SAFETY DATA SHEET according to Regulation (EC) No.

1907/2006

LOGRAN 75 WG
Version 8
Revision Date 11.11.2009 Print Date 11.11.2009

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

PRODUCT INFORMATION
Product name : LOGRAN 75 WG

Design code : A7492A

Use : Herbicide Dangerous for

the environment
Company : Syngenta Crop Protection AG
Postfach
CH-4002 Basel
Switzerland
Telephone : +41 61 323 11 11
Telefax : +41 61 323 12 12
Emergency tele- : +44 1484 538444
phone
E-mail address : safetydatasheetcoordination@syngenta.com

2. HAZARDS IDENTIFICATION

Very toxic to aquatic life with long lasting effects.

May form flammable dust-air mixture.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components
Chemical Name CAS-No. EC-No. Symbol(s) R-phrase(s) Concentration
(REACH Regis-
tration Number )
triasulfuron 82097-50-5 N R50/53 75 % W/W

sodium dibutyl- 25417-20-3 246-960-6 Xn R20/22 2 % W/W

naphthalenesul- R36/38
phonate R52/53

* Substances for which there are Community workplace exposure limits.

For the full text of the R-phrases mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice : Have the product container, label or Material Safety Data Sheet
with you when calling the Syngenta emergency number, a poison
control center or physician, or going for treatment.

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Inhalation : Move the victim to fresh air.

If breathing is irregular or stopped, administer artificial respiration.
Keep patient warm and at rest.
Call a physician or poison control centre immediately.

Skin contact : Take off all contaminated clothing immediately.

Wash off immediately with plenty of water.
If skin irritation persists, call a physician.
Wash contaminated clothing before re-use.

Eye contact : Rinse immediately with plenty of water, also under the eyelids, for
at least 15 minutes.
Remove contact lenses.
Immediate medical attention is required.

Ingestion : If swallowed, seek medical advice immediately and show this con-
tainer or label.
Do NOT induce vomiting.

Medical advice : There is no specific antidote available.

Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing : Extinguishing media - small fires
media Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide.
Extinguishing media - large fires
Alcohol-resistant foam
or
Water spray

Extinguishing media : Do not use a solid water stream as it may scatter and spread fire.
which shall not be used
for safety reasons
Specific hazards during : As the product contains combustible organic components, fire will
fire fighting produce dense black smoke containing hazardous products of
combustion (see section 10).
Exposure to decomposition products may be a hazard to health.

Special protective equip- : Wear full protective clothing and self-contained breathing appara-
ment for fire-fighters tus.

Further information : Do not allow run-off from fire fighting to enter drains or water
courses.
Cool closed containers exposed to fire with water spray.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Refer to protective measures listed in sections 7 and 8.
Avoid dust formation.

Environmental precau- : Do not flush into surface water or sanitary sewer system.
tions
Methods for cleaning up : Contain spillage, pick up with an electrically protected vacuum
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cleaner or by wet-brushing and transfer to a container for disposal

according to local regulations (see section 13).
Do not create a powder cloud by using a brush or compressed air.
Clean contaminated surface thoroughly.

Additional advice : If the product contaminates rivers and lakes or drains inform re-
spective authorities.

7. HANDLING AND STORAGE

HANDLING
Advice on safe handling : This material is capable of forming flammable dust clouds in air,
which, if ignited, can produce a dust cloud explosion. Flames, hot
surfaces, mechanical sparks and electrostatic discharges can
serve as ignition sources for this material. Electrical equipment
should be compatible with the flammability characteristics of this
material. The flammability characteristics will be made worse if
the material contains traces of flammable solvents or is handled in
the presence of flammable solvents.
This material can become readily charged in most operations.
Avoid contact with skin and eyes.
When using do not eat, drink or smoke.
For personal protection see section 8.

STORAGE
Requirements for storage : Keep containers tightly closed in a dry, cool and well-ventilated
areas and containers place.
Keep out of the reach of children.
Keep away from food, drink and animal feedingstuffs.

Other data : Physically and chemically stable for at least 2 years when stored
in the original unopened sales container at ambient temperatures.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components Exposure limit(s) Type of expo- Source
sure limit
triasulfuron 3 mg/m3 8 h TWA SYNGENTA

ENGINEERING MEASURES
Containment and/or segregation is the most reliable technical protection measure if exposure cannot be
eliminated.
The extent of these protection measures depends on the actual risks in use.
If airborne dust is generated, use local exhaust ventilation controls.
Assess exposure and use any additional measures to keep airborne levels below any relevant exposure
limit.
Where necessary, seek additional occupational hygiene advice.

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PERSONAL PROTECTIVE EQUIPMENT

Protective measures : The use of technical measures should always have priority over
the use of personal protective equipment.
When selecting personal protective equipment, seek appropriate
professional advice.
Personal protective equipment should be certified to appropriate
standards.

Respiratory protection : No personal respiratory protective equipment normally required.

A particulate filter respirator may be necessary until effective tech-
nical measures are installed.

Hand protection : Chemical resistant gloves are not usually required.

Select gloves based on the physical job requirements.

Eye protection : Eye protection is not usually required.

Follow any site specific eye protection policies.

Skin and body protection : No special protective equipment required.

Select skin and body protection based on the physical job re-
quirements.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : solid

Form : granules
Colour : beige to beige brown
pH : 4 - 8 at 1 % w/v
Flammability (solid, gas) : not highly flammable
Minimum ignition tempera- : 550 °C
ture
Dust explosion class : Forms flammable dust clouds.
Minimum ignition energy : 0.1 - 0.3 J
Oxidizing properties : not oxidizing
Explosive properties : Not explosive
Bulk density : 0.50 - 0.70 g/cm3
Miscibility : Miscible
Burning number : 2 at 20 °C
: 2 at 100 °C

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10. STABILITY AND REACTIVITY

Hazardous decomposition : Combustion or thermal decomposition will evolve toxic and irritant
products vapors.

Hazardous reactions : None known.

Hazardous polymerisation does not occur.
Stable under normal conditions.

11. TOXICOLOGICAL INFORMATION

Acute oral toxicity : LD50 Rat, > 5,000 mg/kg

GHS-Classification
None

Acute dermal toxicity : LD50 Rat, > 2,000 mg/kg

Derived from components.
GHS-Classification
None

Skin irritation : Rabbit: Non-irritating

GHS-Classification
None

Eye irritation : Rabbit: Non-irritating

GHS-Classification
None

Sensitisation : guinea pig: Not a skin sensitizer in animal tests.

GHS-Classification
None

Long term toxicity

triasulfuron : Did not show carcinogenic, teratogenic or mutagenic effects in
animal experiments.

12. ECOLOGICAL INFORMATION

ELIMINATION INFORMATION (PERSISTENCE AND DEGRADABILITY)

Stability in water
triasulfuron : Degradation half life: ca. 210 d
Triasulfuron is persistent in water.

Stability in soil
triasulfuron : Degradation half life : 3 - 83 d
Triasulfuron is not persistent in soil.

Mobility
triasulfuron : Triasulfuron has medium mobility in soil.

Bioaccumulation
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triasulfuron : Triasulfuron has low potential for bioaccumulation.

ECOTOXICITY EFFECTS

Toxicity to fish : LC50 Oncorhynchus mykiss (rainbow trout), > 1,000 mg/l , 96 h

: LC50 Cyprinus carpio (Carp), > 1,000 mg/l , 96 h

Toxicity to daphnia and : EC50 Daphnia magna (Water flea), > 100 mg/l , 48 h
other aquatic inverte- Derived from components.
brates.

Toxicity to algae : EC50 Pseudokirchneriella subcapitata (green algae), ca. 0.04

mg/l , 12 d
Derived from components.

FURTHER INFORMATION ON ECOLOGY

Additional ecological : GHS-Classification
information Category 1

13. DISPOSAL CONSIDERATIONS

Product : Do not contaminate ponds, waterways or ditches with chemical or

used container.
Do not dispose of waste into sewer.
Where possible recycling is preferred to disposal or incineration.
If recycling is not practicable, dispose of in compliance with local
regulations.

Contaminated packaging : Empty remaining contents.

Triple rinse containers.
Empty containers should be taken to an approved waste handling
site for recycling or disposal.
Do not re-use empty containers.

14. TRANSPORT INFORMATION

Land transport
ADR/RID:
UN-Number: 3077
Class: 9
Labels: 9
Packaging group: III
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(TRIASULFURON)

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Environmentally hazardous: Environmentally hazardous

Sea transport
IMDG:
UN-Number: 3077
Class: 9
Labels: 9
Packaging group: III
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(TRIASULFURON)
Marine pollutant : Marine pollutant

Air transport
IATA-DGR:
UN/ID No.: UN 3077
Class: 9
Labels: 9
Packaging group: III
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(TRIASULFURON)

Further information for Maximum safe package size: 3 m3

transport:

15. REGULATORY INFORMATION

Labelling according to EC Directives

Symbol(s) : N Dangerous for the environment

R-phrase(s) : R50/53 Very toxic to aquatic organisms, may cause

long-term adverse effects in the aquatic envi-
ronment.

S-phrase(s) : S2 Keep out of the reach of children.

S13 Keep away from food, drink and animal fee-
dingstuffs.
S20/21 When using do not eat, drink or smoke.
S35 This material and its container must be dis-
posed of in a safe way.
S57 Use appropriate container to avoid environ-
mental contamination.

Note : The product is classified and labelled in accordance with Directive

1999/45/EC.

Special labelling of cer- : To avoid risks to man and the environment, comply with the in-
tain mixtures structions for use.

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GHS-Labelling

Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

Pictogram

Signal word : Warning

Hazard statements : H410 Very toxic to aquatic life with long lasting ef-
fects.

Precautionary statements : P102 Keep out of reach of children.

P270 Do no eat, drink or smoke when using this
product.
P391 Collect spillage.
P501 Dispose of contents/container to an approved
waste disposal plant.

Remarks : Classified using all GHS hazard classes and categories. Where
the GHS contains options, the most conservative option has been
chosen. Regional or national implementations of GHS may not
implement all hazard classes and categories.

Hazardous components which must be listed on the label:

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16. OTHER INFORMATION

Further information
Text of R-phrases mentioned in Section 3:

R20/22 Harmful by inhalation and if swallowed.

R36/38 Irritating to eyes and skin.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and
belief at the date of its publication. The information given is designed only as a guidance for safe handling,
use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid
for such material used in combination with any other materials or in any process, unless specified in the
text.
Changes since the last version are highlighted in the margin. This version replaces all previous versions.
Product names are a trademark or registered trademark of a Syngenta Group Company.

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