SAFETY DATA SHEET

ZN-50

Version Revision Date: SDS Number: Date of last issue: 10/01/2018

8.2 10/10/2018 114857-00018 Date of first issue: 05/12/2015

SECTION 1. IDENTIFICATION

Product name : ZN-50

SDS-Identcode : 032G

Manufacturer or supplier's details

Company name of supplier : Bestolife Corporation
Address : 2777 N. Stemmons Frwy Ste 1800
Dallas TX 75207,
Telephone : 855-243-9164/972-865-8961
Telefax : 214-631-3047
Emergency telephone : CHEMTREC U.S.: 800-424-9300, International 703-527-3887
(24-hours/7 days)
E-mail address : www.bestolife.com
Recommended use of the chemical and restrictions on use
Recommended use : Industrial use
Thread Compound (Pipe Dope) and Jacking grease for use in
Offshore industries
Mining, (without offshore industries)
Restrictions on use : Do not use on oxygen lines or in oxygen enriched atmos-
pheres.

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with 29 CFR 1910.1200

Eye irritation : Category 2A

Reproductive toxicity : Category 1A

Effects on or via lactation

GHS label elements

Hazard pictograms :

Signal Word : Danger

Hazard Statements : H319 Causes serious eye irritation.

H360FD May damage fertility. May damage the unborn child.
H362 May cause harm to breast-fed children.

Precautionary Statements :
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P263 Avoid contact during pregnancy/ while nursing.

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SAFETY DATA SHEET

ZN-50

Version Revision Date: SDS Number: Date of last issue: 10/01/2018

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P264 Wash skin thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/ atten-
tion.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Components
Chemical name CAS-No. Concentration (% w/w)
Distillates (petroleum), hydrotreated 64742-52-5 >= 30 - < 50
heavy naphthenic
Talc 14807-96-6 >= 5 - < 10
Zinc oxide 1314-13-2 >= 1 - < 5
Calcium oxide 1305-78-8 >= 1 - < 5
12-Hydroxy lithium stearate 7620-77-1 >= 1 - < 5
Dolomite 16389-88-1 >= 1 - < 5
Calcium bis(di C8-C10, branched, C9 57855-77-3 >= 1 - < 5
rich, alkylnaphthalenesulphonate)
Quartz 14808-60-7 >= 0.1 - < 1
Lead 7439-92-1 >= 0.1 - < 0.5
Actual concentration is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

General advice : In the case of accident or if you feel unwell, seek medical
advice immediately.
When symptoms persist or in all cases of doubt seek medical
advice.

If inhaled : If inhaled, remove to fresh air.

Get medical attention.
In case of skin contact : In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes.

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SAFETY DATA SHEET

ZN-50

Version Revision Date: SDS Number: Date of last issue: 10/01/2018

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Get medical attention.

Wash clothing before reuse.
Thoroughly clean shoes before reuse.
In case of eye contact : In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Get medical attention.
If swallowed : If swallowed, DO NOT induce vomiting.
Get medical attention.
Rinse mouth thoroughly with water.
Most important symptoms : Causes serious eye irritation.
and effects, both acute and May damage fertility. May damage the unborn child.
delayed May cause harm to breast-fed children.
Protection of first-aiders : First Aid responders should pay attention to self-protection,
and use the recommended personal protective equipment
when the potential for exposure exists.
Notes to physician : Treat symptomatically and supportively.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Water spray

Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing : None known.
media
Specific hazards during fire : Exposure to combustion products may be a hazard to health.
fighting
Hazardous combustion prod- : Carbon oxides
ucts Metal oxides

Specific extinguishing meth- : Use extinguishing measures that are appropriate to local cir-
ods cumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.
Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters Use personal protective equipment.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Follow safe handling advice and personal protective
gency procedures equipment recommendations.

Environmental precautions : Discharge into the environment must be avoided.

Prevent further leakage or spillage if safe to do so.
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages
cannot be contained.

Methods and materials for : Sweep up or vacuum up spillage and collect in suitable
containment and cleaning up container for disposal.
Local or national regulations may apply to releases and

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SAFETY DATA SHEET

ZN-50

Version Revision Date: SDS Number: Date of last issue: 10/01/2018

8.2 10/10/2018 114857-00018 Date of first issue: 05/12/2015

disposal of this material, as well as those materials and items

employed in the cleanup of releases. You will need to
determine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding
certain local or national requirements.

SECTION 7. HANDLING AND STORAGE

Technical measures : See Engineering measures under EXPOSURE

CONTROLS/PERSONAL PROTECTION section.
Advice on safe handling : Do not get on skin or clothing.
Do not swallow.
Do not get in eyes.
Handle in accordance with good industrial hygiene and safety
practice, based on the results of the workplace exposure
assessment
Keep container tightly closed.
Take care to prevent spills, waste and minimize release to the
environment.
Conditions for safe storage : Keep in properly labeled containers.
Store locked up.
Keep tightly closed.
Store in accordance with the particular national regulations.
Materials to avoid : Do not store with the following product types:
Strong oxidizing agents
Organic peroxides
Explosives
Gases

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
Distillates (petroleum), 64742-52-5 TWA (Mist) 5 mg/m³ OSHA Z-1
hydrotreated heavy naphthenic
TWA (Inhal- 5 mg/m³ ACGIH
able fraction)
TWA (Mist) 5 mg/m³ NIOSH REL
ST (Mist) 10 mg/m³ NIOSH REL
Talc 14807-96-6 TWA (Dust) 20 Million OSHA Z-3
particles per cubic
foot
TWA (Res- 2 mg/m³ NIOSH REL
pirable)
TWA (Res- 2 mg/m³ ACGIH
pirable frac-
tion)
Zinc oxide 1314-13-2 TWA (Res- 2 mg/m³ ACGIH
pirable frac-
tion)

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SAFETY DATA SHEET

ZN-50

Version Revision Date: SDS Number: Date of last issue: 10/01/2018

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STEL (Res- 10 mg/m³ ACGIH

pirable frac-
tion)
TWA (Dust) 5 mg/m³ NIOSH REL
TWA 5 mg/m³ NIOSH REL
(Fumes)
ST (Fumes) 10 mg/m³ NIOSH REL
C (Dust) 15 mg/m³ NIOSH REL
TWA (total 15 mg/m³ OSHA Z-1
dust)
TWA (respir- 5 mg/m³ OSHA Z-1
able fraction)
TWA 5 mg/m³ OSHA Z-1
(Fumes)
Calcium oxide 1305-78-8 TWA 2 mg/m³ ACGIH
TWA 2 mg/m³ NIOSH REL
TWA 5 mg/m³ OSHA Z-1
12-Hydroxy lithium stearate 7620-77-1 TWA (Inhal- 10 mg/m³ ACGIH
able fraction)
TWA (Res- 3 mg/m³ ACGIH
pirable frac-
tion)
Dolomite 16389-88-1 TWA (Res- 5 mg/m³ NIOSH REL
pirable) (Calcium car-
bonate)
TWA (total) 10 mg/m³ NIOSH REL
(Calcium car-
bonate)
Quartz 14808-60-7 TWA (Res- 0.05 mg/m³ OSHA Z-1
pirable dust)
TWA (respir- 10 mg/m3 OSHA Z-3
able) / %SiO2+2
TWA (respir- 250 mppcf OSHA Z-3
able) / %SiO2+5
TWA (Res- 0.025 mg/m³ ACGIH
pirable frac- (Silica)
tion)
TWA (Res- 0.05 mg/m³ NIOSH REL
pirable dust) (Silica)
Lead 7439-92-1 TWA 0.05 mg/m³ NIOSH REL
(Lead)
TWA 0.05 mg/m³ ACGIH
(Lead)
PEL 0.05 mg/m³ OSHA CARC
(Lead)
These substance(s) are inextricably bound in the product and therefore do not contribute
to a dust inhalation hazard.
Quartz

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SAFETY DATA SHEET

ZN-50

Version Revision Date: SDS Number: Date of last issue: 10/01/2018

8.2 10/10/2018 114857-00018 Date of first issue: 05/12/2015

Biological occupational exposure limits

Components CAS-No. Control Biological Sam- Permissible Basis
parameters specimen pling concentra-
time tion
Lead 7439-92-1 Lead In blood Not criti- 200 µg/l ACGIH
(Lead) cal BEI
Engineering measures : Minimize workplace exposure concentrations.
Dust formation may be relevant in the processing of this
product. In addition to substance-specific OELs, general
limitations of concentrations of particulates in the air at
workplaces have to be considered in workplace risk
assessment. Relevant limits include: OSHA PEL for
Particulates Not Otherwise Regulated of 15 mg/m3 - total
dust, 5 mg/m3 - respirable fraction; and ACGIH TWA for
Particles (insoluble or poorly soluble) Not Otherwise
Specified of 3 mg/m3 - respirable particles, 10 mg/m3 -
inhalable particles.
Personal protective equipment
Respiratory protection : General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are
unknown, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any
hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled
release, exposure levels are unknown, or any other
circumstance where air purifying respirators may not provide
adequate protection.
Hand protection

Material : Chemical-resistant gloves

Remarks : Choose gloves to protect hands against chemicals depending

on the concentration specific to place of work. Breakthrough
time is not determined for the product. Change gloves often!
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective
gloves with the glove manufacturer. Wash hands before
breaks and at the end of workday.
Eye protection : Wear the following personal protective equipment:
Safety goggles
Skin and body protection : Select appropriate protective clothing based on chemical
resistance data and an assessment of the local exposure
potential.
Skin contact must be avoided by using impervious protective
clothing (gloves, aprons, boots, etc).
Hygiene measures : Ensure that eye flushing systems and safety showers are
located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.

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SAFETY DATA SHEET

ZN-50

Version Revision Date: SDS Number: Date of last issue: 10/01/2018

8.2 10/10/2018 114857-00018 Date of first issue: 05/12/2015

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Viscous semi-solid

Color : gray
Odor : Petroleum
Odor Threshold : No data available

pH : Not applicable (not an aqueous solution)

Melting point/freezing point : No data available

Initial boiling point and boiling : No data available

range
Flash point : >= 486 °F / >= 252 °C

Method: ASTM D 92, Cleveland open cup

Evaporation rate : Not applicable

Flammability (solid, gas) : Not classified as a flammability hazard

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit / Lower : No data available

flammability limit

Vapor pressure : Not applicable

Relative vapor density : Not applicable

Relative density : 1.8

Solubility(ies)
Water solubility : negligible

Partition coefficient: n- : Not applicable

octanol/water
Autoignition temperature : No data available

Decomposition temperature : No data available

Viscosity
Viscosity, kinematic : Not applicable

Flow time : No data available

Explosive properties : Not explosive

Oxidizing properties : The substance or mixture is not classified as oxidizing.

Molecular weight : No data available

Particle size : No data available

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SAFETY DATA SHEET

ZN-50

Version Revision Date: SDS Number: Date of last issue: 10/01/2018

8.2 10/10/2018 114857-00018 Date of first issue: 05/12/2015

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Not classified as a reactivity hazard.

Chemical stability : Stable under normal conditions.
Possibility of hazardous reac- : Can react with strong oxidizing agents.
tions
Conditions to avoid : None known.
Incompatible materials : Oxidizing agents
Hazardous decomposition : No hazardous decomposition products are known.
products

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Skin contact
Ingestion
Eye contact
Acute toxicity
Not classified based on available information.
Components:

Distillates (petroleum), hydrotreated heavy naphthenic:

Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Method: OECD Test Guideline 401
Remarks: Based on data from similar materials

Acute inhalation toxicity : LC50 (Rat): > 5.53 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
Assessment: The substance or mixture has no acute inhala-
tion toxicity
Remarks: Based on data from similar materials

Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg

Method: OECD Test Guideline 402
Remarks: Based on data from similar materials

Talc:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Remarks: Based on data from similar materials

Zinc oxide:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg

Acute inhalation toxicity : LC50 (Rat): > 5.7 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute inhala-
tion toxicity

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ZN-50

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Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg

Method: OECD Test Guideline 402
Assessment: The substance or mixture has no acute dermal
toxicity

Calcium oxide:
Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg
Method: OECD Test Guideline 425

Acute inhalation toxicity : (Rat): > 5 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 436
Remarks: Based on data from similar materials

Acute dermal toxicity : LD50 (Rabbit): > 2,500 mg/kg

Method: OECD Test Guideline 402
Assessment: The substance or mixture has no acute dermal
toxicity
Remarks: Based on data from similar materials

12-Hydroxy lithium stearate:

Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg
Assessment: The substance or mixture has no acute oral tox-
icity

Dolomite:
Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg
Method: OECD Test Guideline 420
Assessment: The substance or mixture has no acute oral tox-
icity
Remarks: Based on data from similar materials

Acute inhalation toxicity : LC50 (Rat): > 3 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute inhala-
tion toxicity
Remarks: Based on data from similar materials

Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg

Method: OECD Test Guideline 402
Assessment: The substance or mixture has no acute dermal
toxicity
Remarks: Based on data from similar materials

Calcium bis(di C8-C10, branched, C9 rich, alkylnaphthalenesulphonate):

Acute oral toxicity : LD50 (Rat): > 2,500 mg/kg
Remarks: Based on data from similar materials

Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg

Remarks: Based on data from similar materials

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ZN-50

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Quartz:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg

Lead:
Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg
Remarks: Based on data from similar materials

Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg

Remarks: Based on data from similar materials

Skin corrosion/irritation
Not classified based on available information.
Components:

Distillates (petroleum), hydrotreated heavy naphthenic:

Species : Rabbit
Result : No skin irritation
Remarks : Based on data from similar materials

Talc:
Species : Rabbit
Result : No skin irritation

Zinc oxide:
Species : Rabbit
Method : OECD Test Guideline 404
Result : No skin irritation

Calcium oxide:
Species : Rabbit
Method : OECD Test Guideline 404
Result : Skin irritation
Remarks : Based on data from similar materials

12-Hydroxy lithium stearate:

Species : Rabbit
Result : No skin irritation
Remarks : Based on data from similar materials

Dolomite:
Species : Rabbit
Method : OECD Test Guideline 404
Result : No skin irritation
Remarks : Based on data from similar materials

Calcium bis(di C8-C10, branched, C9 rich, alkylnaphthalenesulphonate):

Species : Rabbit

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ZN-50

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Result : Skin irritation

Remarks : Based on data from similar materials

Lead:
Species : Rabbit
Method : OECD Test Guideline 404
Result : No skin irritation
Remarks : Based on data from similar materials

Serious eye damage/eye irritation

Causes serious eye irritation.
Components:

Distillates (petroleum), hydrotreated heavy naphthenic:

Species : Rabbit
Result : No eye irritation
Remarks : Based on data from similar materials

Talc:
Species : Rabbit
Result : No eye irritation

Zinc oxide:
Species : Rabbit
Result : No eye irritation
Method : OECD Test Guideline 405

Calcium oxide:
Species : Rabbit
Result : Irreversible effects on the eye
Method : OECD Test Guideline 405

12-Hydroxy lithium stearate:

Species : Rabbit
Result : No eye irritation
Remarks : Based on data from similar materials

Dolomite:
Species : Rabbit
Result : No eye irritation
Method : OECD Test Guideline 405
Remarks : Based on data from similar materials

Calcium bis(di C8-C10, branched, C9 rich, alkylnaphthalenesulphonate):

Species : Rabbit
Result : Irritation to eyes, reversing within 21 days
Remarks : Based on data from similar materials

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Lead:
Species : Rabbit
Result : No eye irritation
Method : OECD Test Guideline 405
Remarks : Based on data from similar materials

Respiratory or skin sensitization

Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Components:

Distillates (petroleum), hydrotreated heavy naphthenic:

Test Type : Buehler Test
Routes of exposure : Skin contact
Species : Guinea pig
Result : negative
Remarks : Based on data from similar materials

Talc:
Routes of exposure : Skin contact
Species : Humans
Result : negative

Zinc oxide:
Test Type : Maximization Test
Routes of exposure : Skin contact
Species : Guinea pig
Method : OECD Test Guideline 406
Result : negative

Calcium oxide:
Test Type : Local lymph node assay (LLNA)
Routes of exposure : Skin contact
Species : Mouse
Method : OECD Test Guideline 429
Result : negative
Remarks : Based on data from similar materials

12-Hydroxy lithium stearate:

Test Type : Local lymph node assay (LLNA)
Routes of exposure : Skin contact
Species : Mouse
Method : OECD Test Guideline 429
Result : negative

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ZN-50

Version Revision Date: SDS Number: Date of last issue: 10/01/2018

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Dolomite:
Test Type : Local lymph node assay (LLNA)
Routes of exposure : Skin contact
Species : Mouse
Method : OECD Test Guideline 429
Result : negative
Remarks : Based on data from similar materials

Calcium bis(di C8-C10, branched, C9 rich, alkylnaphthalenesulphonate):

Test Type : Human repeat insult patch test (HRIPT)
Routes of exposure : Skin contact
Result : negative

Lead:
Test Type : Maximization Test
Routes of exposure : Skin contact
Species : Guinea pig
Method : OECD Test Guideline 406
Result : negative
Remarks : Based on data from similar materials

Germ cell mutagenicity

Not classified based on available information.
Components:

Distillates (petroleum), hydrotreated heavy naphthenic:

Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES)
Method: OECD Test Guideline 471
Result: negative

Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse
Application Route: Intraperitoneal injection
Method: OECD Test Guideline 474
Result: negative
Remarks: Based on data from similar materials

Talc:
Genotoxicity in vitro : Test Type: DNA damage and repair, unscheduled DNA syn-
thesis in mammalian cells (in vitro)
Result: negative

Genotoxicity in vivo : Test Type: Chromosome aberration test in vitro

Species: Rat
Application Route: Ingestion
Result: negative

Zinc oxide:
Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES)

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Result: positive

Test Type: Bacterial reverse mutation assay (AMES)

Method: OECD Test Guideline 471
Result: negative

Test Type: In vitro mammalian cell gene mutation test

Method: OECD Test Guideline 476
Result: equivocal

Test Type: Chromosome aberration test in vitro

Method: OECD Test Guideline 473
Result: negative

Test Type: Chromosome aberration test in vitro

Result: positive

Test Type: in vitro micronucleus test

Result: positive

Test Type: DNA damage and repair, unscheduled DNA syn-

thesis in mammalian cells (in vitro)
Result: positive

Test Type: In vitro sister chromatid exchange assay in mam-

malian cells
Result: equivocal

Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Rat
Application Route: inhalation (dust/mist/fume)
Method: OECD Test Guideline 474
Result: negative

Test Type: Mutagenicity (in vivo mammalian bone-marrow

cytogenetic test, chromosomal analysis)
Species: Rat
Application Route: inhalation (dust/mist/fume)
Result: positive

Test Type: Mammalian erythrocyte micronucleus test (in vivo

cytogenetic assay)
Species: Mouse
Application Route: Intraperitoneal injection
Method: OECD Test Guideline 474
Result: negative

Germ cell mutagenicity - : Weight of evidence does not support classification as a germ
Assessment cell mutagen.

Calcium oxide:
Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES)
Method: OECD Test Guideline 471

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Result: negative

Test Type: Chromosome aberration test in vitro

Method: OECD Test Guideline 473
Result: negative
Remarks: Based on data from similar materials

Test Type: In vitro mammalian cell gene mutation test

Method: OECD Test Guideline 476
Result: negative
Remarks: Based on data from similar materials

Dolomite:
Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES)
Method: OECD Test Guideline 471
Result: negative
Remarks: Based on data from similar materials

Calcium bis(di C8-C10, branched, C9 rich, alkylnaphthalenesulphonate):

Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES)
Method: OECD Test Guideline 471
Result: negative
Remarks: Based on data from similar materials

Lead:
Genotoxicity in vitro : Test Type: In vitro sister chromatid exchange assay in mam-
malian cells
Result: negative
Remarks: Based on data from similar materials

Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Rat
Application Route: Ingestion
Result: positive
Remarks: Based on data from similar materials

Carcinogenicity
Not classified based on available information.
Product:
Carcinogenicity - Assess- : Petroleum distillates have been classified as not carcinogenic
ment based on DMSO extract content < 3% (Regulation (EC)
1272/2008, Annex VI, Part 3, Note L).

Weight of evidence does not support classification as a car-

cinogen

Components:

Distillates (petroleum), hydrotreated heavy naphthenic:

Species : Mouse

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Application Route : Skin contact

Exposure time : 78 weeks
Method : OECD Test Guideline 451
Result : negative

Talc:
Species : Mouse
Application Route : inhalation (dust/mist/fume)
Exposure time : 2 Years
Result : negative

Zinc oxide:
Species : Mouse
Application Route : Ingestion
Exposure time : 1 Years
Result : negative
Remarks : Based on data from similar materials

Calcium oxide:
Species : Rat
Application Route : Ingestion
Exposure time : 104 weeks
Result : negative
Remarks : Based on data from similar materials

Quartz:
Species : Humans
Application Route : inhalation (dust/mist/fume)
Result : positive
Remarks : IARC: (International Agency for Research on Cancer)
These substance(s) are inextricably bound in the product and
therefore do not contribute to a dust inhalation hazard.

Carcinogenicity - Assess- : Positive evidence from human epidemiological studies (inhala-

ment tion)

Lead:
Species : Rat
Application Route : Ingestion
Exposure time : 2 Years
Result : positive
Remarks : Based on data from similar materials

Carcinogenicity - Assess- : Limited evidence of carcinogenicity in animal studies

ment
IARC Group 1: Carcinogenic to humans
Quartz 14808-60-7
(Silica dust, crystalline)
Group 2B: Possibly carcinogenic to humans
Lead 7439-92-1

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OSHA OSHA specifically regulated carcinogen

Lead 7439-92-1
(Lead and inorganic lead compounds)

NTP Reasonably anticipated to be a human carcinogen

Lead 7439-92-1
Known to be human carcinogen
Quartz 14808-60-7
(Silica, Crystalline (Respirable Size))

Reproductive toxicity
May damage fertility. May damage the unborn child.
May cause harm to breast-fed children.
Components:

Talc:
Effects on fetal development : Test Type: Embryo-fetal development
Species: Rat
Application Route: Ingestion
Result: negative

Zinc oxide:
Effects on fertility : Test Type: Two-generation reproduction toxicity study
Species: Rat
Application Route: Ingestion
Result: negative
Remarks: Based on data from similar materials

Effects on fetal development : Test Type: Embryo-fetal development

Species: Rat
Application Route: inhalation (dust/mist/fume)
Method: OECD Test Guideline 414
Result: negative
Remarks: Based on data from similar materials

Calcium oxide:
Effects on fertility : Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 422
Result: negative
Remarks: Based on data from similar materials

Effects on fetal development : Test Type: Embryo-fetal development

Species: Mouse
Application Route: Ingestion
Method: OECD Test Guideline 414
Result: negative

Dolomite:

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Effects on fertility : Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 422
Result: negative
Remarks: Based on data from similar materials

Effects on fetal development : Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 422
Result: negative
Remarks: Based on data from similar materials

Lead:
Effects on fertility : Test Type: Two-generation reproduction toxicity study
Species: Mouse
Application Route: Ingestion
Result: positive
Remarks: Based on data from similar materials

Effects on fetal development : Test Type: Embryo-fetal development

Species: Rat
Application Route: Ingestion
Result: positive
Remarks: Based on data from similar materials

Reproductive toxicity - As- : Positive evidence of adverse effects on sexual function and
sessment fertility from human epidemiological studies., Positive
evidence of adverse effects on development from human
epidemiological studies., Studies indicating a hazard to babies
during the lactation period

STOT-single exposure
Not classified based on available information.
Components:

Calcium oxide:
Assessment : May cause respiratory irritation.

STOT-repeated exposure
Not classified based on available information.
Components:

Zinc oxide:
Assessment : No significant health effects observed in animals at concentra-
tions of 0.2 mg/l/6h/d or less.

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12-Hydroxy lithium stearate:

Routes of exposure : Ingestion
Assessment : No significant health effects observed in animals at concentra-
tions of 100 mg/kg bw or less.

Quartz:
Routes of exposure : inhalation (dust/mist/fume)
Target Organs : Lungs
Assessment : Shown to produce significant health effects in animals at con-
centrations of 0.02 mg/l/6h/d or less.

Lead:
Target Organs : Kidney, Central nervous system, Blood
Assessment : Causes damage to organs through prolonged or repeated
exposure.

Repeated dose toxicity

Components:

Distillates (petroleum), hydrotreated heavy naphthenic:

Species : Rat
NOAEL : > 0.98 mg/l
Application Route : inhalation (dust/mist/fume)
Exposure time : 28 Days
Remarks : Based on data from similar materials

Zinc oxide:
Species : Rat, male
NOAEL : 0.0015 mg/l
Application Route : inhalation (dust/mist/fume)
Exposure time : 3 Months
Method : OECD Test Guideline 413

Calcium oxide:

Species : Rat
NOAEL : >= 0.399 mg/l
Application Route : inhalation (dust/mist/fume)
Exposure time : 90 Days
Method : OECD Test Guideline 413

12-Hydroxy lithium stearate:

Species : Rat
NOAEL : > 88 mg/kg
Application Route : Ingestion
Exposure time : 90 Days

Dolomite:
Species : Mouse

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NOAEL : 1,300 mg/kg

Application Route : Ingestion
Exposure time : 28 Days
Remarks : Based on data from similar materials

Quartz:
Species : Humans
LOAEL : 0.053 mg/m³
Application Route : inhalation (dust/mist/fume)
Remarks : These substance(s) are inextricably bound in the product and
therefore do not contribute to a dust inhalation hazard.

Lead:
Species : Rat
NOAEL : 0.0015 mg/kg
LOAEL : 0.005 mg/kg
Application Route : Ingestion
Exposure time : 6 - 12 Months
Remarks : Based on data from similar materials

Aspiration toxicity
Not classified based on available information.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:

Distillates (petroleum), hydrotreated heavy naphthenic:

Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 100 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Remarks: Based on data from similar materials

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l
aquatic invertebrates Exposure time: 48 h
Remarks: Based on data from similar materials

Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): > 100

mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201
Remarks: Based on data from similar materials

Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 10 mg/l
aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity) Remarks: Based on data from similar materials

Toxicity to microorganisms : NOEC: > 1.93 mg/l

Exposure time: 10 min
Remarks: Based on data from similar materials

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Talc:
Toxicity to fish : LC50 (Brachydanio rerio (zebrafish)): > 100,000 mg/l
Exposure time: 24 h

Zinc oxide:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 0.1 - 1 mg/l
Exposure time: 96 h
Remarks: Based on data from similar materials

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 0.01 - 0.1 mg/l
aquatic invertebrates Exposure time: 48 h
Remarks: Based on data from similar materials

Toxicity to algae : EC50 (Selenastrum capricornutum (green algae)): > 0.1 - 1

mg/l
Exposure time: 96 h
Remarks: Based on data from similar materials

NOEC (Selenastrum capricornutum (green algae)): > 0.001 -

0.01 mg/l
Exposure time: 72 h
Remarks: Based on data from similar materials

Toxicity to fish (Chronic tox- : NOEC (Oncorhynchus mykiss (rainbow trout)): > 0.01 - 0.1
icity) mg/l
Exposure time: 25 d
Remarks: Based on data from similar materials

Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): > 0.01 - 0.1 mg/l
aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity) Remarks: Based on data from similar materials

Calcium oxide:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Remarks: Based on data from similar materials

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 96 h
Method: OECD Test Guideline 202
Remarks: Based on data from similar materials

Toxicity to algae : ErC50 (Pseudokirchneriella subcapitata (green algae)): > 100

mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201
Remarks: Based on data from similar materials

EC10 (Pseudokirchneriella subcapitata (green algae)): > 1

mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

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Remarks: Based on data from similar materials

Toxicity to daphnia and other : NOEC (Crangon crangon (shrimp)): > 1 mg/l
aquatic invertebrates (Chron- Exposure time: 14 d
ic toxicity) Remarks: Based on data from similar materials

Toxicity to microorganisms : EC50: > 100 mg/l

Exposure time: 3 h
Method: OECD Test Guideline 209
Remarks: Based on data from similar materials

12-Hydroxy lithium stearate:

Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203

Toxicity to daphnia and other : EL50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h
Method: OECD Test Guideline 202

Toxicity to algae : NOELR (Pseudokirchneriella subcapitata (green algae)): >

100 mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

Dolomite:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 16.6 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Remarks: No toxicity at the limit of solubility.
Based on data from similar materials

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 16.6 mg/l
aquatic invertebrates Exposure time: 48 h
Method: OECD Test Guideline 202
Remarks: No toxicity at the limit of solubility.
Based on data from similar materials

Toxicity to algae : NOEC (Desmodesmus subspicatus (green algae)): 14 mg/l

Exposure time: 72 h
Method: OECD Test Guideline 201
Remarks: Based on data from similar materials

Calcium bis(di C8-C10, branched, C9 rich, alkylnaphthalenesulphonate):

Toxicity to fish : LC50 (Cyprinus carpio (Carp)): > 100 mg/l
Exposure time: 96 h
Test substance: Water Accommodated Fraction
Method: OECD Test Guideline 203
Remarks: Based on data from similar materials

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h
Test substance: Water Accommodated Fraction

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Method: OECD Test Guideline 202

Remarks: Based on data from similar materials

Toxicity to microorganisms : EC10: 110 mg/l

Exposure time: 3 h
Method: OECD Test Guideline 209
Remarks: Based on data from similar materials

Quartz:

Ecotoxicology Assessment
Acute aquatic toxicity : No toxicity at the limit of solubility.

Chronic aquatic toxicity : No toxicity at the limit of solubility.

Lead:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.107 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Ceriodaphnia dubia (water flea)): 0.029 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae : ErC50 (Pseudokirchneriella subcapitata (green algae)): 0.025

mg/l
Exposure time: 72 h

EC10 (Pseudokirchneriella subcapitata (green algae)): 6.1

µg/l
Exposure time: 72 h

Toxicity to fish (Chronic tox- : EC10 (Pimephales promelas (fathead minnow)): 20 µg/l
icity) Exposure time: 30 d

Toxicity to daphnia and other : EC10 (Ceriodaphnia dubia (water flea)): 1.7 µg/l
aquatic invertebrates (Chron- Exposure time: 7 d
ic toxicity)
Persistence and degradability

Components:

Distillates (petroleum), hydrotreated heavy naphthenic:

Biodegradability : Result: Not readily biodegradable.
Biodegradation: 2 - 4 %
Exposure time: 28 d
Method: OECD Test Guideline 301B

12-Hydroxy lithium stearate:

Biodegradability : Result: Readily biodegradable.
Biodegradation: 78 %
Exposure time: 28 d
Method: OECD Test Guideline 301C

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Calcium bis(di C8-C10, branched, C9 rich, alkylnaphthalenesulphonate):

Biodegradability : Result: Not readily biodegradable.
Biodegradation: 16 %
Exposure time: 28 d
Method: OECD Test Guideline 301B
Remarks: Based on data from similar materials

Bioaccumulative potential

Components:

Zinc oxide:
Bioaccumulation : Species: Oncorhynchus mykiss (rainbow trout)
Bioconcentration factor (BCF): 78 - 2,060

Mobility in soil
No data available
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Dispose of in accordance with local regulations.
Contaminated packaging : Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Empty containers retain residue and can be dangerous.
Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose such containers to heat, flame, sparks, or other
sources of ignition. They may explode and cause injury and/or
death.
If not otherwise specified: Dispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

International Regulations

UNRTDG
UN number : UN 3077
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(Zinc, Zinc oxide)
Class : 9
Packing group : III
Labels : 9
IATA-DGR
UN/ID No. : UN 3077
Proper shipping name : Environmentally hazardous substance, solid, n.o.s.
(Zinc, Zinc oxide)
Class : 9
Packing group : III
Labels : Miscellaneous

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Packing instruction (cargo : 956

aircraft)
Packing instruction (passen- : 956
ger aircraft)
Environmentally hazardous : yes
IMDG-Code
UN number : UN 3077
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(Zinc, Zinc oxide)
Class : 9
Packing group : III
Labels : 9
EmS Code : F-A, S-F
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation

49 CFR
UN/ID/NA number : UN 3077
Proper shipping name : Environmentally hazardous substance, solid, n.o.s.
(Zinc, Zinc oxide)
Class : 9
Packing group : III
Labels : CLASS 9
ERG Code : 171
Marine pollutant : yes(Zinc, Zinc oxide)
Remarks : Above applies only to containers over 119 gallons or 450
liters.
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

Components CAS-No. Component RQ Calculated product RQ
(lbs) (lbs)
Zinc 7440-66-6 1000 2000
Lead 7439-92-1 10 10000
Cadmium 7440-43-9 10 28571
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 302 Extremely Hazardous Substances Threshold Planning Quantity

This material does not contain any components with a section 302 EHS TPQ.

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SARA 311/312 Hazards : Serious eye damage or eye irritation

Reproductive toxicity

SARA 313 : The following components are subject to reporting levels

established by SARA Title III, Section 313:

Zinc 7440-66-6 >= 50 - < 70 %

Zinc oxide 1314-13-2 >= 1 - < 5 %

Lead 7439-92-1 >= 0.1 - < 1 %

US State Regulations

Pennsylvania Right To Know

Zinc 7440-66-6
Distillates (petroleum), hydrotreated heavy naphthenic 64742-52-5
Talc 14807-96-6
Zinc oxide 1314-13-2
Calcium oxide 1305-78-8
Lead 7439-92-1
Cadmium 7440-43-9
Copper metal powder 7440-50-8
California Prop. 65
WARNING: This product can expose you to chemicals including Quartz, Lead, Cadmium, which
is/are known to the State of California to cause cancer, and Lead, Cadmium, which is/are known
to the State of California to cause birth defects or other reproductive harm. For more information
go to www.P65Warnings.ca.gov.
California List of Hazardous Substances
Zinc 7440-66-6
Distillates (petroleum), hydrotreated heavy naphthenic 64742-52-5
Talc 14807-96-6
Zinc oxide 1314-13-2
Calcium oxide 1305-78-8
California Permissible Exposure Limits for Chemical Contaminants
Distillates (petroleum), hydrotreated heavy naphthenic 64742-52-5
Talc 14807-96-6
Zinc oxide 1314-13-2
Calcium oxide 1305-78-8
California Regulated Carcinogens
Quartz 14808-60-7
Lead 7439-92-1
The ingredients of this product are reported in the following inventories:
DSL : All components of this product are on the Canadian DSL

TSCA : All chemical substances in this product are either listed on the
TSCA Inventory or are in compliance with a TSCA Inventory
exemption.
AICS : All ingredients listed or exempt.

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SECTION 16. OTHER INFORMATION

Further information

NFPA 704: HMIS® IV:

Flammability
HEALTH * 4
1 FLAMMABILITY
Instability

1
Health

2 0
PHYSICAL HAZARD
0

HMIS® ratings are based on a 0-4 rating

scale, with 0 representing minimal haz-
ards or risks, and 4 representing signifi-
Special hazard.
cant hazards or risks. The "*" represents
a chronic hazard, while the "/" represents
the absence of a chronic hazard.

Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV)
ACGIH BEI : ACGIH - Biological Exposure Indices (BEI)
NIOSH REL : USA. NIOSH Recommended Exposure Limits
OSHA CARC : OSHA Specifically Regulated Chemicals/Carcinogens
OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-
its for Air Contaminants
OSHA Z-3 : USA. Occupational Exposure Limits (OSHA) - Table Z-3 Min-
eral Dusts
ACGIH / TWA : 8-hour, time-weighted average
ACGIH / STEL : Short-term exposure limit
NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded
at any time during a workday
NIOSH REL / C : Ceiling value not be exceeded at any time.
OSHA CARC / PEL : Permissible exposure limit (PEL)
OSHA Z-1 / TWA : 8-hour time weighted average
OSHA Z-3 / TWA : 8-hour time weighted average

AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Haz-
ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC -
International Agency for Research on Cancer; IATA - International Air Transport Association; IBC
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals

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in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organiza-
tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime
Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health
Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-
cals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to
50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Pre-
vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth-
erwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable
Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of
Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office
of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub-
stance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti-
tative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act;
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concern-
ing the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable
Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend-
ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance
Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG -
United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent
and Very Bioaccumulative

Sources of key data used to : Internal technical data, data from raw material SDSs, OECD
compile the Material Safety eChem Portal search results and European Chemicals Agen-
Data Sheet cy, http://echa.europa.eu/

Revision Date : 10/10/2018

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and
shall not be considered a warranty or quality specification of any type. The information provided
relates only to the specific material identified at the top of this SDS and may not be valid when the
SDS material is used in combination with any other materials or in any process, unless specified
in the text. Material users should review the information and recommendations in the specific
context of their intended manner of handling, use, processing and storage, including an
assessment of the appropriateness of the SDS material in the user’s end product, if applicable.

US / Z8

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