ~6.0 ~14.0 ~ 1 .2
special care. 5.0 1 1 .5 1 .5
SM1 3 CRS 0.03 0.50 0.50
~6.5 ~ 1 3 .5 ~3.0
Tensile Properties 2.0 4 .5 16.0 2.0
SM1 7 CRS 0.03 0.50 0.50
Yield Strength
3 . Imp act Prop erties ~3.0 ~ 5 .5 ~18.0 ~3.0
Tensile Elongation
Refer b elow tab le. 4 .5 21.0 2 .5 0.08
Grad e min p si max p si Strength min min % SM2 2 CR 0.03 1.00 2.00
~6.5 ~23.0 ~ 3 .5 ~0.20
( MPa) ( MPa) p si ( MPa) in 2 inch es
0.2 5 .5 24.0 2 .5 0.10 0.10
SM2 5 CR 0.03 0.75 1.00
SM-80L 80,000 110,000 100,000 ~0.8 ~ 7 .5 ~26.0 ~ 3 .5 ~0.50 ~0.30
SM-80LL (5 5 2 ) (758) (689) 0.2 6.0 24.0 2 .5 2.01 0.24
SM2 5 CRW 0.03 0.80 1.00
SM-95L 95,000 125,000 105,000 API ~0.8 ~8.0 ~26.0 ~ 3 .5 ~2.50 ~0.32
SM-95LL (655) (862) (7 4 2 ) Formula
SM-110L 110,000 140,000 125,000 1 . 2 CO2 Corrosion Resistance
SM-110LL (758) (965) (862)
(1) High Cr steels such as 13Cr stainless steels are resistant to (2) Effect of Cr content and temperature on CO2 corrosion are
CO2 corrosion and have been used widely, and successfully shown in following Figures. For 13CR & 13CRI critical tem-
Impact Toughness Properties (Charpy impact value) in wells containing CO2 and CL- . perature is 150°C and for 13 CRM & 13CRS that is 180°C.
Duplex stainless steels (25Cr) have excellent corrosion
Min. Average
Min. Value of resistance up to a temperature of 250°C.
Value of Each
Siz e of One Sp ecimen
Grad e Set of Th ree
Sp ecimen mm Only of a Set
Sp ecimens Temp eratu re ( ° F )
ft-lb (J)
ft-lb (J)
0 100 200 300 400 500 600
10 by 10 20 (27) 15 (20)
SM-80L 70
10 by 7.5 15 (20) 1 1 (1 5 )
SM-95L
10 by 5 10 (14) 8 (11)
SM-110L C- steel 2500
10 by 2.5 5 ( 7 ) 4 ( 5 )
60 2Cr
Test temperature : −50 F (−46°C)
5Cr
9 Cr- 1M o
50 2000
13Cr
Min. Average

Corrosi on rate ( mp y )
Min. Value of 22Cr/ 25Cr

Corrosi on rate ( mm/ y )

Value of Each 15
Siz e of One Sp ecimen
Grad e Set of Th ree 40
Sp ecimen mm Only of a Set 1500
Sp ecimens
ft-lb (J) 500
ft-lb (J)

Corrosi on rate ( mm/ y )

SM-80LL 10 by 10 2 3 .1 (3 1 ) 1 5 .4 (2 1 ) 30

Corrosi on rate ( mp y )
10
SM-95LL 10 by 7.5 18.5 (25) 1 2 .3 (1 7 ) 1000
SM-110LL 10 by 5 1 2 .7 (1 7 ) 8.5 (12)
20
Test temperature : −67 F (−55°C)

5 500
10

0
0 0 0
0. 01 0. 05 0. 1 0. 5 1 5 10 0 100 200 300
Cr con ten t ( w t. % ) Temp eratu re ( ° C)

E ffect of Cr content of commercial tubular goods on corrosion rate by loop tester E ffect of temperature on corrosion rate by autoclave
( Sy n theti c sea w ater, CO 2 p arti al p ressu re 0. 1 M P a ( 60° C) , test temp eratu re 60° C, ( Sy n theti c sea w ater, CO 2 p arti al p ressu re ; 3. 0 M P a ( R . T. ) , test d u rati on 72h,
test d u rati on 150h, f l ow v el oci ty 2. 5 m/ s, sp eci f i c v ol u me : 800 cc/ cm2) f l ow v el oci ty 2. 5 m/ s, sp eci f i c v ol u me : 42 cc/ cm2)

16 17
 0. 05 0. 5 5 20 0. 05 0. 5 5 20
100° C 150° C
Sol i d : G en eral corrosi on
5 H al f Sol i d : P i tti n g
( A ) 13Cr
9 Cr- 1M o 5 O p en : P assi v e
13Cr ( 420) 3. 0 M P a
SM 22Cr- D u p l ex CO 2 100
0. 1 M P a L 80- 13Cr
SM 25Cr- D u p l es SM 13CR S
50
1 SM 13CR M A

Corrosi on rate ( mm/ y )

Corrosi on rate ( mm/ y )

0. 5

Corrosi on rate ( mp y )
1

Corrosi on rate ( mm/ y )

10
B
0. 5 5
0. 1
( B) 25Cr

10
0. 2 5
0. 1
0. 1
CO 2 = 3. 0M P a
25w t% N aCl
50 100 150 200 250 ( ° C)
102 103 104 105 102 103 104 105 0 100 200
Cl - ( p p m) 100 200 300 400 500 (°F ) Testi n g temp e ratu re ( ° C)

E ffect of Cl- low concentration on the corrosion rate of Cr steels at 1 5 0 ° C in the E ffect of CO 2 partial pressure and temperature on corrosion rate of Cr steel Effect of temp erature on corrosion rate of conventional 1 3 CR, SM1 3 CRS and SM1 3 CRM in CO2 environment
autoclave. ( 3. 0M P a CO 2 at 25° C, test d u rati on 9 6hr, f l ow v el oci ty 2. 5 m/ s) ( 5% N aCl , CO 2 3. 0 an d 0. 1 M P a at 25° C, test d u rati on 9 6hr, f l ow v el oci ty 2. 5 m/ s) (3.0MPa (450psi) CO2 , 150,000ppm Cl- )

N o Crack reg i on of Su p er 13Cr- 110 N o Crack reg i on of Su p er 13Cr- 110

1 6. 0 6. 0
10
Sol i d mark : Crack ed N o Crack N o Crack
1 Crack Crack
H al f Sol i d : P i tti n g 5. 5 5. 5
G C : G en eral Corrosi on G C
100 G C
5. 0 5. 0
13Cr N o Crack reg i on N o Crack reg i on
of Su p er 17Cr of Su p er 17Cr
1
Corrosi on rate ( mm/ y )

Corrosi on rate/ mm- y ear –

10- 1 4. 5 4. 5

p H

p H
SM 13CR S 4. 0 4. 0
0. 1
10- 2
3. 5 3. 5

22Cr 3. 0 3. 0
10- 3 30b arCO 2, 80° C, 336hr F u rther A ssessmen t R eq u i red
F u rther A ssessmen t R eq u i red
: G en eral corrosi on
: P i tti n g
2. 5 2. 5
0 50 100 150 200 0 50 100 150 200
10 -4 0. 01
0 50 100 150 200 0 10 20 Temp eratu re ( ° C) Temp eratu re ( ° C)
Temp eratu re ( ° C) N aCl con cen trati on / w t% ( ) 1,000mg / l Cl - ( ) 181,000mg / l Cl -

E ffect of temperature on corrosion resistance of SM1 3 CRS The reration of pitting occurrence and NaCl concentration E ffect of pH and Temprature on E AC Susceptibility of Super 1 7 Cr-1 25 in 0 .0 0 1 MP a H2S+CO 2
( 5% N aCl + 3. 0M P a ( 450p si ) CO 2 + 0. 001M P a ( 0. 15p si ) H 2S) ( Con v en ti on al 13Cr) ( Test M ethod : N A CE M ethod A i n 0. 001M P a H 2S+ 0. 09 9 M P a CO 2 at R T, 4P B i n 0. 001M P a H 2S + 3M P a CO 2 at temp eratu re 9 0° C)

18 19
 1.3 Sulfide Stress Corrosion Cracking (SSCC) Resistance 1 .4 Erosion Prop erties

(1) 13CR has a high SSCC susceptibility as shown in below (3) Duplex stainless steels (SM22CR, SM25CR, SM25CRW) (1) 13CR, Super 13CR and Duplex stainless steels have supe-
fig; 13CR usage is not advisable for usage in environments are recommendable over marternsitic stainless steel rior erosion properties.
containing a small amount of H2 S ( 0.003bar). (SM13CRS) in a small amount of H2 S.
(2) 13CRS has good SSCC resistance in environments con-
Effect of Flow velocity (Field test results)
taining up to 0.03bar H2 S. Average test conditions in the DFT (Dynamic Field Tester) experiments 1 (Test duration: 3672h) and 2 (Test duration: 4493h)
Cal cu l ated H 2 S at 80° C ( M P a) Pressure Temp erature
10– 10– 3 Internal Gas flow rate Gas velocity
4
10– 2
10– 1
Ex p eriment Flow p attern
d iameter ( mm) ( m3 / h ) ( p si) ( MPa) ( F) (K )
( m/ s)
13Cr ( Y. S. 602M P a) 13Cr ( Y. S. 768M P a) : Ty p e 316L : SM 25CR
: SM 25CR W
Temp eratu re ( ° C)

Temp eratu re ( ° F ) : SM 22CR SM 25CR

150 300 5 2 9000 1960 13.8 190 361 17.6 Transition Annular mist
Sol i d mark : Crack SM 25CR W
100 SM 22CR 25Cr
200 2 7 9000 1917 1 3 .5 190 361 66.6 Annular mist
Ty p e 316L 22Cr 1
50 100 10

Cl - con cen trati on ( p p m)

5
20 9000 1 7 7 5 1 2 .5 188 360 1 3 1 .4 Annular mist
25Cr ( Y. S. 553M P a) 25Cr ( Y. S. 822M P a)
1 5 9000 1661 1 1 .7 188 360 250.5 Annular mist
104
Temp eratu re ( ° F )
Temp eratu re ( ° C)

150 300 5 2 7860 1 7 5 5 1 2 .1 181 3 5 5 10.6 Transition

100 200
103 2 7 7860 1726 11.9 1 7 5 3 5 2 39.7 Annular mist
50 100 2
20 7860 1598 1 1 .1 1 7 5 3 5 2 78.2 Annular mist
10– 4
10– 3
10– 2 10– 4
10– 3
10– 2

10 2
P H 2S ( M P a) 1 5 7860 1406 9.9 1 7 1 350 1 5 7 .1 Annular mist
E ffect of H2S partial pressure and temperature on the SSCC susceptibility.
5% N aCl , 3. 0M P a CO 2 + H 2S at 25° C ( 77° F ) , test d u rati on 336h, f l ow v el oci ty
10– 4 10– 3
10– 2 10– 1
2. 5m/ s, 1σy w i th n otch
H 2 S ( M P a)

SCC susceptibility of duplex stainless steel in Cl--H2S environment. 13Cr ( E x p . 1)

13Cr Cr:12-16% Ni:5-7% : No SCC, : SCC 13Cr ( E x p . 2)
( SSR T method ; 80° C, strai n rate 4. 2 x 10– 6/ s) ( an n eal ed ) SM 13CR S ( E x p . 2)
120°C D P 1 ( E x p . 2)
0. 2
SM 22Cr ( E x p . 1)
0. 1 0. 1 SM 22Cr ( E x p . 2)

0. 05

Corrosi on rate ( mm/ y )

0. 01

0. 001 0. 01
1. 2
0. 005
SM 25CR W
60°C SM 25CR W
Corrosion rate (mm/y)

SM 25CR
0. 1 1 0. 001
SM 25CR 0. 0005
0. 01

0. 8 0. 0001
0. 001
L /L 0

0 50 100 150 200 250 300

G as v el oci ty V sG ( m/ s)
25°C
0. 6
E ffect of flow velocity on corrosion rate of 1 3 Cr, SM1 3 CRS,
0. 1 D P 1 , and SM22Cr steels in the D F T ex periments 1 and 2.

0. 01
0. 4

0. 001
( : SSC, : N o SSC, : P i tti n g )
0. 2
13Cr 1M o 2M o 3M o 0. 5 1 2 5 10
SM 13CrS Cl - ( 104 p p m)

E ffect of Mo content on corrosion rate and SSCC. < SM1 3 CRS> SCC susceptibility of duplex steel in Cl--H2S environment.
( 5% N aCl + 3. 0M P a ( 450p si ) CO 2 + 0. 001M P a ( 0. 15p si ) H
4-point bent beam with notch, 1σy, 336h
2S
( : No SCC, : SCC
( SSR T method ; 80° C, Cal cu l ated H 2S 0. 015M P a, strai n rate 4. 2 x 10- 6/ s)

20 21
 2 . H2 S+ CO2 + Cl- CORROSION ( Ni BASE ALLOYS)
High Alloy Materials become necessary where severe well con- (3) The effect of fundamental elements on corrosion behaviors 300
W i thou t CH 3CO O H ( p H : H i g h)
N o SCC
ditions with high concentrations of H2 S, CO2 and CI- brines are are shown in the following Figures. i n 10 mon ths
SCC i n 3 mon ths
SCC i n 10 mon ths
encountered. These can be recapped as follows.

Temp eratu re ( ° C)
250
(1) High Ni corrosion resistant alloys for OCTG feature a single • Application limit temperature is strongly depending on Mo
N o SCC
austenitic phase. Strength is developed through cold work- content in the Ni Base Alloys. i n 10 mon ths

ing. • In combined H2 S, CO2 , Cl- media, the basic minimal chem- 200

Addition of essential alloying elements such as Cr, Ni, Mo istry of Cr 18%, Ni 28%, Mo 3% is required. 20Cr
15
determines the corrosion resistance properties. • Hydrogen embrittlement susceptibility increases with ma- 150
0 3 5 9 12 15 18 p H 0. 5
(2) Resistance to general (weight loss) corrosion and localized terial chemistries exceeding 60% Ni. M o(% ) 12
H E
(pitting and crevice) corrosion is achieved by the formation (4) Elemental S is very aggressive to SCC. SM2050 and SM 2050
W i th 0. 5% CH CO O H ( p H : L ow )
of a stable passivation film on the material surface. SMC276 is applicable depending on environmental tem-

M o(% )
3
9
300
N o SCC SCC i n 3 mon ths p H 2. 0
perature. i n 10 mon ths SCC i n 10 mon ths
6

Temp eratu re ( ° C)
250
N o SCC
i n 10 mon ths 3
Ch emical Comp osition ( mass % )
Grad e 200
0
C Si Mn Cu Ni Cr Mo Ti W Fe 30 40 50 60 70
N i (% )
29.5 24.0 2.50
SM2 5 3 5 0.03 0.50 1.00 1 .5 Bal 150
~36.5 ~27.0 ~4.00 0 3 5 9 12 15 18 Corrosion resistant region– pH– alloying element
M o(% ) ( 1) Corrosi on resi stan ce p H 2 ; N o SCC an d C. R . 0. 05 mm/ y ,
1.50 38.0 19.5 2.50
SM2 2 4 2 0.05 0.50 1.00 1.20 Bal ( 2) E n v i ron men t, SCC : 20% N aCl + 0. 5% CH 3CO O H – 1. 0 M P a
~3.00 ~46.0 ~24.0 ~4.00 E ffect of Mo and temperature on SCC resistance H 2S – 1. 0 M P a CO 2 – 250° C, H E : N A CE TM 01- 77 sol u ti on , I ron
33.0 20.5 4.00 0.20 ( C ri n g test, 20% N aCI , 1M P a H 2S + 1 M P a CO 2, 100% YS) cou p l i n g / 400° C 1,000h ag i n g )
SM2035 0.03 0.75 1.00 0.07 Bal
~38.0 ~ 2 3 .5 ~5.00 ~0.80
47.0 23.0 6.00
SM2550 0.03 1.00 1.00 1.20 0.69 3.0 Bal
~54.0 ~26.0 ~9.00
49.0 19.0 10.1
SM2050 0.03 0.50 1.00 2.00 1.50 Bal
~53.0 ~23.0 ~12.0
1 4 .5 15.0 3.0 4.0
SMC276 0.01 0.08 1.00 Co 2 .5 Bal V 0.35
~16.5 ~17.0 ~ 4 .5 ~7.0

SCC SCC
250° C ( 482° F ) 300° C( 572° F ) 350° C( 662° F ) SM C276
0 0 0
450 232 450 232

Temp eratu re ( ° C)
Temp eratu re ( ° C)

Temp eratu re ( ° F )
Temp eratu re ( ° F )
3 3 3
400 204 400 204
6 6 6 L ocal i z ed
SM 2050 corrosi on
0 0 0 350 177 350
10 10 Corrosi on - 10 177
Corrosi on - resi stan t resi stan t
3 3 reg i on 3 SM 2550
Corrosi on - resi stan t reg i on 300
reg i on 300 N o SCC 149 149
6 15 6 15 6 15
M o(% )
M o(% )

M o(% )

30 30 30 SM 2242
SM 2535
C
C

SC

25 25 25
C
SC

SC

10 10 10
SC

3 6 9 12 15 3 6 9 12 15 18
TG
TG

IG

20 20 20
TG
)

M o ( mass % )
(%

(%

(%

15 15 15 M o+ 1/ 2W ( w t% )
Cr

Cr

Cr

15 15 15
60 40 20 0 60 40 20 0 60 40 20 0
N i (% ) N i (% ) N i (% ) Relationship between testing temperature and Mo+½W content of Ni Base Alloys The relationship between testing temperature and Mo content of Ni-base alloys
in H2S-CL- environment in the SSRT tests. in an elemental S-containing sour environment.
Corrosion resistant region of F e-Cr-Ni-Mo alloy ( 20 % NaCl+0 .5 % CH3 CO O H, 1 .0 MP a H2S-1 .0 MP a CO 2 -pH 2) ( SSR T test con d i ti on ; 25% N aCl - 0. 5% CH 3CO O H , 0. 7M P a H 2S, E = 4. 0 10– 6S– 1) ( 25% N aCl + 1g / S, 1. 0M P aH 2S+ 1. 0M P aCO 2, 4P B w i th n otch A p p l i ed Stress;
100% SM YS( 110k si ) , 336h)

22 23
 3 . Guid elines concerning Brines accep tab ility for 1 3 CR, 1 7 CRS, 1 3 CRS, 1 3 CRM, 4 . Mech anical and Th ermal Prop erties
Dup lex stainless and CRA steel
Mechanical properties
The below guidelines are based on laboratory testing excluding quently the brine “package” suitability and long term stability Specific Gravity
Young’ Mod ulus ( GPa) Poisson’ s Ratio
O2 contamination or usage of common brine additives such as needs to be carefully ascertained prior to usage. ( x 1 0 3 k g/ m3 )
corrosion inhibitors, biocide, oxygen scavengers, etc. Conse- No Grad e 2 5 °C 2 5 °C 1 0 0 °C 2 0 0 °C 2 5 0 °C 2 5 °C 1 0 0 ° C 2 0 0 ° C 2 5 0 ° C
1 SM-95XS 7.80 2 1 3 209 203 200 0.30 0.29 0.29 0.28
2 SM-110XS 7 .7 5 2 1 2 209 203 200 0.30 0.30 0.29 0.29
1 7 CRS, 1 3 CRS, 3 SM- 1 2 5 S 7.80 2 1 2 209 203 200 0.30 0.30 0.29 0.29
C- steel 1 3 CR 2 2 Cr ( Dup lex s. s. )
PH 1 1 3 CRM
4 SM13CR-80 7 .7 1 2 2 1 2 1 7 2 1 1 208 0.30 0.29 0.29 0.29
Corrosion 2
Corrosion 3
SCC 5
Pitting 4
SCC 5

5 SM13CRM-110 7.68 204 202 196 192 0.29 0.30 0.30 0.29
N aCl
6 SM13CRS-95 7 .7 3 203 200 194 190 0.30 0.30 0.30 0.29
CaCl2
7 SM13CRS-110 7 .7 2 202 198 193 189 0.30 0.29 0.30 0.29
MgCl2
8 SM17CRS-110/125 7.80 194 190 184 181 0.32 0.31 0.29 0.31
Z nCl2
9 SM22CR-110 7.85 198 194 184 189 0.25 0.24 0.23 0.24
N aBr
10 SM25CR-110 7.85 191 184 1 7 7 193 0.26 0.25 0.24 0.27
CaBr2
1 1 SM2 5 CRW- 1 2 5 7.85 200 198 191 188 0.27 0.27 0.27 0.27
MgBr2
1 2 SM2535-110 8.07 205 194 189 187 0.31 0.29 0.30 0.30
Z nBr2
1 3 SM2242-110 8.14 210 197 184 187 0.31 0.29 0.28 0.29
(1g/m2 /h=1.1mm/year) 1 4 SM2035-110 8.10 203 194 181 1 7 7 0.32 0.30 0.31 0.30
1) In 60°C, 0.1MPaCO2 1 5 SM2550-110 8.29 2 1 1 195 186 185 0.31 0.29 0.29 0.28
: pH 4
: 3 pH 4 16 SM2050-110 8.58 216 201 192 196 0.33 0.31 0.31 0.31
: pH 3 1 7 SMC276-110 8.87 220 207 197 196 0.33 0.31 0.31 0.31

2.3) Autoclave test 150°C, 0.4MPaCO2

2 )
: C. R. 1g/m2 / h Thermal properties
: 1 C. R. 10 Th ermal
: C. R. 10 Th ermal Diffusivity Heat Cap acity Th ermal Cond uctivity Specific Heat
ex p ansion
( x 1 0 – 6 m2 / s) ( x 1 0 6 J/m3 / d eg- C) ( W/ m / d eg- C) (J/kg /deg-C)
( x 1 0 – 6 / d eg- C)
3 ) Brines identified with are acceptable for Completion & packer fluid
applications. 2 5 - 2 5 - 2 5 -
: C. R. 0.1 No Grad e 2 5 °C 1 0 0 °C 2 0 0 °C 2 5 0 °C 2 5 °C 1 0 0 °C 2 0 0 °C 2 5 0 °C 2 5 °C 1 0 0 °C 2 0 0 °C 2 5 0 °C 2 5 °C 1 0 0 °C 2 0 0 °C 2 5 0 °C
1 0 0 °C 2 0 0 °C 2 5 0 °C
: 0.1 C. R. 1.0 Brines identifided with B may be acceptable for short term completion
: C. R. 1.0 fluid applications. 1 SM-95XS 1 2 .4 12.8 13.0 12.30 11.90 10.60 9.96 3.61 3.83 4 . 1 5 4 .3 4 4 4 .4 45.6 44.0 4 3 . 3 463 492 5 3 5 562
Brine applications identified with C are NO GO areas. 2 SM-110XS 1 2 .3 12.6 12.8 11.90 11.50 10.30 9.74 3.49 3 . 7 2 3.97 4 . 1 7 4 1 .5 42.8 40.9 40.6 450 481 516 5 4 3
4) Pitting potential Addition of corrosion inhibitor, biocide, and oxygen scavenger is 3 SM- 1 2 5 S 1 2 .3 12.8 13.0 12.60 12.00 10.80 10.20 3.50 3.66 3.89 4.08 4 4 . 1 43.9 42.0 41.6 449 470 502 528
: Vp 0.3V recommended but these additives long term stability will be carefully
: 0 Vp 0.3 4 SM13CR-80 10.9 10.9 11.0 7 .7 4 7.70 7.02 6.75 3.48 3.64 3.93 4 . 1 1 27.0 28.0 27.6 2 7 . 7 4 5 2 4 7 3 5 1 2 5 3 7
ascertained prior to usage.
: Vp 0 5 SM13CRM-110 10.7 10.8 11.0 4.78 4.99 5.06 5.07 3.38 3.62 3.96 4 . 1 3 16.2 18.0 20.0 20.9 440 4 7 2 518 5 4 2

5 ) Whenever possible an oil base solids free packer fluid will be 6 SM13CRS-95 10.9 11.0 1 1 . 1 4.67 4.85 4.97 5.00 3.39 3.67 3.98 4 . 1 2 15.8 17.8 19.8 20.6 438 476 5 1 7 5 3 7
: Crack Free preferred. 7 SM13CRS-110 10.7 10.8 10.9 4.67 4.87 4.99 5.00 3 . 3 7 3.46 3 . 7 2 3.87 1 5 . 7 16.8 18.5 19.3 436 449 484 504
: Crack
8 SM17CRS-110/125 11.0 1 1 . 2 1 1 .4 4 .4 1 4.67 4.80 4.80 3 . 4 4 3.67 4.03 4 . 2 3 1 5 .2 1 7 .1 19.3 20.3 4 4 1 4 7 2 519 546
9 SM22CR-110 1 2 .5 12.8 1 3 . 3 3.59 4.16 4.39 4.38 3 . 7 7 4 .1 2 4 .5 2 4 .7 3 1 3 .7 16.2 18.1 19.3 468 496 526 562
10 SM25CR-110 1 2 .5 1 2 .7 13.0 3.59 4 .1 4 4 .4 5 4.65 3.86 4.61 4.98 5.36 1 3 . 1 16.0 18.3 20.5 465 492 5 2 4 562
1 1 SM2 5 CRW- 1 2 5 13.0 1 3 . 2 1 3 .5 3 .3 3 3.64 3.93 3.99 3.93 4 . 2 5 4 .5 5 5.08 13.0 1 5 . 3 1 7 .7 19.9 498 536 5 7 4 636
1 2 SM2535-110 1 4 .5 14.9 14.9 2.96 3.26 3 .7 1 4.04 3 . 7 5 3.99 4 . 2 3 4.39 10.8 1 2 . 4 1 4 .7 16.6 4 5 3 4 7 1 491 509
1 3 SM2242-110 14.6 1 4 . 7 14.9 2.83 3 .1 5 3 .7 1 4.16 3.68 3.96 4 . 3 1 4 .5 2 10.4 12.0 1 4 . 7 1 7 .1 4 5 2 467 487 505
1 4 SM2035-110 14.8 14.8 14.8 2.91 3.16 3 .5 4 3.96 3.82 3.93 4 . 1 7 4.39 10.7 12.0 14.0 16.3 4 5 4 469 488 509
1 5 SM2550-110 14.0 1 4 . 1 1 4 .2 2.81 3.07 3.50 4.19 3 . 7 5 4.18 4 . 2 3 4 .5 2 10.3 1 1 . 7 13.9 16.3 4 4 2 460 480 469
16 SM2050-110 1 3 .2 1 3 .5 13.6 2.79 3.03 3.58 3.90 3 . 7 4 4.00 4 . 2 1 4 .4 1 10.1 1 1 . 5 13.9 15.6 4 2 1 4 4 2 4 5 2 466
1 7 SMC276-110 1 2 .2 1 2 .4 1 2 .5 2.69 2.90 3.46 3 .7 4 3.67 4.09 4 . 1 4 4 .2 7 9.5 10.6 1 3 . 2 14.9 399 4 1 3 430 449
Note : 1cal/cm·s·C=360kcal/m·h·°C=419W·m– 1 ·C– 1

24 25
 FEATURES OF PREMIUM CONNECTIONS
5 . Cost Comp arison w ith 1 3 Ch rome
■ Newly patented sealing system with 14° ■ Newly patented sealing system with 20° or
Ex amp le tapered metal to metal seal including VAM 14° tapered metal-to-metal seal provides
stabilizerTM provides gall free gas tightness gall-free gas-tightness which maintains
which is as strong as pipe body, even under their integrity, even under the most severe
the most severe condition such as High condition as true tubing application in
pressure and High temperature well as true casing sizes (23/8”~14”).
tubing application in casing sizes (9 5/8”-13 ■ Hooked thread design increases resistance
$ 7,000,000
3/8”). to jumping-out and decrease hoop stress on
■ VAM stabilizerTM composes double taper coupling under higher bending and tension/
guides for good make up condition, reverse compression, making this connection
6,000,000 angle torque shoulder and extended lip suitable for application in long deviated or
which can sustain most severe collapse horizontal well.
and compression load and results in ■ Reverse angle torque shoulder results in
5,000,000
superior sealing performance and structural superior sealing performance and structural
resistance under severe combined load resistance under severe combined load
4,000,000 condition. condition.
■ Innovative thread form with cylindrical ■ Streamlined internal profile with tight
crest and root for stable stabbing, no- tolerance minimize gas flow turbulance.
3,000,000 cross threading and self alignment can be ■ High compression version (VAM TOP HC)
obtained. Hooked thread design increase is available.
2,000,000
resistance to jumping out and decrease ■ High torque version (VAM TOP HT)
hoop stress on coupling under higher provides reinforced torque capacity for
bending and tension/ compression, making liner application where high torque is
1,000,000 Batch this connection suitable for application in anticipated.
CTS long deviated or horizontal well. ■ Special coupling with 80% and 90% tensile
13 Chrome ■ A fully cleared internal profile with tight efficiency are available.
0 tolerance minimizes gas flow turbulence, no
1 2 3 4 6 8 10 12 14 Years interference with well bore operations and
no invitation to wear.
■ Special coupling with 80% and 90% tensile
efficiency are available.

Batch : $7,016,485.00
(Chemical Inhibition Batch Treating)
CTS: $2,779,800.00
(Continuous Treating System) ■ A make-up arrestor positions the coupling ■ Ideally suited to controlled-yield material
1 3 Ch rome: $289,000.00 accurately on the mill end. ■ T&C design for controlled-yield material
(The economics are dated and the reader is cautioned to compare current prices.) ■ Pin to pin torque shoulder for positive with no cold working or upsetting that could
torque stop on the field end allows alter metallurgy.
overtorque and compression resistance. ■ Self energizing metal-to-metal seal with
■ Modified hook thread profile, with 50% taper provides pressure integrity to
Source of reference: -9°reverse angle on the load flank and API minimum-yield.
Debbie A. Baudoin, David K. Barbin and Jim Skogsberg, +20°on the stabbing flank which provides ■ Tensile efficiency equals 100%
superior load carrying performances. ■ Hook threads with 3°reverse angle and
“Experiences with 13Cr for mitigating CO2 corrosion in the oilfield
■ Increased thread taper, combined with proper thread length prevent jump-out
Case histories: The Gulf of Mexico and inland gas wells”, a wider thread profile which allows deep under tension or bending, and reduce
Corrosion 95, paper No.639 (1995) stabbing with no cross-threading. tensile hoop stresses.
■ Increased thread pitch to reduce make-up ■ Smooth bore for turbulence-free flow. The
time. VAM HW ST is the ideal connection for
■ Jump-out free. extra-heavy casing application.
■ Special thread design to offer superior
thread sealing performances.
■ Vanishing threads, fully covered.
■ 100% tensile efficiency for all sizes with
standard API Buttress OD.
■ Pins shoulder, thereby providing a smooth
bore ID to minimize turbulence and energy
losses.
■ Pins shoulder, thereby providing high
compression resistance and immunity to
jump-in.

26 27
 MATERIAL AND CONNECTION DESIGN
CUSTOMER NIPPON STEEL
SEARCH DATABASE
■ Optimized clearance with 70% to 80% ■ The extreme high torque strength permits
tension efficiencies of the pipe body yield. pipe rotation in deviated wells without Well Information Material Selection ● Application Records

■ Combination of internal and external seals structural failure. ● Failure Records

provides pressure ratings equal or greater ■ The connection OD and ID are 100% ● Well Condition ● Expert System
than pipe body ratings. flush to the pipe body provides maximum ● Well Operation
■ Excellent compression ratings of 70% of clearance. ECONOMICAL EVALUATION
joint strength by 90 degree middle torque ■ Combination of internal and external seals ● Running Condition
● Analysis Profitability
shoulder and thread form. provides pressure ratings equal or greater
■ User friendly, deep stab, withstand severe than pipe body ratings. of Selected Material
excess of thread compound.
■ The negative 10 degree hooked thread
locks the connection and prevent jump-out String Design
under high tension.

STRESS ANALYSIS
● Under Anticipated

Load Conditions

Connection Design Material Design & Evaluation

CAD SYSTEM MATERIAL EVALUATION

FEM ANALYSIS ● Evaluation under Simulated

PHYSICAL TESTS Well Condition

● Make & Break Tests ・Production
■ 15°hooked thread for optimal load ■ Based on the same concept of VAMTOP ● Leak Resistance Evaluation Test ・Acidizing
transmission and resistance to “jump out.” sealing system, thread profile and torque ● Thermal Cycle Tests ・Completion, Packer Fluids
■ Independent metal-to-metal multi-seal shoulder shape, VAMTOP HC maintain
● Measurment of the Stress ● Material Combination
arrangement for excellent gas-tight high performance meeting to ISO13679
performance with burst and collapse Class 4 application ● Failure Tests with DHE
pressure ratings equivalent to the pipe ■ The torque shoulder dimension of ● Fatigue Tests NEW MATERIAL DESIGN
body. VAMTOPHC is significantly larger than
■ External torque shoulder for easy running. VAMTOP and with a mixture of reduced
torque, this enables the connection
to withstand extreme compression.
VAMTOPHC is 100% compression
connection rating with 100% VME ellipse.
■ Special clearance/special bevel of
VAMTOP HC is consulted case by case.
■ Size availability is from 4-1/2” to 7-3/4”.
■ 4-1/2” VAMTOPHC is not compatible with
4-1/2” VAMTOP connection.

28 29
 API AND NIPPON STEEL PROPRIETRY STEEL
Ap p lication
GRADES COLOR CODE CHART
High Collap se and Sour Martensitic
API High Collap se Sour Service Low Temp erature Deep Well Dup lex Stainless Steel Austenitic Stainless Steel
Strength Service Stainless Steel

J55 Tubing

J55 Casing
55 ksi

K 5 5

N80Q SM-80T SM-80XS (D) SM-80TXS (D) SM-80L SM13CR-80

L80-1 SM-80LL SM13CRI-80

80 ksi

L80 13Cr

SM13CR-85
85 ksi

C90-1 SM-90XS (D) SM-90TXS (D)

90 ksi

R95 SM-95T SM-95XS (D) SM-95TXS (D) SM-95L SM13CR-95

T95-1 SM-95TT SM-95LL SM13CRM-95

95 ksi
SM13CRS-95

SM13CRS-95 (ISO 13680)

P110 SM-110T SM-110ES SM-110TES SM-110L SM13CRI-110 SM22CR-110 (ISO 13680) SM2535-110 (ISO 13680)

C110 SM-95TT SM-110XS (D) SM-110TXS (D) SM-110LL SM13CRM-110 SM25CR-110 (ISO 13680) SM2242-110 (ISO 13680)

SM13CRS-110 SM2035-110 (ISO 13680)

110 ksi
SM13CRS-110 (ISO 13680) SM2550-110 (ISO 13680)

SM2050-110 (ISO 13680)

SMC276-110 (ISO 13680)

Q 1 2 5 -1 SM- 1 2 5 TT SM- 1 2 5 S SM- 1 2 5 TES SM22CR-125 (ISO 13680) SM2535-125 (ISO 13680)

SM- 1 2 5 ES SM25CR-125 (ISO 13680) SM2242-125 (ISO 13680)

SM25CRW-125 (ISO 13680) SM2035-125 (ISO 13680)

125 ksi
SM2550-125 (ISO 13680)

SM2050-125 (ISO 13680)

SMC276-125 (ISO 13680)

SM-130G

130 ksi
SM-130CY

SM-140G SM2535-140 (ISO 13680)

140 ksi
SMC276-140 (ISO 13680)

Color identification shall be applied on either coupling or pipe body at manufacture’s option in accordance with above instruction. Note : These materials may be supplied without color coding to avoide chrolide contamination.

30 31
 INQ UIRY AND/ OR ORDER DETAIL

You are requested to specify your conditions for the following items on your
order sheet.

Applicable specification, grade and type:

(Ex.) Nippon Steel SM-95XS
Nippon Steel SM-95T
Nippon Steel SM2535-110
Type of pipe : Casing or Tubing
Type of ends : Threaded or Plain End
Round (Short, Long), Buttress (casing) or Premium joint; VAM
TOP, VAM TOP HC, VAM TOP HT or DINO VAM (casing or tub-
ing)
Size (outside diameter)
Weight per foot or wall thickness
Range length (Range-1, 2, 3)

Quantity
Delivery date, shipping instructions and requirements of mill inspection.
If you have any special requirements, please specify the details accordingly.

Hydrostatic test pressure

Non-destructive inspection
Type of joint (other than regular coupling)
Special clearance coupling (same or higher grade)
Special bevelled coupling
Special designed joints
(VAM TOP, VAM TOP HC, VAM TOP HT, VAMFJL, VAM HWST, DINO
V AM)
Coupling make-up (other than regular power tight):
Torque turn device or hand tight
Special drift or alternative drift (API 5CT)

( EX AMPLE)

ABC CO 1234-90

Specification : Nippon Steel SM2535-110

Type of pipe : Tubing
Type of end : VAM TOP
Size. weight : 3-1/2” * 9.2# Range 2
Quantity : 12000ft
Delivery : xxx.xxx.xxx on site shipping mark as per attached
sheet
Mill inspection : Mill final inspection (No third party inspection)

32