Safety data sheet

according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332 date of compilation: 2018-08-31

Version: 2.0 en Revision: 2020-09-15
Replaces version of: 2018-08-31
Version: (1)

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Identification of the substance Acetic acid ≥99 % for synthesis
Article number 7332
Registration number (REACH) 01-2119475328-30-xxxx
Index No 607-002-00-6
EC number 200-580-7
CAS number 64-19-7
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses: laboratory chemical
laboratory and analytical use
1.3 Details of the supplier of the safety data sheet
Carl Roth GmbH + Co KG
Schoemperlenstr. 3-5
D-76185 Karlsruhe
Germany

Telephone: +49 (0) 721 - 56 06 0

Telefax: +49 (0) 721 - 56 06 149
e-mail: sicherheit@carlroth.de
Website: www.carlroth.de
Competent person responsible for the safety data : Department Health, Safety and Environment
sheet:
e-mail (competent person): sicherheit@carlroth.de
1.4 Emergency telephone number
Name Street Postal code/ Telephone Website
city

National Poisons Inform- Beaumont Road Dublin 9 01 809 2166 https://www.poisons.ie/

ation Centre
Beaumont Hospital

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)

Classification acc. to GHS

Section Hazard class Hazard class and cat- Hazard

egory state-
ment

2.6 flammable liquid (Flam. Liq. 3) H226

3.2 skin corrosion/irritation (Skin Corr. 1A) H314

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

Classification acc. to GHS

Section Hazard class Hazard class and cat- Hazard

egory state-
ment

3.3 serious eye damage/eye irritation (Eye Dam. 1) H318

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)

Signal word Danger

Pictograms

GHS02, GHS05

Hazard statements
H226 Flammable liquid and vapour
H314 Causes severe skin burns and eye damage
Precautionary statements
Precautionary statements - prevention
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statements - response
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water [or shower].
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
Labelling of packages where the contents do not exceed 125 ml
Signal word: Danger

Symbol(s)

H314 Causes severe skin burns and eye damage.

P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.

2.3 Other hazards

There is no additional information.

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

SECTION 3: Composition/information on ingredients

3.1 Substances
Name of substance Acetic acid
Index No 607-002-00-6
Registration number (REACH) 01-2119475328-30-xxxx
EC number 200-580-7
CAS number 64-19-7
Molecular formula C₂H₄O₂
Molar mass 60,05 g/mol

SECTION 4: First aid measures

4.1 Description of first aid measures

General notes
Take off immediately all contaminated clothing. Self-protection of the first aider.
Following inhalation
Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.
Following skin contact
After contact with skin, wash immediately with plenty of water. Immediate medical treatment re-
quired because corrosive injuries that are not treated are hard to cure.
Following eye contact
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes hold-
ing eyelids apart and consult an ophthalmologist. Protect uninjured eye.
Following ingestion
Rinse mouth immediately and drink plenty of water. Call a physician immediately. If swallowed
danger of perforation of the esophagus and the stomach (strong corrosive effects).
4.2 Most important symptoms and effects, both acute and delayed

After eye contact: Risk of serious damage to eyes, Production of tissue damage in the eye, Risk of
blindness, Persistent corneal opacity,
Following skin contact: Corrosion, Causes poorly healing wounds,
Following ingestion: Vomiting, Gastric perforation,
Following inhalation: Cough, pain, choking, and breathing difficulties, Pulmonary oedema
4.3 Indication of any immediate medical attention and special treatment needed
none

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

Co-ordinate fire-fighting measures to the fire surroundings
water spray, foam, dry extinguishing powder, carbon dioxide (CO₂)
Unsuitable extinguishing media
water jet
5.2 Special hazards arising from the substance or mixture
Combustible. Vapours are heavier than air, spread along floors and form explosive mixtures with air.
Vapours can form explosive mixtures with air.
Hazardous combustion products
In case of fire may be liberated: carbon monoxide (CO), carbon dioxide (CO₂)
5.3 Advice for firefighters
Fight fire with normal precautions from a reasonable distance. Wear self-contained breathing appar-
atus. Wear full chemical protective clothing.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

Wearing of suitable protective equipment (including personal protective equipment referred to un-
der Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal cloth-
ing. Avoid contact with skin, eyes and clothes. Do not breathe vapour/spray. Avoidance of ignition
sources.
6.2 Environmental precautions
Keep away from drains, surface and ground water. Explosive properties.
6.3 Methods and material for containment and cleaning up
Advice on how to contain a spill
Covering of drains.
Advice on how to clean up a spill
Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents).
Other information relating to spills and releases
Place in appropriate containers for disposal. Ventilate affected area.
6.4 Reference to other sections
Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom-
patible materials: see section 10. Disposal considerations: see section 13.

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Provision of sufficient ventilation. Use extractor hood (laboratory). Handle and open container with
care. Clear contaminated areas thoroughly.
• Measures to prevent fire as well as aerosol and dust generation

Keep away from sources of ignition - No smoking.

Take precautionary measures against static discharge.

Advice on general occupational hygiene
Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.
When using do not smoke.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed.
Incompatible substances or mixtures
Observe hints for combined storage.
Consideration of other advice
Ground/bond container and receiving equipment.
• Ventilation requirements
Use local and general ventilation.
• Specific designs for storage rooms or vessels
Recommended storage temperature: 15 – 25 °C.
7.3 Specific end use(s)
No information available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
National limit values
Occupational exposure limit values (Workplace Exposure Limits)
Cou Name of agent CAS No Nota- Identi- TW TWA STE STEL Ceil- Ceil- Source
ntr tion fier A [mg/ L [mg/ ing-C ing-C
y [pp m³] [pp m³] [ppm [mg/
m] m] ] m³]

EU acetic acid 64-19-7 IOELV 10 25 20 50 2017/

164/EU

IE acetic acid 64-19-7 OELV 10 25 20 50 S.I. No.

619 of
2001

Notation
Ceiling-C Ceiling value is a limit value above which exposure should not occur
STEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-
minute period (unless otherwise specified)
TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8
hours time-weighted average (unless otherwise specified)

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

8.2 Exposure controls
Individual protection measures (personal protective equipment)
Eye/face protection

Use safety goggle with side protection. Wear face protection.

Skin protection

• hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374.
Check leak-tightness/impermeability prior to use. For special purposes, it is recommended to check
the resistance to chemicals of the protective gloves mentioned above together with the supplier of
these gloves. The times are approximate values from measurements at 22 ° C and permanent con-
tact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effect-
ive layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in
doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective
breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred
to substance mixtures, they may only be considered as a guide.
• type of material
Butyl caoutchouc (butyl rubber)
• material thickness
0,7mm
• breakthrough times of the glove material
>480 minutes (permeation: level 6)
• other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is
recommended.
Respiratory protection

Respiratory protection necessary at: Aerosol or mist formation. Type: E (against acidic gases like sul-
phur dioxide or hydrogen chloride, colour code: Yellow). Type: ABEK (combined filters against gases
and vapours, colour code: Brown/Grey/Yellow/Green). Type: ABEK-P2 (combined filters against gases,
vapours and particles, colour code: Brown/Grey/Yellow/Green/White).
Environmental exposure controls
Keep away from drains, surface and ground water.

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state liquid (fluid)
Colour colourless
Odour pungent
Odour threshold 0,2 – 100,1 ppm
Other physical and chemical parameters
pH (value) 2,4
Melting point/freezing point 16,64 °C
Initial boiling point and boiling range 117,9 °C at 101,3 kPa
Flash point 39 °C at 101,3 kPa
Evaporation rate no data available
Flammability (solid, gas) not relevant (fluid)
Explosive limits
• lower explosion limit (LEL) 4 vol%
• upper explosion limit (UEL) 19,9 vol%
Explosion limits of dust clouds not relevant
Vapour pressure 20,79 hPa at 25 °C
Density 1,04 g/cm³ at 25 °C

Vapour density 2,07 at 20 °C (air = 1)

Bulk density Not applicable
Relative density Information on this property is not available.
Solubility(ies)
Water solubility 602,9 g/l at 25 °C

Partition coefficient
n-octanol/water (log KOW) -0,17 (pH value: 7, 25 °C) (ECHA)
Soil organic carbon/water (log KOC) 0,062 (ECHA)
Auto-ignition temperature 463 °C - ECHA
Decomposition temperature no data available
Viscosity
• kinematic viscosity 1,015 mm²/s at 25 °C

• dynamic viscosity 1,056 mPa s at 25 °C

Explosive properties Shall not be classified as explosive
Oxidising properties none

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

9.2 Other information
Temperature class (EU, acc. to ATEX) T1 (Maximum permissible surface temperature
on the equipment: 450°C)

SECTION 10: Stability and reactivity

10.1 Reactivity
Risk of ignition. In case of warming: Vapours can form explosive mixtures with air.
10.2 Chemical stability
The material is stable under normal ambient and anticipated storage and handling conditions of tem-
perature and pressure.
10.3 Possibility of hazardous reactions

Danger of explosion: Perchlorates, Permanganates, Organic peroxides, Hydrogen peroxide, Strong

oxidiser, Sulphuric acid, concentrated, May cause strong formation of hydrogen by contact with am-
photeric metals (e.g. aluminia, lead, zinc) - danger of explosion, Violent reaction with: Aldehydes, Al-
kali hydroxide (caustic alkali), Alcohols, Strong alkali, Nitric acid
10.4 Conditions to avoid
There are no specific conditions known which have to be avoided.
10.5 Incompatible materials
different metals
10.6 Hazardous decomposition products
Hazardous combustion products: see section 5.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Shall not be classified as acutely toxic.
Exposure route Endpoint Value Species Source

oral LD50 3.310 mg/ rat TOXNET

kg

Skin corrosion/irritation
Causes severe burns.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitisation
Shall not be classified as a respiratory or skin sensitiser.
Summary of evaluation of the CMR properties
Shall not be classified as germ cell mutagenic, carcinogenic nor as a reproductive toxicant
• Specific target organ toxicity - single exposure
Shall not be classified as a specific target organ toxicant (single exposure).
• Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

Symptoms related to the physical, chemical and toxicological characteristics

• If swallowed
If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects)
• If in eyes
causes burns, Causes serious eye damage, risk of blindness
• If inhaled
cough, pain, choking, and breathing difficulties, pulmonary oedema
• If on skin
causes severe burns, causes poorly healing wounds
Other information
None

SECTION 12: Ecological information

12.1 Toxicity
acc. to 1272/2008/EC: Shall not be classified as hazardous to the aquatic environment.
Aquatic toxicity (acute)
Endpoint Value Species Source Exposure
time

LC50 >300,8 mg/l fish ECHA 96 h

EC50 >300,8 mg/l aquatic invertebrates ECHA 48 h

ErC50 >300,8 mg/l algae ECHA 72 h

12.2 Process of degradability

The substance is readily biodegradable.
Theoretical Oxygen Demand: 1,066 mg/mg
Theoretical Carbon Dioxide: 1,466 mg/mg
Process Degradation rate Time

biotic/abiotic 99 % 30 d

12.3 Bioaccumulative potential

Does not significantly accumulate in organisms.
n-octanol/water (log KOW) -0,17 (pH value: 7, 25 °C)
BCF 3,16 (ECHA)
12.4 Mobility in soil
Henry's law constant 0,21 Pa m³/mol at 25 °C

The Organic Carbon normalised adsorption 0,062

coefficient
12.5 Results of PBT and vPvB assessment

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

Data are not available.

12.6 Other adverse effects
Data are not available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

This material and its container must be disposed of as hazardous waste. Dispose of contents/contain-
er in accordance with local/regional/national/international regulations.
Sewage disposal-relevant information
Do not empty into drains.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.
13.2 Relevant provisions relating to waste
The allocation of waste identity numbers/waste descriptions must be carried out according to the
EEC, specific to the industry and process.
13.3 Remarks
Waste shall be separated into the categories that can be handled separately by the local or national
waste management facilities. Please consider the relevant national or regional provisions.

SECTION 14: Transport information

14.1 UN number 2789
14.2 UN proper shipping name ACETIC ACID, GLACIAL
Hazardous ingredients Acetic acid
14.3 Transport hazard class(es)

Class 8 (corrosive substances)

14.4 Packing group II (substance presenting medium danger)
14.5 Environmental hazards none (non-environmentally hazardous acc. to the danger-
ous goods regulations)

14.6 Special precautions for user

Provisions for dangerous goods (ADR) should be complied within the premises.
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
The cargo is not intended to be carried in bulk.
14.8 Information for each of the UN Model Regulations
• Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN)
UN number 2789
Proper shipping name ACETIC ACID, GLACIAL

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

Particulars in the transport document UN2789, ACETIC ACID, GLACIAL, 8 (3), II, (D/E)
Class 8
Classification code CF1
Packing group II
Danger label(s) 8+3

Excepted quantities (EQ) E2

Limited quantities (LQ) 1L
Transport category (TC) 2
Tunnel restriction code (TRC) D/E
Hazard identification No 83
• International Maritime Dangerous Goods Code (IMDG)
UN number 2789
Proper shipping name ACETIC ACID, GLACIAL
Particulars in the shipper's declaration UN2789, ACETIC ACID, GLACIAL, 8 (3), II, 39°C c.c.
Class 8
Subsidiary risk(s) 3
Marine pollutant -
Packing group II
Danger label(s) 8+3

Excepted quantities (EQ) E2

Limited quantities (LQ) 1L
EmS F-E, S-C
Stowage category A
Segregation group 1 - Acids
• International Civil Aviation Organization (ICAO-IATA/DGR)
UN number 2789
Proper shipping name Acetic acid, glacial
Particulars in the shipper's declaration UN2789, Acetic acid, glacial, 8 (3), II
Class 8
Subsidiary risk(s) 3
Packing group II

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

Danger label(s) 8+3

Excepted quantities (EQ) E2

Limited quantities (LQ) 0,5 L

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
• Regulation 649/2012/EU concerning the export and import of hazardous chemicals (PIC)
Not listed.
• Regulation 1005/2009/EC on substances that deplete the ozone layer (ODS)
Not listed.
• Regulation 850/2004/EC on persistent organic pollutants (POP)
Not listed.
• Restrictions according to REACH, Annex XVII
Name of substance Type of registration Conditions of re- No
striction

Acetic acid 1907/2006/EC annex XVII R3 3

Acetic acid 1907/2006/EC annex XVII R40 40

Legend
R3 1. Shall not be used in:
- ornamental articles intended to produce light or colour effects by means of different phases, for example in or-
namental lamps and ashtrays,
- tricks and jokes,
- games for one or more participants, or any article intended to be used as such, even with ornamental aspects,
2. Articles not complying with paragraph 1 shall not be placed on the market.
3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or per-
fume, or both, if they:
- can be used as fuel in decorative oil lamps for supply to the general public, and,
- present an aspiration hazard and are labelled with R65 or H304,
4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to
the European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisa-
tion (CEN).
5. Without prejudice to the implementation of other Community provisions relating to the classification, pack-
aging and labelling of dangerous substances and mixtures, suppliers shall ensure, before the placing on the mar-
ket, that the following requirements are met:
(a) lamp oils, labelled with R65 or H304, intended for supply to the general public are visibly, legibly and indelibly
marked as follows: ‘Keep lamps filled with this liquid out of the reach of children’; and, by 1 December 2010, ‘Just a
sip of lamp oil - or even sucking the wick of lamps - may lead to life-threatening lung damage’;
(b) grill lighter fluids, labelled with R65 or H304, intended for supply to the general public are legibly and indelibly
marked by 1 December 2010 as follows: ‘Just a sip of grill lighter may lead to life threatening lung damage’;
(c) lamp oils and grill lighters, labelled with R65 or H304, intended for supply to the general public are packaged in
black opaque containers not exceeding 1 litre by 1 December 2010.
6. No later than 1 June 2014, the Commission shall request the European Chemicals Agency to prepare a dossier,
in accordance with Article 69 of the present Regulation with a view to ban, if appropriate, grill lighter fluids and
fuel for decorative lamps, labelled R65 or H304, intended for supply to the general public.
7. Natural or legal persons placing on the market for the first time lamp oils and grill lighter fluids, labelled with
R65 or H304, shall by 1 December 2011, and annually thereafter, provide data on alternatives to lamp oils and grill
lighter fluids labelled R65 or H304 to the competent authority in the Member State concerned. Member States
shall make those data available to the Commission.

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

Legend
R40 1. Shall not be used, as substance or as mixtures in aerosol dispensers where these aerosol dispensers are inten-
ded for supply to the general public for entertainment and decorative purposes such as the following:
- metallic glitter intended mainly for decoration,
- artificial snow and frost,
- ‘whoopee’ cushions,
- silly string aerosols,
- imitation excrement,
- horns for parties,
- decorative flakes and foams,
- artificial cobwebs,
- stink bombs.
2. Without prejudice to the application of other Community provisions on the classification, packaging and la-
belling of substances, suppliers shall ensure before the placing on the market that the packaging of aerosol dis-
pensers referred to above is marked visibly, legibly and indelibly with:
‘For professional users only’.
3. By way of derogation, paragraphs 1 and 2 shall not apply to the aerosol dispensers referred to Article 8 (1a) of
Council Directive 75/324/EEC (2).
4. The aerosol dispensers referred to in paragraphs 1 and 2 shall not be placed on the market unless they con-
form to the requirements indicated.

• Restrictions according to REACH, Title VIII

None.
• List of substances subject to authorisation (REACH, Annex XIV)/SVHC - candidate list
not listed
• Seveso Directive

2012/18/EU (Seveso III)

No Dangerous substance/hazard categories Qualifying quantity (tonnes) for the ap- Notes
plication of lower and upper-tier re-
quirements

P5c flammable liquids (cat. 2, 3) 5.000 50.000 51)

Notation
51) Flammable liquids, categories 2 or 3 not covered by P5a and P5b

• Directive 75/324/EEC relating to aerosol dispensers

Filling batch
Deco-Paint Directive (2004/42/EC)
VOC content 100 %
1.040 g/l
Directive on industrial emissions (VOCs, 2010/75/EU)
VOC content 100 %

VOC content 1.040 g/l

Directive 2011/65/EU on the restriction of the use of certain hazardous substances in electrical
and electronic equipment (RoHS) - Annex II
not listed
Regulation 166/2006/EC concerning the establishment of a European Pollutant Release and
Transfer Register (PRTR)
not listed
Directive 2000/60/EC establishing a framework for Community action in the field of water policy
(WFD)
not listed

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

Regulation 98/2013/EU on the marketing and use of explosives precursors
not listed
Regulation 111/2005/EC laying down rules for the monitoring of trade between the Community
and third countries in drug precursors
not listed

National inventories
Substance is listed in the following national inventories:
Country National inventories Status

AU AICS substance is listed

CA DSL substance is listed

CN IECSC substance is listed

EU ECSI substance is listed

EU REACH Reg. substance is listed

JP CSCL-ENCS substance is listed

KR KECI substance is listed

MX INSQ substance is listed

NZ NZIoC substance is listed

PH PICCS substance is listed

TR CICR substance is listed

TW TCSI substance is listed

US TSCA substance is listed

Legend
AICS Australian Inventory of Chemical Substances
CICR Chemical Inventory and Control Regulation
CSCL-ENCS List of Existing and New Chemical Substances (CSCL-ENCS)
DSL Domestic Substances List (DSL)
ECSI EC Substance Inventory (EINECS, ELINCS, NLP)
IECSC Inventory of Existing Chemical Substances Produced or Imported in China
INSQ National Inventory of Chemical Substances
KECI Korea Existing Chemicals Inventory
NZIoC New Zealand Inventory of Chemicals
PICCS Philippine Inventory of Chemicals and Chemical Substances (PICCS)
REACH Reg. REACH registered substances
TCSI Taiwan Chemical Substance Inventory
TSCA Toxic Substance Control Act

15.2 Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance.

SECTION 16: Other information

Indication of changes (revised safety data sheet)

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

Section Former entry (text/value) Actual entry (text/value) Safety-

relev-
ant
8.1 Occupational exposure limit values (Workplace yes
Exposure Limits):
change in the listing (table)

8.1 Relevant DNELs/DMELs/PNECs and other yes

threshold levels

8.1 • human health values yes

8.1 • human health values: yes

change in the listing (table)

8.1 • environmental values yes

8.1 • environmental values: yes

change in the listing (table)

14.8 Special provisions (SP): yes

-

Abbreviations and acronyms

Abbr. Descriptions of used abbreviations

2017/164/EU Commission Directive establishing a fourth list of indicative occupational exposure limit values pursuant to
Council Directive 98/24/EC, and amending Commission Directives 91/322/EEC, 2000/39/EC and 2009/161/EU

ADN Accord européen relatif au transport international des marchandises dangereuses par voies de navigation
intérieures (European Agreement concerning the International Carriage of Dangerous Goods by Inland Wa-
terways)

ADR Accord européen relatif au transport international des marchandises dangereuses par route (European
Agreement concerning the International Carriage of Dangerous Goods by Road)

BCF bioconcentration factor

CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

Ceiling-C ceiling value

CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

CMR Carcinogenic, Mutagenic or toxic for Reproduction

DGR Dangerous Goods Regulations (see IATA/DGR)

EC50 Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing 50
% changes in response (e.g. on growth) during a specified time interval

EINECS European Inventory of Existing Commercial Chemical Substances

ELINCS European List of Notified Chemical Substances

EmS Emergency Schedule

ErC50 ≡ EC50: in this method, that concentration of test substance which results in a 50 % reduction in either
growth (EbC50) or growth rate (ErC50) relative to the control

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations

IATA International Air Transport Association

IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)

ICAO International Civil Aviation Organization

IMDG International Maritime Dangerous Goods Code

index No the Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation (EC)
No 1272/2008

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Acetic acid ≥99 % for synthesis

article number: 7332

Abbr. Descriptions of used abbreviations

IOELV indicative occupational exposure limit value

LC50 Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing 50 %
lethality during a specified time interval

LD50 Lethal Dose 50 %: the LD50 corresponds to the dose of a tested substance causing 50 % lethality during a
specified time interval

MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant")

NLP No-Longer Polymer

PBT Persistent, Bioaccumulative and Toxic

ppm parts per million

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regulations
concerning the International carriage of Dangerous goods by Rail)

S.I. No. 619 of Safety, Health and Welfare at Work (Chemical Agents) Regulations 2001
2001

STEL short-term exposure limit

SVHC Substance of Very High Concern

TWA time-weighted average

VOC Volatile Organic Compounds

vPvB very Persistent and very Bioaccumulative

Key literature references and sources for data

- Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
- Regulation (EC) No. 1272/2008 (CLP, EU GHS)
- Dangerous Goods Regulations (DGR) for the air transport (IATA)
- International Maritime Dangerous Goods Code (IMDG)

List of relevant phrases (code and full text as stated in chapter 2 and 3)
Code Text

H226 flammable liquid and vapour

H314 causes severe skin burns and eye damage

H318 causes serious eye damage

Disclaimer
The above information describes exclusively the safety requirements of the product and is based on
our present-day knowledge. The information is intended to give you advice about the safe handling of
the product named in this safety data sheet, for storage, processing, transport and disposal. The in-
formation cannot be transferred to other products. In the case of mixing the product with other
products or in the case of processing, the information on this safety data sheet is not necessarily val-
id for the new made-up material.

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