METTLER - Toledo SevenCompact S213 - EN - 30325043B

Operating Instructions SevenCompact™ Duo S213
pH/Conductivity Meter
Table of Contents
1 Introduction 3
2 Safety Instructions 4
2.1 Definition of signal warnings and symbols 4
2.2 Product specific safety notes 4
3 Design and Function 7
3.1 Overview 7
3.2 Rear panel connections 7
3.3 Display and icons 8
3.4 Key controls 9
3.5 Softkeys 9
3.6 Alphanumeric keypad 10
3.6.1 Entering alphanumeric characters 10
3.6.2 Editing values in tables 11
3.7 Navigating within a menu 11
3.8 Navigating between menus 11
3.9 Endpoint types 11
4 Putting into Operation 13
4.1 Scope of delivery 13
4.2 Mounting uPlace™ electrode arm 13
4.3 Installing power supply 14
4.4 Connecting sensors 15
4.5 Switching the instrument on and off 15
4.6 Connectivity 15
5 Configuring the Instrument 17
5.1 Sample ID 17
5.2 User ID 17
5.3 Stirrer 18
5.4 Data storage 18
5.5 System settings 19
5.5.1 Language 19
5.5.2 Time and Date 19
5.5.3 Access Control 19
5.5.4 Audio signal 20
5.5.5 Operator mode 20
5.5.6 Screen settings 20
5.6 Service 20
5.7 Instrument Self-test 21
6 Measuring pH 23
6.1 Measurement settings 23
6.1.1 Sensor ID / SN 23
6.1.2 Calibration Settings 24
6.1.3 Measurement Settings 24
6.1.4 Endpoint Type 25
6.1.5 Temperature Settings 25
6.1.6 Measurement Limits 26
6.2 Sensor Calibration 26
6.2.1 Running a one-point pH calibration 26
6.2.2 Running a multi-point pH calibration 27
6.3 Sample Measurement 27
SevenCompact™ Duo S213 Table of Contents 1

7 Measuring Conductivity 29
7.1 Measurement settings 29
7.1.1 Sensor ID / SN 29
7.1.2 Calibration Settings 30
7.1.3 Measurement Settings 30
7.1.3.1 Reference temperature 30
7.1.3.2 Temperature correction/alpha-coefficient 31
7.1.3.3 TDS Factor 32
7.1.3.4 Conductivity Unit 32
7.1.3.5 Conductivity Ash 32
7.1.3.6 Salinity unit 33
7.1.4 Endpoint Type 33
7.1.5 Temperature Settings 33
7.1.6 Measurement Limits 33
7.2 Sensor Calibration 34
7.3 Sample Measurement 34
8 Dual Channel Operation 36
9 Managing data 37
9.1 Measurement data 37
9.2 Calibration data 38
9.3 ISM data 38
9.4 Transfer Interfaces 39
10 Troubleshooting 40
10.1 Instrument messages 40
10.2 Error limits 41
11 Sensors, Solutions and Accessories 43
12 Technical Data 45
13 Appendix 49
13.1 Buffers 49
13.2 Conductivity standards 51
13.3 Temperature correction factors 53
13.4 Temperature coefficients (alpha-values) 54
13.5 Practical salinity scale (UNESCO 1978) 54
13.6 Conductivity to TDS conversion factors 54
13.7 USP/EP tables 55
13.8 Conductivity ash methods 55
13.8.1 Refined sugar (28 g/100 g solution) ICUMSA GS2/3-17 55
13.8.2 Raw sugar or melasses (5 g / 100 mL solution) ICUMSA GS 1/3/4/7/8-13 55
2 Table of Contents SevenCompact™ Duo S213

1 Introduction
Thank you for purchasing this METTLER TOLEDO instrument. The SevenCompact Series is not only a new
generation of intuitive and easy-to-operate bench meters for reliable measurements, they also provide extra
security against mistakes and support your workflow in the laboratory.
Mistakes can be reduced to a minimum because of the following characteristics:
• ISM® (Intelligent Sensor Management) technology: the meter automatically recognizes the sensor and
transfers the latest set of calibration data from the sensor chip to the meter. The last five calibrations as
well as the initial calibration certificate are also stored on the sensor chip. These can be reviewed, trans-
ferred and printed. ISM® provides additional security and helps eliminate mistakes.
• Multi-language graphical user interface on a large 4.3 inch display with intuitive menu guidance,
making the operating instructions primarily a source of reference.
• Expert and Routine mode for the needs of any operator: in the routine mode, the deletion of data is
prevented and changing those settings that would potentially jeopardize the collection of reliable results,
such as measurement settings, are blocked. This provides extra security for routine daily work. Skilled
workers are advised to employ the GLP mode to enjoy the instruments’ powerful full functional range.
This instrument supports the workflow of a modern laboratory in all stages of the data collection and
archiving process:
• The uPlace™ electrode arm can be operated with one hand and moves perfectly straight up and down
to bring the electrode in the perfect position for the best measurement performance. This allows faster
measurements and poses less risk to tip over the sample vessel and/or damage the head of the sensor!
• Only one keypress required: Read starts a measurement and Cal a calibration. It’s so easy!
• Easy switching between the normal view and the uFocus™. The normal view has all the
measurement parameters and IDs on the display to provide you an instant complete overview. In the
uFocus™ only the most important information is shown in large digits, such as measurement value and
temperature. This enables you to focus completely on the measurement, without getting distracted by
information that is not relevant to you.
• Easy toggling with the soft key Mode. Toggle between the various measurement parameters either
before or during a measurement.
• Versatile data archiving options: print data, export data to a USB-stick, or send data to a PC with
EasyDirect pH software! EasyDirect pH allows to store the data electronically almost unlimited and
export them to Excel, or any other comma separated file for further use seamleassly and easy.
• Versatile data entry procedures: Enter sample / user and sensor IDs either directly on the instrument,
or use a barcode reader or USB-Keyboard to increase efficiency.
At METTLER TOLEDO we are committed to providing you instruments of highest quality and we do all we
can to support you in maximizing the lifetime of your instrument:
• IP54 rating – water and dust protection: we have designed our instrument in such way, that it
withstands spray of aqueous solutions on the housing and connections. This not only provides extra
protection, but also allows easy cleaning of the instrument with a damp cloth.
• Rubber plugs and protective cover provide extra security against dust and spills of aqueous solutions.
Just keep the plug attached to the connections and cover the instrument with the transparent protective
cover when not in use.
Have fun and many reliable measurements with our SevenCompact series of pH, Ion and conductivity
meters!
SevenCompact™ Duo S213 Introduction 3

2 Safety Instructions
2.1 Definition of signal warnings and symbols
Signal words
Safety notes are marked with signal words and warning symbols. These show safety issues and warnings.
Ignoring the safety notes may lead to personal injury, damage to the instrument, malfunctions and false
results.
WARNING for a hazardous situation with medium risk, possibly resulting in death or severe
injury if not avoided.
CAUTION for a hazardous situation with low risk, resulting in minor or moderate injury if not
avoided.
NOTICE for a hazardous situation with low risk, resulting in damage to the instrument, other
material damage, malfunctions and erroneous results, or loss of data.
Attention (no symbol)

for important information about the product.
Note (no symbol)

for useful information about the product.
Warning symbols
General hazard Electrical shock
Toxic substance Inflammable or explosive substance
Acid / Corrosion
2.2 Product specific safety notes

The instrument has been tested for the experiments and intended purposes documented in the appropriate
manual. However, this does not absolve you from the responsibility of performing your own tests of the
products supplied by us regarding their suitability for the methods and purposes you intend to use them for.
Intended use
This instrument is designed to be used in analytical laboratories by qualified staff. The instrument is suitable
for the processing of reagents and solvents.
Site requirements
The instrument has been developed for indoor operation in a well-ventilated area. Avoid the following
environmental influences:
• Conditions outside of the ambient conditions specified in the technical data
• Powerful vibrations
• Direct sunlight
• Corrosive gas atmosphere
• Explosive atmosphere of gases, steam, fog, dust and flammable dust
• Powerful electric or magnetic fields
4 Safety Instructions SevenCompact™ Duo S213

Staff qualification
Incorrect use of the instrument or the chemicals used in the analysis can lead to death or injury. The
following qualifications are needed for operating the instrument.
• Knowledge and experience in working with toxic and caustic substances.
• Knowledge and experience in working with standard laboratory equipment.
• Knowledge and experience in working in accordance with general lab safety rules.
Responsibilities of the instrument owner
The instrument owner is the person that uses the instrument for commercial use or places the instrument at
the disposal of his staff. The instrument owner is responsible for product safety and the safety of staff, user
and third party.
The operator has the following responsibilities:
• Know the rules for safety at the workplace that are in effect and enforce them.
• Ensure that only qualified staff uses the instrument.
• Define the responsibilities for installation, operation, cleaning, troubleshooting and maintenance and
ensure that the tasks are done.
• Train the staff in regular intervals and inform them about dangers.
• Provide the necessary protective gear for the staff.
Shut down of the instrument in emergency situations
− Pull the plug from the electrical outlet.
Protective Clothing
Wear protective clothing in the laboratory when working with hazardous or toxic substances.
Wear suitable eye protection such as goggles.
Use appropriate gloves when handling chemicals or hazardous substances and check
their integrity before use.
Wear a lab coat.
Safety notes
WARNING
Danger of death or serious injury due to electric shock!
Contact with parts that contain a live current can lead to injury and death.
− Keep all electrical cables and connections away from liquids.
SevenCompact™ Duo S213 Safety Instructions 5

WARNING
Danger of injuries and death due to harmful substances!
Chemicals can cause injuries if they come in contact with bare skin or are inhaled.
1 When using chemicals and solvents, comply with the instructions of the producer and
the general lab safety rules.
2 Set up the instrument in a well-ventilated location.
3 Clean any spills immediately.
4 If you measure substances which form toxic gases, place the instrument in a fume
hood.
WARNING
Danger of death and serious injuries due to flammable solvents!
Flammable solvents can ignite and lead to fire and explosions.
1 Keep flammable solvents away from naked flames.
2 When using chemicals and solvents, comply with the instructions of the producer and
the general lab safety rules.
Any other type of use and operation beyond the limits of technical specifications without written consent
from Mettler-Toledo GmbH, is considered as not intended.
FCC Rules
This device complies with Part 15 of the FCC Rules and Radio Interference Requirements of the Canadian
Department of Communications. Operation is subject to the following conditions: (1) this device may not
cause harmful interference, and (2) this device must accept any interference received, including interference
that may cause undesired operation.
This equipment has been tested and found to comply with the limits for a Class A digital device, pursuant to
Part 15 of the FCC rules. These limits are designed to provide reasonable protection against harmful inter-
ference when the equipment is operated in a commercial environment. This equipment generates, uses, and
can radiate radio frequency energy and, if not installed and used in accordance with the instruction manual,
may cause harmful interference to radio communications. Operation of this equipment in a residential area
is likely to cause harmful interference in which case the user will be required to correct the interference at his
own expense.
6 Safety Instructions SevenCompact™ Duo S213

3 Design and Function
3.1 Overview
2
3
4
5
1 On/Off key 2 Display

3 Softkeys 4 Read key
5 Cal key
3.2 Rear panel connections

3 4 7 8
1 2 5 6 9 10
1 BNC socket for mV/pH signal input 2 RCA (Cinch) socket for temperature signal
input
3 Socket for reference electrodes 4 Socket for digital sensor (pH or Conduc-
tivity)
5 Mini-DIN socket for conductivity signal input 6 Mini DIN socket for METTLER TOLEDO stirrer
7 RS232 interface (Printer) 8 DC power supply socket
9 USB-B interface (Computer) 10 USB-A interface (USB-Stick, printer, barcode
reader, keyboard)
PIN assignment for the RS-232 interface. METTLER TOLEDO printers such as RS-P25 can be connected to
this interface.
SevenCompact™ Duo S213 Design and Function 7

3.3 Display and icons
There are two modes available for the display representation: the full-information screen with all the infor-
mation displayed, and the measurement close-up screen uFocus™, where the measurement information is
shown in large font. To toggle between these views, press and hold Read during, after or before a
measurement.
Standard view uFocus™ view
24-06-2016 24-06-2016
10:34 10:34
InLab 742 InLab 742

Data Channel Menu Mode Data Channel Menu Mode
1 2 3 4 5 6 8 9 10 11
24-06-2016
10:34
17 12
18 13
14
19 InLab Pure Pro
20
15
InLab 742 16
Data Channel Menu Mode
24 25 26 27
Icon Description
1 Interval Readings icon (timed interval reading)
2 Routine Mode icon (user access rights are restricted)
3 USB device connected
4 PC connected (for EasyDirect pH)
5 Stirrer icon (appears when stirring is active)
6 User ID
7 Calibration is running
8 7.000 pH Measurement value and used measurement unit
9 Sample ID
10 ◀ Channel selection if both channels are active
11 24-06-2016 Date and time
10:34
12 25°C Measurement temperature
13 MTC Temperature Correction
ATC: Temperature sensor connected
MTC: no temperature sensor connected or detected
14 Stability Criterion (pH only)
Strict
Standard
Fast
8 Design and Function SevenCompact™ Duo S213

Icon Description
15 Endpoint Type
A: Auto measurement stops automatically when the signal is stable
M: Manual to manually stop the measurement
T: Timed the measurement stops after the preset time
Stability Signal appears if the signal is stable
16 M Number of data sets in memory
17 ISM® sensor connected
18 pH electrode condition
Slope: 95-105% / Offset: ±(0-20) mV (Electrode is in good condition)
Slope: 94-90% / Offset: ±(20-35) mV (Electrode needs cleaning)
Slope: 89-85% / Offset: ±(>35) mV (Electrode is defective or too old)
19 Sensor ID
20 Ref.T. Reference Temperature
21 CC The cell constant of the conductivity sensor
22 Buffer groups or standards
23 Warning messages
24 Softkeys are buttons whose function changes depending on the context.
25 See [Softkeys } 9]
26
27
3.4 Key controls

Key Press and release Press and hold for 2 seconds
Switch meter on Switch meter off
• Start or end measurement Switch between measurement close-up

(measurement screen) screen and full-information screen
• Confirm input or start editing a table
• Exit menu and go back to
measurement screen
Start calibration Review the last calibration data
Softkeys The function of the softkeys varies from

screen to screen
3.5 Softkeys
The meter has four softkeys. The functions assigned to them change during operation depending on the
application. The assignment is shown on the bottom line of the screen.
Data Access data menu Mode Change measurement mode
Press and hold to change the channel
selection
Menu Access meter settings Channel Select measuring channels
Move one position to the right Increase value

Move one position to the left Decrease value
Scroll up in the menu Scroll to next page of results
Scroll down in the menu Calculate Calculate the calibration values
Edit Edit table or value Select Select the highlighted function or setting
Delete Delete selected data Start Start the measurement
Save Save data, setting or value Interface Choose the transfer interface.
Yes Confirm an entry Transfer Transfer selected data
No Reject an entry
3.6 Alphanumeric keypad
3.6.1 Entering alphanumeric characters

The meter has a screen keypad for entering IDs, SNs and PINs. Both numbers and letters are allowed for
these entries. When entering a PIN, each character entered will be displayed as ( * ).
Enter Sample ID
Press 'Read' to confirm
Exit
1 Move the cursor position using the , or keys.

2 Press Read to confirm an entry.
ð The position of the next character that is entered is blinking.
3 Repeat these steps to enter additional characters.
- or -
To delete an entry, select the character. Navigate to Delete and press Read.
4 To confirm and save the entries, navigate to OK and press Read.
- or -
To reject the entries, press Exit.
Entering IDs / PIN
The four softkeys and the Read key are used for navigating on the keypad and entering the ID/PIN.
Example text: WATER
1 If 1 is highlighted, press once.
ð Q is highlighted.
2 Press once.
ð W is highlighted.
3 Press Read to enter W.
4 Reposition the selection to A, T, E and R, confirm each selection with Read.
5 Reposition the selection to OK, and press Read to save the ID.

Note
• Instead of entering an ID with the alphanumeric keypad, you can also use a USB-keyboard or a USB-
barcode scanner. In case a character is entered or scanned that is not available on the instrument
keyboard, the entry will be displayed as an underscore (_).
3.6.2 Editing values in tables

The meter allows you to enter, edit or remove values in tables. (for example, temperature and buffer values
for a customized buffer group). This is accomplished by using the softkeys to navigate from cell to cell.
1 Press Read to start editing the cell in the table.
ð The softkeys on the display change.
2 Press and to enter the value and press Read to confirm.
ð The softkeys change back to and .
3 Navigate to a cell and press Delete to remove a value.
4 To finish editing the table, navigate with the and to highlight Save.
5 Press Read to confirm the action and exit the menu.
3.7 Navigating within a menu

1 Press Menu to enter the settings.
2 Move the selection to a menu item using the or keys and press Select to open the
selection.
3 Apply the required settings using the navigation keys.
- or -
If applicable, move the selection to the next menu item in the hierarchy using the or
keys.
4 Press Exit to return to the previous menu screen, or press Read to return to the measurement screen
directly.
3.8 Navigating between menus

The meter display consists of a measurement frame, softkeys, areas for status icons and underlying menu
areas. To access the menu areas and to navigate between them, use the softkeys.
1 Press Menu to enter the settings.
2 Move the selection to the top of the screen to select the tab using the or keys.
ð The navigation keys to navigate left and right are shown.
3 Move the selection to chose another tab using the or keys.
4 Press Exit to return to the measurement screen.
3.9 Endpoint types

A general setting that defines how the endpoint of the measurement is to be determined.

Measurement stopped automatically,
A A reading was stable
Measurement stopped manually,
M M reading was stable
Measurement stopped manually,
M M reading was not stable
Measurement stopped after time,
T T reading was stable
T Measurement stopped after time,
T
reading was not stable
Defined measurement time elapsed
User presses Read
Signal becomes stable

4 Putting into Operation
4.1 Scope of delivery
Unpack the instrument and check the scope of delivery. Keep the calibration certificate in a safe place.
SevenCompact™ is delivered with:
• uPlace™ electrode arm
• Sensors (kit version or according to your order)
• Universal AC adapter
• Transparent protective cover
• CD-ROM with Operating instructions and User Manual (English, German, French, Italian, Spanish,
Portuguese, Polish, Russian, Chinese, Japanese Korean, Thai)
• User Manual (print version, English, German, French, Italian, Spanish, Portuguese, Polish)
• Declaration of conformity
• Calibration certificate
4.2 Mounting uPlace™ electrode arm

The electrode arm can be used as stand alone or it
can be attached to the instrument on the left or right
side, according to your preferences. The height of the
electrode arm can be varied by using the extension
shaft part. Use the wrench to attach the extension
part .
Assembly of the electrode arm

1 Use the wrench to attach the base to the electrode
arm by tightening the screws. The electrode arm
can now be used in the stand alone mode.
SevenCompact™ Duo S213 Putting into Operation 13

2 Then insert the foot of the meter to the arm base
and shift the meter in the direction of the arrow to
make the foot fit.
3 Use the lock screw to attach the meter to the base

of the arm.
4.3 Installing power supply
WARNING
Danger of death or serious injury due to electric shock!
Contact with parts that contain a live current can lead to injury and death. If the
instrument cannot be shut down in an emergency situations, people can be injured or the
instrument can be damaged.
1 Check the cables and the plug for damage and replace damaged cables and plugs.
2 Ensure that the cables are arranged so that they cannot be damaged or interfere with
the operation.
3 Ensure that the power plug is accessible at all times.
NOTICE
Danger of damage to the AC adapter due to overheating!
If the AC adapter is covered or in a container, it is not sufficiently cooled and overheats.
1 Do not cover the AC adapter.
2 Do not put the AC adapter in a container.
The instrument is operated using an AC adapter. The AC adapter is suitable for all supply line voltages
ranging from 100...240 V AC ±10% and 50-60 Hz.
1 Insert the correct connector plug into the AC adapter until it is
completely inserted.
2 Connect the cable of the AC adapter with the DC socket of
PUSH
the instrument.
3 Plug the AC adapter into the wall socket.
14 Putting into Operation SevenCompact™ Duo S213

To remove the connector plug, push the release button and withdraw the connector plug.
4.4 Connecting sensors

When connecting a sensor, make sure that the plugs are properly inserted. If you are using a sensor with a
built-in temperature probe or a separate temperature probe, connect the second cable to the ATC socket.
Example
− Connect a pH sensor to the BNC plug and if a temperature probe is integrated, connect the RCA (chinch)
plug to the ATC input.
- or -
Connect a conductivity probe to the conductivity input, a temperature probe is always built in and does
not need to be connected seperatly. If you have a digital sensor connect it to the digital input.
ISM® sensor
When connecting an ISM® sensor to the meter, one of the following conditions have to be met for the
calibration data to be transferred automatically from the chip of the sensor into the meter and is used for
further measurements. After attaching the ISM® sensor ...
• The meter must be switched on.
• (If the meter is already switched on) the Read key is pressed.
• (If the meter is already switched on) the Cal key is pressed.
We strongly recommend you to switch off the meter when disconnecting an ISM sensor. In doing so, you
make sure that the sensor is not removed while the instrument is reading data from or writing data to the
ISM-chip of the sensor.
The ISM icon appears on the display and the sensor ID of the sensor chip is registered and appears on
the display.
The calibration history, the initial certificate and the maximum temperature can be reviewed and printed in
the data memory.
4.5 Switching the instrument on and off

Switching on
− Press and release On/Off to switch on the instrument.
ð The firmware version, the serial number and the current date are displayed for a few seconds. After
that the instrument is ready for use.
Switching off
− Press and hold the On/Off key until the instrument switches to standby mode.
Note
• In the standby mode, the control circuit for the On/Off switch is energized. The rest of the instrument is
no longer energized.
4.6 Connectivity
Thanks to the plug & play capability, USB-sticks, barcode reader and printers are detected automatically.
Connection Use
RS232 interface RS-Printers
USB B interface EasyDirect pH PC Software
USB A interface USB-printer, USB barcode reader
USB-stick with file format FAT12/FAT16/FAT32
SevenCompact™ Duo S213 Putting into Operation 15

The instrument adjusts the baud rate to the following settings in case no automatic baud rate synchro-
nization occurs (only with printer types RS-P25, RS-P26, RS-P28):
Printer Baud rate: 1200
Data bits: 8
Parity: none
Stop bits: 1
Handshake: none
16 Putting into Operation SevenCompact™ Duo S213

5 Configuring the Instrument
1. Sample ID 5. System Settings
1. Enter Sample ID 1. Language
2. Auto Sequential 2. Time and Date
3. Select Sample ID 3. Access Control
4. Delete Sample ID 4. Beep
2. User ID 5. Routine/Expert Mode
1. Enter User ID 6. Screen Settings
2. Select User ID 6. Service
3. Delete User ID 1. Software Update
3. Stirrer 2. Export Settings to USB-stick
1. Stir Before Measurement 3. Factory Reset
2. Stir During Measurement 7. Instrument Self-test
3. Stir Speed
4. Stirrer Voltage Settings
4. Data Storage
1. Storage Mode
2. Storage Destination
3. Time Interval Readings
4. Printout Format
5.1 Sample ID
Navigation: Menu > > Sample ID
Parameter Description Value
Enter Sample Alphanumeric sample ID with up to 16 characters can be 1…16 characters
ID entered.
A maximum of 10 sample IDs are stored in memory and listed
for selection. If the maximum number of IDs has been stored,
the meter will display the message Memory is full.
Auto Sequential On: Using this setting will automatically increment the sample On | Off
ID by 1 for each reading. If the last character of the sample ID
is not a number, then the number 1 will be added to the
sample ID with the second sample. This requires the sample ID
to have less than 16 characters.
Off: The sample ID is not incremented automatically.
Select Sample To select a sample ID out of a list of already entered sample List of available
ID IDs. sample IDs
Delete Sample To delete an existing sample ID out of the list, select the List of available
ID sample ID you want to delete and press Read. sample IDs
5.2 User ID
Navigation: Menu > > User ID
Enter User ID Alphanumeric user IDs with up to 16 characters can be 1…16 characters
entered. A maximum of 10 user IDs are stored in memory and
listed for selection. If the maximum number of IDs has been
stored, the meter will display the message Memory is full.
Select User ID To select a user out of a list of existing users. List of available user
IDs
SevenCompact™ Duo S213 Configuring the Instrument 17

Delete User ID To delete an existing user ID out of the list, select the user ID List of available user
you want to delete and press Read. IDs
5.3 Stirrer
You can connect the METTLER TOLEDO external magnetic stirrer to the instrument. This stirrer is powered by
the instrument and will be automatically switched on/off according to the settings.
If a uMix or Compact stirrer is connected to the stirrer output, the option Stir During Measurement or Stir
Before Measurement can be selected. When the stirrer is active, the symbol is displayed.
Navigation: Menu > > Stirrer
Stir Before On: Using this setting will include a stirring period before the On | Off
Measurement measurement starts (after pressing Read).
Off: No stirring before the measurement will take place.
Enter Time Defines the stir duration [s] if Stir Before Measurement is 3…60
activated.
Stir During On: Using this setting will results in stirring during the On | Off
Measurement measurement. When the measurement is stopped, the stirrer is
automatically switched off.
Off: No stirring during the measurement will take place.
Stir Speed Defines the stir speed in steps, according to preferences and 1…5
the characteristics of the sample.
Stirrer Voltage Defines the minimum and maximum voltages for the stirrer. 0.5…8.0 V
Settings Stir Speed 1: Defines the voltage for the lowest stirring speed.
Stir Speed 5: Defines the voltage for the highest stirring speed.
5.4 Data storage

Navigation: Menu > > Data Storage
The meter stores up to 2000 sets of measurement data in the memory. The number of data sets already
stored in the memory is indicated by MXXXX on the display. A message appears on the display when the
memory is full. To save further measurements if the memory is full, data has to be deleted first. You can
select between automatic and manual storage. Press Exit to discard the endpoint readings.
Storage Mode Automatic Storage: Stores/transfers every found reading to the Automatic Storage |
memory/interface or both automatically. Manual Storage
Manual Storage: If selected, Save appears on the display as
soon as a measurement has found an endpoint. Press Save to
save or transfer the endpoint readings. The readings can only
be stored once. When the data is stored, Save disappears from
the measurement screen.
Storage Desti- Select to transfer the data to the memory, Printer or PC. Memory | Printer | PC
nation Memory: Data will be stored in the internal memory of the
instrument.
Printer: Data will be printed to the connected printer.
PC: Data will be transferred to the connected PC, running
EasyDirect pH.
Interval Activates the function to measure at intervals. On | Off
Readings The measurement series stops according to the selected
endpoint format or manually by pressing Read.
18 Configuring the Instrument SevenCompact™ Duo S213

Interval Time Define the time interval between the measurement points in [s] 3…3600
if Interval Readings is activated.
5.5 System settings
5.5.1 Language
Navigation: Menu > > System Settings > Language
Language Defines the language for operation of the instrument. English | Deutsch |
French | Italian |
Spanish | Portuguese |
Russian | Polish |
Chinese | Korean |
Japanese | Thai
5.5.2 Time and Date

Navigation: Menu > > System Settings > Time and Date
When starting the meter for the first time, the display for entering time and date appears automatically.
Time Define the time and the time format for operation of the 12h | 24h
instrument.
24-hour format (for example, 06:56 and 18:56)
12-hour format (for example, 06:56 AM and 06:56 PM)
Time and Date Defines the date and the date format for operation of the List of available date
instrument. formats
Date
28-11-20xx (day-month-year)
11-28-20xx (month-day-year)
28-Nov-20xx (day-month-year)
28/11/20xx (day-month-year)
5.5.3 Access Control

Navigation: Menu > > System Settings > Access Control
A maximum of 6 characters can be entered as PIN. In the factory default settings, the PIN for deleting data
is set to 000000 and is activated, no instrument login password is set.
System Settings To enable a PIN protection for the required access control ON. 1…6 characters
When selected, the window for entering an alphanumeric PIN
appears.
Deletion of Defines if the deletion of data is PIN protected. On | Off
Data
Instrument Defines if the instrument login is PIN protected. On | Off
Login

5.5.4 Audio signal
Navigation: Menu > > System Settings > Beep
Beep Defines if an audio signal should be enabled. Keypress | Alarm
Messages |
Measurement
Endpoint
5.5.5 Operator mode

Navigation: Menu > > System Settings > Routine / Expert Mode
The concept of the two working modes is a GLP feature that ensures that important settings and stored data
cannot be deleted cannot be unintentionally changed under routine working conditions.
The meter only allows the following functions in the routine mode:
• Calibrating and measuring
• Editing user, sample and sensor IDs
• Editing the MTC temperature
• Editing data transfer settings
• Editing system-settings (PIN-protected)
• Running the instrument self-test
• Storing, viewing, printing and exporting data
• Exporting settings to USB-stick
Routine / Expert Routine Mode: Some of the menu settings are blocked. Routine Mode | Expert
Mode Expert Mode: The factory default setting enables all functions Mode
of the meter.
5.5.6 Screen settings

Navigation: Menu > > System Settings > Screen Settings
Screen Defines the screen brightness. 1…16
Brightness
Screen Saver Defines whether the screen saver should be used. On | Off
Interval Time Defines how long in [min] the system should wait after the 5…99
user's last action on the terminal before activating the screen
saver.
Screen Color Defines the display background color. Blue | Grey | Red |
Green
5.6 Service
Navigation: Menu > > Service > Software Update
NOTICE
Danger of data loss due to reset!
When performing a software update, all settings will be set to default values and all data
will be deleted.

You can perform a software update via USB-stick.
§ Make sure that the firmware is in the root directory of the USB-stick and has a name S<xxx>v<yyy>.bin,
with <xxx> being the number of the instrument type and <yyy> being the version number.
1 Connect the USB-stick to the instrument.
2 Select the option Software Update.
ð A message appears that the software update is in progress
3 When the software update is completed you need to restart the instrument for the changes to become
effective.
Note
• The instrument will be reverted back to factory settings. All data will be deleted and the PIN will be set
back to “000000”.
• If the USB-stick is removed during the update process or the power supply is interrupted, the instrument
is no longer functional. Please contact METTLER TOLEDO service for further assistance.
Export Settings to USB-stick
With this feature you can export the settings. These can for example be sent via e-mail to METTLER TOLEDO
service.
1 Insert the USB stick into the corresponding interface of the meter
ð appears on the display
2 Select Export Settings to USB-stick in the service menu to start the transfer.
ð The instrument has created a new folder on the USB-stick in which the name corresponds to the date in
the international format. The date "25th November 2016" becomes "20161125".
ð The exported file is in text (extension .txt) format. The file name consists of the time in 24h format (hr
min sec) with the prefix S. The time "15:12:25 (3:12:25 pm)" becomes "S151225.txt".
Note
• Pressing Exit during the export will cancel process.
Factory Reset
NOTICE
Danger of data loss due to reset!
When performing a factory reset, all settings will be set to default values and all data will
be deleted.
1 Select the option Factory Reset.

ð A dialog box appears.
2 Press Yes to confirm the procedure.
ð The instrument has been reverted back to factory settings. All data has been deleted and the PIN will be
set back to “000000”.
5.7 Instrument Self-test

Navigation: Menu > > Service > Instrument Self-test
The instrument self-test requires user interaction.
1 Select the option Instrument Self-test.
ð A display test is performed. Subsequently, the self-test screen appears.
2 Press the function keys on the keypad one by one in any order.
ð The self-test result is displayed after a few seconds.
ð The meter returns to the system settings menu automatically.

Note
• You need to finish pressing all the keys within two minutes, otherwise Self-test failure appears and the
procedure has to be repeated.
• If error messages repeatedly appear, contact METTLER TOLEDO Service.

6 Measuring pH
6.1 Measurement settings
Navigation: Menu > pH
1. Sensor ID / SN 4. Endpoint Type
1. Enter Sensor ID / SN 5. Temperature Settings
2. Select Sensor ID 1. Set MTC Temperature
2. Delete Sensor ID 2. Temperature Unit
2. Calibration Settings 3. Temp. Sensor Recognition
1. Buffer Group / Standard 6. Measurement Limits
2. Calibration Mode 1. pH Limit
3. Calibration Reminder 2. mV Limit
3. Measurement Settings 3. Rel. mV Limit
1. Resolution 4. Temperature Limit
2. Stability Criterion
3. Rel. mV Offset
6.1.1 Sensor ID / SN
Navigation: Menu > pH > Sensor ID
When connecting an ISM® sensor to the meter, the meter will:
• Automatically recognize the sensor when it's turned on (alternatively, when pressing READ or CAL)
• Load the stored sensor ID, sensor SN and sensor type as well as the latest calibration data of this
sensor
• Use this calibration for the subsequent measurements
The sensor ID for ISM® sensors can be changed. Sensor SN and sensor type, however, are blocked for
modification.
Sensor ID Enter alphanumeric IDs for sensors. 1…12 characters
A maximum of 30 sensor IDs are stored in the memory and
Sensor SN Enter alphanumeric serial numbers for sensors. Serial numbers 1…12 characters
of ISM® sensors are detected automatically.
If a new sensor ID is entered, the theoretical calibration slope and offset for this type of electrode will be
loaded. The sensor has to be newly calibrated.
If a sensor ID is entered, which is already in the memory of the meter and has been calibrated before, the
specific calibration data for this sensor ID will be loaded.
Select Sensor To select a sensor out of a list of existing sensors. If a sensor List of available sensor
ID ID is selected, which has been calibrated before, the specific IDs
calibration data for this sensor ID will be loaded.
Delete Sensor To delete an existing sensor ID out of the list, select the sensor List of available sensor
ID ID you want to delete and press Read. IDs
SevenCompact™ Duo S213 Measuring pH 23

6.1.2 Calibration Settings
Navigation: Menu > pH > Calibration Settings
Buffer group Predefined Buffer Groups: One of eight predefined buffer Predefined Buffer
groups can be selected. Groups | Customized
Customized Buffer Group: A set of user-defined pH buffers Buffer Group
with up to 5 different temperatures for each buffer can be
created. The temperature difference must be at least 5 °C and
the difference between the pH values must be at least 1.
When switching from predefined buffer group to customized
buffer group, press Save in the table even if no values have
changed.
List of buffers
B1 1.68 4.01 7.00 10.01 (at 25°C) Mettler US
B2 2.00 4.01 7.00 9.21 11.00 (at 25°C) Mettler Europe
B3 2.00 4.00 7.00 9.00 12.00 (at 20°C) Standard Merck buffer
B4 1.680 4.008 6.865 9.184 12.454 (at 25°C) DIN19266:2000
B5 1.09 4.65 6.79 9.23 12.75 (at 25°C) DIN19267
B6 1.680 4.003 6.864 9.182 12.460 (at 25°C) Chinese
B7 2.00 4.01 7.00 10.00 (at 25°C) Technical buffer
B8 1.679 4.008 6.865 9.180 (at 25°C) JIS Z 8802
Temperature tables for these buffers are programmed in the meter and can be found in the "Appendix".
Calibration Segmented: the calibration curve is made up of linear Segmented | Linear
Mode segments joining the individual calibration points. If high
accuracy is required, the segment method is recommended.
Linear: the calibration curve is determined using linear
regression. This method is recommended for samples with
widely varying values.
Calibration If activated, a reminder to perform a calibration appears after a On | Off
Reminder defined time period.
See also
2 Appendix [} 49]
6.1.3 Measurement Settings

Navigation: Menu > pH > Measurement Settings
Measurement The resolution for pH and mV needs to be set for the display. pH | mV
Resolution Up to 3 decimal places can be chosen depending on the unit
of measurement
Decimal places
mV X no decimal places
pH, mV X.X one decimal place
pH X.XX two decimal places
pH X.XXX three decimal places
24 Measuring pH SevenCompact™ Duo S213

Stability Strict: The measured signal should not change by more than Strict | Standard | Fast
Criterion 0.03 mV in 8 seconds or by more than 0.1 mV in 20 seconds.
Standard: The measured signal should not change by more
than 0.1 mV in 6 seconds.
Fast Stability-Fast icon The measured signal should not
change by more than 0.6 mV in 4 seconds.
Rel. mV Offset Rel. mV Offset: In the rel. mV mode the offset value is Enter Offset Value |
subtracted from the measured value. Test a Reference
Enter Offset Value: An offset value can be entered. Sample
Test a Reference Sample: Determine by measuring the mV of
a reference sample.
Enter Offset Enter an offset value in mV. -1999.9…+1999.9
Value
Test a Reference Sample
1 Place an electrode in the reference sample.
2 Press Start to begin the reference measurement and wait until the measurement display freezes.
- or-
3 Press Read to manually end the measurement.
4 Press Save to enter the measured mV value as offset into the meter.
6.1.4 Endpoint Type

Navigation: Menu > pH > Endpoint Type
Endpoint Type Auto EP: The meter determines when a measurement is to be Auto EP | Manual EP |
stopped, based on the programmed stability criteria. Timed EP
Manual EP: The user is required to stop the measurement
manually.
Timed EP: The meter stops the measurement after a defined
time.
Enter Time Period of time [s] until the endpoint of the measurement is 5…3600 s
reached if Endpoint Type is set to Timed EP.
See also
2 Endpoint types [} 11]
6.1.5 Temperature Settings

Navigation: Menu > pH > Temperature Settings
Set MTC If the meter does not detect a temperature probe, MTC appears -30 °C…130 °C |
Temperature on the display. In this case the sample temperature should be -22 °F…266 °F
entered manually.
Temperature Defines the temperature unit applicable for the measurements. °C | °F
Unit The temperature value is automatically converted between the
two units.

Temp. Sensor You can select between automatic recognition or manual Automatic | Manual
Recognition selection of the temperature sensor type. For temperatures
below 100 °C the instrument can reliably distinguish between
NTC30 kΩ and Pt1000. At higher temperatures however, it is
necessary to select the type of temperature sensor manually.
Temp. Sensor Defines the type of temperature sensor to be used if Manual is NTC30 kOhm |
Recognition selected. Pt 1000
6.1.6 Measurement Limits

The upper and lower limits for measurement data can be defined. If a limit is either not reached or exceeded
(in other words, less than or greater than a specific value), a warning is displayed on the screen and may
be accompanied by an acoustic signal. The message Outside limits! also appears on the GLP printout.
Navigation: Menu > pH > Measurement Limits
pH Limit Defines the upper and lower limit in [pH]. -2.000…20.000
mV Limit Defines the upper and lower limit in [mV]. -1999.9…1999.9
Rel. mV Limit Defines the upper and lower limit in [mV]. -1999.9…1999.9
Temperature Defines the upper and lower limit for the temperature. -30…130 °C |
Limit -22.0…266 °F
6.2 Sensor Calibration

The meter allows you to perform calibrations with up to 5 points. Calibration is only possible in the full-
information screen. When starting a calibration by pressing the Cal key while the instrument displays the
close-up screen, it will automatically switch to the full-information screen.
Note
• The use of a temperature sensor or electrode with a built-in temperature sensor is recommended.
• If you use the MTC mode, you should enter the correct temperature value and keep all buffer and
sample solutions at the set temperature.
• To ensure the most accurate pH readings, you should perform calibrations regularly.
6.2.1 Running a one-point pH calibration

Before performing a calibration, select the pH channel by using the Channel key.
§ Press and hold Read to change the display mode (uFocus™).
§ Ensure that the appropriate buffer group has been selected.
1 Place the sensor in a calibration buffer and press Cal.
ð Cal 1 appears on the display and the Endpoint Type icon is blinking.
2 The icon appears as soon as the signal is stable, the measurement will stop automatically if
Endpoint Type > Auto is selected.
- or -
To manually stop the measurement, press Read.
ð Two soft buttons Exit and Calculate are shown.
3 Press Calculate to accept the calibration.
ð The offset value and the slope are shown on the display.
4 Press Save to save the result.
- or -
Press Exit to reject the calibration and return to the measurement screen.

Note
• With the one-point calibration only the offset is adjusted. If the sensor was previously calibrated with a
multipoint calibration the previously stored slope will remain. Otherwise the theoretical slope (–
59.16 mV/pH) will be used.
See also
2 Calibration Settings [} 24]
6.2.2 Running a multi-point pH calibration

Before performing a calibration, select the pH channel by using the Channel key.
§ Select the channel by using the key Channel.
§ Ensure that the appropriate buffers have been selected.
1 Place the sensor in a buffer and press Cal.
- or -
3 Rinse the sensor with deionized water and place the sensor in the next calibration buffer/standard.
4 Press Cal.
- or -
6 Rinse the sensor with deionized water and repeat the steps with all buffers.
7 Press Calculate to accept the calibration procedure. The meter will end the calibration automatically
when 5 calibrations are performed.
ð The offset value and slope are shown on the display.
8 Press to scroll down to next page of result.
9 Press Save to accept the calibration.
- or -
See also
6.3 Sample Measurement

§ Select the channels by using the key Channel.
§ Press and hold Mode to change the channel selection if both channels are active. Then press Mode to
change the measurement mode.
1 Place the sensor in the sample and press Read to start a measurement.
ð The Endpoint Type icon is blinking, indicating a measurement is in progress. The display shows the
measurement value of the sample.

- or -
ð The measurement has been stopped and the measured values are displayed.
Endpoint Type
• Auto: the measurement stops automatically when the signal is stable.
• Manual: press Read to manually stop the measurement.
• Timed: the measurement stops after the preset time.
See also

7 Measuring Conductivity
7.1 Measurement settings
Navigation: Menu > Cond.
1. Sensor ID / SN 4. Endpoint Type
1. Enter Sensor ID / SN 5. Temperature Settings
2. Select Sensor ID 1. Set MTC Temperature
2. Calibration Settings 2. Temperature Unit
1. Calibration Standard 6. Measurement Limits
2. Calibration Reminder 1. Conductivity Limit
3. Measurement Settings 2. TDS Limit
1. Reference Temperature 2. Salinity Limit
2. Temperature Correction 4. Resistivity Limit
3. TDS Factor 5. Conductivity Ash Limit
4. Conductivity Unit 6. Temperature Limit
5. Conductivity Ash
6. Salinity Unit
7.1.1 Sensor ID / SN
Navigation: Menu > Cond. > Sensor ID
When connecting an ISM® sensor to the meter, the meter will:
• Automatically recognize the sensor when it's turned on (alternatively, when pressing READ or CAL)
• Load the stored sensor ID, sensor SN and sensor type as well as the latest calibration data of this
sensor
• Use this calibration for the subsequent measurements
The sensor ID for ISM® sensors can be changed. Sensor SN and sensor type, however, are blocked for
modification.
Sensor ID Enter alphanumeric IDs for sensors. 1…12 characters
A maximum of 30 sensor IDs are stored in the memory and
Sensor SN Enter alphanumeric serial numbers for sensors. Serial numbers 1…12 characters
of ISM® sensors are detected automatically.
If a new sensor ID is entered, the theoretical calibration slope and offset for this type of electrode will be
loaded. The sensor has to be newly calibrated.
If a sensor ID is entered, which is already in the memory of the meter and has been calibrated before, the
specific calibration data for this sensor ID will be loaded.
Select Sensor To select a sensor out of a list of existing sensors. If a sensor List of available sensor
ID ID is selected, which has been calibrated before, the specific IDs
calibration data for this sensor ID will be loaded.
SevenCompact™ Duo S213 Measuring Conductivity 29

7.1.2 Calibration Settings
Navigation: Menu > Cond. > Calibration Settings
Calibration Predefined Standard: Use one of the predifend conductivity Predefined Standard |
Standard standards. Customized Standard
Customized Standard: Up to 5 temperature-dependent values | Enter Cell Constant
(in mS/cm only) can be entered in the table. Lowest possible
special standard: 0.00005 mS/cm (0.05 μS/cm). This value
corresponds to the conductivity of pure water at 25 °C, exclu-
sively caused by the autoprotolysis of water.
Enter Cell Constant:
If the cell constant of the conductivity cell being used is
accurately known, it can be entered directly in the meter. You
are prompted to enter the cell constant when calibrating the
sensor.
Predefined Standard
International Chinese Japanese
10 μS/cm 146.5 μS/cm 1330.00 μS/cm
84 μS/cm 1408 μS/cm 133.00 μS/cm
500 μS/cm 12.85 mS/cm 26.6 μS/cm
1413 μS/cm 111.35 mS/cm
12.88 mS/cm
Saturated NaCl
When switching from a predefined standard to customized standard, you should always save the table even
if no values have changed.
Calibration If activated, a reminder to perform a calibration appears after a On | Off
Reminder defined time period.
7.1.3 Measurement Settings
7.1.3.1 Reference temperature

Navigation: Menu > Cond. > Measurement Settings > Reference Temperature
Reference Defines the reference temperature which will be used to correct 20 °C (68 °F) | 25 °C
Temperature the conductivity reading. (77 °F)
30 Measuring Conductivity SevenCompact™ Duo S213

7.1.3.2 Temperature correction/alpha-coefficient
Navigation: Menu > Cond. > Measurement Settings > Temperature Correction
Temperature Defines the relationship between conductivity, temperature and Linear | Non-linear |
Correction concentration. Pure Water | Off
Linear: Use for the temperature correction of medium and
highly conductive solutions.
Non-linear: Use for natural water (only for temperature
between 0…36 °C). The measured conductivity at the sample
temperature is corrected to the defined reference temperature
(20 °C or 25 °C).
Pure Water: An optimized type of temperature algorithm is
used.
Off: The conductivity value at the current temperature is
displayed.
Linear
The conductivity of a solution increases when the temperature rises. With most solutions, a linear interrela-
tionship between conductivity and temperature is given.
The measured conductivity is corrected and displayed using the following formula:
whereras
• GT = conductivity measured at temperature T (mS/cm)
• GTRef = conductivity (mS/cm) displayed by the instrument, calculated back to the reference temperature
TRef
• α = linear temperature correction coefficient (%/°C); α = 0: no temperature correction
• T = measured temperature (°C)
• TRef = Reference temperature (20 °C or 25 °C)
Each sample has different temperature behavior. For pure salt solutions the correct coefficient can be found
in literature, otherwise you need to determine the α-coefficient by measuring the conductivity of the sample
at two temperatures and calculate the coefficient by using the formula below.
T1: Typical sample temperature

T2: Reference temperature
GT1: Measured conductivity at typical sample temperature
GT2: Measured conductivity at reference temperature
Non-linear
The conductivity of natural water shows strong non-linear temperature behavior. For this reason, use the
non-linear correction for natural water.
The measured conductivity is multiplied by the factor f25 for the measured temperature and thus corrected to
the reference temperature of 25 °C:
If another reference temperature is used, for example 20 °C, the conductivity corrected to 25 °C is divided
by 1.116 (see f25 for 20.0 °C)

Pure Water
Similar to non-linear correction for natural water a different type of non-linear correction is used for ultra-
pure and pure water. The values are compensated in the range from 0.005 to 5.00 μS/cm at temperatures
(0 - 50 °C) that differ from the reference temperature (25 °C). This could for example be when checking the
pure or ultra-pure water production equipment, or when checking if the cleaning-in-progress procedure for
which ultra-pure water has been used had led to the removal of all soluble substances. Due to the high
influence of CO2 from the air, we strongly suggest to use the flow-through-cell for this type of
measurements.
Note
• Conductivity measurements using the pure water compensation mode can only be performed at temper-
atures ranging from 0 °C to 50 °C. Otherwise, the warning message Temp. out of pure water range
appears.
• In case the conductivity reading exceeds the upper limit of 5.00 μS/cm in the mode pure warer, the
compensation will resemble a linear compensation mode with α = 2.00 %/°C.
7.1.3.3 TDS Factor

Navigation: Menu > Cond. > Measurement Settings > TDS Factor
TDS Factor TDS (Total dissolved solids) is calculated by multiplying the 0.10…2.00
conductivity value with the TDS factor.
See also
2 Conductivity to TDS conversion factors [} 54]
7.1.3.4 Conductivity Unit

Navigation: Menu > Cond. > Measurement Settings > Conductivity Unit
Conductivity μS/cm and mS/cm: The instrument will switch automatically μS/cm and mS/cm |
Unit between μS/cm and mS/cm depending on the measurement μS/m and mS/m
value. This unit is the standard for most conductivity
measurements.
μS/m and mS/m: The instrument will switch automatically
between μS/m and mS/m depending on the measurement
value. This unit is for example used for determination of the
conductivity of ethanol according to the ABNT / ABR 10547
method.
7.1.3.5 Conductivity Ash

Navigation: Menu > Cond. > Measurement Settings > Conductivity Ash
Conductivity Ash (%) is an important parameter that reflects the content of soluble inorganic salts in refined
sugar or raw sugar/melasses. These soluble inorganic impurities directly affect the purity of the sugar. The
instrument will directly convert the measured conductivity to conductivity ash % according to the selected
method.
Conductivity ash measurements are only possible in the temperature range from 15 °C to 25 °C.
ICUMSA Select the method for conductivity ash measuring. 28g (Refined Sugar) |
Method 28g (Refined Sugar): 28 g / 100 g solution (refined sugar - 5g (Raw Sugar)
ICUMSA GS2/3-17)
5g (Raw Sugar) : 5 g / 100 mL solution (raw sugar – ICUMSA
GS1/3/4/7/8-13)

Enter Cond. of The conductivity of the used water can be entered for preparing 0.0…100.0 μS/cm
Used Water the sugar solutions. This value is then used for correcting the
measured conductivity ash values.
See also
2 Conductivity ash methods [} 55]
7.1.3.6 Salinity unit

Navigation: Menu > Cond. > Measurement Settings > Salinity Unit
Salinity Unit Select the unit for salinity measurement. psu | ppt
See also
2 Practical salinity scale (UNESCO 1978) [} 54]
7.1.4 Endpoint Type

Navigation: Menu > Cond. > Endpoint Type
Endpoint Type Auto EP: The meter determines when a measurement is to be Auto EP | Manual EP |
stopped, based on the programmed stability criteria. Timed EP
Manual EP: The user is required to stop the measurement
manually.
Timed EP: The meter stops the measurement after a defined
time.
Enter Time Period of time [s] until the endpoint of the measurement is 5…3600 s
reached if Endpoint Type is set to Timed EP.
See also
7.1.5 Temperature Settings

Navigation: Menu > Cond. > Temperature Settings
Set MTC If the meter does not detect a temperature probe, MTC appears -30 °C…130 °C |
Temperature on the display. In this case the sample temperature should be -22 °F…266 °F
entered manually.
Temperature Defines the temperature unit applicable for the measurements. °C | °F
Unit The temperature value is automatically converted between the
two units.
7.1.6 Measurement Limits

The upper and lower limits for measurement data can be defined. If a limit is either not reached or exceeded
(in other words, less than or greater than a specific value), a warning is displayed on the screen and may
be accompanied by an acoustic signal. The message Outside limits! also appears on the GLP printout.
Navigation: Menu > Cond. > Measurement Limits
Conductivity Defines the upper and lower limit for the conductivity value in 0.00001…1000.00
Limit [mS/cm].
TDS Limit Defines the upper and lower limit for the TDS value in [g/L]. 0.00001…1000.00

Salinity Limit Defines the upper and lower limit for the salinity value in [psu/ 0.00…80.00
ppt].
Resistivity Limit Defines the upper and lower limit for the resistivity value in 0.00…100.00
[MΩ · cm].
Cond. Ash Limit Defines the upper and lower limit in [%]. 0.00…2022.00
Temperature Defines the upper and lower limit for the temperature. -30…130 °C |
Limit -22.0…266 °F
7.2 Sensor Calibration

Before performing a calibration, select the Conductivity channel by using the Channel key.
§ Ensure that the appropriate calibration standard has been selected.
1 Place the sensor in a calibration standard and press Cal.
ð Cal appears on the display and the Endpoint Type icon is blinking.
- or -
ð The calibration result is shown on the display.
3 Press Save to save the result.
- or -
Note
• The second point required for the conductivity calibration curve is permanently programmed in the meter
and is 0 S/m for a specific resistivity moving toward infinity. To ensure the most accurate conductivity
readings, verify the cell constant with a standard solution regularly and recalibrate if necessary.
See also
7.3 Sample Measurement

§ Select the channels by using the key Channel.
§ Press and hold Mode to change the channel selection if both channels are active. Then press Mode to
change the measurement mode.
1 Place the sensor in the sample and press Read to start a measurement.
ð The Endpoint Type icon is blinking, indicating a measurement is in progress. The display shows the
measurement value of the sample.
- or -
ð The measurement has been stopped and the measured values are displayed.
Endpoint Type
• Auto: the measurement stops automatically when the signal is stable.
• Manual: press Read to manually stop the measurement.
• Timed: the measurement stops after the preset time.

See also

8 Dual Channel Operation
With the thorough galvanic isolation of the electronics layout, it is possible to simultaneously measure with
both measurement channels in the very same sample beaker, without interfering the measurements.
By pressing the key Channel the instrument can be toggled between the channels. By default the instrument
is in Dual mode. By pressing Channel once, the instrument switches to pH mode. By pressing Channel a
second time, the instrument switches to Conductivity mode.
The dual channel mode will use the settings from the respective measurement settings. Measurements can
be started by pressing Read. Calibrations however need to be carried out in single channel mode. Changing
the measurement mode is possible during dual channel operation (e.g. from Conductivity to TDS. A small
arrow (◀) next to the unit indicates the selection of the unit that can be changed by pressing Mode. To
change the channel selection, press and hold Mode.
You can switch between measurement close-up screen uFocus™ and full-information screen in single
channel mode or in dual channel mode. Press and hold Read to switch.
See also
2 Measurement settings [} 23]
2 Measurement settings [} 29]
36 Dual Channel Operation SevenCompact™ Duo S213

9 Managing data
Navigation: Data
1. Measurement Data 3. ISM Data (Electrode Records)
1. View 1. pH
2. Transfer 1.1 Initial Calibration Data
3. Delete 1.2 Calibration History
2. Calibration Data 1.3 Electrode Records
1. pH 1.4 Reset ISM
1.1 View 2. Conductivity
1.2 Transfer 2.1 Initial Calibration Data
1.3 Delete 2.2 Calibration History
2. Conductivity 2.3 Electrode Records
2.1 View 2.4 Reset ISM
2.2 Transfer 4. Transfer Interfaces
2.3 Delete
9.1 Measurement data

Navigation: Data > Measurement Data
All stored measurement data can be reviewed, transferred to selected options, or deleted. Deletion is
protected by a PIN. Upon delivery, the PIN is set to 000000. Change the PIN code to prevent unauthorized
access. The measurement data can be filtered according to different criteria.
1 Select the desired action View, Transfer or Delete.
2 Select All to select all the data.
- or -
Select Partial to apply a filter to the selection.
- or -
Select New to select all not yet transferred data.
ð The selected action will be applied to the filtered data.
Filter options
Parameter Description
Partial by Date/Time − Enter the time range of the data and press Select.
ð The measurement data is displayed.
Partial by Channel − Enter the channel of the data and press Select.
Partial by Memory Number 1 Enter the memory numbers of the data and press Select.
ð The measurement data is displayed.
2 Scroll through the measurement data to review all measurements
between the two memory numbers.
Partial by Sample ID 1 Enter the sample ID and press OK.
ð The meter finds all stored measurements with this sample ID.
2 Scroll through the measurement data to review all measurements with
the entered sample ID.
Partial by Measurement 1 Select a measurement mode from list. The meter finds all stored
Mode measurements of the selected measurement mode.
2 Scroll through the measurement data of the selected measurement
mode.
SevenCompact™ Duo S213 Managing data 37

9.2 Calibration data
Navigation: Data > Calibration Data
All stored calibration data can be reviewed, transferred to selected options, or deleted. Deletion is protected
by a PIN. Upon delivery, the PIN is set to 000000. Change the PIN code to prevent unauthorized access.
1 Select channel pH or Conductivity.
2 Select the desired action View, Transfer or Delete.
ð The list of calibrated sensor IDs appears.
3 Select a sensor from the list to start the selected action.
ð The selected action will be applied to the sensor.
Note
• After deletion, the sensor ID disappears from the list in the sensor ID menu.
9.3 ISM data

Navigation: Data > ISM Data
The SevenCompact meters incorporate Intelligent Sensor Management (ISM®) technology. This ingenious
functionality provides extra security, safety and eliminates mistakes.
• After connecting the ISM® sensor, the sensor is automatically recognized and the sensor ID and serial
number are transferred from the sensor chip to the meter. The data is also printed on the GLP printout.
• After calibration of the ISM® sensor, the calibration data is automatically stored from the meter to the
sensor chip. The most recent data is always stored where it should be – on the sensor chip!
• After connecting the ISM® sensor, the five most recent calibrations are transferred to the meter. These can
be reviewed to see the development of the sensor over time. This information provides an indication if
the sensor should be cleaned or renewed.
• After connecting an ISM® sensor, the last set of calibration data is automatically used for measurements.
Initial calibration data pH sensors
When connecting a ISM® sensor, the initial calibration data in the sensor can be reviewed or transferred.
The following data is included:
• Response time between pH 4.01 and 7.00
• Temperature tolerance
• Membrane resistance
• Slope (calibration with pH 4.01 and 7.00) and offset
• Type (and name) of electrode (for example, InLab Expert Pro-ISM®)
• Serial number (SN) and order number
• Production date
Initial calibration data conductivity sensors
When connecting a ISM® sensor, the initial calibration data in the sensor can be reviewed or transferred.
The following data is included:
• Response time
• Temperature tolerance
• Cell constant
• Cell constant tolerance
• Type (and name) of electrode (for example, InLab 731-ISM®)
• Serial number (SN) and order number
• Production date
38 Managing data SevenCompact™ Duo S213

Options
Parameter Description
Calibration History The last 5 calibrations data stored in ISM® sensor including current
calibration can be reviewed or transferred.
Maximum Temperature The maximum temperature that the ISM® sensor has been exposed to
during measurement is monitored automatically and can be reviewed for
the evaluation of the electrode lifetime.
Reset ISM The calibration history in this menu can be deleted. This menu is
protected by a deletion PIN. Upon delivery, the PIN for deletion is set to
000000. Change the PIN to prevent unauthorized access.
9.4 Transfer Interfaces

Navigation: Data > Transfer Interfaces
All stored measurement data can be transferred to selected interface.
Interface USB-stick: Data will be stored to the connected USB-stick in USB-stick | Printer |
*.txt format. PC
Printer: Data will be printed to the connected printer.
PC: Data will be transferred to the connected PC, running
EasyDirect pH.
SevenCompact™ Duo S213 Managing data 39

10 Troubleshooting
10.1 Instrument messages
Message Description and Resolution
Temperature exceeds max. limit Measurement limits are activated in the menu settings and measured value is
Temperature below min. limit outside these limits.
• Check the sample.
• Check sample temperature.
• Make sure that the pH electrode wetting cap has been removed and that the
electrode is properly connected and placed in the sample solution.
Memory is full Max. 2000 measurement data can be stored in the memory. Too many sensor
IDs are stored.
• Delete all or partial data in the memory, otherwise you will not be able to
store new measurement data.
Please calibrate electrode Calibration reminder has been switched on in the menu settings and last
calibration has expired.
• Calibrate the electrode.
Active sensor cannot be deleted Deleting the calibration data of the selected sensor ID is not possible, because
it is currently the active sensor ID in the meter shown on the display.
• Enter new sensor ID in the menu settings.
• Select another sensor ID from the list in the menu settings.
Wrong buffer Meter cannot recognize the buffer or standard/buffer. The buffers differ by less
than 60 mV.
• Make sure that you use the correct buffers.
• Make sure that the buffers are fresh.
• Make sure that the same buffer has not been used more than once during
the calibration.
Slope out of range The calibration result is outside the following limits: Slope < 85% or > 110%,
Offset out of range Offset < -60 mV or > + 60 mV.
• Make sure that you have the correct buffer and that it is fresh.
• Check mV signal of electrode, clean or replace the electrode.
Standard temp. out of range The ATC measured temperature is out of pH calibration buffer range: 5…50 °C.
Buffer temp. out of range • Keep the buffer/standard temperature within the range.
• Change the temperature setting.
ISM sensor communication error Data has not been transferred correctly between ISM® sensor and meter.
• Reconnect the ISM® sensor and try again.
Standard temp. out of range The ATC measured temperature is out of conductivity calibration standard
range: 5…35 °C for international standards and 15…35 °C for chinese
standards
• Keep the standard temperature within the range.
• Change the temperature setting.
Temp. out of nLF correction range Conductivity measurements of natural water can only be performed at temper-
atures from 0…36 °C.
• Keep the sample temperature within the range.
Temp. out of pure water range Conductivity measurements of pure water can only be performed at temper-
atures from 0…50 °C.
Temp. out of conductivity ash correction range Conductivity ash measurements can only be performed at temperatures from
15…25 °C.
Self-test failure Self-test has not been completed within 2 minutes or meter is defective.
• Restart self-test and finish within 2 minutes.
• Contact METTLER TOLEDO service if problem persists.
Wrong settings Entered value differs by less than 1 pH unit/5°C from other preset values.
• Enter a higher/lower value in order to get a bigger difference.
40 Troubleshooting SevenCompact™ Duo S213

Message Description and Resolution
Out of range Either entered value is out of range.
• Enter a value which is within the range shown on display.
or
Measured value out of range.
• Make sure the electrode wetting cap has been removed and that the
electrode is properly connected and placed in the sample solution.
• If no electrode is connected, put the shorting clip in the socket.
Wrong password The entered PIN is not correct.
• Re-enter the PIN.
• Reset to factory settings, all data and settings will be lost.
Passwords do not match, try again The confirmation PIN does not match with the entered PIN.
• Reenter PIN.
Program memory error Meter recognizes internal error during start-up.
• Switch the meter off and back on.
• Contact METTLER TOLEDO service if the problem persists.
Data memory error The data could not be stored into memory.
• Switch the meter off and back on.
• Contact METTLER TOLEDO service if the problem persists.
No matching data found in memory The entered filter criterion does not exist.
• Enter a new filter criterion.
Sensor ID already exists, previous SN will be Two sensors with the same ID but different SN are not allowed in the meter. If a
overwritten different SN has been entered for this sensor ID previously, the old SN will be
overwritten.
• Enter a different Sensor ID in order to keep the previous ID and SN.
Software update failed The software update process failed. This could be due to the following reasons:
• The USB stick is not connected or it is disconnected during the update
process
• The update software is not in the correct folder
Export failed The exporting process failed. This could be due to the following reasons:
• The USB stick is not connected or it is disconnected during the exporting
process
• The USB stick is full
10.2 Error limits

pH Channel
Message Range not accepted
pH exceeds max. limit pH < -2.000 or > 20.000
mV exceeds max. limit mV < -2000.0 or > 2000.0
Buffer temp. out of range/Standard T (pH) < 5 or > 50 °C
temp. out of range
Offset out of range Eref1-Eb > 60 mV
Slope out of range Slope < 85% or > 110%
Wrong buffer ∆Eref1 < 0 mV
Conductivity Channel
Conductivity exceeds max. limit Conductivity < 0.00 µS/cm or > 1000 mS/
cm
TDS exceeds max. limit TDS < 0.00 mg/L or > 1000 g/L
Salinity exceeds max. limit Salinity < 0.00 psu or > 80.0 psu
Resistivity exceeds max. limit Resistivity < 0.00 MΩ*cm or
> 100.0 MΩ*cm
SevenCompact™ Duo S213 Troubleshooting 41

Conductivity Ash exceeds max. limit Conductivity ash < 0.00% or > 2022%
Standard temp. out of range Temperature < 0 °C or > 35 °C
Temperature exceeds max. limit Temperature < -5 °C or > 105 °C
Temp. out of nLF corr. Temperature < 0°C or > 50 °C
Temp. out of pure water range Temperature < 0 °C or > 50 °C
Temp. out of conductivity ash correction Temperature < 15 °C or > 25 °C
range
42 Troubleshooting SevenCompact™ Duo S213

11 Sensors, Solutions and Accessories
pH Sensors
Parts Order No.
ISM® sensors with multi-pin head
InLab®Micro Pro-ISM, 3-in-1 pH sensor, glass shaft, 5 mm shaft diameter, ATC, 51344163
refillable
InLab®Power Pro-ISM, 3-in-1 pH sensor, glass shaft, ATC, pressurized Steady- 51344211
Force™ reference system
InLab®Pure Pro-ISM, 3-in-1 pH sensor, glass shaft, immovable glass sleeve, ATC, 51344172
refillable
InLab®Routine Pro-ISM, 3-in-1 pH sensor, glass shaft, ATC, refillable 51344055
®
InLab Science Pro-ISM, 3-in-1 pH sensor, glass shaft, movable glass sleeve, ATC, 51344072
refillable
InLab®Solids Pro-ISM, 3-in-1 pH sensor, glass shaft, open junction, sharp 51344155
membrane, ATC
pH solutions
Solutions Order No.
pH 2.00 buffer sachets, 30 x 20 mL 30111134
pH 2.00 buffer solution, 250 mL 51350002
pH 2.00 buffer solution, 6 x 250 mL 51350016
Rainbow sachets I (10 sachets of pH 4.01 / 7.00 / 9.21) 51302068
Rainbow sachets II (10 sachets of pH 4.01 / 7.00 / 10.01) 51302080
Rainbow bottles I (2 x 250 mL of pH 4.01 / 7.00 / 9.21) 30095312
Rainbow bottles II (2 x 250 mL of pH 4.01 / 7.00 / 10.00) 30095313
InLab storage solution (for all InLab pH and redox electrodes), 250 mL 30111142
Electrolyte 3 mol/L KCl, 25 mL 51343180
Electrolyte 3 mol/L KCl, 250 mL 51350072
Electrolyte 3 mol/L KCl, 6 x 250 mL 51350080
HCl/Pepsin solution (removes protein contamination), 250 mL 51350100
Thiourea solution (removes silver sulfide contamination), 250 mL 51350102
SevenCompact™ Duo S213 Sensors, Solutions and Accessories 43

Solutions Order No.
Regeneration solution for pH electrodes, 25 mL 51350104
Conductivity sensors
Parts Order No.
®
InLab 731-ISM (steel) 30014092
InLab®741-ISM (steel) 30014094
®
InLab 710 (glass) 51302256
®
InLab 720 (glass) 51302255
®
InLab 751-4mm (narrow shaft) 51344030
Conductivity solutions
Parts Order No.
10 μS/cm conductivity standard solution, 250 mL 51300169
10 μS/cm conductivity standard solution, 30 x 20 mL sachets 30111141
1413 μS/cm conductivity standard solution, 6 x 250 mL 51350096
12.88 mS/cm conductivity standard solution, 30 x 20 mL sachets 51302050
12.88 mS/cm conductivity standard solution, 6 x 250 mL 51350098
Guides
Parts Order No.
Guide to pH measurement 51300047
Guide to conductivity measurement 30099121
44 Sensors, Solutions and Accessories SevenCompact™ Duo S213

12 Technical Data
General
Screen Color TFT
Interfaces RS232 9-pin male D-sub (Printer,
barcode reader, PC keyboard)
USB-A USB-Stick (FAT12/FAT16/FAT32)/
Printer
USB-B Computer
Stirrer Socket 5-pin Mini-DIN
Voltage range 0.5…18 V
Current Max. 300 mA
Ambient conditions Ambient temperature 5…40 °C
Relative humidity 5…80% (non-condensing)
Overvoltage category Class II
Pollution degree 2
Range of application For indoor use only
Maximum operating altitude Up to 2000 m
Standards for safety and EMC See Declaration of Conformity
Dimensions Width 204 mm
Depth 174 mm
Height 74 mm
Weight 890 g
Power rating instrument Input voltage 9 - 12 V
Power consumption 2.5 W
Power rating AC adapter Line voltage 100 - 240 V ±10 %
Input frequency 50/60 Hz
Input current 0.3 A
Output voltage 12 V
Output current 0.84 A
Materials Housing ABS/PC reinforced
Window Polymethyl methacrylate (PMMA)
Keypad Membrane keypad: Polyethelene
terephtalate (PET)
SevenCompact™ Duo S213 Technical Data 45

pH measuring
Measurement range pH -2.000…20.000
mV -2000.0…+2000.0 mV
Automatic temperature capture -5…130 °C
Manual temperature capture -30…130 °C
Resolution pH 0.1/0.01/0.001
mV 1/0.1
Temperature 0.1 °C
Limits of error pH ± 0.002
mV ± 0.1 mV (-1000…+1000 mV)
± 0.2 mV (> ±1000 mV)
Temperature ± 0.1 °C (-5…100 °C)
± 0.3 °C (> 100 °C)
Isopotential point pH 7.00
pH input BNC Impedance > 3 · 1012 Ω
Temperature input RCA (Cinch) NTC 30kΩ, Pt1000
Digital sensor input Mini-LTW
Calibration (pH) Calibration points 5
Predefined buffer groups 8
User-defined buffer groups 1 user-defined group of 5 buffers
Automatic buffer recognition Yes
Calibration methods Linear, segmented
46 Technical Data SevenCompact™ Duo S213

Conductivity measurement
Measurement range Conductivity 0.000 μS/cm…1000 mS/cm
TDS 0.00 mg/L...1000 g/L
Salinity 0.00…80.00 psu
0.00…80.00 ppt
Resistivity 0.00…100.0 MΩ·cm
Conductivity ash 0.00…2022%
Automatic temperature capture -5…130 °C
Manual temperature capture -30…130 °C
Resolution Conductivity Auto range
0.000 µS/cm…9.999 µS/cm
10.00 µS/cm…99.99 µS/cm
100.0 µS/cm…999.9 µS/cm
1000 uS/cm…9999 uS/cm
10.00 mS/cm…99.99 mS/cm
100.0 mS/cm…999.9 mS/cm
1000 mS/cm
TDS Auto range, same values as
conductivity
Salinity 0.00…80.00 psu/ppt
Resistivity 0.00 Ω·cm…99.99 Ω·cm
100.0 Ω·cm…999.9 Ω·cm
1000 Ω·cm…9999 Ω·cm
10.00 kΩ·cm…99.99 kΩ·cm
100.0 kΩ·cm…999.9 kΩ·cm
1000 kΩ·cm…9999 kΩ·cm
10.00 MΩ·cm…99.99MΩ·cm
100.0 MΩ·cm… –
Conductivity ash 0.000%…9.999%
10.00%…99.99%
100.0%…999.9%
1000%…2020%
Temperature ±0.1 °C
Limits of error Conductivity ±0.5% of measured value
TDS ±0.5% of measured value
Salinity ±0.5% of measured value
Resistivity ±0.5% of measured value
Conductivity ash ±0.5% of measured value
Temperature ± 0.1 °C (-5…100 °C)
± 0.5 °C (> 100 °C)
Inputs Conductivity Mini-DIN conductivity sensors
Digital sensor input Mini-LTW digital sensors
SevenCompact™ Duo S213 Technical Data 47

Calibration Calibration points 1
Predefined conductivity standards 13
User-defined conductivity Yes
standards
Manual cell constant entry Yes
48 Technical Data SevenCompact™ Duo S213

13 Appendix
13.1 Buffers
METTLER TOLEDO USA (Ref. 25°C)
T [°C] 1.68 4.01 7.00 10.01
5 1.67 4.00 7.09 10.25
10 1.67 4.00 7.06 10.18
15 1.67 4.00 7.04 10.12
20 1.68 4.00 7.02 10.06
25 1.68 4.01 7.00 10.01
30 1.68 4.01 6.99 9.97
35 1.69 4.02 6.98 9.93
40 1.69 4.03 6.97 9.89
45 1.70 4.04 6.97 9.86
50 1.71 4.06 6.97 9.83
METTLER TOLEDO Europe (Ref. 25°C)
T [°C] 2.00 4.01 7.00 9.21 11.00
5 2.02 4.01 7.09 9.45 11.72
10 2.01 4.00 7.06 9.38 11.54
15 2.00 4.00 7.04 9.32 11.36
20 2.00 4.00 7.02 9.26 11.18
25 2.00 4.01 7.00 9.21 11.00
30 1.99 4.01 6.99 9.16 10.82
35 1.99 4.02 6.98 9.11 10.64
40 1.98 4.03 6.97 9.06 10.46
45 1.98 4.04 6.97 9.03 10.28
50 1.98 4.06 6.97 8.99 10.10
MERCK (Ref. 20°C)
T [°C] 2.00 4.00 7.00 9.00 12.00
5 2.01 4.04 7.07 9.16 12.41
10 2.01 4.02 7.05 9.11 12.26
15 2.00 4.01 7.02 9.05 12.10
20 2.00 4.00 7.00 9.00 12.00
25 2.00 4.01 6.98 8.95 11.88
30 2.00 4.01 6.98 8.91 11.72
35 2.00 4.01 6.96 8.88 11.67
40 2.00 4.01 6.95 8.85 11.54
45 2.00 4.01 6.95 8.82 11.44
50 2.00 4.00 6.95 8.79 11.33
SevenCompact™ Duo S213 Appendix 49

JIS Z 8802 (Ref. 25°C)
T [°C] 1.679 4.008 6.865 9.180
5 1.668 3.999 6.951 9.395
10 1.670 3.998 6.923 9.332
15 1.672 3.999 6.900 9.276
20 1.675 4.002 6.881 9.225
25 1.679 4.008 6.865 9.180
30 1.683 4.015 6.853 9.139
35 1.688 4.024 6.844 9.102
40 1.694 4.035 6.838 9.068
45 1.700 4.047 6.834 9.038
50 1.707 4.060 6.833 9.011
DIN(19266:2000) NIST (Ref. 25°C)
T [°C] 1.68 4.008 6.865 9.184 12.454
5 1.668 4.004 6.950 9.392 13.207
10 1.670 4.001 6.922 9.331 13.003
15 1.672 4.001 6.900 9.277 12.810
20 1.676 4.003 6.880 9.228 12.627
25 1.680 4.008 6.865 9.184 12.454
30 1.685 4.015 6.853 9.144 12.289
35 1.691 4.026 6.845 9.110 12.133
40 1.697 4.036 6.837 9.076 11.984
45 1.704 4.049 6.834 9.046 11.841
50 1.712 4.064 6.833 9.018 11.705
DIN(19267) (Ref. 25°C)
T [°C] 1.09 4.65 6.79 9.23 12.75
5 1.08 4.67 6.87 9.43 13.63
10 1.09 4.66 6.84 9.37 13.37
15 1.09 4.66 6.82 9.32 13.16
20 1.09 4.65 6.80 9.27 12.96
25 1.09 4.65 6.79 9.23 12.75
30 1.10 4.65 6.78 9.18 12.61
35 1.10 4.65 6.77 9.13 12.45
40 1.10 4.66 6.76 9.09 12.29
45 1.10 4.67 6.76 9.04 12.09
50 1.11 4.68 6.76 9.00 11.98
50 Appendix SevenCompact™ Duo S213

JJG119 (Ref. 25°C)
T [°C] 1.680 4.003 6.864 9.182 12.460
5 1.669 3.999 6.949 9.391 13.210
10 1.671 3.996 6.921 9.330 13.011
15 1.673 3.996 6.898 9.276 12.820
20 1.676 3.998 6.879 9.226 12.637
25 1.680 4.003 6.864 9.182 12.460
30 1.684 4.010 6.852 9.142 12.292
35 1.688 4.019 6.844 9.105 12.130
40 1.694 4.029 6.838 9.072 11.975
45 1.700 4.042 6.834 9.042 11.828
50 1.706 4.055 6.833 9.015 11.697
Technical (Ref. 25°C)
T [°C] 2.00 4.01 7.00 10.00
5 2.02 4.01 7.09 10.52
10 2.01 4.00 7.06 10.39
15 2.00 4.00 7.04 10.26
20 2.00 4.00 7.02 10.13
25 2.00 4.01 7.00 10.00
30 1.99 4.01 6.99 9.87
35 1.99 4.02 6.98 9.74
40 1.98 4.03 6.97 9.61
45 1.98 4.04 6.97 9.48
50 1.98 4.06 6.97 9.35
13.2 Conductivity standards

International (Ref. 25°C)
T [°C] 10 µS/cm 84 µS/cm 500 µS/cm 1413 µS/cm 12.88 mS/cm
5 6.13 53.02 315.3 896 8.22
10 7.10 60.34 359.6 1020 9.33
15 7.95 67.61 402.9 1147 10.48
20 8.97 75.80 451.5 1278 11.67
25 10.00 84.00 500.0 1413 12.88
30 11.03 92.19 548.5 1552 14.12
35 12.14 100.92 602.5 1696 15.39
Chinese Standards (Ref. 25°C)
T [°C] 146.5 µS/cm 1408 µS/cm 12.85 mS/cm 111.3 mS/cm
15 118.5 1141.4 10.455 92.12
18 126.7 1220.0 11.163 97.80
20 132.2 1273.7 11.644 101.70
25 146.5 1408.3 12.852 111.31
35 176.5 1687.6 15.353 131.10

Japanese Standards (Ref. 20°C)
T [°C] 1330.00 µS/cm 133.00 µS/cm 26.6 µS/cm
0 771.40 77.14 15.428
5 911.05 91.11 18.221
10 1050.70 105.07 21.014
15 1190.35 119.04 23.807
20 1330.00 133.00 26.600
25 1469.65 146.97 29.393
30 1609.30 160.93 32.186
35 1748.95 174.90 34.979
Saturated NaCl (Ref. 25°C)
T [°C] Saturated NaCl [mS/cm]
5 155.5
10 177.9
15 201.5
20 226.0
25 251.3
30 277.4
35 304.1

13.3 Temperature correction factors
Temperature correction factors f25 for non-linear conductivity correction
°C .0 .1 .2 .3 .4 .5 .6 .7 .8 .9
0 1.918 1.912 1.906 1.899 1.893 1.887 1.881 1.875 1.869 1.863
1 1.857 1.851 1.845 1.840 1.834 1.829 1.822 1.817 1.811 1.805
2 1.800 1.794 1.788 1.783 1.777 1.772 1.766 1.761 1.756 1.750
3 1.745 1.740 1.734 1.729 1.724 1.719 1.713 1.708 1.703 1.698
4 1.693 1.688 1.683 1.678 1.673 1.668 1.663 1.658 1.653 1.648
5 1.643 1.638 1.634 1.629 1.624 1.619 1.615 1.610 1.605 1.601
6 1.596 1.591 1.587 1.582 1.578 1.573 1.569 1.564 1.560 1.555
7 1.551 1.547 1.542 1.538 1.534 1.529 1.525 1.521 1.516 1.512
8 1.508 1.504 1.500 1.496 1.491 1.487 1.483 1.479 1.475 1.471
9 1.467 1.463 1.459 1.455 1.451 1.447 1.443 1.439 1.436 1.432
10 1.428 1.424 1.420 1.416 1.413 1.409 1.405 1.401 1.398 1.384
11 1.390 1.387 1.383 1.379 1.376 1.372 1.369 1.365 1.362 1.358
12 1.354 1.351 1.347 1.344 1.341 1.337 1.334 1.330 1.327 1.323
13 1.320 1.317 1.313 1.310 1.307 1.303 1.300 1.297 1.294 1.290
14 1.287 1.284 1.281 1.278 1.274 1.271 1.268 1.265 1.262 1.259
15 1.256 1.253 1.249 1.246 1.243 1.240 1.237 1.234 1.231 1.228
16 1.225 1.222 1.219 1.216 1.214 1.211 1.208 1.205 1.202 1.199
17 1.196 1.193 1.191 1.188 1.185 1.182 1.179 1.177 1.174 1.171
18 1.168 1.166 1.163 1.160 1.157 1.155 1.152 1.149 1.147 1.144
19 1.141 1.139 1.136 1.134 1.131 1.128 1.126 1.123 1.121 1.118
20 1.116 1.113 1.111 1.108 1.105 1.103 1.101 1.098 1.096 1.093
21 1.091 1.088 1.086 1.083 1.081 1.079 1.076 1.074 1.071 1.069
22 1.067 1.064 1.062 1.060 1.057 1.055 1.053 1.051 1.048 1.046
23 1.044 1.041 1.039 1.037 1.035 1.032 1.030 1.028 1.026 1.024
24 1.021 1.019 1.017 1.015 1.013 1.011 1.008 1.006 1.004 1.002
25 1.000 0.998 0.996 0.994 0.992 0.990 0.987 0.985 0.983 0.981
26 0.979 0.977 0.975 0.973 0.971 0.969 0.967 0.965 0.963 0.961
27 0.959 0.957 0.955 0.953 0.952 0.950 0.948 0.946 0.944 0.942
28 0.940 0.938 0.936 0.934 0.933 0.931 0.929 0.927 0.925 0.923
29 0.921 0.920 0.918 0.916 0.914 0.912 0.911 0.909 0.907 0.905
30 0.903 0.902 0.900 0.898 0.896 0.895 0.893 0.891 0.889 0.888
31 0.886 0.884 0.883 0.881 0.879 0.877 0.876 0.874 0.872 0.871
32 0.869 0.867 0.866 0.864 0.863 0.861 0.859 0.858 0.856 0.854
33 0.853 0.851 0.850 0.848 0.846 0.845 0.843 0.842 0.840 0.839
34 0.837 0.835 0.834 0.832 0.831 0.829 0.828 0.826 0.825 0.823
35 0.822 0.820 0.819 0.817 0.816 0.814 0.813 0.811 0.810 0.808

13.4 Temperature coefficients (alpha-values)
Substance at 25°C Concentration Temperature coefficient alpha
[%] [%/°C]
HCl 10 1.56
KCl 10 1.88
CH3COOH 10 1.69
NaCl 10 2.14
H2SO4 10 1.28
HF 1.5 7.20
α-coefficients of conductivity standards for a calculation to reference temperature 25 °C
Standard Measurement Measurement Measurement Measurement
temp.: 15 °C temp.: 20 °C temp.: 30 °C temp.: 35 °C
84 µS/cm 1.95 1.95 1.95 2.01
1413 µS/cm 1.94 1.94 1.94 1.99
12.88 mS/cm 1.90 1.89 1.91 1.95
13.5 Practical salinity scale (UNESCO 1978)

The salinity is calculated according to the official definition of UNESCO 1978. Therefore the salinity Spsu of
a sample in psu (practical salinity unit) at standard atmospheric pressure is calculated as follows:
a0 = 0.0080 b0 = 0.0005 k = 0.00162

a1 = -0.1692 b1 = -0.0056
a2 = 25.3851 b2 = -0.0066
a3 = 14.0941 b3 = -0.0375
a4 = -7.0261 b4 = 0.0636
a5 = 2.7081 b5 = -0.0144
(32.4356 g KCl per 1000 g of solution)
13.6 Conductivity to TDS conversion factors

Conductivity TDS KCl TDS NaCl
at 25 °C ppm value factor ppm value factor
84 µS/cm 40.38 0.5048 38.04 0.4755
447 µS/cm 225.6 0.5047 215.5 0.4822
1413 µS/cm 744.7 0.527 702.1 0.4969
1500 µS/cm 757.1 0.5047 737.1 0.4914
8974 µS/cm 5101 0.5685 4487 0.5000
12.880 µS/cm 7447 0.5782 7230 0.5613
15.000 µS/cm 8759 0.5839 8532 0.5688
80 mS/cm 52.168 0.6521 48.384 0.6048

13.7 USP/EP tables
Conductivity requirements (µS/cm) for USP / EP (highly purfied water) / EP (purfied water)
Temperature USP EP EP
(highly purfied water) (purfied water)
[°C] [µS/cm] [µS/cm] [µS/cm]
0 0.6 0.6 2.4
5 0.8 0.8 -
10 0.9 0.9 3.6
15 1.0 1.0 -
20 1.1 1.1 4.3
25 1.3 1.3 5.1
30 1.4 1.4 5.4
35 1.5 1.5 -
40 1.7 1.7 6.5
45 1.8 1.8 -
50 1.9 1.9 7.1
55 2.1 2.1 -
60 2.2 2.2 8.1
65 2.42 2.42 -
70 2.5 2.5 9.1
75 2.7 2.7 9.7
80 2.7 2.7 9.7
85 2.7 2.7 -
90 2.7 2.7 9.7
95 2.9 2.9 -
100 3.1 3.1 10.2
13.8 Conductivity ash methods

The meter can measure the conductivity ash (%) according to the two ICUMSA methods:
13.8.1 Refined sugar (28 g/100 g solution) ICUMSA GS2/3-17

The formula that the instrument uses is:
C1 = conductivity of the sugar solution in μS/cm with cell constant = 1 cm-1

C2 = conductivity of the water used in μS/cm to prepare the sugar solution with cell constant = 1 cm-1
T = temperature in °C between 15 °C and 25 °C
K = cell constant
13.8.2 Raw sugar or melasses (5 g / 100 mL solution) ICUMSA GS 1/3/4/7/8-13

The formula that the instrument uses is:
C1 = conductivity of the sugar solution in μS/cm with cell constant = 1 cm-1

C2 = conductivity of the water used to prepare the sugar solution in μS/cm with cell constant = 1 cm-1
T = temperature in °C between 15 °C and 25 °C
K = cell constant of the used sensor

www.mt.com/phlab
For more information
Mettler-Toledo GmbH
Im Langacher 44
8606 Greifensee, Switzerland
Tel. +41 22 567 53 22
Fax +41 22 567 53 23
www.mt.com/contact
Subject to technical changes.

© Mettler-Toledo GmbH 07/2016
*30325043B*
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Operating Instructions SevenCompact™ Duo S213

SevenCompact™ Duo S213 Table of Contents 1

2 Table of Contents SevenCompact™ Duo S213

SevenCompact™ Duo S213 Introduction​ 3

Attention (no symbol)

Note (no symbol)

Toxic substance Inflammable or explosive substance

2.2 Product specific safety notes

4 Safety Instructions SevenCompact™ Duo S213

Wear a lab coat.

SevenCompact™ Duo S213 Safety Instructions 5

6 Safety Instructions SevenCompact™ Duo S213

1 On/Off key 2 Display

3.2 Rear panel connections

SevenCompact™ Duo S213 Design and Function 7

InLab 742 InLab 742

8 Design and Function SevenCompact™ Duo S213

3.4 Key controls

• Start or end measurement Switch between measurement close-up

Softkeys The function of the softkeys varies from

Move one position to the right Increase value

SevenCompact™ Duo S213 Design and Function 9

Scroll up in the menu Scroll to next page of results

Scroll down in the menu Calculate Calculate the calibration values

Delete Delete selected data Start Start the measurement

Yes Confirm an entry Transfer Transfer selected data

3.6 Alphanumeric keypad

3.6.1 Entering alphanumeric characters

Press 'Read' to confirm

1 Move the cursor position using the , or keys.

10 Design and Function SevenCompact™ Duo S213

3.6.2 Editing values in tables

3.7 Navigating within a menu

3.8 Navigating between menus

3.9 Endpoint types

SevenCompact™ Duo S213 Design and Function 11

12 Design and Function SevenCompact™ Duo S213

4.2 Mounting uPlace™ electrode arm

Assembly of the electrode arm

SevenCompact™ Duo S213 Putting into Operation 13

3 Use the lock screw to attach the meter to the base

4.3 Installing power supply

14 Putting into Operation SevenCompact™ Duo S213

4.4 Connecting sensors

4.5 Switching the instrument on and off

SevenCompact™ Duo S213 Putting into Operation 15

16 Putting into Operation SevenCompact™ Duo S213

SevenCompact™ Duo S213 Configuring the Instrument 17

5.4 Data storage

18 Configuring the Instrument SevenCompact™ Duo S213

5.5 System settings

5.5.2 Time and Date

5.5.3 Access Control

SevenCompact™ Duo S213 Configuring the Instrument 19

5.5.5 Operator mode

5.5.6 Screen settings

20 Configuring the Instrument SevenCompact™ Duo S213

SevenCompact™ Duo S213 Introduction 3